for Journals by Title or ISSN
for Articles by Keywords
help
  Subjects -> CHEMISTRY (Total: 860 journals)
    - ANALYTICAL CHEMISTRY (53 journals)
    - CHEMISTRY (603 journals)
    - CRYSTALLOGRAPHY (21 journals)
    - ELECTROCHEMISTRY (25 journals)
    - INORGANIC CHEMISTRY (42 journals)
    - ORGANIC CHEMISTRY (48 journals)
    - PHYSICAL CHEMISTRY (68 journals)

CHEMISTRY (603 journals)                  1 2 3 4 | Last

Showing 1 - 200 of 735 Journals sorted alphabetically
2D Materials     Hybrid Journal   (Followers: 13)
Accreditation and Quality Assurance: Journal for Quality, Comparability and Reliability in Chemical Measurement     Hybrid Journal   (Followers: 26)
ACS Catalysis     Full-text available via subscription   (Followers: 40)
ACS Chemical Neuroscience     Full-text available via subscription   (Followers: 20)
ACS Combinatorial Science     Full-text available via subscription   (Followers: 23)
ACS Macro Letters     Full-text available via subscription   (Followers: 25)
ACS Medicinal Chemistry Letters     Full-text available via subscription   (Followers: 41)
ACS Nano     Full-text available via subscription   (Followers: 260)
ACS Photonics     Full-text available via subscription   (Followers: 12)
ACS Synthetic Biology     Full-text available via subscription   (Followers: 23)
Acta Chemica Iasi     Open Access   (Followers: 2)
Acta Chimica Sinica     Full-text available via subscription   (Followers: 1)
Acta Chimica Slovaca     Open Access   (Followers: 1)
Acta Chimica Slovenica     Open Access  
Acta Chromatographica     Full-text available via subscription   (Followers: 9)
Acta Facultatis Medicae Naissensis     Open Access  
Acta Metallurgica Sinica (English Letters)     Hybrid Journal   (Followers: 5)
Acta Scientifica Naturalis     Open Access   (Followers: 2)
adhäsion KLEBEN & DICHTEN     Hybrid Journal   (Followers: 5)
Adhesion Adhesives & Sealants     Hybrid Journal   (Followers: 8)
Adsorption Science & Technology     Full-text available via subscription   (Followers: 5)
Advanced Functional Materials     Hybrid Journal   (Followers: 51)
Advanced Science Focus     Free   (Followers: 3)
Advances in Chemical Engineering and Science     Open Access   (Followers: 59)
Advances in Chemical Science     Open Access   (Followers: 14)
Advances in Chemistry     Open Access   (Followers: 16)
Advances in Colloid and Interface Science     Full-text available via subscription   (Followers: 18)
Advances in Drug Research     Full-text available via subscription   (Followers: 23)
Advances in Enzyme Research     Open Access   (Followers: 9)
Advances in Fuel Cells     Full-text available via subscription   (Followers: 16)
Advances in Heterocyclic Chemistry     Full-text available via subscription   (Followers: 9)
Advances in Materials Physics and Chemistry     Open Access   (Followers: 24)
Advances in Nanoparticles     Open Access   (Followers: 14)
Advances in Organometallic Chemistry     Full-text available via subscription   (Followers: 16)
Advances in Polymer Science     Hybrid Journal   (Followers: 41)
Advances in Protein Chemistry     Full-text available via subscription   (Followers: 18)
Advances in Protein Chemistry and Structural Biology     Full-text available via subscription   (Followers: 20)
Advances in Quantum Chemistry     Full-text available via subscription   (Followers: 6)
Advances in Science and Technology     Full-text available via subscription   (Followers: 12)
African Journal of Bacteriology Research     Open Access  
African Journal of Chemical Education     Open Access   (Followers: 2)
African Journal of Pure and Applied Chemistry     Open Access   (Followers: 7)
Agrokémia és Talajtan     Full-text available via subscription   (Followers: 2)
Al-Kimia : Jurnal Penelitian Sains Kimia     Open Access  
Alkaloids: Chemical and Biological Perspectives     Full-text available via subscription   (Followers: 3)
AMB Express     Open Access   (Followers: 1)
Ambix     Hybrid Journal   (Followers: 3)
American Journal of Biochemistry and Biotechnology     Open Access   (Followers: 67)
American Journal of Biochemistry and Molecular Biology     Open Access   (Followers: 15)
American Journal of Chemistry     Open Access   (Followers: 28)
American Journal of Plant Physiology     Open Access   (Followers: 14)
American Mineralogist     Hybrid Journal   (Followers: 15)
Analyst     Full-text available via subscription   (Followers: 39)
Angewandte Chemie     Hybrid Journal   (Followers: 167)
Angewandte Chemie International Edition     Hybrid Journal   (Followers: 237)
Annales UMCS, Chemia     Open Access   (Followers: 1)
Annals of Clinical Chemistry and Laboratory Medicine     Open Access   (Followers: 4)
Annual Reports in Computational Chemistry     Full-text available via subscription   (Followers: 3)
Annual Reports Section A (Inorganic Chemistry)     Full-text available via subscription   (Followers: 4)
Annual Reports Section B (Organic Chemistry)     Full-text available via subscription   (Followers: 9)
Annual Review of Chemical and Biomolecular Engineering     Full-text available via subscription   (Followers: 12)
Annual Review of Food Science and Technology     Full-text available via subscription   (Followers: 16)
Anti-Infective Agents     Hybrid Journal   (Followers: 3)
Antiviral Chemistry and Chemotherapy     Hybrid Journal   (Followers: 1)
Applied Organometallic Chemistry     Hybrid Journal   (Followers: 7)
Applied Spectroscopy     Full-text available via subscription   (Followers: 22)
Applied Surface Science     Hybrid Journal   (Followers: 28)
Arabian Journal of Chemistry     Open Access   (Followers: 6)
ARKIVOC     Open Access   (Followers: 2)
Asian Journal of Biochemistry     Open Access   (Followers: 1)
Atomization and Sprays     Full-text available via subscription   (Followers: 4)
Australian Journal of Chemistry     Hybrid Journal   (Followers: 7)
Autophagy     Hybrid Journal   (Followers: 2)
Avances en Quimica     Open Access   (Followers: 1)
Biochemical Pharmacology     Hybrid Journal   (Followers: 10)
Biochemistry     Full-text available via subscription   (Followers: 339)
Biochemistry Insights     Open Access   (Followers: 6)
Biochemistry Research International     Open Access   (Followers: 6)
BioChip Journal     Hybrid Journal  
Bioinorganic Chemistry and Applications     Open Access   (Followers: 9)
Bioinspired Materials     Open Access   (Followers: 5)
Biointerface Research in Applied Chemistry     Open Access   (Followers: 2)
Biointerphases     Open Access   (Followers: 1)
Biology, Medicine, & Natural Product Chemistry     Open Access   (Followers: 1)
Biomacromolecules     Full-text available via subscription   (Followers: 19)
Biomass Conversion and Biorefinery     Partially Free   (Followers: 10)
Biomedical Chromatography     Hybrid Journal   (Followers: 6)
Biomolecular NMR Assignments     Hybrid Journal   (Followers: 3)
BioNanoScience     Partially Free   (Followers: 5)
Bioorganic & Medicinal Chemistry     Hybrid Journal   (Followers: 121)
Bioorganic & Medicinal Chemistry Letters     Hybrid Journal   (Followers: 85)
Bioorganic Chemistry     Hybrid Journal   (Followers: 10)
Biopolymers     Hybrid Journal   (Followers: 18)
Biosensors     Open Access   (Followers: 2)
Biotechnic and Histochemistry     Hybrid Journal   (Followers: 1)
Bitácora Digital     Open Access  
Boletin de la Sociedad Chilena de Quimica     Open Access  
Bulletin of the Chemical Society of Ethiopia     Open Access   (Followers: 2)
Bulletin of the Chemical Society of Japan     Full-text available via subscription   (Followers: 24)
Bulletin of the Korean Chemical Society     Hybrid Journal   (Followers: 1)
C - Journal of Carbon Research     Open Access   (Followers: 3)
Cakra Kimia (Indonesian E-Journal of Applied Chemistry)     Open Access  
Canadian Association of Radiologists Journal     Full-text available via subscription   (Followers: 2)
Canadian Journal of Chemistry     Hybrid Journal   (Followers: 10)
Canadian Mineralogist     Full-text available via subscription   (Followers: 6)
Carbohydrate Research     Hybrid Journal   (Followers: 26)
Carbon     Hybrid Journal   (Followers: 69)
Catalysis for Sustainable Energy     Open Access   (Followers: 7)
Catalysis Reviews: Science and Engineering     Hybrid Journal   (Followers: 8)
Catalysis Science and Technology     Free   (Followers: 8)
Catalysis Surveys from Asia     Hybrid Journal   (Followers: 3)
Catalysts     Open Access   (Followers: 9)
Cellulose     Hybrid Journal   (Followers: 7)
Cereal Chemistry     Full-text available via subscription   (Followers: 5)
ChemBioEng Reviews     Full-text available via subscription   (Followers: 1)
ChemCatChem     Hybrid Journal   (Followers: 8)
Chemical and Engineering News     Free   (Followers: 16)
Chemical Bulletin of Kazakh National University     Open Access  
Chemical Communications     Full-text available via subscription   (Followers: 71)
Chemical Engineering Research and Design     Hybrid Journal   (Followers: 25)
Chemical Research in Chinese Universities     Hybrid Journal   (Followers: 3)
Chemical Research in Toxicology     Full-text available via subscription   (Followers: 22)
Chemical Reviews     Full-text available via subscription   (Followers: 190)
Chemical Science     Open Access   (Followers: 23)
Chemical Technology     Open Access   (Followers: 16)
Chemical Vapor Deposition     Hybrid Journal   (Followers: 5)
Chemical Week     Full-text available via subscription   (Followers: 8)
Chemie in Unserer Zeit     Hybrid Journal   (Followers: 56)
Chemie-Ingenieur-Technik (Cit)     Hybrid Journal   (Followers: 24)
ChemInform     Hybrid Journal   (Followers: 8)
Chemistry & Biodiversity     Hybrid Journal   (Followers: 7)
Chemistry & Biology     Full-text available via subscription   (Followers: 31)
Chemistry & Industry     Hybrid Journal   (Followers: 5)
Chemistry - A European Journal     Hybrid Journal   (Followers: 153)
Chemistry - An Asian Journal     Hybrid Journal   (Followers: 16)
Chemistry and Materials Research     Open Access   (Followers: 20)
Chemistry Central Journal     Open Access   (Followers: 4)
Chemistry Education Research and Practice     Free   (Followers: 5)
Chemistry in Education     Open Access   (Followers: 9)
Chemistry International     Hybrid Journal   (Followers: 2)
Chemistry Letters     Full-text available via subscription   (Followers: 43)
Chemistry of Materials     Full-text available via subscription   (Followers: 244)
Chemistry of Natural Compounds     Hybrid Journal   (Followers: 9)
Chemistry World     Full-text available via subscription   (Followers: 22)
Chemistry-Didactics-Ecology-Metrology     Open Access   (Followers: 1)
ChemistryOpen     Open Access   (Followers: 2)
Chemkon - Chemie Konkret, Forum Fuer Unterricht Und Didaktik     Hybrid Journal  
Chemoecology     Hybrid Journal   (Followers: 4)
Chemometrics and Intelligent Laboratory Systems     Hybrid Journal   (Followers: 14)
Chemosensors     Open Access  
ChemPhysChem     Hybrid Journal   (Followers: 11)
ChemPlusChem     Hybrid Journal   (Followers: 2)
ChemTexts     Hybrid Journal  
CHIMIA International Journal for Chemistry     Full-text available via subscription   (Followers: 2)
Chinese Journal of Chemistry     Hybrid Journal   (Followers: 6)
Chinese Journal of Polymer Science     Hybrid Journal   (Followers: 10)
Chromatographia     Hybrid Journal   (Followers: 24)
Chromatography     Open Access   (Followers: 2)
Clay Minerals     Full-text available via subscription   (Followers: 10)
Cogent Chemistry     Open Access  
Colloid and Interface Science Communications     Open Access  
Colloid and Polymer Science     Hybrid Journal   (Followers: 10)
Colloids and Interfaces     Open Access  
Colloids and Surfaces B: Biointerfaces     Hybrid Journal   (Followers: 6)
Combinatorial Chemistry & High Throughput Screening     Hybrid Journal   (Followers: 4)
Combustion Science and Technology     Hybrid Journal   (Followers: 22)
Comments on Inorganic Chemistry: A Journal of Critical Discussion of the Current Literature     Hybrid Journal   (Followers: 2)
Composite Interfaces     Hybrid Journal   (Followers: 6)
Comprehensive Chemical Kinetics     Full-text available via subscription   (Followers: 2)
Comptes Rendus Chimie     Full-text available via subscription  
Comptes Rendus Physique     Full-text available via subscription   (Followers: 1)
Computational and Theoretical Chemistry     Hybrid Journal   (Followers: 9)
Computational Biology and Chemistry     Hybrid Journal   (Followers: 11)
Computational Chemistry     Open Access   (Followers: 2)
Computers & Chemical Engineering     Hybrid Journal   (Followers: 10)
Coordination Chemistry Reviews     Full-text available via subscription   (Followers: 3)
Copernican Letters     Open Access   (Followers: 1)
Corrosion Series     Full-text available via subscription   (Followers: 6)
Critical Reviews in Biochemistry and Molecular Biology     Hybrid Journal   (Followers: 5)
Croatica Chemica Acta     Open Access  
Crystal Structure Theory and Applications     Open Access   (Followers: 4)
CrystEngComm     Full-text available via subscription   (Followers: 13)
Current Catalysis     Hybrid Journal   (Followers: 2)
Current Chromatography     Hybrid Journal  
Current Green Chemistry     Hybrid Journal  
Current Metabolomics     Hybrid Journal   (Followers: 5)
Current Microwave Chemistry     Hybrid Journal  
Current Opinion in Colloid & Interface Science     Hybrid Journal   (Followers: 9)
Current Opinion in Molecular Therapeutics     Full-text available via subscription   (Followers: 18)
Current Research in Chemistry     Open Access   (Followers: 9)
Current Science     Open Access   (Followers: 64)
Dalton Transactions     Full-text available via subscription   (Followers: 23)
Detection     Open Access   (Followers: 2)
Developments in Geochemistry     Full-text available via subscription   (Followers: 2)
Diamond and Related Materials     Hybrid Journal   (Followers: 12)
Dislocations in Solids     Full-text available via subscription  
Doklady Chemistry     Hybrid Journal  
Drying Technology: An International Journal     Hybrid Journal   (Followers: 4)
Eclética Química     Open Access   (Followers: 1)
Ecological Chemistry and Engineering S     Open Access   (Followers: 3)

        1 2 3 4 | Last

Journal Cover Advances in Colloid and Interface Science
  [SJR: 2.314]   [H-I: 130]   [18 followers]  Follow
    
   Full-text available via subscription Subscription journal
   ISSN (Print) 0001-8686
   Published by Elsevier Homepage  [3120 journals]
  • Recent developments in dopamine-based materials for cancer diagnosis and
           therapy
    • Authors: Hong Li; Yi Jia; Haonan Peng; Junbai Li
      Abstract: Publication date: Available online 31 January 2018
      Source:Advances in Colloid and Interface Science
      Author(s): Hong Li, Yi Jia, Haonan Peng, Junbai Li
      Dopamine-based materials are emerging as novel biomaterials and have attracted considerable interests in the fields of biosensing, bioimaging and cancer therapy due to their unique physicochemical properties, such as versatile adhesion property, high chemical reactivity, excellent biocompatibility and biodegradability, strong photothermal conversion capacity, etc. In this review, we present an overview of recent research progress on dopamine-based materials for diagnosis and therapy of cancer. The review starts with a summary of the physicochemical properties of dopamine-based materials in general. Then detailed description is followed on their applications in the fields of diagnosis and treatment of cancers. The review concludes with an outline of some remaining challenges for dopamine-based materials to be used for clinical applications.
      Graphical abstract image

      PubDate: 2018-02-05T16:21:52Z
      DOI: 10.1016/j.cis.2018.01.001
       
  • A review on suppression and utilization of the coffee-ring effect
    • Authors: Dileep Mampallil; Huseyin Burak Eral
      Abstract: Publication date: Available online 2 January 2018
      Source:Advances in Colloid and Interface Science
      Author(s): Dileep Mampallil, Huseyin Burak Eral
      Evaporation of sessile droplets containing non-volatile solutes dispersed in a volatile solvent leaves behind ring-like solid stains. As the volatile species evaporates, pinning of the contact line gives rise to capillary flows that transport non-volatile solutes to the contact line. This phenomenon, called the coffee-ring effect, compromises the overall performance of industrially relevant manufacturing processes involving evaporation such as printing, biochemical analysis, manufacturing of nano-structured materials through colloidal and macromolecular patterning. Various approaches have been developed to suppress this phenomenon, which is otherwise difficult to avoid. The coffee-ring effect has also been leveraged to prepare new materials through convection induced assembly. This review underlines not only the strategies developed to suppress the coffee-ring effect but also sheds light on approaches to arrive at novel processes and materials. Working principles and applicability of these strategies are discussed together with a critical comparison.
      Graphical abstract image

      PubDate: 2018-02-05T16:21:52Z
      DOI: 10.1016/j.cis.2017.12.008
       
  • Gel-forming mucin interactome drives mucus viscoelasticity
    • Authors: Bastien Demouveaux; Valérie Gouyer; Frédéric Gottrand; Tetsuharu Narita; Jean-Luc Desseyn
      Abstract: Publication date: Available online 28 December 2017
      Source:Advances in Colloid and Interface Science
      Author(s): Bastien Demouveaux, Valérie Gouyer, Frédéric Gottrand, Tetsuharu Narita, Jean-Luc Desseyn
      Mucus is a hydrogel that constitutes the first innate defense in all mammals. The main organic component of mucus, gel-forming mucins, forms a complex network through both reversible and irreversible interactions that drive mucus gel formation. Significant advances in the understanding of irreversible gel-forming mucins assembly have been made using recombinant protein approaches. However, little is known about the reversible interactions that may finely modulate mucus viscoelasticity, which can be characterized using rheology. This approach can be used to investigate both the nature of gel-forming mucins interactions and factors that influence hydrogel formation. This knowledge is directly relevant to the development of new drugs to modulate mucus viscoelasticity and to restore normal mucus functions in diseases such as in cystic fibrosis. The aim of the present review is to summarize the current knowledge about the relationship between the mucus protein matrix and its functions, with emphasis on mucus viscoelasticity.
      Graphical abstract image

      PubDate: 2018-02-05T16:21:52Z
      DOI: 10.1016/j.cis.2017.12.005
       
  • High pressure-elevated temperature x-ray micro-computed tomography for
           subsurface applications
    • Authors: Stefan Iglauer; Maxim Lebedev
      Abstract: Publication date: Available online 28 December 2017
      Source:Advances in Colloid and Interface Science
      Author(s): Stefan Iglauer, Maxim Lebedev
      Physical, chemical and mechanical pore-scale (i.e. micrometer-scale) mechanisms in rock are of key importance in many, if not all, subsurface processes. These processes are highly relevant in various applications, e.g. hydrocarbon recovery, CO2 geo-sequestration, geophysical exploration, water production, geothermal energy production, or the prediction of the location of valuable hydrothermal deposits. Typical examples are multi-phase flow (e.g. oil and water) displacements driven by buoyancy, viscous or capillary forces, mineral-fluid interactions (e.g. mineral dissolution and/or precipitation over geological times), geo-mechanical rock behaviour (e.g. rock compaction during diagenesis) or fines migration during water production, which can dramatically reduce reservoir permeability (and thus reservoir performance). All above examples are 3D processes, and 2D experiments (as traditionally done for micro-scale investigations) will thus only provide qualitative information; for instance the percolation threshold is much lower in 3D than in 2D. However, with the advent of x-ray micro-computed tomography (μCT) – which is now routinely used – this limitation has been overcome, and such pore-scale processes can be observed in 3D at micrometer-scale. A serious complication is, however, the fact that the subsurface high pressures and elevated temperatures (HPET) prevail, due to the hydrostatic and geothermal gradients imposed upon it. Such HPET-reservoir conditions significantly change the above mentioned physical and chemical processes, e.g. gas density is much higher at high pressure, which strongly affects buoyancy and wettability and thus gas distributions in the subsurface; or chemical reactions are significantly accelerated at increased temperature, strongly affecting fluid-rock interactions and thus diagenesis and deposition of valuable minerals. It is thus necessary to apply HPET conditions to the aforementioned μCT experiments, to be able to mimic subsurface conditions in a realistic way, and thus to obtain reliable results, which are vital input parameters required for building accurate larger-scale reservoir models which can predict the overall reservoir-scale (hectometer-scale) processes (e.g. oil production or diagenesis of a formation). We thus describe here the basic workflow of such HPET-μCT experiments, equipment requirements and apparatus design; and review the literature where such HPET-μCT experiments were used and which phenomena were investigated (these include: CO2 geo-sequestration, oil recovery, gas hydrate formation, hydrothermal deposition/reactive flow). One aim of this paper is to give a guideline to users how to set-up a HPET-μCT experiment, and to provide a quick overview in terms of what is possible and what not, at least up to date. As a conclusion, HPET-μCT is a valuable tool when it comes to the investigation of subsurface micrometer-scaled processes, and we expect a rapidly expanding usage of HPET-μCT in subsurface engineering and the subsurface sciences.
      Graphical abstract image

      PubDate: 2018-02-05T16:21:52Z
      DOI: 10.1016/j.cis.2017.12.009
       
  • Biological applications of kinetics of wetting and spreading
    • Authors: G. Ahmed; O. Arjmandi Tash; J. Cook; A. Trybala; V. Starov
      Pages: 17 - 36
      Abstract: Publication date: November 2017
      Source:Advances in Colloid and Interface Science, Volume 249
      Author(s): G. Ahmed, O. Arjmandi Tash, J. Cook, A. Trybala, V. Starov
      Wetting and spreading kinetics of biological fluids has gained a substantial interest recently. The importance of these fluids in our lives has driven the pace of publications. Globally scientists have ever growing interest in understanding wetting phenomena due to its vast applications in biological fluids. It is impractical to review extremely large number of publications in the field of kinetics of complex biological fluids and cosmetic solutions on diverse surfaces. Therefore, biological and cosmetic applications of wetting and spreading dynamics are considered in the following areas: (i) Spreading of Newtonian liquids in the case of non-porous and porous substrates. It is shown that the spreading kinetics of a Newtonian droplet on non-porous and porous substrate can be defined through theoretical relations for droplet base radius on time, which agree well with the experimental results; (ii) Spreading of blood over porous substrates. It is shown that blood, which has a complex non-Newtonian rheology, can be successfully modelled with the help of simple power-law model for shear-thinning non-Newtonian liquids; (iii) Simultaneous spreading and evaporation kinetics of blood. This part enlightens different underlying mechanisms present in the wetting, spreading, evaporation and dried pattern formation of the blood droplets on solid substrates; (iv) Spreading over hair. In this part the wetting of hair tresses by aqueous solutions of two widely used by industry commercially available polymers, AculynTM 22 and AculynTM 33, are discussed. The influence of non-Newtonian rheology of these polymer solutions on the drainage of foams produced from these solutions is also briefly discussed.
      Graphical abstract image

      PubDate: 2017-12-12T13:48:47Z
      DOI: 10.1016/j.cis.2017.08.004
      Issue No: Vol. 249 (2017)
       
  • Zinc oxide nanoparticles: Synthesis, antiseptic activity and toxicity
           mechanism
    • Authors: A. Król; P. Pomastowski; K. Rafińska; V. Railean-Plugaru; B. Buszewski
      Pages: 37 - 52
      Abstract: Publication date: November 2017
      Source:Advances in Colloid and Interface Science, Volume 249
      Author(s): A. Król, P. Pomastowski, K. Rafińska, V. Railean-Plugaru, B. Buszewski
      Zinc oxide (ZnO), as a material with attractive properties, has attracted great interest worldwide, particularly owing to the implementation of the synthesis of nano-sized particles. High luminescent efficiency, a wide band gap (3.36eV), and a large exciton binding energy (60meV) has triggered intense research on the production of nanoparticles using different synthesis methods and on their future applications. ZnO nanomaterials can be used in industry as nano-optical and nano-electrical devices, in food packaging and in medicine as antimicrobial and antitumor agents. The increasing focus on nano zinc oxide resulted in the invention and development of methods of nanoparticles synthesis. Recently, various approaches including physical, chemical and biological (“green chemistry”) have been used to prepare ZnO nanocomposites with different morphologies. The obtained nanoparticles can be characterized with a broad range of analytical methods including dynamic light scattering (DLS), electron microscopy (TEM, SEM), UV–VIS spectroscopy, X-ray diffraction (XRD) or inductively coupled plasma with mass spectrometry (ICP-MS). With these it is possible to obtain information concerning the size, shape and optical properties of nanoparticles. ZnO NPs exhibit attractive antimicrobial properties against bacteria (Gram-positive and Gram-negative) and fungi. Zinc oxide nanocomposites show also selective toxicity toward normal and cancerous cells, which is explained by reactive oxygen formation (ROS). Yet despite the potentially interesting antitumor activity of ZnO nanoparticles, it has been proven that they can be also cytotoxic and genotoxic for multiple types of human cells (i.e. neuronal or epithelial cells). This paper reviews the methods of synthesizing zinc oxide nanocomposites as well as their characteristics, antimicrobial activity and cytotoxicity against normal and tumor cells.
      Graphical abstract image

      PubDate: 2017-12-12T13:48:47Z
      DOI: 10.1016/j.cis.2017.07.033
      Issue No: Vol. 249 (2017)
       
  • Emerging nanotechnology based strategies for diagnosis and therapeutics of
           urinary tract infections: A review
    • Authors: M.S. Kumar; A.P. Das
      Pages: 53 - 65
      Abstract: Publication date: November 2017
      Source:Advances in Colloid and Interface Science, Volume 249
      Author(s): M.S. Kumar, A.P. Das
      At present, various diagnostic and therapeutic approaches are available for urinary tract infections. But, still the quest for development of more rapid, accurate and reliable approach is an unending process. The pathogens, especially uropathogens are adapting to new environments and antibiotics day by day rapidly. Therefore, urinary tract infections are evolving as hectic and difficult to eradicate, increasing the economic burden to the society. The technological advances should be able to compete the adaptability characteristics of microorganisms to combat their growth in new environments and thereby preventing their infections. Nanotechnology is at present an extensively developing area of immense scientific interest since it has diverse potential applications in biomedical field. Nanotechnology may be combined with cellular therapy approaches to overcome the limitations caused by conventional therapeutics. Nanoantibiotics and drug delivery using nanotechnology are currently growing areas of research in biomedical field. Recently, various categories of antibacterial nanoparticles and nanocarriers for drug delivery have shown their potential in the treatment of infectious diseases. Nanoparticles, compared to conventional antibiotics, are more beneficial in terms of decreasing toxicity, prevailing over resistance and lessening costs. Nanoparticles present long term therapeutic effects since they are retained in body for relatively longer periods. This review focuses on recent advances in the field of nanotechnology, principally emphasizing diagnostics and therapeutics of urinary tract infections.
      Graphical abstract image

      PubDate: 2017-12-12T13:48:47Z
      DOI: 10.1016/j.cis.2017.06.010
      Issue No: Vol. 249 (2017)
       
  • Sensors and bioassays powered by upconverting materials
    • Authors: Diego Mendez-Gonzalez; Enrique Lopez-Cabarcos; Jorge Rubio-Retama; Marco Laurenti
      Pages: 66 - 87
      Abstract: Publication date: November 2017
      Source:Advances in Colloid and Interface Science, Volume 249
      Author(s): Diego Mendez-Gonzalez, Enrique Lopez-Cabarcos, Jorge Rubio-Retama, Marco Laurenti
      In recent years, considerable efforts have been done to better understand the peculiar emission properties of upconverting materials due to their widespread applications in different and important technological fields such as upconversion-based photoactivated cancer therapies, photoactivated drug-delivery, magnetic resonance imaging contrast agents, bioimaging. However, one of the most promising applications of upconverting materials concerns the field of sensing, due to their unique emission properties. In fact, the minimal autofluorescence, blinking, photo-bleaching, and high photostability makes them an excellent alternative to organic dyes or quantum dots. This article reviews the state-of-the-art, design, and sensing strategies of upconversion-based sensing platforms, with special attention to upconverting nanoparticles, as well as how the incorporation of these materials into pre-existing diagnostic tests and bioassays have improved their capabilities for the detection of different kinds of analytes.
      Graphical abstract image

      PubDate: 2017-12-12T13:48:47Z
      DOI: 10.1016/j.cis.2017.06.003
      Issue No: Vol. 249 (2017)
       
  • Liposomes and lipid bilayers in biosensors
    • Authors: Federico Mazur; Marta Bally; Brigitte Städler; Rona Chandrawati
      Pages: 88 - 99
      Abstract: Publication date: November 2017
      Source:Advances in Colloid and Interface Science, Volume 249
      Author(s): Federico Mazur, Marta Bally, Brigitte Städler, Rona Chandrawati
      Biosensors for the rapid, specific, and sensitive detection of analytes play a vital role in healthcare, drug discovery, food safety, and environmental monitoring. Although a number of sensing concepts and devices have been developed, many longstanding challenges to obtain inexpensive, easy-to-use, and reliable sensor platforms remain largely unmet. Nanomaterials offer exciting possibilities for enhancing the assay sensitivity and for lowering the detection limits down to single-molecule resolution. In this review, we present an overview of liposomes and lipid bilayers in biosensing applications. Lipid assemblies in the form of spherical liposomes or two-dimensional planar membranes have been widely used in the design of biosensing assays; in particular, we highlight a number of recent promising developments of biosensors based on liposomes in suspension, liposome arrays, and lipid bilayers arrays. Assay sensitivity and specificity are discussed, advantages and drawbacks are reviewed, and possible further developments are outlined.
      Graphical abstract image

      PubDate: 2017-12-12T13:48:47Z
      DOI: 10.1016/j.cis.2017.05.020
      Issue No: Vol. 249 (2017)
       
  • Formulation, stabilisation and encapsulation of bacteriophage for phage
           therapy
    • Authors: Danish J. Malik; Ilya J. Sokolov; Gurinder K. Vinner; Francesco Mancuso; Salvatore Cinquerrui; Goran T. Vladisavljevic; Martha R.J. Clokie; Natalie J. Garton; Andrew G.F. Stapley; Anna Kirpichnikova
      Pages: 100 - 133
      Abstract: Publication date: November 2017
      Source:Advances in Colloid and Interface Science, Volume 249
      Author(s): Danish J. Malik, Ilya J. Sokolov, Gurinder K. Vinner, Francesco Mancuso, Salvatore Cinquerrui, Goran T. Vladisavljevic, Martha R.J. Clokie, Natalie J. Garton, Andrew G.F. Stapley, Anna Kirpichnikova
      Against a backdrop of global antibiotic resistance and increasing awareness of the importance of the human microbiota, there has been resurgent interest in the potential use of bacteriophages for therapeutic purposes, known as phage therapy. A number of phage therapy phase I and II clinical trials have concluded, and shown phages don't present significant adverse safety concerns. These clinical trials used simple phage suspensions without any formulation and phage stability was of secondary concern. Phages have a limited stability in solution, and undergo a significant drop in phage titre during processing and storage which is unacceptable if phages are to become regulated pharmaceuticals, where stable dosage and well defined pharmacokinetics and pharmacodynamics are de rigueur. Animal studies have shown that the efficacy of phage therapy outcomes depend on the phage concentration (i.e. the dose) delivered at the site of infection, and their ability to target and kill bacteria, arresting bacterial growth and clearing the infection. In addition, in vitro and animal studies have shown the importance of using phage cocktails rather than single phage preparations to achieve better therapy outcomes. The in vivo reduction of phage concentration due to interactions with host antibodies or other clearance mechanisms may necessitate repeated dosing of phages, or sustained release approaches. Modelling of phage-bacterium population dynamics reinforces these points. Surprisingly little attention has been devoted to the effect of formulation on phage therapy outcomes, given the need for phage cocktails, where each phage within a cocktail may require significantly different formulation to retain a high enough infective dose. This review firstly looks at the clinical needs and challenges (informed through a review of key animal studies evaluating phage therapy) associated with treatment of acute and chronic infections and the drivers for phage encapsulation. An important driver for formulation and encapsulation is shelf life and storage of phage to ensure reproducible dosages. Other drivers include formulation of phage for encapsulation in micro- and nanoparticles for effective delivery, encapsulation in stimuli responsive systems for triggered controlled or sustained release at the targeted site of infection. Encapsulation of phage (e.g. in liposomes) may also be used to increase the circulation time of phage for treating systemic infections, for prophylactic treatment or to treat intracellular infections. We then proceed to document approaches used in the published literature on the formulation and stabilisation of phage for storage and encapsulation of bacteriophage in micro- and nanostructured materials using freeze drying (lyophilization), spray drying, in emulsions e.g. ointments, polymeric microparticles, nanoparticles and liposomes. As phage therapy moves forward towards Phase III clinical trials, the review concludes by looking at promising new approaches for micro- and nanoencapsulation of phages and how these may address gaps in the field.
      Graphical abstract image

      PubDate: 2017-12-12T13:48:47Z
      DOI: 10.1016/j.cis.2017.05.014
      Issue No: Vol. 249 (2017)
       
  • Colloid particle formulations for antimicrobial applications
    • Authors: Ahmed F. Halbus; Tommy S. Horozov; Vesselin N. Paunov
      Pages: 134 - 148
      Abstract: Publication date: November 2017
      Source:Advances in Colloid and Interface Science, Volume 249
      Author(s): Ahmed F. Halbus, Tommy S. Horozov, Vesselin N. Paunov
      Colloidal particles are being extensively studied in various antimicrobial applications due to their small size to volume ratio and ability to exhibit a wide spectrum of antibacterial, antifungal, antialgal and antiviral action. The present review focuses on various nanoparticles (NPs) of inorganic, organic and hybrid materials, and discusses some of the methods for their preparation as well as mechanisms of their antimicrobial action. We consider the antimicrobial applications of metal oxide nanoparticles (ZnO, MgO, CuO, Cu2O, Al2O3, TiO2, CeO2 and Y2O3), metal nanoparticles (NPs), such as copper, silver and gold, metal hydroxide NPs such as Mg(OH)2 as well as hybrid NPs made from biodegradable materials, such as chitosan, lignin and dextran, loaded with other antimicrobial agents. Recent developments for targeted delivery of antimicrobials by using colloid antibodies for microbial cell shape and surface recognition are also discussed. We also consider recent advances in the functionalization of nanoparticles and their potential antimicrobial applications as a viable alternative of conventional antibiotics and antiseptic agents which can help to tackle antimicrobial resistance. The review also covers the recently developed environmentally benign NPs (EbNPs) as a “safer-by-design” green chemistry solution of the post use fate of antimicrobial nanomaterials.
      Graphical abstract image

      PubDate: 2017-12-12T13:48:47Z
      DOI: 10.1016/j.cis.2017.05.012
      Issue No: Vol. 249 (2017)
       
  • Atomic force microscopy: From red blood cells to immunohaematology
    • Authors: Natasha Yeow; Rico F. Tabor; Gil Garnier
      Pages: 149 - 162
      Abstract: Publication date: November 2017
      Source:Advances in Colloid and Interface Science, Volume 249
      Author(s): Natasha Yeow, Rico F. Tabor, Gil Garnier
      Atomic force microscopy (AFM) offers complementary imaging modes that can provide morphological and structural details of red blood cells (RBCs), and characterize interactions between specific biomolecules and RBC surface antigen. This review describes the applications of AFM in determining RBC health by the observation of cell morphology, elasticity and surface roughness. Measurement of interaction forces between plasma proteins and antibodies against RBC surface antigen using the AFM also brought new information to the immunohaematology field. With constant improvisation of the AFM in resolution and imaging time, the reaction of RBC to changes in the physico-chemistry of its environment and the presence of RBC surface antigen specific-biomolecules is achievable.
      Graphical abstract image

      PubDate: 2017-12-12T13:48:47Z
      DOI: 10.1016/j.cis.2017.05.011
      Issue No: Vol. 249 (2017)
       
  • Recent advances in smart biotechnology: Hydrogels and nanocarriers for
           tailored bioactive molecules depot
    • Authors: Gesmi Milcovich; Stefania Lettieri; Filipe E. Antunes; Bruno Medronho; Ana C. Fonseca; Jorge F.J. Coelho; Paolo Marizza; Francesca Perrone; Rossella Farra; Barbara Dapas; Gabriele Grassi; Mario Grassi; Silvia Giordani
      Pages: 163 - 180
      Abstract: Publication date: November 2017
      Source:Advances in Colloid and Interface Science, Volume 249
      Author(s): Gesmi Milcovich, Stefania Lettieri, Filipe E. Antunes, Bruno Medronho, Ana C. Fonseca, Jorge F.J. Coelho, Paolo Marizza, Francesca Perrone, Rossella Farra, Barbara Dapas, Gabriele Grassi, Mario Grassi, Silvia Giordani
      Over the past ten years, the global biopharmaceutical market has remarkably grown, with ten over the top twenty worldwide high performance medical treatment sales being biologics. Thus, biotech R&D (research and development) sector is becoming a key leading branch, with expanding revenues. Biotechnology offers considerable advantages compared to traditional therapeutic approaches, such as reducing side effects, specific treatments, higher patient compliance and therefore more effective treatments leading to lower healthcare costs. Within this sector, smart nanotechnology and colloidal self-assembling systems represent pivotal tools able to modulate the delivery of therapeutics. A comprehensive understanding of the processes involved in the self-assembly of the colloidal structures discussed therein is essential for the development of relevant biomedical applications. In this review we report the most promising and best performing platforms for specific classes of bioactive molecules and related target, spanning from siRNAs, gene/plasmids, proteins/growth factors, small synthetic therapeutics and bioimaging probes.
      Graphical abstract image

      PubDate: 2017-12-12T13:48:47Z
      DOI: 10.1016/j.cis.2017.05.009
      Issue No: Vol. 249 (2017)
       
  • Recent developments in drug eluting devices with tailored interfacial
           properties
    • Authors: Eva Sanchez-Rexach; Emilio Meaurio; Jose-Ramon Sarasua
      Pages: 181 - 191
      Abstract: Publication date: November 2017
      Source:Advances in Colloid and Interface Science, Volume 249
      Author(s): Eva Sanchez-Rexach, Emilio Meaurio, Jose-Ramon Sarasua
      Drug eluting devices have greatly evolved during past years to become fundamental products of great marketing importance in the biomedical field. There is currently a large diversity of highly specialized devices for specific applications, making the development of these devices an exciting field of research. The replacement of the former bare metal devices by devices loaded with drugs allowed the sustained and controlled release of drugs, to achieve the desired local therapeutic concentration of drug. The newer devices have been “engineered” with surfaces containing micro- and nanoscale features in a well-controlled manner, that have shown to significantly affect cellular and subcellular function of various biological systems. For example, the topography can be structured to form an antifouling surface mimicking the defense mechanisms found in nature, like the skin of the shark. In the case of bone implants, well-controlled nanostructured interfaces can promote osteoblast differentiation and matrix production, and enhance short-term and long-term osteointegration. In any case, the goal of current research is to design implants that induce controlled, guided, and rapid healing. This article reviews recent trends in the development of drug eluting devices, as well as recent developments on the micro/nanotechnology scales, and their future challenges. For this purpose medical devices have been divided according to the different systems of the body they are focused to: orthopedic devices, breathing stents, gastrointestinal and urinary systems, devices for cardiovascular diseases, neuronal implants, and wound dressings.
      Graphical abstract image

      PubDate: 2017-12-12T13:48:47Z
      DOI: 10.1016/j.cis.2017.05.005
      Issue No: Vol. 249 (2017)
       
  • Iron oxide nanoparticles – In vivo/in vitro biomedical applications
           and in silico studies
    • Authors: Miroslava Nedyalkova; Borjana Donkova; Julia Romanova; George Tzvetkov; Sergio Madurga; Vasil Simeonov
      Pages: 192 - 212
      Abstract: Publication date: November 2017
      Source:Advances in Colloid and Interface Science, Volume 249
      Author(s): Miroslava Nedyalkova, Borjana Donkova, Julia Romanova, George Tzvetkov, Sergio Madurga, Vasil Simeonov
      The review presents a broad overview of the biomedical applications of surface functionalized iron oxide nanoparticles (IONPs) as magnetic resonance imaging (MRI) agents for sensitive and precise diagnosis tool and synergistic combination with other imaging modalities. Then, the recent progress in therapeutic applications, such as hyperthermia is discussed and the available toxicity data of magnetic nanoparticles concerning in vitro and in vivo biomedical applications are addressed. This review also presents the available computer models using molecular dynamics (MD), Monte Carlo (MC) and density functional theory (DFT), as a basis for a complete understanding of the behaviour and morphology of functionalized IONPs, for improving NPs surface design and expanding the potential applications in nanomedicine.
      Graphical abstract image

      PubDate: 2017-12-12T13:48:47Z
      DOI: 10.1016/j.cis.2017.05.003
      Issue No: Vol. 249 (2017)
       
  • HAP nanoparticle and substrate surface electrical potential towards bone
           cells adhesion: Recent results review
    • Authors: Vladimir Bystrov; Anna Bystrova; Yuri Dekhtyar
      Pages: 213 - 219
      Abstract: Publication date: November 2017
      Source:Advances in Colloid and Interface Science, Volume 249
      Author(s): Vladimir Bystrov, Anna Bystrova, Yuri Dekhtyar
      Nanostructured hydroxyapatite (HAP) and its nanoparticles are widely used for implantation into the human organism. The biocompatibility of the implants depends very much on the interaction between the implant and the cells regenerating tissue to be connected to the implant. An implant surface electrical charged density plays an important role in these processes. Possible instruments managing the surface electrical potential of HAP are in the focus of this paper. Both theoretical and experimental results evidence that: - the surface electrical charge density of the nanoparticle depends on its size and shape; - the electrical charge density of HAP could be engineered by contact less technique because of deposition of the electrical charge from the external radiation source, surface couples reconstruction.
      Graphical abstract image

      PubDate: 2017-12-12T13:48:47Z
      DOI: 10.1016/j.cis.2017.05.002
      Issue No: Vol. 249 (2017)
       
  • Incorporation of ion and solvent structure into mean-field modeling of the
           electric double layer
    • Authors: Klemen Bohinc; Guilherme Volpe Bossa; Sylvio May
      Pages: 220 - 233
      Abstract: Publication date: November 2017
      Source:Advances in Colloid and Interface Science, Volume 249
      Author(s): Klemen Bohinc, Guilherme Volpe Bossa, Sylvio May
      An electric double layer forms when the small mobile ions of an electrolyte interact with an extended charged object, a macroion. The competition between electrostatic attraction and translational entropy loss of the small ions results in a diffuse layer of partially immobilized ions in the vicinity of the macroion. Modeling structure and energy of the electric double layer has a long history that has lead to the classical Poisson-Boltzmann theory and numerous extensions that account for ion-ion correlations and structural ion and solvent properties. The present review focuses on approaches that instead of going beyond the mean-field character of Poisson-Boltzmann theory introduce structural details of the ions and the solvent into the Poisson-Boltzmann modeling framework. The former include not only excluded volume effects but also the presence of charge distributions on individual ions, spatially extended ions, and internal ionic degrees of freedom. The latter treat the solvent either explicitly as interacting Langevin dipoles or in the form of effective non-electrostatic interactions, in particular Yukawa interactions, that are added to the Coulomb potential. We discuss how various theoretical models predict structural properties of the electric double layer such as the differential capacitance and compare some of these predictions with computer simulations.
      Graphical abstract image

      PubDate: 2017-12-12T13:48:47Z
      DOI: 10.1016/j.cis.2017.05.001
      Issue No: Vol. 249 (2017)
       
  • Nano-carrier based drug delivery systems for sustained antimicrobial agent
           release from orthopaedic cementous material
    • Authors: Yazan Al Thaher; Stefano Perni; Polina Prokopovich
      Pages: 234 - 247
      Abstract: Publication date: November 2017
      Source:Advances in Colloid and Interface Science, Volume 249
      Author(s): Yazan Al Thaher, Stefano Perni, Polina Prokopovich
      Total joint replacement (TJR), such as hip and knee replacement, is a popular procedure worldwide. Prosthetic joint infections (PJI) after this procedure have been widely reported, where treatment of such infections is complex with high cost and prolonged hospital stay. In cemented arthroplasties, the use of antibiotic loaded bone cement (ALBC) is a standard practice for the prophylaxis and treatment of PJI. Recently, the development of bacterial resistance by pathogenic microorganisms against most commonly used antibiotics increased the interest in alternative approaches for antimicrobial delivery systems such as nanotechnology. This review summarizes the efforts made to improve the antimicrobial properties of PMMA bone cements using nanotechnology based antibiotic and non-antibiotic delivery systems to overcome drawbacks of ALBC in the prophylaxis and treatment of PJIs after hip and knee replacement.
      Graphical abstract image

      PubDate: 2017-12-12T13:48:47Z
      DOI: 10.1016/j.cis.2017.04.017
      Issue No: Vol. 249 (2017)
       
  • Lipid vesicles in pulsed electric fields: Fundamental principles of the
           membrane response and its biomedical applications
    • Authors: Dayinta L. Perrier; Lea Rems; Pouyan E. Boukany
      Pages: 248 - 271
      Abstract: Publication date: November 2017
      Source:Advances in Colloid and Interface Science, Volume 249
      Author(s): Dayinta L. Perrier, Lea Rems, Pouyan E. Boukany
      The present review focuses on the effects of pulsed electric fields on lipid vesicles ranging from giant unilamellar vesicles (GUVs) to small unilamellar vesicles (SUVs), from both fundamental and applicative perspectives. Lipid vesicles are the most popular model membrane systems for studying biophysical and biological processes in living cells. Furthermore, as vesicles are made from biocompatible and biodegradable materials, they provide a strategy to create safe and functionalized drug delivery systems in health-care applications. Exposure of lipid vesicles to pulsed electric fields is a common physical method to transiently increase the permeability of the lipid membrane. This method, termed electroporation, has shown many advantages for delivering exogenous molecules including drugs and genetic material into vesicles and living cells. In addition, electroporation can be applied to induce fusion between vesicles and/or cells. First, we discuss in detail how research on cell-size GUVs as model cell systems has provided novel insight into the basic mechanisms of cell electroporation and associated phenomena. Afterwards, we continue with a thorough overview how electroporation and electrofusion have been used as versatile methods to manipulate vesicles of all sizes in different biomedical applications. We conclude by summarizing the open questions in the field of electroporation and possible future directions for vesicles in the biomedical field.
      Graphical abstract image

      PubDate: 2017-12-12T13:48:47Z
      DOI: 10.1016/j.cis.2017.04.016
      Issue No: Vol. 249 (2017)
       
  • Bio-templated silica composites for next-generation biomedical
           applications
    • Authors: Karunya Albert; Xin-Chun Huang; Hsin-Yun Hsu
      Pages: 272 - 289
      Abstract: Publication date: November 2017
      Source:Advances in Colloid and Interface Science, Volume 249
      Author(s): Karunya Albert, Xin-Chun Huang, Hsin-Yun Hsu
      Silica-based materials have extensive biomedical applications owing to their unique physical, chemical, and biological properties. Recently, increasing studies have examined the mechanisms involved in biosilicification to develop novel, fine-tunable, eco-friendly materials and/or technologies. In this review, we focus on recent developments in bio-templated silica synthesis and relevant applications in drug delivery systems, tissue engineering, and biosensing.
      Graphical abstract image

      PubDate: 2017-12-12T13:48:47Z
      DOI: 10.1016/j.cis.2017.04.011
      Issue No: Vol. 249 (2017)
       
  • Layer-by-Layer polyelectrolyte assemblies for encapsulation and release of
           active compounds
    • Authors: Eduardo Guzmán; Ana Mateos-Maroto; Marta Ruano; Francisco Ortega; Ramón G. Rubio
      Pages: 290 - 307
      Abstract: Publication date: November 2017
      Source:Advances in Colloid and Interface Science, Volume 249
      Author(s): Eduardo Guzmán, Ana Mateos-Maroto, Marta Ruano, Francisco Ortega, Ramón G. Rubio
      Soft assemblies obtained following the Layer-by-Layer (LbL) approach are accounted among the most interesting systems for designing biomaterials and drug delivery platforms. This is due to the extraordinary versatility and flexibility offered by the LbL method, allowing for the fabrication of supramolecular multifunctional materials using a wide range of building blocks through different types of interactions (electrostatic, hydrogen bonds, acid-base or coordination interactions, or even covalent bonds). This provides the bases for the building of materials with different sizes, shapes, compositions and morphologies, gathering important possibilities for tuning and controlling the physico-chemical properties of the assembled materials with precision in the nanometer scale, and consequently creating important perspective for the application of these multifunctional materials as cargo systems in many areas of technological interest. This review studies different physico – chemical aspects associated with the assembly of supramolecular materials by the LbL method, paying special attention to the description of these aspects playing a central role in the application of these materials as cargo platforms for encapsulation and release of active compounds.
      Graphical abstract image

      PubDate: 2017-12-12T13:48:47Z
      DOI: 10.1016/j.cis.2017.04.009
      Issue No: Vol. 249 (2017)
       
  • Engineering and delivery of nanocolloids of hydrophobic drugs
    • Authors: Luyang Zhao; Guizhi Shen; Guanghui Ma; Xuehai Yan
      Pages: 308 - 320
      Abstract: Publication date: November 2017
      Source:Advances in Colloid and Interface Science, Volume 249
      Author(s): Luyang Zhao, Guizhi Shen, Guanghui Ma, Xuehai Yan
      A lot of efforts have been devoted to engineering the delivery of hydrophobic drugs due to the high demand of chemotherapy against cancer. While early developed liposomes and polymeric nanoparticles did not meet the requirements of high drug loading efficiency, pure drug nanoparticles appeared to meet these together with high stability. Current drug delivery systems demand an improved performance over the whole aspects of stability, loading capacity, and therapeutic effects. As a result, both new techniques based on traditional methods and totally new procedures are under investigation. In this review, we focus on the evaluation of pure drug nanolloids fabricated by different engineering protocols with emphasis on the size and morphology, delivery and controlled release, and therapeutic effects of these drug nanocolloids.
      Graphical abstract image

      PubDate: 2017-12-12T13:48:47Z
      DOI: 10.1016/j.cis.2017.04.008
      Issue No: Vol. 249 (2017)
       
  • A review on cationic lipids with different linkers for gene delivery
    • Authors: Defu Zhi; Yuchao Bai; Jian Yang; Shaohui Cui; Yinan Zhao; Huiying Chen; Shubiao Zhang
      Abstract: Publication date: Available online 26 December 2017
      Source:Advances in Colloid and Interface Science
      Author(s): Defu Zhi, Yuchao Bai, Jian Yang, Shaohui Cui, Yinan Zhao, Huiying Chen, Shubiao Zhang
      Cationic lipids have become known as one of the most versatile tools for the delivery of DNA, RNA and many other therapeutic molecules, and are especially attractive because they can be easily designed, synthesized and characterized. Most of cationic lipids share the common structure of cationic head groups and hydrophobic portions with linker bonds between both domains. The linker bond is an important determinant of the chemical stability and biodegradability of cationic lipid, and further governs its transfection efficiency and cytotoxicity. Based on the structures of linker bonds, they can be grouped into many types, such as ether, ester, amide, carbamate, disulfide, urea, acylhydrazone, phosphate, and other unusual types (carnitine, vinyl ether, ketal, glutamic acid, aspartic acid, malonic acid diamide and dihydroxybenzene). This review summarizes some research results concerning the nature (such as the structure and orientation of linker groups) and density (such as the spacing and the number of linker groups) of linker bond for improving the chemical stability, biodegradability, transfection efficiency and cytotoxicity of cationic lipid to overcome the critical barriers of in vitro and in vivo transfection.
      Graphical abstract image

      PubDate: 2017-12-27T07:11:37Z
      DOI: 10.1016/j.cis.2017.12.006
       
  • Advances in Self-Healing Materials Based on Vascular Networks with
           Mechanical Self-Repair Characteristics
    • Authors: Min Wook Lee; Seongpil An; Sam S. Yoon; Alexander L. Yarin
      Abstract: Publication date: Available online 24 December 2017
      Source:Advances in Colloid and Interface Science
      Author(s): Min Wook Lee, Seongpil An, Sam S. Yoon, Alexander L. Yarin
      Here, we review the state-of-the-art in the field of engineered self-healing materials. These materials mimic the functionalities of various natural materials found in the human body (e.g., the healing of skin and bones by the vascular system). The fabrication methods used to produce these “vascular-system-like” engineered self-healing materials, such as electrospinning (including co-electrospinning and emulsion spinning) and solution blowing (including coaxial solution blowing and emulsion blowing) are discussed in detail. Further, a few other approaches involving the use of hollow fibers are also described. In addition, various currently used healing materials/agents, such as dicyclopentadiene and Grubbs' catalyst, poly(dimethyl siloxane), and bisphenol-A-based epoxy, are described. We also review the characterization methods employed to verify the physical and chemical aspects of self-healing, that is, the methods used to confirm that the healing agent has been released and that it has resulted in healing, as well as the morphological changes induced in the damaged material by the healing agent. These characterization methods include different visualization and spectroscopy techniques and thermal analysis methods. Special attention is paid to the characterization of the mechanical consequences of self-healing. The effects of self-healing on the mechanical properties such as stiffness and adhesion of the damaged material are evaluated using the tensile test, double cantilever beam test, plane strip test, bending test, and adhesion test (e.g., blister test). Finally, the future direction of the development of these systems is discussed.
      Graphical abstract image

      PubDate: 2017-12-27T07:11:37Z
      DOI: 10.1016/j.cis.2017.12.010
       
  • Nanodarts, nanoblades, and nanospikes: Mechano-bactericidal nanostructures
           and where to find them
    • Authors: Nicholas Lin; Paula Berton; Christopher Moraes; Robin D. Rogers; Nathalie Tufenkji
      Abstract: Publication date: Available online 24 December 2017
      Source:Advances in Colloid and Interface Science
      Author(s): Nicholas Lin, Paula Berton, Christopher Moraes, Robin D. Rogers, Nathalie Tufenkji
      Over the past ten years, a next-generation approach to combat bacterial contamination has emerged: one which employs nanostructure geometry to deliver lethal mechanical forces causing bacterial cell death. In this review, we first discuss advances in both colloidal and topographical nanostructures shown to exhibit such “mechano-bactericidal” mechanisms of action. Next, we highlight work from pioneering research groups in this area of antibacterials. Finally, we provide suggestions for unexplored research topics that would benefit the field of mechano-bactericidal nanostructures. Traditionally, antibacterial materials are loaded with antibacterial agents with the expectation that these agents will be released in a timely fashion to reach their intended bacterial metabolic target at a sufficient concentration. Such antibacterial approaches, generally categorized as chemical-based, face design drawbacks as compounds diffuse in all directions, leach into the environment, and require replenishing. In contrast, due to their mechanisms of action, mechano-bactericidal nanostructures can benefit from sustainable opportunities. Namely, mechano-bactericidal efficacy needs not replenishing since they are not consumed metabolically, nor are they designed to release or leach compounds. For this same reason, however, their action is limited to the bacterial cells that have made direct contact with mechano-bactericidal nanostructures. As suspended colloids, mechano-bactericidal nanostructures such as carbon nanotubes and graphene nanosheets can pierce or slice bacterial membranes. Alternatively, surface topography such as mechano-bactericidal nanopillars and nanospikes can inflict critical membrane damage to microorganisms perched upon them, leading to subsequent cell lysis and death. Despite the infancy of this area of research, materials constructed from these nanostructures show remarkable antibacterial potential worthy of further investigation.
      Graphical abstract image

      PubDate: 2017-12-27T07:11:37Z
      DOI: 10.1016/j.cis.2017.12.007
       
  • The surface chemistry of sapphire-c: A literature review and a study on
           various factors influencing its IEP
    • Authors: J. Lützenkirchen; G.V. Franks; M. Plaschke; R. Zimmermann; F. Heberling; A. Abdelmonem; G.K. Darbha; D. Schild; A. Filby; P. Eng; J.G. Catalano; J. Rosenqvist; T. Preocanin; T. Aytug; D. Zhang; Y. Gan; B. Braunschweig
      Abstract: Publication date: Available online 13 December 2017
      Source:Advances in Colloid and Interface Science
      Author(s): J. Lützenkirchen, G.V. Franks, M. Plaschke, R. Zimmermann, F. Heberling, A. Abdelmonem, G.K. Darbha, D. Schild, A. Filby, P. Eng, J.G. Catalano, J. Rosenqvist, T. Preocanin, T. Aytug, D. Zhang, Y. Gan, B. Braunschweig
      A wide range of isoelectric points (IEPs) has been reported in the literature for sapphire-c (α-alumina), also referred to as basal plane, (001) or (0001), single crystals. Interestingly, the available data suggest that the variation of IEPs is comparable to the range of IEPs encountered for particles, although single crystals should be much better defined in terms of surface structure. One explanation for the range of IEPs might be the obvious danger of contaminating the small surface areas of single crystal samples while exposing them to comparatively large solution reservoirs. Literature suggests that factors like origin of the sample, sample treatment or the method of investigation all have an influence on the surfaces and it is difficult to clearly separate the respective, individual effects. In the present study, we investigate cause-effect relationships to better understand the individual effects. The reference IEP of our samples is between 4 and 4.5. High temperature treatment tends to decrease the IEP of sapphire-c as does UV treatment. Increasing the initial miscut (i.e. the divergence from the expected orientation of the crystal) tends to increase the IEP as does plasma cleaning, which can be understood assuming that the surfaces have become less hydrophobic due to the presence of more and/or larger steps with increasing miscut or due to amorphisation of the surface caused by plasma cleaning. Pre-treatment at very high pH caused an increase in the IEP. Surface treatments that led to IEPs different from the stable value of reference samples typically resulted in surfaces that were strongly affected by subsequent exposure to water. The streaming potential data appear to relax to the reference sample behavior after a period of time of water exposure. Combination of the zeta-potential measurements with AFM investigations support the idea that atomically smooth surfaces exhibit lower IEPs, while rougher surfaces (roughness on the order of nanometers) result in higher IEPs compared to reference samples. Two supplementary investigations resulted in either surprising or ambiguous results. On very rough surfaces (roughness on the order of micrometers) the IEP lowered compared to the reference sample with nanometer-scale roughness and transient behavior of the rough surfaces was observed. Furthermore, differences in the IEP as obtained from streaming potential and static colloid adhesion measurements may suggest that hydrodynamics play a role in streaming potential experiments. We finally relate surface diffraction data from previous studies to possible interpretations of our electrokinetic data to corroborate the presence of a water film that can explain the low IEP. Calculations show that the surface diffraction data are in line with the presence of a water film, however, they do not allow to unambiguously resolve critical features of this film which might explain the observed surface chemical characteristics like the dangling OH-bond reported in sum frequency generation studies. A broad literature review on properties of related surfaces shows that the presence of such water films could in many cases affect the interfacial properties. Persistence or not of the water film can be crucial. The presence of the water film can in principle affect important processes like ice-nucleation, wetting behavior, electric charging, etc.
      Graphical abstract image

      PubDate: 2017-12-27T07:11:37Z
      DOI: 10.1016/j.cis.2017.12.004
       
  • Improving emulsion formation, stability and performance using mixed
           emulsifiers: A review
    • Authors: David Julian McClements; Seid Mahdi Jafari
      Abstract: Publication date: Available online 9 December 2017
      Source:Advances in Colloid and Interface Science
      Author(s): David Julian McClements, Seid Mahdi Jafari
      The formation, stability, and performance of oil-in-water emulsions may be improved by using combinations of two or more different emulsifiers, rather than an individual type. This article provides a review of the physicochemical basis for the ability of mixed emulsifiers to enhance emulsion properties. Initially, an overview of the most important physicochemical properties of emulsifiers is given, and then the nature of emulsifier interactions in solution and at interfaces is discussed. The impact of using mixed emulsifiers on the formation and stability of emulsions is then reviewed. Finally, the impact of using mixed emulsifiers on the functional performance of emulsifiers is given, including gastrointestinal fate, oxidative stability, antimicrobial activity, and release characteristics. This information should facilitate the selection of combinations of emulsifiers that will have improved performance in emulsion-based products.
      Graphical abstract image

      PubDate: 2017-12-12T13:48:47Z
      DOI: 10.1016/j.cis.2017.12.001
       
  • Fundamental interfacial mechanisms underlying electrofreezing
    • Authors: Palash V. Acharya; Vaibhav Bahadur
      Abstract: Publication date: Available online 8 December 2017
      Source:Advances in Colloid and Interface Science
      Author(s): Palash V. Acharya, Vaibhav Bahadur
      This article reviews the fundamental interfacial mechanisms underlying electrofreezing (promotion of ice nucleation via the application of an electric field). Electrofreezing has been an active research topic for many decades, with applications in food preservation, cryopreservation, cryogenics and hydrate formation. There is substantial literature detailing experimental and simulations-based studies, which aim to understand the complex mechanisms underlying accelerated ice nucleation in the presence of electric fields and electrical charge. This work provides a critical review of all such studies. It is noted that application-focused studies of electrofreezing are excluded from this review; such studies have been previously reviewed in literature. This review focuses only on fundamental studies, which analyze the physical mechanisms underlying electrofreezing. Topics reviewed include experimental studies on electrofreezing (DC and AC electric fields), pyroelectricity-based control of freezing, molecular dynamics simulations of electrofreezing, and thermodynamics-based explanations of electrofreezing. Overall, it is seen that while electrofreezing can enable disruptive advancements in the control of liquid-to-solid phase change, our current understanding of the underlying mechanisms can be significantly improved through further studies of various interfacial effects coming into play.
      Graphical abstract image

      PubDate: 2017-12-12T13:48:47Z
      DOI: 10.1016/j.cis.2017.12.003
       
  • Nanotherapy for Alzheimer's disease and vascular dementia: Targeting
           senile endothelium
    • Authors: Joseph DArrigo
      Abstract: Publication date: Available online 8 December 2017
      Source:Advances in Colloid and Interface Science
      Author(s): Joseph S. D'Arrigo
      Due to the complexity of Alzheimer's disease, multiple cellular types need to be targeted simultaneously in order for a given therapy to demonstrate any major effectiveness. Ultrasound-sensitive coated microbubbles (in a targeted lipid nanoemulsion) are available. Versatile small molecule drug(s) targeting multiple pathways of Alzheimer's disease pathogenesis are known. By incorporating such drug(s) into the targeted “lipid-coated microbubble” [LCM]/“nanoparticle-derived” [ND] (or LCM/ND) nanoemulsion type, one obtains a multitasking combination therapeutic for translational medicine. This multitasking therapeutic targets cell-surface scavenger receptors (mainly class B type I), or SR-BI, making possible for various Alzheimer's-related cell types to be simultaneously searched out for localized drug treatment in vivo. Besides targeting cell-surface SR-BI, the proposed LCM/ND-nanoemulsion combination therapeutic(s) include a characteristic lipid-coated microbubble [LCM] subpopulation (i.e., a stable LCM suspension); such film-stabilized microbubbles are well known to substantially reduce the acoustic power levels needed for accomplishing temporary noninvasive (transcranial) ultrasound treatment, or sonoporation, if additionally desired for the Alzheimer's patient.
      Graphical abstract image

      PubDate: 2017-12-12T13:48:47Z
       
  • ifc (ed board)
    • Abstract: Publication date: November 2017
      Source:Advances in Colloid and Interface Science, Volume 249


      PubDate: 2017-12-12T13:48:47Z
       
  • special contents
    • Abstract: Publication date: November 2017
      Source:Advances in Colloid and Interface Science, Volume 249


      PubDate: 2017-12-12T13:48:47Z
       
  • Hardening of particle/oil/water suspensions due to capillary bridges:
           Experimental yield stress and theoretical interpretation
    • Authors: Krassimir D. Danov; Mihail T. Georgiev; Peter A. Kralchevsky; Gergana M. Radulova; Theodor D. Gurkov; Simeon D. Stoyanov; Eddie G. Pelan
      Abstract: Publication date: Available online 21 November 2017
      Source:Advances in Colloid and Interface Science
      Author(s): Krassimir D. Danov, Mihail T. Georgiev, Peter A. Kralchevsky, Gergana M. Radulova, Theodor D. Gurkov, Simeon D. Stoyanov, Eddie G. Pelan
      Suspensions of colloid particles possess the remarkable property to solidify upon the addition of minimal amount of a second liquid that preferentially wets the particles. The hardening is due to the formation of capillary bridges (pendular rings), which connect the particles. Here, we review works on the mechanical properties of such suspensions and related works on the capillary-bridge force, and present new rheological data for the weakly studied concentration range 30–55 vol% particles. The mechanical strength of the solidified capillary suspensions, characterized by the yield stress Y, is measured at the elastic limit for various volume fractions of the particles and the preferentially wetting liquid. A quantitative theoretical model is developed, which relates Y with the maximum of the capillary-bridge force, projected on the shear plane. A semi-empirical expression for the mean number of capillary bridges per particle is proposed. The model agrees very well with the experimental data and gives a quantitative description of the yield stress, which increases with the rise of interfacial tension and with the volume fractions of particles and capillary bridges, but decreases with the rise of particle radius and contact angle. The quantitative description of capillary force is based on the exact theory and numerical calculation of the capillary bridge profile at various bridge volumes and contact angles. An analytical formula for Y is also derived. The comparison of the theoretical and experimental strain at the elastic limit reveals that the fluidization of the capillary suspension takes place only in a deformation zone of thickness up to several hundred particle diameters, which is adjacent to the rheometer's mobile plate. The reported experimental results refer to water-continuous suspension with hydrophobic particles and oily capillary bridges. The comparison of data for bridges from soybean oil and hexadecane surprisingly indicate that the yield strength is greater for the suspension with soybean oil despite its lower interfacial tension against water. The result can be explained with the different contact angles of the two oils in agreement with the theoretical predictions. The results could contribute for a better understanding, quantitative prediction and control of the mechanical properties of three-phase capillary suspensions solid/liquid/liquid.
      Graphical abstract image

      PubDate: 2017-11-24T16:14:09Z
      DOI: 10.1016/j.cis.2017.11.004
       
  • The flotation and adsorption of mixed collectors on oxide and silicate
           minerals
    • Authors: Longhua Xu; Jia Tian; Houqin Wu; Zhongyuan Lu; Wei Sun; Yuehua Hu
      Abstract: Publication date: Available online 11 November 2017
      Source:Advances in Colloid and Interface Science
      Author(s): Longhua Xu, Jia Tian, Houqin Wu, Zhongyuan Lu, Wei Sun, Yuehua Hu
      The analysis of flotation and adsorption of mixed collectors on oxide and silicate minerals is of great importance for both industrial applications and theoretical research. Over the past years, significant progress has been achieved in understanding the adsorption of single collectors in micelles as well as at interfaces. By contrast, the self-assembly of mixed collectors at liquid/air and solid/liquid interfaces remains a developing area as a result of the complexity of the mixed systems involved and the limited availability of suitable analytical techniques. In this work, we systematically review the processes involved in the adsorption of mixed collectors onto micelles and at interface by examining four specific points, namely, theoretical background, factors that affect adsorption, analytical techniques, and self-assembly of mixed surfactants at the mineral/liquid interface. In the first part, the theoretical background of collector mixtures is introduced, together with several core solution theories, which are classified according to their application in the analysis of physicochemical properties of mixed collector systems. In the second part, we discuss the factors that can influence adsorption, including factors related to the structure of collectors and environmental conditions. We summarize their influence on the adsorption of mixed systems, with the objective to provide guidance on the progress achieved in this field to date. Advances in measurement techniques can greatly promote our understanding of adsorption processes. In the third part, therefore, modern techniques such as optical reflectometry, neutron scattering, neutron reflectometry, thermogravimetric analysis, fluorescence spectroscopy, ultrafiltration, atomic force microscopy, analytical ultracentrifugation, X-ray photoelectron spectroscopy, Vibrational Sum Frequency Generation Spectroscopy and molecular dynamics simulations are introduced in virtue of their application. Finally, focusing on oxide and silicate minerals, we review and summarize the flotation and adsorption of three most widely used mixed surfactant systems (anionic–cationic, anionic–nonionic, and cationic–nonionic) at the liquid/mineral interface in order to fully understand the self-assembly progress. In the end, the paper gives a brief future outlook of the possible development in the mixed surfactants.
      Graphical abstract image

      PubDate: 2017-11-11T14:37:13Z
      DOI: 10.1016/j.cis.2017.11.003
       
  • Surface self-assembly of colloidal crystals for micro- and nano-patterning
    • Authors: Ryan van Dommelen; Paola Fanzio; Luigi Sasso
      Abstract: Publication date: Available online 8 November 2017
      Source:Advances in Colloid and Interface Science
      Author(s): Ryan van Dommelen, Paola Fanzio, Luigi Sasso
      The controlled patterning of polymeric surfaces at the micro- and nanoscale offers potential in the technological development of small-scale devices, particularly within the fields of photovoltaics, micro-optics and lab- and organ-on-chip, where the topological arrangement of the surface can influence a system's power generation, optical properties or biological function - such as, in the latter case, biomimicking surfaces or topological control of cellular differentiation. One of the most promising approaches in reducing manufacturing costs and complexity is by exploitation of the self-assembling properties of colloidal particles. Self-assembly techniques can be used to produce colloidal crystals onto surfaces, which can act as replicative masks, as has previously been demonstrated with colloidal lithography, or templates in mold-replication methods with resolutions dependent on particle size. Within this context, a particular emerging interest is focused on the use of self-assembled colloidal crystal surfaces in polymer replication methods such as soft lithography, hot and soft embossing and nano-imprint lithography, offering low-cost and high-resolution alternatives to conventional lithographic techniques. However, there are still challenges to overcome for this surface patterning approach to reach a manufacturing reliability and process robustness comparable to competitive technologies already available in the market, as self-assembly processes are not always 100% effective in organizing colloids within a structural pattern onto the surface. Defects often occur during template fabrication. Furthermore, issues often arise mainly at the interface between colloidal crystals and other surfaces and substrates. Particularly when utilized in high-temperature pattern replication processes, poor adhesion of colloidal particles onto the substrate results in degradation of the patterning template. These effects can render difficulties in creating stable structures with little defect that are well controlled such that a large variety of shapes can be reproduced reliably. This review presents an overview of available self-assembly methods for the creation of colloidal crystals, organized by the type of forces governing the self-assembly process: fluidic, physical, external fields, and chemical. The main focus lies on the use of spherical particles, which are favorable due to their high commercial availability and ease of synthesis. However, also shape-anisotropic particle self-assembly will be introduced, since it has recently been gaining research momentum, offering a greater flexibility in terms of patterning. Finally, an overview is provided of recent research on the fabrication of polymer nano- and microstructures by making use of colloidal self-assembled templates.
      Graphical abstract image

      PubDate: 2017-11-11T14:37:13Z
      DOI: 10.1016/j.cis.2017.10.007
       
  • Fluorescence enhancement for noble metal nanoclusters
    • Authors: Dan Li; Zhenhua Chen; Xifan Mei
      Abstract: Publication date: Available online 7 November 2017
      Source:Advances in Colloid and Interface Science
      Author(s): Dan Li, Zhenhua Chen, Xifan Mei
      Noble metal nanoclusters have attracted great attentions in the area of fluorescence related applications due to their special properties such as low toxicity, excellent photostability and bio-compatibility. However, they still describe disadvantages for low quantum yield compared to quantum dots and organic dyes though the brightness of the fluorescence play an important role for the efficiency of the applications. Attentions have been attracted for exploring strategies to enhance the fluorescence based on the optical fundamentals through various protocols. Some methods have already been successfully proposed for obtaining relative highly fluorescent nanoclusters, which will potentially describe advantages for the application. In this review, we summarize the approach for enhancement of the fluorescence of the nanoclusters based on the modification of the properties, improvement of the synthesis process and optimization of the environment. The limitation and directions for future development of the fabrication of highly fluorescent metal nanoclusters are demonstrated.
      Graphical abstract image

      PubDate: 2017-11-11T14:37:13Z
      DOI: 10.1016/j.cis.2017.11.001
       
  • Physico-chemistry of bacterial transmission versus adhesion
    • Authors: Niar Gusnaniar; Henny C. van der Mei; Wenwen Qu; Titik Nuryastuti; Johanna M.M. Hooymans; Jelmer Sjollema; Henk J. Busscher
      Abstract: Publication date: Available online 5 November 2017
      Source:Advances in Colloid and Interface Science
      Author(s): Niar Gusnaniar, Henny C. van der Mei, Wenwen Qu, Titik Nuryastuti, Johanna M.M. Hooymans, Jelmer Sjollema, Henk J. Busscher
      Bacterial adhesion is a main problem in many biomedical, domestic, natural and industrial environments and forms the onset of the formation of a biofilm, in which adhering bacteria grow into a multi-layered film while embedding themselves in a matrix of extracellular polymeric substances. It is usually assumed that bacterial adhesion occurs from air or by convective-diffusion from a liquid suspension, but often bacteria adhere by transmission from a bacterially contaminated donor to a receiver surface. Therewith bacterial transmission is mechanistically different from adhesion, as it involves bacterial detachment from a donor surface followed by adhesion to a receiver one. Transmission is further complicated when the donor surface is not covered with a single layer of adhering bacteria but with a multi-layered biofilm, in which case bacteria can be transmitted either by interfacial failure at the biofilm-donor surface or through cohesive failure in the biofilm. Transmission through cohesive failure in a biofilm is more common than interfacial failure. The aim of this review is to oppose surface thermodynamics and adhesion force analyses, as can both be applied towards bacterial adhesion, with their appropriate extensions towards transmission. Opposition of surface thermodynamics and adhesion force analyses, will allow to distinguish between transmission of bacteria from a donor covered with a (sub)monolayer of adhering bacteria or a multi-layered biofilm. Contact angle measurements required for surface thermodynamic analyses of transmission are of an entirely different nature than analyses of adhesion forces, usually measured through atomic force microscopy. Nevertheless, transmission probabilities based on Weibull analyses of adhesion forces between bacteria and donor and receiver surfaces, correspond with the surface thermodynamic preferences of bacteria for either the donor or receiver surface. Surfaces with low adhesion forces such as polymer-brush coated or nanostructured surfaces are thus preferable for use as non-adhesive receiver surfaces, but at the same time should be avoided for use as a donor surface. Since bacterial transmission occurs under a contact pressure between two surfaces, followed by their separation under tensile or shear pressure and ultimately detachment, this will affect biofilm structure. During the compression phase of transmission, biofilms are compacted into a more dense film. After transmission, and depending on the ability of the bacterial strain involved to produce extracellular polymeric substances, biofilm left-behind on a donor or transmitted to a receiver surface will relax to its original, pre-transmission structure owing to the viscoelasticity of the extracellular polymeric substances matrix, when present. Apart from mechanistic differences between bacterial adhesion and transmission, the low numbers of bacteria generally transmitted require careful selection of suitably sensitive enumeration methods, for which culturing and optical coherence tomography are suggested. Opposing adhesion and transmission as done in this review, not only yields a better understanding of bacterial transmission, but may stimulate researchers to more carefully consider whether an adhesion or transmission model is most appropriate in the specific area of application aimed for, rather than routinely relying on adhesion models.
      Graphical abstract image

      PubDate: 2017-11-11T14:37:13Z
      DOI: 10.1016/j.cis.2017.11.002
       
  • Water adsorption on carbon - A review
    • Authors: Lumeng Liu; Shiliang (Johnathan) Tan; Toshihide Horikawa; D.D. Do; D. Nicholson; Junjie Liu
      Abstract: Publication date: Available online 2 November 2017
      Source:Advances in Colloid and Interface Science
      Author(s): Lumeng Liu, Shiliang (Johnathan) Tan, Toshihide Horikawa, D.D. Do, D. Nicholson, Junjie Liu
      Water adsorption on carbonaceous materials has been studied increasingly in the recent years, not only because of its impact on many industrial processes, but also motivated by a desire to understand, at a fundamental level, the distinctive character of directional interactions between water molecules, and between water molecules and other polar groups, such as the functional groups (FGs) at the surfaces of graphene layers. This paper presents an extensive review of recent experimental and theoretical work on water adsorption on various carbonaceous materials, with the aim of gaining a better understanding of how water adsorption in carbonaceous materials relates to the concentration of FGs, their topology (arrangement of the groups) and the structure of the confined space in porous carbons. Arising from this review we are able to propose mechanisms for water adsorption in carbonaceous materials as the adsorbate density increases. The intricate interplay between the roles of FGs and confinement makes adsorption of water on carbon materials very different from that of other simple molecules.
      Graphical abstract image

      PubDate: 2017-11-11T14:37:13Z
      DOI: 10.1016/j.cis.2017.10.002
       
  • Complex coacervation in charge complementary biopolymers: Electrostatic
           versus surface patch binding
    • Authors: Jyotsana Pathak; Eepsita Priyadarshini; Kamla Rawat; H.B. Bohidar
      Abstract: Publication date: Available online 3 November 2017
      Source:Advances in Colloid and Interface Science
      Author(s): Jyotsana Pathak, Eepsita Priyadarshini, Kamla Rawat, H.B. Bohidar
      In this review, a number of systems are described to demonstrate the effect of polyelectrolyte chain stiffness (persistence length) on the coacervation phenomena, after we briefly review the field. We consider two specific types of complexation/coacervation: in the first type, DNA is used as a fixed substrate binding to flexible polyions such as gelatin A, bovine serum albumin and chitosan (large persistence length polyelectrolyte binding to low persistence length biopolymer), and in the second case, different substrates such as gelatin A, bovine serum albumin, and chitosan were made to bind to a polyion gelatin B (low persistence length substrate binding to comparable persistence length polyion). Polyelectrolyte chain flexibility was found to have remarkable effect on the polyelectrolyte-protein complex coacervation. The competitive interplay of electrostatic versus surface patch binding (SPB) leading to associative interaction followed by complex coacervation between these biopolymers is elucidated. We modelled the SPB interaction in terms of linear combination of attractive and repulsive Coulombic forces with respect to the solution ionic strength. The aforesaid interactions were established via a universal phase diagram, considering the persistence length of polyion as the sole independent variable.
      Graphical abstract image

      PubDate: 2017-11-05T14:21:28Z
      DOI: 10.1016/j.cis.2017.10.006
       
  • Polyoxyethylene alkyl ether carboxylic acids: an overview of a neglected
           class of surfactants with multiresponsive properties
    • Authors: Leonardo Chiappisi
      Abstract: Publication date: Available online 13 October 2017
      Source:Advances in Colloid and Interface Science
      Author(s): Leonardo Chiappisi
      In this work, an overview on aqueous solutions of polyoxyethylene alkyl ether carboxylic acids is given. Unique properties arise from the combination of the nonionic, temperature-responsive polyoxyethylene block with the weakly ionic, pH-responsive carboxylic acid termination in a single surfactant headgroup. Accordingly, this class of surfactant finds broad application across very different sectors. Despite their large use on an industrial and a technical scale, the literature lacks a systematic and detailed characterization of their physico-chemical properties which is provided herein. In addition, a comprehensive overview is given of their self-assembly and interfacial behavior, of their use as colloidal building blocks and for large-scale applications.
      Graphical abstract image

      PubDate: 2017-10-14T15:05:32Z
      DOI: 10.1016/j.cis.2017.10.001
       
  • Durable superhydrophobic and superamphiphobic polymeric surfaces and their
           applications: A review
    • Authors: Kosmas Ellinas; Angeliki Tserepi; Evangelos Gogolides
      Abstract: Publication date: Available online 1 October 2017
      Source:Advances in Colloid and Interface Science
      Author(s): Kosmas Ellinas, Angeliki Tserepi, Evangelos Gogolides
      Wetting control is essential for many applications, such as self-cleaning, anti-icing, anti-fogging, antibacterial action as well as anti-reflection and friction control. While significant effort has been devoted to fabricate superhydrophobic/superamphiphobic surfaces (repellent to water and other low surface tension liquids), very few polymeric superhydrophobic/superamphiphobic surfaces can be considered as durable against various externally imposed stresses (e.g. application of heating, pressure, mechanical forces, chemical, etc.). Therefore, durability tests are extremely important for applications especially when such surfaces are made of “soft” materials. Here, we review the most recent and promising efforts reported towards the realization of durable, superhydrophobic/superamphiphobic, polymeric surfaces emphasizing the durability tests performed, and some important applications. We compare and put in context the scattered durability tests reported in the literature, and present conclusions, perspectives and challenges in the field.
      Graphical abstract image

      PubDate: 2017-10-08T12:38:10Z
      DOI: 10.1016/j.cis.2017.09.003
       
  • Macroion adsorption—Electrokinetic and optical methods
    • Authors: Aneta Michna
      Abstract: Publication date: Available online 29 September 2017
      Source:Advances in Colloid and Interface Science
      Author(s): Aneta Michna
      Recent studies on macroion adsorption at solid/liquid interfaces evaluated by electrokinetic and optical methods are reviewed. In the first section a description of electrokinetic phenomena at a solid surface is briefly outlined. Various methods for determining both static and dynamic properties of the electrical double layer, such as the appropriate location of the slip plane, are presented. Theoretical approaches are discussed concerning quantitative interpretation of streaming potential/current measurements of homogeneous macroscopic interfaces, both bare and formed by microsphere adsorption. Experimental results are presented, involving electrokinetic characteristics of bare surfaces, such as mica, silicon, glass etc. obtained from various types of electrokinetic cells. The surface conductivity effect on zeta potential is underlined. In the next section, various theoretical approaches, proposed to determine a distribution of electrostatic potential and flow distribution within macroion layers, are discussed. Accordingly, the influence of the uniform as well as non-uniform distribution of charges within macroion layer, the dissociation degree, and the surface conductance on electrokinetic parameters are discussed. The principles, the advantages and limits of optical techniques as well as AFM are briefly discussed in Section 4. The last section is devoted to the discussion of experimental data obtained by streaming potential/current measurements and optical methods, such as reflectometry, ellipsometry, surface plasmon resonance (SPR), colloid enhancement, and fluorescence technique, for mono- and multilayers of macroions. Results of polycations (PEI, PAMAM dendrimers, PAH, PDADMAC) and polyanions (PAA, PSS) adsorption on mica, silicon, gold, and PTFE are quantitatively interpreted in terms of theoretical approaches postulating the three dimensional charge distribution or the random sequential adsorption model (RSA). Macroion bilayer formation, experimentally examined by streaming current measurements, and theoretically interpreted in terms of the comprehensive formalism is also reviewed. The utility of electrokinetic measurements, combined with optical methods, for a precise, in situ characteristics of macroion mono- and multilayer formation at solid/liquid interfaces is pointed out.
      Graphical abstract image

      PubDate: 2017-09-30T10:37:34Z
      DOI: 10.1016/j.cis.2017.09.004
       
  • Surface modification using TEMPO and its derivatives
    • Authors: Megiel
      Abstract: Publication date: Available online 20 September 2017
      Source:Advances in Colloid and Interface Science
      Author(s): Elżbieta Megiel
      This article provides an overview of the methods for surface modification based on the use of stable radicals: 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and its derivatives. Two approaches are discussed. The first relies on the immobilization of TEMPO moieties on the surface of various materials including silicon wafers, silica particles, organic polymers as well as diverse nanomaterials. Applications of such materials with spin labeled surface/interface, in (electro)catalysis, synthesis of novel hybrid nanostructures and nanocomposites as well as in designing of organic magnets and novel energy storage devices are also included in the discussion. The second approach utilizes TEMPO and its derivatives for the grafting of polymer chains and polymer brushes formation on flat and nanostructure surfaces via Nitroxide Mediated Radical Polymerization (NMRP). The influence of such polymer modification on surface/interface physicochemical properties is also presented.
      Graphical abstract image

      PubDate: 2017-09-23T16:27:19Z
       
  • Functional polymer materials affecting cell attachment
    • Authors: Bo Jiang; Jian Yang; Nahla Rahoui; Nadia Taloub; Yu Dong Huang
      Abstract: Publication date: Available online 14 September 2017
      Source:Advances in Colloid and Interface Science
      Author(s): Bo Jiang, Jian Yang, Nahla Rahoui, Nadia Taloub, Yu Dong Huang
      This review discusses the functional polymer materials effect on the cell adhesion. The applied polymer materials for the cell adhesion purpose was prepared based on organic fibers and biocompatible hydrogel. On the other hand, the active peptides are incorporated into the polymer materials substrate via the cysteine-containing peptides and N-hydroxysuccinimide-active group. Cancer cells and normal cells were presented for the selective adhesion via the introduced polymer materials substrate containing active peptides including Arginine–Glycine-Aspartic and Isoleucine-Lysine–Valine-Alanine–Valine sequence peptides. This selectivity is revealed by a significant cooperativity between specific and non-specific cell adhesion. This study is of a great impact for the design of the polymeric structures for cell attachment.
      Graphical abstract image

      PubDate: 2017-09-17T15:52:00Z
      DOI: 10.1016/j.cis.2017.09.002
       
  • Functionalization of single solid state nanopores to mimic biological ion
           channels: A review
    • Authors: Mathilde Lepoitevin; Tianji Ma; Mikhael Bechelany; Jean-Marc-Janot; Sebastien Balme
      Abstract: Publication date: Available online 14 September 2017
      Source:Advances in Colloid and Interface Science
      Author(s): Mathilde Lepoitevin, Tianji Ma, Mikhael Bechelany, Jean-Marc-Janot, Sebastien Balme
      In nature, ion channels are highly selective pores and act as gate to ensure selective ion transport, allowing ions to cross the membrane. By mimicking them, single solid state nanopore devices emerge as a new, powerful class of molecule sensors that allow for the label-free detection of biomolecules (DNA, RNA, and proteins), non-biological polymers, as well as small molecules. In this review, we exhaustively describe the fabrication and functionalization techniques to design highly robust and selective solid state nanopores. First we outline the different materials and methods to design nanopores, we explain the ionic conduction in nanopores, and finally we summarize some techniques to modify and functionalize the surface in order to obtain biomimetic nanopores, responding to different external stimuli.
      Graphical abstract image

      PubDate: 2017-09-17T15:52:00Z
      DOI: 10.1016/j.cis.2017.09.001
       
  • A critical review on the prospect of polyaniline-grafted biodegradable
           nanocomposite
    • Authors: Mohammad Shahadat; Mohammad Zain Khan; Parveen Fatimah Rupani; Asha Embrandiri; Saima Sultana; Z.A. Shaikh; S. Wazed Ali; T.R. Sreekrishnan
      Abstract: Publication date: Available online 6 September 2017
      Source:Advances in Colloid and Interface Science
      Author(s): Mohammad Shahadat, Mohammad Zain Khan, Parveen Fatimah Rupani, Asha Embrandiri, Saima Sultana, Z.A. Shaikh, S. Wazed Ali, T.R. Sreekrishnan
      Among the various electrically conducting polymers, polyaniline (PANI) has gained attentions due to its unique properties and doping chemistry. A number of electrically conducting biodegradable polymers has been synthesized by incorporating a biodegradable content of cellulose, chitin, chitosan, etc. in the matrix of PANI. The hybrid materials are also employed as photocatalysts, antibacterial agents, sensors, fuel cells and as materials in biomedical applications. Furthermore, these biodegradable and biocompatible conducting polymers are employed in tissue engineering, dental implants and targeted drug delivery. This review presents state of the art of PANI based biodegradable polymers along with their synthesis routes and unique applications in diverse fields. In future, the synthesis of PANI-grafted biodegradable nanocomposite material is expected to open innovative ways for their outstanding applications.
      Graphical abstract image

      PubDate: 2017-09-09T15:28:50Z
      DOI: 10.1016/j.cis.2017.08.006
       
 
 
JournalTOCs
School of Mathematical and Computer Sciences
Heriot-Watt University
Edinburgh, EH14 4AS, UK
Email: journaltocs@hw.ac.uk
Tel: +00 44 (0)131 4513762
Fax: +00 44 (0)131 4513327
 
Home (Search)
Subjects A-Z
Publishers A-Z
Customise
APIs
Your IP address: 54.196.145.24
 
About JournalTOCs
API
Help
News (blog, publications)
JournalTOCs on Twitter   JournalTOCs on Facebook

JournalTOCs © 2009-