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Catalysis Science and Technology
Journal Prestige (SJR): 1.797  Citation Impact (citeScore): 5 Number of Followers: 10  Hybrid journal (It can contain Open Access articles)ISSN (Print) 2044-4753 - ISSN (Online) 2044-4761 Published by RSC  [50 journals]
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- Coral-shaped PtRu/Ni(OH)2 electrocatalyst promotes selective hydrogenation
of benzoic acid-
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Abstract:Catal. Sci. Technol., 2023, Advance Article
DOI : 10.1039/D3CY00364G, PaperMenghui Liu, Chenhui Wang, Zifan Cao, Aiqun Kong, Yusheng Gao, Jinli Zhang, You Han, Wei Li, Yan Fu
A novel PtRu/Ni(OH)2 electrode with a unique coral-shaped architecture was developed for electrocatalytic hydrogenation of benzoic acid into cyclohexanecarboxylic acid, simultaneously showing record conversion, selectivity and faradaic efficiency.
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- Constructing 1T-MoS2/Ni3S4 heterostructure to balance water dissociation
and hydroxyl desorption for efficient hydrogen evolution-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00616F, PaperLijuan Xiang, Xilin Liu, Shaonan Xu, Kaiwen Wang, Shisheng Yuan, Nan Li
Alkaline water electrolysis is a viable technique for large-scale hydrogen production. The metallic polymorph of molybdenum disulfide (1T-MoS2) has been proven to be an efficient electro-catalyst for the hydrogen evolution...
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- Copper-Based Metal-Organic Frameworks for CO2 Reduction: Selectivity
Trends, Design Paradigms, and Perspectives-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00408B, Paper
Open Access 
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ugochukwu Nwosu, Samira Siahrostami
Can the carbon budget be balanced' Increasing greenhouse gas emissions and worsening environmental effects demand that humankind find a solution for anthropogenic climate change. As a carbon recycling strategy, electrochemical...
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- Invitation to submit to Catalysis Science & Technology special Issue
“Integrated Approaches for Methane Activation” "Functionalization of
methane using molecular metal complexes as catalysts"-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00647F, PaperTakahiko Kojima, Hiroto Fujisaki
Efficient and selective functionalization of methane is one of the most important tasks in chemistry in light of its utilization as naturally abundant feedstock toward the development of a sustainable...
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- Synthesis of High Yield, Crystalline and Thermally Stable Rare Earth (Sm,
Eu, Gd) Oxide Square Nanoplates for Near-Infrared Light Activatable
Photocatalysis-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00184A, PaperSanjeevan Rajagopal, Suresh Thangudu, Kuo Chu Hwang
Nanomaterial-mediated photocatalytic dye degradations are playing a key role in future environmental remedy applications. However, current photocatalysts are typically activated by ultraviolet (UV) and visible light, whereas near-infrared (NIR) light,...
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- Tethering chiral Rh diene complexes inside mesoporous solids: experimental
and theoretical study of substituent, pore and linker effects on
asymmetric catalysis-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00381G, PaperManuel Kirchhof, Katrin Gugeler, Ann-Katrin Beurer, Felix Richard Fischer, Derman Batman, Soeren M. Bauch, Sofia Kolin, Elliot Nicholas, Roland Schoch, Charlotte Vogler, Shravan R. Kousik, Anna Zens, Bernd Plietker, Petia Atasanova, Stefan Naumann, Matthias Bauer, Johanna Bruckner, Yvonne Traa, Johannes Kästner, Sabine Laschat
Understanding confinement effects in molecular heterogeneous catalysis is a challenging task. In a combined experimental and theoretical approach, we studied the influence of the type, polarity, pore size and shape...
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- "Methyl mercaptan production – catalysts and processes"
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00384A, MinireviewAbdelilah Bayout, Claudia Cammarano, Izabel C Medeiros-Costa, Gleb Veryasov, Vasile Hulea
Methyl mercaptan is a useful commercial molecule, with well established applications in agro-industry, petrochemistry, mining and polymer industry. Because the market of this intermediate should grow by 5.5% per year,...
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- Synthesis of highly-uniform titania overcoats on a mesoporous alumina
catalyst support by atomic layer deposition and their application in
hydroprocessing-
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Abstract:Catal. Sci. Technol., 2023, Advance Article
DOI : 10.1039/D3CY00335C, Paper Open Access 
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jacob A. Moulijn, J. Ruud van Ommen, Aristeidis Goulas, David Valdesueiro, Jana Juan-Alcañiz, Kar-Ming Au-Yeung, Leo Woning, Jaap A. Bergwerff
The feasibility of gas phase deposition using a Ti alkoxide precursor for precise surface modification of catalysts was demonstrated by modifying a mesoporous alumina support with a Ti oxide overcoat.
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- Efficient Electrochemical CO2 Conversion by Cobalt-Based Metal Organic
Frameworks Modified by Bimetallic Gold-Silver Nanostructures-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00373F, PaperMohammadali Beheshti, Mohsen Saiedi, Mahsasadat Adel Rastkhiz, Shohreh Shahrestani, Ali Zarrabi, Jing Bai, Abdolreza Simchi, Samineh Akbarmolaie
The ongoing and rapid growth of atmospheric CO2 levels causes a crucial worldwide concern. Herein, an efficient electrocatalyst has been introduced for electrochemical CO2 reduction reaction (CO2RR) to address the...
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- Biocatalytic reduction of alkenes in micro-aqueous organic solvent
catalysed by an immobilised ene reductase-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00541K, Communication Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Rocio Villa, Claudia Ferrer-Carbonell, Caroline Emilie Paul
Biocatalytic asymmetric reduction of alkenes in organic solvent is attractive for enantiopurity and product isolation, yet remains under developed. Herein we demonstrate the robustness of an ene reductase immobilised on...
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- Nanotubular Pt-loaded TiO2 catalysts with vanadium-doping to enhance
water-gas shift reaction activity-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00551H, PaperJihyeon Song, Myeong Gon Jang, Kyung-Jong Noh, Yunkyung Kim, Jeong Woo Han
We increased the reactivity of Pt-loaded TiO2 catalysts for the water-gas shift reaction (WGSR) by inducing the TiO2 support to form nanotubes, and by doping it with vanadium (V). To...
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- Graphdiyne(CnH2n-2) coupled with ZnCo-MOF double S-scheme heterojunctions
formed efficient electron transport layer characterized with in suit XPS-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00525A, PaperLinqing Zhang, Xuanpu Wang, Youji Li, Zhiliang Jin
Graphdiyne (GDY) is a new material which is formed by the combination of sp and sp2 heterojunction with a 1,3 diacetylene bond attached to a phencyclidine ring. It has the...
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- Multi-functionality of rhodium-loaded MOR zeolite: production of H2via the
water gas shift reaction and its use in the formation of NH3-
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Abstract:Catal. Sci. Technol., 2023, 13,2994-3000
DOI : 10.1039/D3CY00043E, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Shunsaku Yasumura, Ken Nagai, Yucheng Qian, Takashi Toyao, Zen Maeno, Ken-ichi Shimizu
Rh-loaded mordenite (RhMOR) zeolite was investigated as a catalyst that can use CO + H2O as a H2 source for NO reduction.
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- Sustainable synthesis of azobenzenes, quinolines and quinoxalines via
oxidative dehydrogenative couplings catalysed by reusable transition metal
oxide–Bi(III) cooperative catalysts-
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Abstract:Catal. Sci. Technol., 2023, 13,3069-3083
DOI : 10.1039/D3CY00327B, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Marianna Kocsis, Kornélia Baán, Sándor B. Ötvös, Ákos Kukovecz, Zoltán Kónya, Pál Sipos, István Pálinkó, Gábor Varga
Heterogeneous catalytic oxidative dehydrogenative processes for N-heterocycles are presented, which enable waste-minimized (additive-, oxidant-, base-free), efficient cyclisations/couplings via transition metal oxide–Bi(III) cooperative catalysis.
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- Water-assisted sonochemically-induced demethylenation of benzyl alcohol to
phenol over a structurally stable cupric oxide catalyst-
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Abstract:Catal. Sci. Technol., 2023, 13,2982-2993
DOI : 10.1039/D3CY00100H, PaperTeseer Bahry, Shang Jiang, Umesh Jonnalagadda, Wen Liu, Benoit Teychene, Francois Jerome, Samir H. Mushrif, Prince N. Amaniampong
Novel catalytic chemistry of demethylenation of benzyl alcohol to phenol is presented here using the synergy between an earth-abundant transition metal oxide (CuO) catalyst and high frequency ultrasound.
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- The preparation of silica supported, dilute limit PdAu alloys via
simultaneous strong electrostatic adsorption-
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Abstract:Catal. Sci. Technol., 2023, 13,3020-3034
DOI : 10.1039/D2CY01662A, PaperAnhua Dong, Abolfazl Shakouri, Starvros Karakalos, Doug Blom, Christopher T. Williams, John R. Regalbuto
Supported, dilute Pd-in-Au alloyed nanoparticles might possess enhanced reactivity due to the altered structural and electronic properties of the Pd atoms isolated in an Au nanoparticle matrix.
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- Lithium catalysed sequence selective ring opening terpolymerisation: a
mechanistic study-
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Abstract:Catal. Sci. Technol., 2023, 13,2937-2945
DOI : 10.1039/D3CY00301A, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Peter Deglmann, Sara Machleit, Cesare Gallizioli, Susanne M. Rupf, Alex J. Plajer
A combined experimental and computational study is reported revealing how the combination of two copolymerisations results in a sequence selective terpolymer.
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- Schottky junction with Bi/Bi2O3 core–shell nanoparticle modified g-C3N4
for boosting photocatalytic H2O2 evolution from pure water-
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Abstract:Catal. Sci. Technol., 2023, 13,3094-3105
DOI : 10.1039/D3CY00235G, PaperXinyue Yan, Guiyang Yu, Chuanwang Xing, Yujia Hu, Heyuan Liu, Xiyou Li
The Schottky junction of the coupled metallic Bi/Bi2O3 core–shell structure and g-C3N4 significantly improves the photocatalytic H2O2 evolution efficiency in pure water.
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- Ternary PdNiO nanocrystals-ornamented porous CeO2/onion-like carbon for
electrooxidation of carbon monoxide: unveiling the effect of supports and
electrolytes-
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Abstract:Catal. Sci. Technol., 2023, 13,3035-3046
DOI : 10.1039/D3CY00253E, PaperAdewale K. Ipadeola, Aderemi B. Haruna, Aboubakr M. Abdullah, Rashid S. Al-Hajri, Roman Viter, Kenneth I. Ozoemena, Kamel Eid
Porous ternary Pd-based catalysts at low Pd mass exhibit inimitable surface area, accessible active sites, and tunable electronic structure advantageously utilized for high CO oxidation (COoxid) activity and stability in different electrolyte media.
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- Full-crystalline monolithic EU-1 zeolite: sustainable synthesis and its
applications in the hydroisomerization of ethylbenzene with meta-xylene-
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Abstract:Catal. Sci. Technol., 2023, 13,3060-3068
DOI : 10.1039/D3CY00140G, PaperGuanghua Liang, Jianyi Chen, Tao Dou, Zhijie Wu, Xiaofeng Li, Yuanshuai Liu
A novel strategy for the effective production of monolithic EU-1 zeolite as an active component of catalyst in C8 hydroisomerization.
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- Tunable phosphorization degree of CoxPy@N,P-doped carbon as a
highly-active bifunctional electrocatalyst for rechargeable zinc–air
batteries-
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Abstract:Catal. Sci. Technol., 2023, 13,3084-3093
DOI : 10.1039/D3CY00287J, PaperYang Liu, Chen Li, Min Yuan, Xinghao Zhang, Haikuo Lan, Yuting Chen, Minge Tian, Kang Liu, Lei Wang
CoxPy@NPPC was developed by precise control the degree of phosphorylation in one-step carbonization of CoCo-PBA and MPSA. The prepared nanocatalyst can be used as a highly-active bifunctional electrocatalyst for rechargeable zinc–air batteries.
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- Recent progress of Cu-based electrocatalysts for upgrading biomass-derived
furanic compounds-
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Abstract:Catal. Sci. Technol., 2023, 13,2899-2921
DOI : 10.1039/D3CY00041A, MinireviewJingwen Tan, Mei Jiang, Kun Yu, Yuyang Song, Wenbiao Zhang, Qingsheng Gao
Cu-based electrocatalysts for the valorization of furans are comprehensively reviewed, which elucidates the working mechanism and provides guidance for catalyst design in the electrochemical refining of biomass feedstock.
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- A heterogeneous Pd complex catalyst for allylation with allylic alcohols
enhanced by an aluminum-doped mesoporous silica support-
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Abstract:Catal. Sci. Technol., 2023, 13,3047-3059
DOI : 10.1039/D2CY01768G, PaperSiming Ding, Yuichi Manaka, Masayuki Nambo, Wang-Jae Chun, Ikuyoshi Tomita, Ken Motokura
Concerted catalysis between an immobilized Pd complex and Lewis acidic Al sites in a support framework for allylation reaction.
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- Recent advances on g-C3N4-based Z-scheme photocatalysts for organic
pollutant removal-
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Abstract:Catal. Sci. Technol., 2023, 13,2877-2898
DOI : 10.1039/D3CY00242J, MinireviewChunxue Li, Hao Lu, Guixiang Ding, Qing Li, Guangfu Liao
The recent advances of g-C3N4-based Z-scheme photocatalysts for organic pollutant removal was comprehensively reviewed.
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- Metal–organic framework-loaded carbon-encapsulated nano-catalyst as a
pH-universal oxygen reduction reaction electrocatalyst for various fuel
cell devices-
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Abstract:Catal. Sci. Technol., 2023, 13,3009-3019
DOI : 10.1039/D3CY00189J, PaperXintao Zhou, Mingyang Wu, Kai Chen, Suqin Ci, Zhenhai Wen
In pH-universal electrolyte environments, FeN0.056 supported on a B, N co-doped carbon matrix electrocatalyst demonstrated greater ORR performance and was applied for various types of fuel cells.
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- Post-plasma catalysis: charge effect on product selectivity in conversion
of methane and nitrogen plasma to ethylene and ammonia-
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Abstract:Catal. Sci. Technol., 2023, 13,2966-2981
DOI : 10.1039/D2CY02077G, PaperSarojini Tiwari, Saleh Ahmat Ibrahim, Brandon Robinson, Sean Brown, Qiang Wang, Fanglin Che, Jianli Hu
A combined experimental and theoretical study of the post-microwave plasma interaction with catalytic surfaces to enhance the ethylene and ammonia production from methane and nitrogen conversion.
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- Structure sensitivity of alumina- and zeolite-supported platinum ammonia
slip catalysts-
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Abstract:Catal. Sci. Technol., 2023, 13,2946-2965
DOI : 10.1039/D2CY02095E, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Vasyl Marchuk, Xiaohui Huang, Jan-Dierk Grunwaldt, Dmitry E. Doronkin
NH3 is effectively oxidised on Pt via O-activated dissociation when a minimum particle size to contain a favourable surface atom configuration is reached. Different mechanisms were found to govern NH3 oxidation on nanoparticles and single sites.
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- Catalytic conversion to ammonia through solid-state nitrate as a proposal
for the emerging usage of nitrogen oxides-
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Abstract:Catal. Sci. Technol., 2023, 13,2927-2936
DOI : 10.1039/D3CY00169E, PaperAtsuko Tomita, Ryutaro Wakabayashi, Tatsuo Kimura
A gas-switching catalytic reaction process for low-energy nitrogen resource circulation by selective NH3 synthesis starting from NOx storage.
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- Homogeneous Interfacial Electron Transfer Promotes Photoinduced Hole
Extraction for Phenol Mineralization-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00415E, CommunicationYao Fang, Xuhui Wei, Haifeng Liu, Shugong Gao, Kun Jia, Junwei Wang, Jiazang Chen
The inherent correlation of photoinduced hole extraction to Fermi level can promote contaminant mineralization by facilitating the transfer of electrons from semiconductor to the solution. We here develop a fixed...
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- Enhancing the performance of Cu catalysts for the Reverse Water-Gas Shift
Reaction using N-doped CNT-ZnO composite as support-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00308F, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Ana Rita Querido, Liliana P. L. Gonçalves, Yury V. Kolen'ko, Manuel Fernando Pereira, Salomé Soares
The Reverse Water-Gas Shift reaction (RWGS) allows the conversion of CO2 to syngas, a mixture of H2 and CO, used to manufacture most chemicals and synthetic fuels. Consequently, it is...
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- Hydrothermal treatment: an effective method to improve the catalytic
activity of the Pt/ZSM-5 catalyst for complete benzene oxidation-
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Abstract:Catal. Sci. Technol., 2023, Advance Article
DOI : 10.1039/D3CY00320E, CommunicationYunchong Wang, Kaixuan Fu, Haolong Huang, Cangpeng Shan, Yanfei Zheng, Rui Han, Qingling Liu
Hydrothermal treatment surprisingly enhanced the catalytic activity of Pt/ZSM-5 in benzene oxidation and the treated catalyst exhibited outstanding stability.
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- Ultra-stable Pd ions at Al T1/T2 sites on a dealuminated Pd/beta passive
NOx adsorber-
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Abstract:Catal. Sci. Technol., 2023, Advance Article
DOI : 10.1039/D3CY00430A, PaperYi Zhu, Jun Wang, Chen Wang, Jianqiang Wang, Gurong Shen, Meiqing Shen
The oxalic-acid modified Pd/beta shows a more stable performance of NOx storage due to its more stable Pd ions and more stable Al T1/T2 species when exposed to reducing agents or treated under hydrothermal conditions.
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- Pentacoordinated Al3+ stabilized polyoxometalates for the efficient
catalytic valorization of biomass-derived feedstocks-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00142C, PaperLihua Wang, Shuangxiu Ma, Chunhong Chen, Bing Lu, Zhe Wang, Yong Wang, Shanjun Mao
The high-loading, well distribution and stable heterogenization of polyoxometalates (POMs) salts with supports such as oxides is rather challenging since the structural integrity of POMs is easily destroyed if strong...
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- Enhanced Thermal assisted Photocatalysis Reduction of Carbon dioxide over
Fe2-xGaxO3 solid Solution-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00417A, PaperLingtong Lin, Danning Xing, Caiyun Zhang, Yuanyuan Liu, Zeyan Wang, Peng Wang, Zhaoke Zheng, Hefeng Cheng, Ying Dai, Baibiao Huang
α-Fe2O3 is considered as a promising photocatalytic material due to its cheap, easy availability and excellent visible light absorption. However, the photocatalytic efficiency of it is still limited by the...
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- Aromatic aldehydes as tuneable and ppm level potent promoters for zeolite
catalysed methanol dehydration to DME-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00105A, PaperGlenn John Sunley, Zhiqiang Yang, Benjamin J Dennis-Smither, Corneliu Buda, Fiona Jackson, Gregory A Price, Neil Sainty, Xingzhi Tan, Zhuoran Xu, Amie Easey
Dimethyl ether (DME) is a valuable chemical intermediate and renewable fuel that can be made, via methanol, from many sources of carbon, including carbon dioxide and biomass. Benzaldehyde and its...
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- Pd-catalysed Hydrodehalogenation of Aryl Chlorides: A Mild Method for
Deuteration and Detoxification-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00432E, PaperAngela Burhenn, Roberta Bravo, Viktoria H. Gessner
(Poly)halogenated arenes are important electrophiles in organic synthesis but often also toxic and harmful to human health and the environment. Hydrodehalogenation represents a powerful method for detoxification, but usually requires...
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- Electrocatalytic Hydrogen Evolution by Robust Square Planar Nickel
Complexes in a S2P2 Coordination Environment-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D2CY02158G, PaperLuo Chen, Tao Li, Bin Xie, Chuan Lai, Run-Wu Ji, Jia-Yu He, Jia-Xi Cao, Meng-Nan Liu, Wei Li, Dongliang Zhang
Stimulated by the structural feature of the [NiFe]-hydrogenases active sites, five new heteroleptic 1,2-bis(p-substitutedphenyl)ethylene-1,2-dithiolate nickel complexes containing N-(p-methoxyphenyl)-bis(diphenylphosphine)-amine ligand, [p-CH3OC6H4N(PPh2)2]Ni[S2C2(C6H4R-p)2)] (R = CH3O (1), CH3 (2), H (3), Br (4),...
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- A promoted PtFe/SiO2 catalyst with low Pt concentration for propane
dehydrogenation-
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Abstract:Catal. Sci. Technol., 2023, Advance Article
DOI : 10.1039/D3CY00060E, PaperLei Luo, Zekun Zeng, Tao Zhou, Jun Luo, Xiaoheng Chen, Xu Li, Han Yan, Jie Zeng
Small PtFe clusters with electron-rich Pt sites show great sintering-resistances and high stability for propane dehydrogenation. The propylene formation rate is 39.52 mol propylene per gram of Pt per hour with 99.9% selectivity for 60 h at a WHSV of 48 h−1.
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- Revealing the nature of crystal size on high-temperature hydrothermal
stability of Cu/SSZ-13 NH3-SCR catalysts-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00162H, PaperHuabo Liu, Meiqing Shen, Chen Wang, Jun Wang, Jianqiang Wang, Gurong Shen
To reveal how crystal size improve the long-term stability of Cu/SSZ-13 zeolites under high-temperature hydrothermal aging, a series of different crystal size of Na/SSZ-13 supports from micron to nanometer level...
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- Manganese Catalysed Dehydrogenative Synthesis of Polyureas from
Diformamide and Diamines-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00284E, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Angus McLuskie, Claire N Brodie, Michele Tricarico, Chang Gao, Gavin Peters, Aaron Naden, Logan Mackay, Jin-Chong Tan, Amit Kumar
We report here the synthesis of polyureas from the dehydrogenative coupling of diamines and diformamides. The reaction is catalysed by a manganese pincer complex and releases H2 gas as the...
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- Facile implantation of imidazole ring into graphitic carbon nitride for
efficient photocatalytic hydrogen production-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00383C, CommunicationSiyuan He, Guanchao Wang, Zhongkui Zhao
Herein, the two carbon nitrides implanted with imidazole-rings were prepared by heating a mixture containing urea and imidazolium chloride, which were denoted as PI-CN and MI-CN by using poly-(imidazolium-methylene) chloride...
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- Promotion effects of different method in COx-free hydrogen production from
ammonia decomposition-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00042G, PaperDaotong Liang, Chao Feng, Li Xu, Da Wang, Yuanshuai Liu, Xuebing Li, Zhong Wang
Ammonia can be decomposed to produce exclusively hydrogen and nitrogen, so that it could function as a means for hydrogen storage. In situ hydrogen production from ammonia decomposition can effectively...
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- Isolated PdO sites on SiO2-supported NiO nanoparticles as active sites for
allylic alcohol selective oxidation.-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00198A, Communication Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Aleksandra Ziarko, Thomas Slater, Mark Andrew Isaacs, Lee Durndell, Christopher Parlett
Catalytic allylic alcohol oxidation to aldehydes is an industrial process that necessitates chemoselectivity. Surface PdO (on Pd) enables this transformation but does not represent optimal metal utilisation. Here we report...
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- MOF-derived Fe2O3/MoSe2 composites for promoted electrocatalytic nitrogen
fixation-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00486D, PaperLiming Huang, Leiming Tao, Kui Pang, Shuying He, Guanhua Zhu, Linhai Duan, Chenglin Wen, Changlin Yu, Hongbing Ji
Due to the low activity and poor selectivity of current artificial nitrogen fixation catalysts, there is an urgent need to develop efficient and environmentally friendly Electrochemical ammonia synthesis (EAS) electrocatalysts....
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- Revealing the Gas Sensitive Stability of Formate Species during CO2
Hydrogenation-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00419H, CommunicationDidi Li, Shiqing Jin, Zhen Wang, Zhaocong Jiang, Feng Xiong, Jianqiang Wang, Minghui Zhu
A series of in situ time-resolved diffuse reflectance Fourier transform spectroscopy (DRIFTS) - mass spectrometry experiments were performed on the supported Cu/CeO2 catalyst. It is revealed that formates are formed...
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- Fabrication of high-performance CeO2–MnOx/TiO2/Ti monolithic catalysts
for low-temperature and stable CO oxidation-
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Abstract:Catal. Sci. Technol., 2023, Advance Article
DOI : 10.1039/D3CY00233K, PaperJunchao Wang, Xinyue Tang, Jing Li, Shizhi Dong, Xinglai Zhang, Baodan Liu
The CeO2–MnOx/TiO2/Ti catalysts synthesized in this work show excellent low temperature CO oxidation performance and long-term stability.
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- Spatial Imaging of Catalyst Poisoning with SO2 on Pt/C PEFC
Electrocatalyst by Operando Pt LIII-edge XAFS-CT Imaging-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00241A, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hirosuke Matsui, Koshin Sato, Naoko Isobe, Gabor Samjeské, Tomoya Uruga, Mizuki Tada
Sulfur dioxide (SO2), which is one of air contaminants, causes drastic power loss of Pt electrocatalysts in polymer electrolyte fuel cells (PEFCs). Herein, we report the spatial imaging of catalyst...
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- Solvent-modulated binding selectivity of reaction substrates to
onium-based σ-hole donors-
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Abstract:Catal. Sci. Technol., 2023, Advance Article
DOI : 10.1039/D3CY00071K, PaperAlexandra A. Sysoeva, Alexander S. Novikov, Mikhail V. Il'in, Dmitrii S. Bolotin
Solvation effects might play the dominant role in the catalysis providing an increase or suppression of the activity of the organocatalysts.
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- Insights into Coverage-affected Selective Catalytic Oxidation of Ethylene
on Ag(111) from Comprehensive Microkinetical Analyses-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D2CY01477G, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zhuozheng Wang, Wenbo Xie, Yarong Xu, Menglei Jia, Jiayan Xu, Peijun Hu
Ethylene epoxidation is one of the most critical industrial reactions. Although there have been many studies on the reaction, the details of the reaction kinetics remain elusive. In this work,...
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- Catalytic oxidation of NO to NO2 for industrial nitric acid production
using Ag-promoted MnO2/ZrO2 catalysts-
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Abstract:Catal. Sci. Technol., 2023, 13,2783-2793
DOI : 10.1039/D2CY02178A, PaperJithin Gopakumar, Sunniva Vold, Bjørn Christian Enger, David Waller, Per Erik Vullum, Magnus Rønning
Low-temperature nitric oxide oxidation using silver promoted manganese catalyst can reduce energy footprint of industrial nitric acid production.
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- The effect of the C5-substituent on regioselectivity in the
Rh(I)-catalyzed intermolecular transannulation of 1,2,3-thiadiazoles with
phenylacetylene-
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Abstract:Catal. Sci. Technol., 2023, 13,2772-2782
DOI : 10.1039/D3CY00290J, PaperMarina A. Tokareva, Indrek Pernik, Barbara A. Messerle, Tatiana V. Glukhareva, Sinead T. Keaveney
The nature of the C5-substituent on the 1,2,3-thiadiazole ring has a remarkable effect on regioselectivity of the intermolecular transannulation of thiadiazole substrates with phenylacetylene leading to different thiophene regioisomers.
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- Rhodium-catalyzed double hydroboration of pyridine: the origin of the
chemo- and regioselectivities-
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Abstract:Catal. Sci. Technol., 2023, 13,2735-2747
DOI : 10.1039/D3CY00347G, PaperHyoju Choi, Ruibin Wang, Suyeon Kim, Dongwook Kim, Mu-Hyun Baik, Sehoon Park
Rhodium catalyzes double hydroboration of pyridine via an unique mechanism involving a Rh-1,2-dihydropyridine adduct to give a mixture of unprecedented tetrahydropyridines bearing a sp3 C–B bond in a specific position.
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- Evaluating metal oxide support effects on the RWGS activity of Mo2C
catalysts-
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Abstract:Catal. Sci. Technol., 2023, 13,2685-2695
DOI : 10.1039/D3CY00026E, PaperCameron F. Holder, James R. Morse, Patrick M. Barboun, Andrew R. Shabaev, Jeffrey W. Baldwin, Heather D. Willauer
Mo2C supported on nonreducible metal oxides shows increased activity for the reverse water gas shift reaction compared to reducible oxides.
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- CoP decorated 2D/2D red phosphorus/B doped g-C3N4 type II heterojunction
for boosted pure water splitting activity via the two-electron pathway-
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Abstract:Catal. Sci. Technol., 2023, 13,2714-2727
DOI : 10.1039/D3CY00054K, PaperZhiqi Guo, Yao Tian, Guangjin Dou, Ye Wang, Jiaping He, Hao Song
CoP decorated 2D/2D red phosphorus/B doped g-C3N4 heterojunction enabled photocatalytic pure water splitting to produce H2 with a two-electron process.
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- Influence of reduction temperature on Pt–ZrO2 interfaces for the
gas-phase hydrogenation of acetone to isopropanol-
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Abstract:Catal. Sci. Technol., 2023, 13,2675-2684
DOI : 10.1039/D2CY02139K, PaperKun Liu, Tingting Zhang, Xiaodong Liu, Tingyu Wang, Yan Su, Hong Wang, Liping Sun, Xiaoqun Cao, Yushui Bi, Kaiqi Wang, Li Zhang
Pt/ZrO2 reduced at 200 °C offers higher Ov and Pt0 contents, thus leading to excellent acetone hydrogenation activity.
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- Sustainable routes to alkenes: applications of homogeneous catalysis to
the dehydration of alcohols to alkenes-
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Abstract:Catal. Sci. Technol., 2023, 13,2638-2647
DOI : 10.1039/D2CY01690G, Minireview Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Daniel J. Ward, Daniel J. Saccomando, Gary Walker, Stephen M. Mansell
Homogeneous catalysis applied to alcohol dehydration.
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- Understanding W/H-ZSM-5 catalysts for the dehydroaromatization of methane
-
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Abstract:Catal. Sci. Technol., 2023, 13,2748-2762
DOI : 10.1039/D3CY00103B, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Mustafa Çağlayan, Abdallah Nassereddine, Stefan-Adrian F. Nastase, Antonio Aguilar-Tapia, Alla Dikhtiarenko, Sang-Ho Chung, Genrikh Shterk, Tuiana Shoinkhorova, Jean-Louis Hazemann, Javier Ruiz-Martinez, Luigi Cavallo, Samy Ould-Chikh, Jorge Gascon
Tungsten is the most interesting and promising metal to replace molybdenum in methane dehydroaromatization (MDA) catalysis.
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- Impacts of framework Al distribution and acidic properties of Cu-exchanged
CHA-type zeolite on catalytic conversion of methane into methanol followed
by lower hydrocarbons-
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Abstract:Catal. Sci. Technol., 2023, 13,2648-2651
DOI : 10.1039/D3CY00127J, CommunicationKengo Nakamura, Peipei Xiao, Ryota Osuga, Yong Wang, Shuhei Yasuda, Takeshi Matsumoto, Junko N. Kondo, Mizuho Yabushita, Atsushi Muramatsu, Hermann Gies, Toshiyuki Yokoi
This work highlighted the significance of the Al distribution in the CHA-type zeolite in the formation of active Cu species for the oxidative conversion of CH4; isolated Al atoms in the zeolite framework are found to be advantageous for producing CH3OH.
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- Significantly boosted activity for styrene oxidation through simultaneous
regulation of porosity and copper sites in microporous metal–organic
framework Cu-BTC-
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Abstract:Catal. Sci. Technol., 2023, 13,2728-2734
DOI : 10.1039/D2CY01909D, PaperPenghu Guo, Shuhua Zhang, Huicheng Cheng, Xingye Zeng, Hanlu Wang, Roland A. Fischer, Martin Muhler
Herein, a series of novel HP-DEMOFs were prepared and employed as catalysts for the heterogeneous styrene oxidation reaction. They exhibited much higher conversion than that of the microporous Cu-BTC structure under the same reaction conditions.
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- Supported transition metal (Mo, W) carbide and nitride catalysts for
lignin hydrodeoxygenation: interplay of supports, structure, and catalysis
-
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Abstract:Catal. Sci. Technol., 2023, 13,2618-2637
DOI : 10.1039/D3CY00097D, MinireviewNa Ji, Poknam Ri, Xinyong Diao, Yue Rong, Changsok Kim
In-depth understanding of the structure–performance relationship for transition metal (Mo, W) carbide- and nitride-catalyzed lignin hydrodeoxygenation was summarized.
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- Synthetic strategies for fluorosulfonylated compounds: application to
click chemistry reactions-
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Abstract:Catal. Sci. Technol., 2023, 13,2597-2617
DOI : 10.1039/D2CY01998A, MinireviewSebastián Barata-Vallejo, Damian E. Yerien, Al Postigo
Fluorosulfonylation of (hetero)aromatic and aliphatic compounds with emphasis on the use of fluorosulfonylating hubs is discussed. Examples on click chemistry (SuFEx) reactions and diversity oriented clicking (DOC) processes are provided.
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- Insights into the ruthenium-catalysed selective reduction of cardanol
-
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Abstract:Catal. Sci. Technol., 2023, 13,2662-2674
DOI : 10.1039/D3CY00135K, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Shahbaz Ahmad, Ellis Crawford, Muhammad Bilal, Johannes G. de Vries, Michael Bühl
The detailed mechanism for ruthenium-catalysed selective reduction of cardanol derivatives by transfer hydrogenation has been fully characterised at the B3PW91-D3/ECP2/PCM//B3PW91/ECP1 level of density functional theory.
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- Expedient tandem dehydrogenative alkylation and cyclization reactions
under Mn(I)-catalysis-
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Abstract:Catal. Sci. Technol., 2023, 13,2763-2771
DOI : 10.1039/D3CY00009E, PaperReshma Babu, Subarna S. Padhy, Ganesan Sivakumar, Ekambaram Balaraman
Sustainable chemical production requires fundamentally new types of catalysts and catalytic technologies.
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- FEFOS: A method to derive oxide formation energies from oxidation states
-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00107E, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Michael John Craig, Felix Kleuker, Michal Bajdich, Max Garcia-Melchor
Herein we report a method to extract formation energies from oxidation states, which we call FEFOS. This new scheme predicts the formation energies of binary oxides through analysing unary oxide...
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- ZIF-8@CoFe2O4 as a highly efficient bifunctional electrocatalyst for
methanol oxidation and oxygen evolution reactions-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00378G, PaperT. V. M. Sreekanth, Prasad Kumcham, Jihyung Yoo, Jonghoon Kim, Kisoo Yoo
Developing low-cost, highly active, and stable electrocatalysts are essential for a range of renewable energy storage and conversion systems. Zeolite imidazole frameworks (ZIFs) or ZIF-based composites have garnered a lot...
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- Water pretreatment promoting the removal of indoor formaldehyde over
nano-CeO2 at ambient temperature-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00416C, PaperMeng Zhang, Jiaqi Chen, Zhihua Xu, Yingjie Ding, Zhaoxiong Yan, Lin Yue, Ling Shi
An efficient and noble-metal-free catalyst is of practicality for ambient temperature removal of indoor formaldehyde (HCHO) which severely haunts human’s health. In this work, a commonly used nano-CeO2 material is...
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- Effect of the Preparation Method on the Catalytic Properties of
Copper-containing Zeolite Y Applied for NH3-SCR-DeNOx-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00269A, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Rujito Sesariojiwandono Suharbiansah, Muhammad Fernandi Lukman, Chiara Nannuzzi, Anna Wach, Kinga Góra-Marek, Ana Palcic, Michael Liebau, Andreas Poppl, Gloria Berlier, Silvia Bordiga, Roger Gläser, Magdalena Jablonska
Two series of zeolite Y were prepared with varying particle size (estimated 100 or 400 nm) by applying different synthesis gel composition ratios as well as different ageing and hydrothermal...
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- Hydrogenolysis of 5-hydroxymethylfurfural by in-situ produced hydrogen
from water on an iron catalyst-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00027C, PaperXin Li, Peng Rui, Tongqi Ye, Xin Yao, Rulong Zhou, Dongdong Li, Sheng Wang, James Carter, Graham Hutchings
The hydrogenolysis of 5-hydroxymethylfurfural in a flow reactor was investigated over iron catalysts in the presence of water. The reaction proceeds in the presence of hydrogen or an inert atmosphere....
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- Environmental applications of single-atom catalysts based on graphdiyne
-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00240C, MinireviewMengdie Zhao, Liyun Jiang, Qi Yu
Single-atom catalysts (SACs) have attracted significant attention because of their high atomic efficiency and unique catalytic performance for various catalytic reactions. As a two-dimensional (2D) layered structure, Graphdiyne (GDY) is...
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- Stereo-controlled Cyclopropanation Catalysis within the confined Pores of
Porphyrin MOFs-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D2CY02144G, PaperKarina Hemmer, Raphael Bühler, Martin Elsner, Mirza Cokoja, Roland A. Fischer
In analogy to the confined reaction environment in enzymes where different functionalities are responsible for substrate coordination, specific substrate-catalyst interactions within the pores of metal-organic frameworks (MOFs) can impact the...
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- Surface Silanol Sites in Mesoporous MFI Zeolites for Catalytic Beckmann
Rearrangement-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00543G, PaperHanyoung Park, Jisuk Bang, Hongjun Park, Jaeheon Kim, Jeong-Chul Kim, Jeong Y. Park, Ryong Ryoo
Silanol groups were generated in siliceous MFI zeolite nanosheets, via alkali-free synthesis routes, for catalytic application for gas-phase Beckmann rearrangement. The catalytic conversion by the zeolite nanosheets was investigated at...
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- Catalysts for selective conversion of nitric oxide to ammonia (NTA) with
propene in the presence of large excess oxygen and water vapor-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00119A, PaperBungo Suzumura, Kiyokazu Tanaka, Kasumi Kitazume, Shougo Hioki, Ayaka Kubo, Masakazu Iwamoto
Catalysts for the NO to NH3 reaction in the presence of 10% O2 and 10% H2O were investigated on a TiO2(rutile) support. The activity sequence of the various metals supported...
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- Visible light responsive radial TiO2 mesocrystal photocatalysts for
oxidation of organics-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00195D, MinireviewHiroaki Tada, Atsunobu Akita, Shin-ichi Naya
Radial TiO2 mesocrystals (rad-TiO2 MCs), the so-called “sea urchin-like microspheres”, usually consisting of rutile TiO2 nanorods with a length of several microns and a diameter of several tens of nanometers...
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- Rational identification of catalytically promiscuous nitrilase by
predicting a unique catalytic triad motif feature through an in-silico
strategy-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00259D, PaperKe Zhang, Tingze Pan, Yangyang Sun, Zhuzhu Tang, Yuhong Ren, Hualei Wang, Dongzhi Wei
Catalytically promiscuous nitrilase (CP-NLase) with unnatural hydration activity is regarded as a promising alternative for benzylic amide production compared to the classic nitrile hydratase pathway. However, most nitrilases are high-fidelity...
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- Electrochemical CO2 Reduction Towards Formic Acid and Methanol on
Transition Metal Oxide Surfaces as a Function of CO Coverage-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D2CY02175G, PaperNarges Atrak, Ebrahim Tayyebi, Egill Skulason
Density functional theory is used to study the effect of varying CO coverage on selectivity and activity of CO2 reduction reaction (CO2RR) towards methanol and formic acid formation on transition...
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- Bifunctional catalysts for the conversion of CO2 into value-added products
- Proximity as a design parameter for new catalysts-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00194F, Minireview Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Maik Alexander Rudolph, Philipp Isbrücker, Reinhard Schomäcker
More than 1,000 CO2 chemistry publications within the last five years have featured the application of bifunctional catalysts. The majority of these articles investigate hydrogenation reactions of CO2 for producing...
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- Spatial analysis of CO2 hydrogenation to higher hydrocarbons over
alkali-metal promoted iron(II)oxalate-derived catalysts-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00143A, PaperAndrey S. Skrypnik, Henrik Lund, Qingxin Yang, Evgenii V. Kondratenko
A simple incipient wetness impregnation of ferrous oxalate dihydrate with an aqueous solution of an alkali metal carbonate without any calcination stage results in active and selective catalysts for CO2...
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- Insight into the electronic modulation of bimetallic Pt-Sn cluster for
selective hydrogenation of 1,3-butadiene-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00016H, PaperNengfeng Gong, Huizi He, Hongliu Wan, Huaming Hou, Ziyu Zhou, Yibo Yang, Gaolei Qin, Anping Yin, Yuhang Cai, Xiaodong Sun, Yongwang Li, Zhi Cao
Elucidation of the intrinsic working principle of the electronic property of Pt catalysts within selective hydrogenation of 1,3-butadiene in the presence of CO remains a substantial challenge. We solve this...
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- Unravelling the mechanism of CO2 activation over low-loaded Cu/CeO2(111)
catalysts using operando and transient spectroscopies-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00494E, Communication Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Marc Ziemba, Christian Hess
Using operando Raman and UV-Vis spectroscopy as well as transient IR spectroscopy, low-loaded Cu/CeO2(111) catalysts were investigated with respect to their redox behavior and the importance of adsorbates for the...
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- Aqueous-phase Fischer-Tropsch reaction for production of oxygenates from
syngas over colloidal ruthenium nanoparticles-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00273J, CommunicationJunli Zhang, Fei Yu, Yunlei An, Tiejun Lin, Liangshu Zhong
Low temperature aqueous Fischer-Tropsch reaction for production of value-added oxygenates with low selectivity to CH4 and CO2 was uncovered over colloidal Ru nanoparticles with synergism effect of Ruδ+-Ru0 as dual...
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- Newly Synthesized Imidazolium Precursors for CO2 Utilization and
Sequestration: Aprotic versus Protic Salts-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00270E, PaperAbdussalam K. Qaroush, Alaa F. Eftaiha, Feda'a Al-Qaisi, Khaleel I. Assaf, Suhad B. Hammad, Malak H. Anati, Enas S. Radwan, Firas Awwadi
Herein, a first-time, one pot synthesis of 1,3-bis(3-(1,3-dioxoisoindolin-2-yl)propyl)-1H-imidazol-3-ium bromide (7) which can be considered a vital precursor for the synthesis of highly pure, facile synthesis of task specific ionic liquids...
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- Palladium Single-Atom Catalyst Supported on Ceria for α-Alkylation of
Ketones with Primary Alcohols-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00374D, PaperDongyuan Yang, Hongli Wang, Ce Liu, Chun-Ran Chang
Herein, a highly active and dispersed palladium single-atom supported on cubic CeO2 was prepared by the simply impregnation, which exhibited excellent catalytic performance in α-alkylation of ketones with primary alcohols...
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- Photocatalytic activity towards antibiotic degradation and H2 evolution by
development of a Z-scheme heterojunction constructed from 1T/2H-MoS2
nanoflowers embellished on BCN nanosheets-
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Abstract:Catal. Sci. Technol., 2023, Advance Article
DOI : 10.1039/D3CY00266G, PaperSarmistha Das, Lopamudra Acharya, Lijarani Biswal, Bhagyashree Priyadarshini Mishra, Kulamani Parida
The current work includes the study of metallic 1T phase mediated 1T/2H-MoS2@BCN Z-scheme heterojunction towards augmented photocatalytic H2 evolution and TCH degradation.
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- Efficient biosynthesis of 5-aminolevulinic acid from glutamate via
whole-cell biocatalyst in immobilized engineered Escherichia coli-
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Abstract:Catal. Sci. Technol., 2023, Advance Article
DOI : 10.1039/D2CY02172B, PaperYing Luo, Liang Liu, Jinshui Yang, Anping Su, Qijun Yu, Entao Wang, Hongli Yuan
Development of a whole-cell catalysis system for an efficient conversion of glutamate to 5-aminolevulinic acid.
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- Understanding the structure of isolated iridium sites anchored on a
covalent triazine framework-
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Abstract:Catal. Sci. Technol., 2023, Advance Article
DOI : 10.1039/D3CY00232B, CommunicationNina M. Sackers, Andree Iemhoff, Philippe Sautet, Regina Palkovits
As a showcase for experimentally accessible single-site catalysts, well-defined and characterized isolated Ir sites anchored on a covalent triazine framework (CTF) were investigated with computational methods.
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- Insight into the mechanism of carboxylic acids hydrogenation into alcohols
at MnO/Cu (111) interface: A combined DFT and kinetic Study-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00247K, PaperJingbo Du, Yifei Chen, Lingtao Wang, Minhua Zhang
Hydrodeoxygenation (HDO) process of carboxylic acids (CAs) is a promising way to utilize biomass resources and refine high-grade fuels. The Mn addition could improve the performance of Cu-based catalysts, but...
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- Mechanism of NO reduction by NH3 over MnCuOx catalysts and the influence
mechanism of CO-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00403A, PaperChengbo Xuan, Shiwang Han, Luyuan Wang, Xingyu Zhang, Rongfeng Sun, Xingxing Cheng, Zhiqiang Wang, Chunyuan Ma, Tiantian Zhao, Xukai Hou
A series of CuMnOx catalysts were prepared through the coprecipitation method to explore the effect of CO participation on the NH3- SCR reaction. The results showed that the CM-3 sample...
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- Insights into the deactivation mechanism of self-supported nickel
electrode for 5-hydroxymethyl furfural electrooxidation: focus on the
stability of electrode as a whole-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00183K, PaperFangbing Liu, Nan Lin, Deyuan Xin, Xinxin Li, Linchuan Cong, Fuyu Han, Haibo Lin
The electro-conversion of 5-hydroxymethylfurfural (HMF), an important biomass-derived building block chemical, is a promising approach to realize the utilization of biomass. Nickel foam is normally used as the substrate of...
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- Ethane dehydrogenation over manganese oxides supported on ZSM-5 zeolites
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Abstract:Catal. Sci. Technol., 2023, Advance Article
DOI : 10.1039/D2CY02062A, PaperJian Pan, Raul F. Lobo
Mn-ZSM5 catalysts are shown to have high reaction rates, C2H4 selectivity and stability for ethane dehydrogenation reaction.
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- Oxygen Storage Modeling of Three-Way Catalyst Based on NARX Network
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D2CY01133F, PaperZhuoxiao Yao, Tao Chen, Weipeng Lin, Yifang Feng, Ran Xia, Le Li, Tao Song
The oxygen storage in the Three-Way Catalyst (TWC) influences the removal efficiency of pollutants when the exhaust gas concentration deviates from the equivalence ratio. To calculate oxygen storage, a neural...
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- Mn mixed oxide catalysts supported on Sn-doped CoAl-LDO for
low-temperature NH3-SCR-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00272A, PaperHange Wang, Wen Chen, Wei Jin, Yueli Liu
SCR technology is considered to be the most effective method for denitrification. However, low NOx conversion rate of the current catalysts at low temperatures limits their further application. Herein, Sn-doped...
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- Supramolecular confinement synthesis of ultrafine iron nitride
nanocrystals for oxygen reduction reaction in Zn-air batteries-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D2CY02130G, PaperFanglei Yao, Jiabao Bi, Lei Yu, Liming Dai, Wenkang Xue, Jingyao Deng, Zhihui Yao, Yunyan Wu, Jingwen Sun, Junwu Zhu
Non-noble metal nitrides have emerged as a highly efficient and robust substitute for platinum-based catalysts toward oxygen reduction reaction. Herein, we demonstrate a supramolecular confinement strategy to synthesis ultrafine iron...
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- In situ preparation of programmable curli nanomaterials as fine-tuned
sustainable supports enabling selective and oriented incorporation of
enzymes-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00158J, PaperHao Dong, Wenxue Zhang, Chao Chen, Ping Wang
Pollution caused by phthalic acid esters (PAEs) has shown interference with hormone homeostasis. To reduce the influence of PAEs on the environment, a two-step method for magnetic curli nanomaterial preparation...
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- Oxygen Assisted Conversion of Butanol to Value-added Product on Nanocarbon
Catalysts: Tuning Product Selectivity via Nitrogen Doping-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D2CY02075K, PaperXueya Dai, Fan Li, Di Wang, Miao Guo, Yunli Bai, Wei Qi
n-Butanol (nB) dehydrogenation to butyr aldehyde or dehydration to butene are important high-value-added industrial processes for refinery of biomass resources. The present work reported the activity, mechanistic and kinetic analysis...
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- 2D Boron Nitride Supported Cu2O Promotes Photocatalytic Nitrogen Fixation
at Normal Temperature and Pressure-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00315A, PaperLiangchen Chen, Min Liu, Yutong Chen, Shouxin Zhu, Can Sun, Xuewei Tu, Hui Zheng
Boron nitride (BN) semiconductors, as graphene analogues, have attracted extensive attention in the field of photocatalysis due to their unique physical and chemical properties. In this study, a low-cost visible...
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- Reversion of Catalyst Valence States for Highly Efficient Water Oxidation
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00217A, PaperXiaolei Huang, Fenghe Wang, lipo Ma, Jiawei Wang, Tianyi Zhang, Xiaoyu Hao, Xiao Chi, Hao Cheng, Ming Yang, Jun Ding, Diing Shenp Ang
The conventional four-electron electrochemical process which drives water splitting requires a high overpotential and is energy inefficient. Thus, it is highly desirable to develop an alternative theoretical framework for catalyst...
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- A Data-driven High-throughput Workflow Applied to Promoted In-oxide
Catalysts for CO2 Hydrogenation to Methanol-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00148B, Communication Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Mohammad Khatamirad, Edvin Fako, Chiara Boscagli, Matthias Mueller, Fabian Ebert, Raoul Naumann d'Alnoncourt, Ansgar Schäfer, Stephan A Schunk, Ivana Jevtovikj, Frank Rosowski, Sandip De
We propose a novel high-throughput workflow, combining DFTderived atomic scale interaction parameters with experimental data to identify key performance-related descriptors in CO2 to methanol reaction, for In-based catalysts. Utilizing advanced...
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- Chemodivergent coupling of azoarenes with benzyl alcohols via borrowing
hydrogen strategy using a well-defined nickel catalyst-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00090G, PaperSadhna Bansal, Rajesh G. Gonnade, Benudhar Punji
Chemodivergent (de)hydrogenative coupling of azoarenes with benzyl alcohols is achieved via the N=N bond activation using an inexpensive and well-defined (6-OH-bpy)NiCl2 catalyst. This protocol highlights the construction of C–N bonds...
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- Strontium-induced phase, energy band and microstructure regulating in
Ba1-xSrxTiO3 photocatalysts for boosting visible-light photocatalytic
activity-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D3CY00278K, PaperYan Han, Shifa Wang, Maoyuan Li, Huajing Gao, Mengjun Han, Hua Yang, Leiming Fang, Jagadeesha V. Angadi, Alaa Abdel Rehim, Atif Mossad Ali, Dengfeng Li
The polyacrylamide gel method has been developed for fabrication of Ba1-xSrxTiO3 (BST, x=0.1-0.5) photocatalysts. When x=0.1-02, BST photocatalyst is tetragonal phase, and when x is other values, BST photocatalyst is...
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- Interfacial Anion Vacancies Engineered Graphitic Carbon Nitride
Photoelectrode for Promoting Charge Separation-
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Abstract: Catal. Sci. Technol., 2023, Accepted Manuscript
DOI : 10.1039/D2CY02089K, PaperP. V. R. K. Ramacharyulu, Chang Woo Kim
Anion vacancies at the interface play a vital role in the augmented performance of oxide semiconductors in photocatalysis. The existence of the anion vacancies not only improves the conductivity but...
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