JournalTOCs

Chemical Communications
Journal Prestige (SJR): 2.555

Citation Impact (citeScore): 6
Number of Followers: 83

Hybrid journal (It can contain Open Access articles)
ISSN (Print) 1359-7345 - ISSN (Online) 1364-548X
Published by RSC

[50 journals]

Selective Anion Sensing in High Salt Water via a Remote Indicator
Displacement Assay
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC01974H, CommunicationBriana L Hickey, Alexie Andrea P. Raz, Junyi Chen, Jose L. Moreno, Joshua D Hartman, Wenwan Zhong, Richard James Hooley
  Water-soluble deep cavitands with cationic functions at the lower rim can selectively bind iodide anions in purely aqueous solution. By pairing this lower rim recognition with an indicator dye that...
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Correction: Reinforced hydrogel network building by a rapid
dual-photo-coupling reaction for 3D printing
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  Abstract: Chem. Commun., 2023, Advance Article
  
  DOI : 10.1039/D3CC90186F, Correction Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Renjie Zhou, Yujie Hua, Lipeng Yang, Bingkun Bao, Qiuning Lin, Linyong Zhu
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Regulating structural asymmetry via fluorination engineering in hybrid
lead bromide perovskites
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC02098C, CommunicationHua-Yang Ru, Zhao-Yang Wang, Hua-Li Liu, Shuang-Quan Zang
  Here, we synthesized a pair of chiral two-dimensional lead bromide perovskite R-/S-(C3H7NF3)2PbBr4 (1R/2S) by H/F substitution strategy, which exhibit circular dichroism and CPL activity. Compared with one-dimensional non-centrosymmetric (C3H10N)3PbBr5 with...
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Gold-based Enantioselective Bimetallic Catalysis
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC01966G, HighlightNitin T. Patil, Shivhar B. Ambegave , Tushar R. More, Shubham NA
  Multimetallic catalysis is a powerful strategy to access complex molecular scaffolds efficiently from easily available starting materials. Numerous reports in the literature have demonstrated the effectiveness of this approach, particularly...
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Ring Expansion reactions of P=O-containing molecules
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC02087H, Communication Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Zhongzhen Yang, Jerry Tam, Jack Wootton, Jason Martin Lynam, William Paul Unsworth
  A series of ring expansion reactions of P=O-containing molecules have been developed for the synthesis of medium-sized ring cyclic phosphonate esters and phosphonamidates. The reactivity trends initially appear to be...
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Monomeric Lithium and Sodium Silylbenzyl Complexes: Syntheses, Structures,
and C=O bond Olefination
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC01376F, Communication Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jordan Barker, Nathan Davison, Paul G Waddell, Erli Lu
  Herein we report the syntheses, structures and reactivity studies of two new monomeric alkali metal silylbenzyl complexes stabilised by a tetradentate amine ligand, tris[2-(dimethylamino)ethyl]amine (Me6Tren). The two complexes, namely [MR’(Me6Tren)]...
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Cage-like structures based on constrained cyclic arylopeptoids
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC01956J, CommunicationAyman Akhdar, Lionel Nauton, Laurent Jouffret, Sophie Faure, Arnaud Gautier
  The access to cupola-like or tube-like structures from ortho- and meta-arylopeptoid macrocycles was explored through CuAAC reaction using a partially flexible bis(azide) and CuI-N-heterocyclic carbene as catalyst. NMR studies showed...
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A high-performance electrochemical biosensor using an engineered urate
oxidase
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC01869E, Communication Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zheng Wei, Tanja Knaus, Yuxin Liu, Ziran Zhai, Andrea Gargano , Gadi Rothenberg, Ning Yan, Francesco G. Mutti
  We constructed a high-performance biosensor for detecting uric acid by immobilizing an engineered urate oxidase on gold nanoparticles deposited on a carbon-glass electrode. This biosensor showed a low limit-of-detection (9.16...
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Hydroarylation of Alkynes via Dual ortho-C-H Functionalization of Diaryl
Amines on a Dicopper(I,I) Platform
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC01251D, CommunicationNilay Kumar Pal, Moumita Patra, Prabhakar K. Pandey, Jitendra K Bera
  A pyridine and morpholine-functionalized dicopper(I,I)-NHC complex (1) features both terminal and bridging coordination modes of NHC within the same molecule, and catalyzes dual ortho-C-H functionalization of diaryl amines for the...
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Coomassie brilliant blue G-250 acts as a potential chemical chaperone to
stabilize therapeutic insulin
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC01791E, CommunicationRanit Pariary, Sandip Dolui, Gourav Shome, Sk Abdul Mohid, Achintya Saha, Bhisma N Ratha, Amaravadhi Harikishore, Kuladip Jana, Atin K Mandal, Nakul Chandra Maiti, Anirban Bhunia
  Our studies show Coomassie Brilliant Blue G-250 as a promising chemical chaperone that stabilises the α-helical native human insulin conformers, disrupting its aggregation. Furthermore, it also increases the insulin secretion....
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Structural transition and chemical reactivity of atomic carbon chains
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  Abstract: Chem. Commun., 2023, Advance Article
  
  DOI : 10.1039/D3CC01711G, CommunicationSiyuan Fang, Xiao Tong, Dario Stacchiola, Yun Hang Hu
  The temperature-dependent reversible structural transition, chemical reactivities, and stabilization strategy of sp-hybridized atomic carbon chains were unprecedentedly demonstrated.
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Lanthanide-based logic: a venture for the future of molecular computing
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  Abstract: Chem. Commun., 2023, Advance Article
  
  DOI : 10.1039/D3CC01827J, Feature Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Sofia Zanella, Miguel A. Hernández-Rodríguez, Rute A. S. Ferreira, Carlos D. S. Brites
  This review critically examines the use of Ln3+-based molecular logic systems and discusses their potential integration into future molecular photonic-electronic hybrid systems.
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Understanding and managing peak shape for basic solutes in reversed-phase
high performance liquid chromatography
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  Abstract: Chem. Commun., 2023, Advance Article
  
  DOI : 10.1039/D3CC01535A, Feature ArticleDavid Victor McCalley
  In this feature article, the causes of low efficiency and peak asymmetry are discussed in reversed-phase high performance liquid chromatography, including the choices of stationary and mobile phases that can minimise these detrimental effects.
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Electrogenerated chemiluminescence at boron-doped diamond electrodes
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  Abstract: Chem. Commun., 2023, Advance Article
  
  DOI : 10.1039/D3CC01507F, Feature Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Andrea Fiorani, Giovanni Valenti, Francesco Paolucci, Yasuaki Einaga
  Electrogenerated chemiluminescence at boron-doped diamond electrodes is reviewed for systems involving either co-reactants or the in situ generation of co-reactants, and tris(bipyridine)ruthenium(II) or luminol, comprising immunoassay applications.
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Facet-dependence of Fe3O4 for enhancing osteogenic differentiation of
BMSCs
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  Abstract: Chem. Commun., 2023, 59,6742-6744
  
  DOI : 10.1039/D3CC00703K, CommunicationXinlin Wei, Fei Wang, Jie Tao, Jian Mao
  Herein, the facet-dependence of Fe3O4 for enhancing osteogenic differentiation is demonstrated for the first time.
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A dual-function probe with aggregation-induced emission feature for Cu2+
detection and chemodynamic therapy
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  Abstract: Chem. Commun., 2023, 59,6738-6741
  
  DOI : 10.1039/D2CC06350F, CommunicationJuan Fu, Xin Hu, Teng Guo, Weifeng Zhu, Jianwen Tian, Meiying Liu, Xiaoyong Zhang, Yen Wei
  Herein, a fluorescent probe (named TPACP) with aggregation-induced emission (AIE) feature was developed and utilized for the selective detection of Cu2+ with high sensitivity and fast-response.
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Single-atomic Fe sites decorated N-doped carbon toward oxygen reduction in
MFCs
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  Abstract: Chem. Commun., 2023, 59,6749-6752
  
  DOI : 10.1039/D3CC01415K, CommunicationCuie Zhao, Wei Luo, Haoran Tian, Tao Lu, Lei Yi, Ying Zhang, Li Shi, Yanwen Ma
  Atomically dispersed Fe–N4 sites embedded in an Fe–N–C catalyst play a significant role in enhancing the catalytic activity of the oxygen reduction reaction (ORR), enabling a high power-out performance in microbial fuel cells (MFCs).
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Synthesis and photochemical properties of caged peroxides for photocontrol
of cellular oxidative stress
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  Abstract: Chem. Commun., 2023, 59,6706-6709
  
  DOI : 10.1039/D3CC01192E, CommunicationMieko Tsuji, Haruno Taira, Taro Udagawa, Tatsuya Aoki, Tasuku Hirayama, Hideko Nagasawa
  We developed a caged hydroperoxide, BhcTBHP, releasing prooxidant TBHP under blue light irradiation.
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Applying deep learning to iterative screening of medium-sized molecules
for protein–protein interaction-targeted drug discovery
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  Abstract: Chem. Commun., 2023, 59,6722-6725
  
  DOI : 10.1039/D3CC01283B, Communication Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yugo Shimizu, Tomoki Yonezawa, Yu Bao, Junichi Sakamoto, Mariko Yokogawa, Toshio Furuya, Masanori Osawa, Kazuyoshi Ikeda
  Updating predicting models could greatly improve the hit rate of virtual screening for identifying Keap1/Nrf2 protein–protein interaction inhibitors.
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Chromic triboluminescence of self-assembled platinum(II) complexes
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  Abstract: Chem. Commun., 2023, 59,6745-6748
  
  DOI : 10.1039/D3CC01525D, CommunicationKono Sasaki, Daisuke Saito, Masaki Yoshida, Fuka Tanaka, Atsushi Kobayashi, Kazuki Sada, Masako Kato
  A Pt(II) complex bearing N-heterocyclic carbene exhibits chromic triboluminescence during the process of rubbing and also vapor exposure.
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Integrating resonance energy transfer with enzyme-triggered hydrolysis for
ultrasensitive electrochemiluminescence detection of exosomes
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  Abstract: Chem. Commun., 2023, 59,6753-6756
  
  DOI : 10.1039/D3CC01795H, CommunicationYuanyuan Wang, Xianwen Kan
  A facile electrochemiluminescence biosensor was constructed based on resonance energy transfer and enzyme-triggered hydrolysis for the ultrasensitive detection of exosomes.
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Molecular design of two-dimensional donor–acceptor covalent organic
frameworks for intramolecular singlet fission
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  Abstract: Chem. Commun., 2023, 59,6757-6760
  
  DOI : 10.1039/D3CC01554H, CommunicationMaria Fumanal
  The donor–acceptor copolymer strategy for intramolecular Singlet Fission is applied for the molecular design of functional 2D covalent organic frameworks.
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Solubilization of elemental sulfur by surfactants promotes reduction to
H2S by thiols
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  Abstract: Chem. Commun., 2023, 59,6702-6705
  
  DOI : 10.1039/D3CC01914D, CommunicationArman C. Garcia, Michael D. Pluth
  Surfactants solubilize S8 in water and promote thiol-mediated reduction to form H2S. Anionic and cationic surfactants have different impacts on the resultant reactive sulfur species distribution.
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Electrochemical C–F bond activation of trifluoromethylarenes using
silylium ions
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  Abstract: Chem. Commun., 2023, 59,6694-6697
  
  DOI : 10.1039/D3CC01850D, CommunicationSubhojit Mondal, Boris Stevanovic, Eric Butler, Jason W. Wang, Michael W. Meanwell
  We report a mild, electrochemical trihydrodefluorination (e-THDF) for breaking highly stable C–F bonds in trifluoromethyl arenes to form the corresponding methyl arene products.
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Enhanced interface stability of ammine magnesium borohydride by in situ
decoration of MgBr2·2NH3 nanoparticles
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  Abstract: Chem. Commun., 2023, 59,6726-6729
  
  DOI : 10.1039/D3CC00994G, CommunicationQian Wang, Zhaoyue Li, Hanyu Deng, Yungui Chen, Yigang Yan
  The in situ decoration of MgBr2·2NH3 nanoparticles with an average size of 3.7 nm on the surface of Mg(BH4)2·1.9NH3 offers long-term stability towards the Mg metal anode.
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Remote template effect in the synthesis of bipyridine-strapped porphyrins
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  Abstract: Chem. Commun., 2023, 59,6718-6721
  
  DOI : 10.1039/D3CC01697H, Communication Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Mathilde Berthe, Yoshiyuki Kagawa, Axel Riquet, Takashi Hayashi, Jean Weiss, Jennifer A. Wytko
  The use of a remote template improves the yields of bipyridine-strapped porphyrins by up to 10 times.
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Dealloying of Pt1Bi2 intermetallic toward optimization of electrocatalysis
on a Bi-continuous nanoporous core–shell structure
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  Abstract: Chem. Commun., 2023, 59,6730-6733
  
  DOI : 10.1039/D3CC01206A, CommunicationYacheng Wang, Wubin Wang, Wangyan Hu, Dongtang Zhang, Guangsheng Guo, Xiayan Wang
  During the process of dealloying, passivation of the particle surface by the migration of precious metals is prevented due to fluctuations on the surface.
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Direct synthesis of alkylated 4-hydroxycoumarin derivatives via a cascade
Cu-catalyzed dehydrogenation/conjugate addition sequence
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  Abstract: Chem. Commun., 2023, 59,6686-6689
  
  DOI : 10.1039/D3CC01960H, CommunicationZhiliang Chen, Hongyi Li, Yanjing Liao, Mengqi Wang, Weiping Su
  An efficient approach for the direct synthesis of alkylated 4-hydroxycoumarin derivatives via a Cu-catalyzed cascade dehydrogenation/conjugate addition sequence starting from simple saturated ketones and 4-hydroxycoumarins has been developed.
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Fluorescence detected circular dichroism (FDCD) of a stereodynamic probe
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  Abstract: Chem. Commun., 2023, 59,6714-6717
  
  DOI : 10.1039/D3CC01249B, Communication Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Roberto Penasa, Federico Begato, Giulia Licini, Klaus Wurst, Sergio Abbate, Giovanna Longhi, Cristiano Zonta
  Fluorescence detected circular dichroism (FDCD) has been used to determine e.e. of carboxylic acids at sensor concentrations down to 0.1 μM also in the presence of chiroptical active contaminants.
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Mechanism of rate controllability of water-soluble bifunctional
cyclooctadiynes through cation-anion interactions
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  Abstract: Chem. Commun., 2023, 59,6678-6681
  
  DOI : 10.1039/D3CC01356A, CommunicationMoeka Yoshinaga, Fumiya Sato, Kohei Kitagawa, Natsuki Yokota, Shogo Sasaki, Manami Takeuchi, Hiroshi Tsugawa, Kohtaro Sugahara, Shoko Mori, Masayuki Tera
  The rate-enhancement mechanism of the ion-pair-guided click reaction has been elucidated and applied to selective protein modification.
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Fluorescence labeling of extracellular vesicles for diverse
bio-applications in vitro and in vivo
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  Abstract: Chem. Commun., 2023, 59,6609-6626
  
  DOI : 10.1039/D3CC00998J, HighlightYun He, Yanlong Xing, Tongmeng Jiang, Juan Wang, Shenggang Sang, Hong Rong, Fabiao Yu
  We provide comprehensive highlights of the state-of-the-art studies on fluorescent labelling of EVs, covering the various labelling strategies, the biomedical application in vitro, and the study on EV biology in vivo based on bioimaging tools.
  The content of this RSS Feed (c) The Royal Society of Chemistry
Three-component regioselective carboamidation of 1,3-enynes via
rhodium(III)-catalyzed C–H activation
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  Abstract: Chem. Commun., 2023, 59,6690-6693
  
  DOI : 10.1039/D3CC01666H, CommunicationLingheng Kong, Xi Han, Panjie Hu, Fen Wang, Xingwei Li
  Rhodium-catalyzed regio- and stereoselective three-component carboamidation of 1,3-enynes has been realized using indoles and dioxazolones as the functionalizing reagents.
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TiFeNb10O29−δ anode for high-power and durable lithium-ion
batteries
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  Abstract: Chem. Commun., 2023, 59,6710-6713
  
  DOI : 10.1039/D3CC00678F, CommunicationGuangshuo Wang, Yuanyuan Sun, Yonghua Sun, Chao Yan, Yuepeng Pang, Tao Yuan, Shiyou Zheng
  TiFeNb10O29−δ has a Wadsley–Roth shear polycrystalline structure with larger lattice parameter and more defects, leading to improved e−/Li+ conductivity and a greater pseudocapacitance contribution. It achieves excellent electrochemical performance.
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3D graphene: synthesis, properties, and solar cell applications
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  Abstract: Chem. Commun., 2023, 59,6660-6673
  
  DOI : 10.1039/D3CC01004J, Feature ArticleHanrui Su, Yun Hang Hu
  This feature article summarizes the progress in 3D graphene materials for solar cells, highlighting their performance, challenges, and potential solutions.
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Quantitative NMR spectroscopy of complex mixtures
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  Abstract: Chem. Commun., 2023, 59,6627-6642
  
  DOI : 10.1039/D3CC01455J, Feature ArticlePatrick Giraudeau
  The latest developments and applications in highly accurate quantitative NMR of complex mixtures.
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Enhancing the gastrointestinal stability of salmon calcitonin through
peptide stapling
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  Abstract: Chem. Commun., 2023, 59,6682-6685
  
  DOI : 10.1039/D3CC01140B, CommunicationHiba Ghareeb, Norman Metanis
  Salmon calcitonin (sCT) is a polypeptide hormone available in the clinic.
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Förster resonance energy transfer involving the triplet state
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  Abstract: Chem. Commun., 2023, 59,6643-6659
  
  DOI : 10.1039/D3CC00748K, Feature ArticleBahadur Sk, Shuzo Hirata
  This feature article outlines the triplet harvesting via Förster resonance energy transfer (FRET) from both the fundamental aspects to emerging applications in optoelectronics and bioimaging.
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Reduction of 2-H-substituted pyrrolinium cations: the carbon–carbon
single bond in air stable 2,2′-bipyrrolidines as a two-electron-source
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  Abstract: Chem. Commun., 2023, 59,6698-6701
  
  DOI : 10.1039/D3CC00891F, CommunicationMithilesh Kumar Nayak, Benedict J. Elvers, Debdeep Mandal, Ayan Das, Raghunathan Ramakrishnan, Kaustubh R. Mote, Carola Schulzke, Cem Burak Yildiz, Anukul Jana
  2-Substituted pyrrolinium cations are reduced to air and moisture stable 2,2′-bipyrrolidines − the newly formed carbon–carbon single bond is electron-rich and may be utilized as an organic electron donor for various chemical transformations.
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Ultra-selective 1D clean in-phase correlation spectroscopy
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  Abstract: Chem. Commun., 2023, 59,6734-6737
  
  DOI : 10.1039/D3CC01333B, Communication Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Daniel A. Taylor, Peter Kiraly, Paul Bowyer, Mathias Nilsson, Laura Castañar, Gareth A. Morris, Ralph W. Adams
  GEMSTONE CLIP-COSY: a new NMR experiment for determination of the direct bonding network of nuclei whose NMR signals overlap.
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Green light enhanced the photostability and catalytic performance of fatty
acid photodecarboxylase
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  Abstract: Chem. Commun., 2023, 59,6674-6677
  
  DOI : 10.1039/D3CC00995E, CommunicationAo Xia, Xiaobo Guo, Yingxin Chai, Wuyuan Zhang, Yun Huang, Xianqing Zhu, Xun Zhu, Qiang Liao
  Green light improved the photostability of fatty acid photodecarboxylase (FAP) by reducing the generation of O2˙− and 1O2. Blue light facilitated the catalytic activity of FAP due to the high substrate affinity and low apparent activation energy.
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Beyond DNA: new probes for PAINT super-resolution microscopy
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC00757J, Feature Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Marrit Tholen, Roderick Tas, Yuyang Wang, Lorenzo Albertazzi
  In the last decade, point accumulation for imaging in nanoscale topography (PAINT) has emerged as a versatile tool for single-molecule localization microscopy (SMLM). Currently, DNA-PAINT is the most widely used,...
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On the Role of Wall Thickness in Determining the Plasmonic Properties of
Silver-Gold Nanocages
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC02068A, CommunicationShikuan Shao, Ankai Wang, Ria Gupta, Shengli Zou, Xiaohu Xia
  This work examines the roles played by wall thickness in determining the plasmonic properties of gold-silver (Ag-Au) nanocages. Ag-Au cages with different wall thicknesses, but the same void or outer...
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Activatable BODIPY-Chromene NIR-II probes with small spectral crosstalk
endow high-contrast in vivo bioimaging
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC01742G, CommunicationLiao Zhang, Chenxu Yan, Yutao Zhang, Dun Ma, Jialiang Huang, Zijun Zhao, Yining Tao, Caiqi Liu, Juan Li, Weihong Zhu, Zhiqian Guo
  Herein, we design a novel "crossbreeding" dye (BC-OH) within the second near-infrared (NIR-II) window based on BODIPY and Chromene chromophores. BC-OH can serve as a platform to construct activatable NIR-II...
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An activity-based fluorescent sensor with a penta-coordinate N-donor
binding site detects Cu ions in living systems
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC02201C, CommunicationKunika Gupta, Ankona Datta
  An activity-based sensor afforded a 63 times fluorescence-enhancement with Cu2+/Cu+ ions and could image Cu2+/Cu+ in living cells and in a multicellular organism. The sensor functioned only in presence of...
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In situ evaluation of in vivo sialylation with a dual-color imaging
strategy
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC01949G, CommunicationShiya Zhao, Yuanjiao Yang, Yuru Wang, Huipu Liu, Huangxian Ju, Yunlong Chen
  This work designs a functional dendrimer probe to conveniently identify the newly generated sialic acid groups in vivo with a dual-color imaging strategy, which achieves in situ semiquantitative evaluation of...
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Integrated separation and detection of exosomes via a label-free magnetic
SERS platform
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC01530K, CommunicationLingfei Han, Chengcheng Zhu, Zheng Tan, Jin Wang, Xuewei Liao, Xing-Hua Xia, Chen Wang
  A label-free magnetic surface enhanced Raman scattering (SERS) platform was constructed, which was composed of superparamagnetic Fe3O4 nanoparticles as cores for separation and an Au layer as shells for label-free...
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Enantioselective synthesis of 3a-azido-pyrroloindolines by
copper-catalyzed asymmetric dearomative azidation of tryptamines
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC01438J, CommunicationCheng-Zhou Lin, Ling-Feng Jiang, Guang-Yi Zhang, Fang-Shuai Zhou, Shao-Hua Wu, Jing Cao, Qing-Hai Deng
  Copper-catalyzed asymmetric dearomative azidation of tryptamines using azidobenziodoxolone as an azidating reagent was developed, which affords a variety of 3a-azido-pyrroloindolines in good to high enantioselectivities under mild reaction conditions. The...
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Cobalt/aluminum co-substitution in LiNi0.9Mn0.1O2 layered cathode for
improving kinetics
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC01099F, CommunicationZhiming Xiao, bao Zhang, Xinyou He, Xing Ou
  We report the improved kinetic mechanism of a nickel-rich LiNi0.84Mn0.10Co0.03Al0.03O2 cathode prepared by a wet co-precipitation process. The important role of Co and Al in inhibiting Li+/Ni2+ disorder to increase...
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Target-switched artificial biochemical circuit for a versatile and
sensitive colorimetric detection platform
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC01765F, CommunicationXianzhu Meng, Hui-Wen Gu, Xiaoli Yin, HongChao Yi, Ying Chen
  The presence of target causes the structure switch of a metastable hairpin template probe (MH) for triggering the self-primed artificial biochemical circuit to produce numerous DNAzyme replicates, which in turn...
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Dinuclear gold-catalyzed cyclization of 1,7-enynes with unactivated alkyl
bromides
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC02317F, CommunicationJin Xie, Jiajun Li, Xinyi Zhai, Cheng-Long Ji, Weipeng Li
  Dinuclear gold-catalyzed radical difunctionalization of alkyl bromides with 1,7-enynes has been established via dehalogenation and 1,5-HAT processes. This protocol leads to a facile and efficient construction of a wide range...
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Hydrogen production by traditional and novel alkaline water electrolysis
on Nickel or Iron based electrocatalysts
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC00996C, Feature ArticleRufei Zhang, Ao Xie, Linting Cheng, Zhiqun Bai, Yang Tang, Pingyu Wan
  Hydrogen production through alkaline water electrolysis holds great promise as a scalable solution for renewable energy storage and conversion. The development of non-precious metal-based electrocatalysts with low-overpotential for alkaline water...
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An azoreductase activatable, endonuclease-gated nanodevice for
spatiotemporal amplification imaging of microRNA-21 in hypoxic tumor cells
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  Abstract: Chem. Commun., 2023, Advance Article
  
  DOI : 10.1039/D3CC00980G, CommunicationCan Peng, Fan Wu, Youhui Zeng, Bo Liu, Ruiying Peng, Jing Zheng
  In this communication, we proposed an azoreductase activatable, endonuclease-gated fluorescent nanodevice for spatiotemporal amplification imaging of microRNA-21 in hypoxic tumor cells.
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Synthesis and structural evaluation of closed-shell folded and open-shell
twisted hexabenzo[5.6.7]quinarene
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC02157B, Communication Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Tomohiko Nishiuchi, Kazuyuki Uchida, Takashi Kubo
  We describe the synthesis and characterization of hexabenzo[5.6.7]quinarene, which is composed of an anthraquinodimethane (AQD) central core that is end-capped with fluorenyl and dibenzosuberenyl groups. Due to strong intramolecular spin-spin...
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Synthesis of complex aryl MIDA boronates by Rh-catalyzed [2+2+2]
cycloaddition
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC00761H, Communication Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.John Halford-McGuff, David Bradford Cordes, Allan John Bell Watson
  A Rh-catalyzed [2+2+2] cycloaddition approach for the synthesis of BMIDA-functionalized arenes is reported. The developed method overcomes the long-standing reactivity problems associated with internal alkynes and allows access to highly...
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Correction: Co-electrocatalytic CO2 reduction mediated by a
dibenzophosphole oxide and a chromium complex
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  Abstract: Chem. Commun., 2023, Advance Article
  
  DOI : 10.1039/D3CC90167J, Correction Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Connor A. Koellner, Amelia G. Reid, Charles W. Machan
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Rapid Post-Synthetic Modification of Porous Coordination Cages with
Copper-Catalyzed Click Chemistry
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC02015K, CommunicationMichael Dworzak, Christine M. Montone, Nicole Irene Halaszynski, Glenn P A Yap, Christopher Kloxin, Eric D Bloch
  Novel cobalt calixarene-capped and zirconium-based porous coordination cages were prepared with alkyne and azide functionality to leverage post-synthetic modification by click chemistry. While the calixarene-capped cages showed impressive stability when...
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Catalytic dehydrative amide bond formation using aqueous ammonia:
synthesis of primary amides utilizing diboronic acid anhydride catalysis
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  Abstract: Chem. Commun., 2023, Advance Article
  
  DOI : 10.1039/D3CC02071A, CommunicationNaoya Takahashi, Hinata Iwasawa, Tatsuhito Kinashi, Kazuishi Makino, Naoyuki Shimada
  We have developed a first catalytic methodology for the synthesis of primary amides by the catalytic dehydrative amidation of α- or β-hydroxycarboxylic acids using inexpensive and safe aqueous ammonia.
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Oxygen Vacancy Promoted Carbon Dioxide Activation over Cu/ZrO2 for
CO2-to-Methanol Conversion
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC01834B, CommunicationHaohao Chang, Feifan Gao, Alin Luo, Yong-Mei Liu, Yifeng Zhu, Heyong He, Yong Cao
  Oxygen vacancy-enriched ultrafine tetragonal ZrO2 was introduced as a support for copper nanoparticles to enhance the energy effici- ency of CO2 hydrogenation for methanol synthesis. This approach generates the critical...
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Reducing volume expansion in micro silicon anodes via aramid nanofibers
for stable lithium-ion batteries
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC01909H, CommunicationQingqing Liu, Wei Tang, Yang Chen, Wenlong Cai, Feng Chen, Qiang Fu
  The aramid nanofibers (ANFs) form networks on SMPs (ANF-SMPs) by cryofixation and acid-induced protonation, whose zongzi-like wrapping structure reduces volume expansion during (de)lithiation. The obtained ANF-SMP electrode achieves a high...
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Reversible interconversion of pharmaceutical salt polymorphs facilitated
by mechanical methods
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC02188B, CommunicationLiulei Ma, Qixuan Zheng, Daniel K Unruh, Kristin M Hutchins
  Salification of the drug trimethoprim with enantiopure D- or L-lactic acid afforded salts with up to five times improved solubility. Both salts are polymorphic and we demonstrate fully reversible interconversion...
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Helicity induction and memory of a lipophilic Brønsted acid-type
poly(phenylacetylene) in non-polar solvents
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  Abstract: Chem. Commun., 2023, Advance Article
  
  DOI : 10.1039/D3CC01521A, CommunicationYuki Nishikawa, Daisuke Hirose, Shota Sona, Katsuhiro Maeda
  Lipophilic Brønsted acid-type poly(phenylacetylene) forms a one-handed helical conformation upon complexation with chiral amines and shows static helicity memory.
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Transmembrane fluoride anion transport by
meso-3,5-bis(trifluoromethyl)phenyl picket calix[4]pyrrole
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  Abstract: Chem. Commun., 2023, Advance Article
  
  DOI : 10.1039/D3CC02032K, CommunicationAshoke Kumar Patra, Soumya Srimayee, Dibakar Halder, Anik Roy, Souvik Mukherjee, Somenath Kundu, Maidul Hossain, Rajat Saha, Chang-Hee Lee, Debasis Manna, Indrajit Saha
  Meso-3,5-bis(trifluoromethyl)phenyl picket calix[4]pyrrole 1 transports fluoride anions efficiently across an artificial lipid bilayer membrane, displaying high fluoride over chloride ion selectivity.
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Reaction mechanism – explored with the unified reaction valley
approach
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  Abstract: Chem. Commun., 2023, Advance Article
  
  DOI : 10.1039/D3CC01576A, Feature ArticleElfi Kraka, Juliana J. Antonio, Marek Freindorf
  One of the ultimate goals of chemistry is to understand and manipulate chemical reactions, which implies the ability to monitor the reaction and its underlying mechanism at an atomic scale.
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Dansyl-triazole-based fluorescent macrocycle for selective detection of
nitro-antibiotic drugs and protein interaction
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  Abstract: Chem. Commun., 2023, Advance Article
  
  DOI : 10.1039/D3CC01769A, Communication Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Liya Thurakkal, Rakhi Mol K. M., Mintu Porel
  A novel dansyl-triazole-based fluorescent macrocycle with high Stokes shift and positive solvatochromism has been developed for sensing nitro-containing antibiotics from real water and in paper strips.
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A two-step lighting DNA tetrahedral nanoprobe for precise imaging-guided
photodynamic therapy of tumors
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  Abstract: Chem. Commun., 2023, Advance Article
  
  DOI : 10.1039/D3CC00883E, CommunicationFan Wu, Yuancheng Li, Lijuan Wang, Can Peng, Youhui Zeng, Jinfeng Yang, Huijun Zhou, Jing Zheng
  In this manuscript, we propose a two-step lighting DNA tetrahedral nanoprobe for precise imaging-guided photodynamic therapy of tumors.
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Self-assembly of benzophenone-diphenylalanine conjugate into a
nanostructured photocatalyst
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC01673K, Communication Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Simone Adorinni, Giulio Goti, Lorenzo Rizzo, Federica Grassi, Slavko Kralj, Fatima Matroodi, Mirco Natali, Rita De Zorzi, Silvia Marchesan, Luca Dell'Amico
  The conjugation of photoactive benzophenone with diphenylalanine yielded a self-assembling photocatalyst that was probed in the cis-trans photoisomerisation of stilbene derivatives.
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Heteroannulation of bicyclobutane derivatives via Au-catalyzed hydration
to enol ethers and intramolecular cyclization giving spirocyclobutanes
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC01955A, CommunicationMasaharu Takatsuki, Hiroshi Aoyama, Kenichi Murai, Mitsuhiro Arisawa, Makoto Sako
  We report the heteroannulations of bicyclobutane derivatives bearing enol ether groups in the presence of H2O under mild conditions. The reaction affords spirocyclobutanes with cyclic acetal groups via the Au-catalyzed...
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Fluorescence correlation spectroscopy and fluorescence lifetime imaging
microscopy for deciphering the morphological evolution of supramolecular
self-assembly
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D2CC06607F, HighlightSubhankar Kundu, Subhadeep Das, Abhijit Patra
  Properties and functions of noncovalent interactions-driven fluorescent supramolecular self-assembly greatly depend on their evolution dynamics. Electron microscopy, atomic force microscopy, and confocal laser scanning microscopy have been used to elucidate...
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Modulation of bulk and surface electronic structures for oxygen evolution
by Cr, P co-doped Co3S4
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC01936E, CommunicationYiting Chen, Xiaoyun Zhang, Xiaoshuang Ma, Yuqiao Wang
  Co3S4 was doped by Cr in bulk phase and P on surface to achieve a low overpotential of 257 mV and a long-term durability over 48 h during oxygen evolution...
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A mesoporous Zr-based metal-organic framework driven by the assembly of an
octatopic linker
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC01831H, Communication Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Borja Ortín-Rubio, Cristina Perona, José A. Suárez del Pino, Francisco J. Carmona, Felipe Gándara, Jorge A R Navarro, Judith Juanhuix, Inhar Imaz, Daniel Maspoch
  Metal-organic frameworks (MOFs) based on high-connected nets are generally very attractive due to their combined robustness and porosity. Here, we describe the synthesis of BCN-348, a new high-connected Zr-MOF built...
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Hierarchical zeolites containing embedded Cd0.2Zn0.8S as a photocatalyst
for hydrogen production from seawater
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  Abstract: Chem. Commun., 2023, Advance Article
  
  DOI : 10.1039/D3CC01409F, CommunicationYue Yuan, Feng-Juan Wu, Shi-Tian Xiao, Yi-Tian Wang, Zhi-Wen Yin, Gustaaf Van Tendeloo, Gang-Gang Chang, Ge Tian, Zhi-Yi Hu, Si-Ming Wu, Xiao-Yu Yang
  Cd0.2Zn0.8S@Silicalite-1 composites were prepared and shown to have remarkably high catalytic activity, stability and salt resistance in seawater.
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A laser-induced Fe3O4-graphene nanozyme for catalytic–photothermal
synergetic bactericidal applications
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  Abstract: Chem. Commun., 2023, Advance Article
  
  DOI : 10.1039/D3CC01782F, CommunicationLimin Yang, Liuying Chen, Zhiliang Feng, Haiyan Shi, Baokun Wang, Wenjie Liu, Xiaojuan Liu, Ting Hou, Lei Ge, Feng Li
  The in situ and straightforward fabrication of an Fe3O4-decorated 3D macroporous graphene nanozyme is developed via a facile and scalable direct-laser-writing method for catalytic–photothermal synergetic bactericidal applications.
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Organocatalytic atroposelective synthesis of naphthoquinone thioglycosides
from aryl-naphthoquinones and thiosugars
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  Abstract: Chem. Commun., 2023, Advance Article
  
  DOI : 10.1039/D3CC01705B, CommunicationYuling Wu, Wu-Jingyun Zhou, Laiping Yao, Yadi Niu, Hongli Zhao, Cheng Peng, Bo Han, Wei Huang, Gu Zhan
  A stereoselective organocatalytic strategy was developed to synthesize the axially chiral naphthoquinone thioglycosides from aryl-naphthoquinones and thiosugars. The reaction pathway involves atroposelective addition and stereoretentive oxidation.
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Aryldimethylelement cations of the heavier group 14 elements. An
essentially three-coordinate plumbylium ion
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  Abstract: Chem. Commun., 2023, Advance Article
  
  DOI : 10.1039/D3CC00397C, CommunicationMarvin Janssen, Stefan Mebs, Jens Beckmann
  The first essentially three-coordinated plumbylium cation [RindMe2Pb]+ was obtained with the aid of a bulky and rigid Rind substituent (Rind = dispiro[fluorene-9,3′-(1′,1′,7′,7′-tetramethyl-s-hydrindacen-4′-yl)-5′,9′′-fluorene).
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Base-mediated ynone-isocyanide [3+2] cycloaddition: a general method to
2,3,4-tri-substituted 1-H-pyrroles and bis-pyrroles
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  Abstract: Chem. Commun., 2023, Advance Article
  
  DOI : 10.1039/D3CC01586F, CommunicationAnkit Kumar, Pawan K. Mishra, Akhilesh K. Verma
  A general method for the synthesis of functionalized pyrroles and bis-pyrroles from ynones under transition-metal-free conditions in good to excellent yields has been developed.
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Comment on “Structural transition and superconductivity in
hydrothermally synthesized FeX (X = S, Se)” by U. Pachmayr, N. Fehn and
D. Johrendt, Chem. Commun., 2016, 52, 194
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  Abstract: Chem. Commun., 2023, 59,6592-6596
  
  DOI : 10.1039/D3CC01182H, Comment Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Alberto Martinelli
  The hypothetical occurrence of triclinic structural modification of β-FeSe is revised and corrected.
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Stereoselective synthesis of difunctionalized succinimides from
aza-1,6-enynes by radical cascade reaction
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  Abstract: Chem. Commun., 2023, Advance Article
  
  DOI : 10.1039/D3CC01391J, CommunicationShivam A. Meena, Poonam Sharma, Akhilesh K. Verma
  A transition-metal-free one-pot synthesis of di-functionalized succinimides by radical cascade seleno/thiosulfonation of aza-1,6 enynes has been reported.
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Bilateral π-extension of an open-[60]fullerene in a helical manner
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  Abstract: Chem. Commun., 2023, 59,6560-6563
  
  DOI : 10.1039/D3CC00784G, Communication Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yoshifumi Hashikawa, Shumpei Sadai, Yasujiro Murata
  Bilateral π-elongation of an open-[60]fullerene produces a π-extended (5,5) end-cap with two-fold embedded diaza[n]helicene motifs.
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Identification of PdPt alloys for preferential C6 olefin hydrogenation
over aromatic hydrocarbons through density functional theory and
microkinetic modeling
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  Abstract: Chem. Commun., 2023, 59,6529-6532
  
  DOI : 10.1039/D3CC01856C, CommunicationHaowen Ma, Jiayi Wang, Xuecheng Zhan, Yuan Xie, Limin Sun, Xiaoli Hu, Haoxiang Xu, Daojian Cheng
  Pd3Pt1 is identified with high selectivity (low aromatic depletion), while Pd1Pt1 and Pd1Pt3 are more active for olefin hydrogenation. The PdPt alloys present superior sulfur tolerance compared to Pd.
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Palladium-loaded ceramic membrane-catalyzed flow-through
Suzuki–Miyaura reaction
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  Abstract: Chem. Commun., 2023, 59,6568-6571
  
  DOI : 10.1039/D3CC01518A, CommunicationShuangqiang Wang, Jinliang Chen, Fei Zhang, Yao Zhao, Xiaojin Wu, Rizhi Chen
  A general Suzuki–Miyaura reaction catalyzed by a Pd-loaded ceramic membrane in a flow-through membrane reactor is reported for the first time.
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Visible-light-driven oxidation of organosilanes by a charge-transfer
complex
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  Abstract: Chem. Commun., 2023, 59,6588-6591
  
  DOI : 10.1039/D3CC01972A, CommunicationYi-Xuan Chen, Jun-Tao He, Mei-Chun Wu, Zhi-Lin Liu, Peng-Ju Xia, Kai Chen, Hao-Yue Xiang, Hua Yang
  A novel photo-induced strategy for oxidation of organosilanes to access silanols, promoted by a photoactive charge-transfer complex (CTC) between sodium benzenesulfinate and molecular O2, has been developed.
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NBS-induced intramolecular annulation reactions for the divergent
synthesis of fused- and spirocyclic indolines
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  Abstract: Chem. Commun., 2023, 59,6576-6579
  
  DOI : 10.1039/D3CC01920A, CommunicationXian Luo, Meng-Meng Xu, Xiao-Ping Xu, Shun-Jun Ji
  An NBS-induced intramolecular annulation of 3-(1H-indol-3-yl)-propanamide is described. The C2-substituents on indole ring have great influence upon the generation of fused- and spirocyclic indolines.
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Insights into desalination battery concepts: current challenges and future
perspectives
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  Abstract: Chem. Commun., 2023, 59,6437-6452
  
  DOI : 10.1039/D3CC00513E, Feature Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Cleis Santos, Fabio La Mantia
  Water plays an essential role in the development of society.
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Simultaneous quantification of serum albumin and gamma globulin using
Zn(II)-metallosurfactant via a coffee ring pattern
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  Abstract: Chem. Commun., 2023, 59,6536-6539
  
  DOI : 10.1039/D3CC01221B, Communication Aastha, Priyanka, Subhabrata Maiti
  A coffee ring pattern-based sensor for simultaneous detection of serum albumin and gamma globulin based on their differential aggregate forming propensity with Zn(II)-metallosurfactant has been demonstrated.
  The content of this RSS Feed (c) The Royal Society of Chemistry
Interfacial engineering of hydrophobic octadecanethiol/Pd metallene toward
electrocatalytic nitrogen reduction
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  Abstract: Chem. Commun., 2023, 59,6552-6555
  
  DOI : 10.1039/D3CC01234D, CommunicationHongjing Wang, Xu Mu, Qiqi Mao, Kai Deng, Hongjie Yu, You Xu, Xiaonian Li, Ziqiang Wang, Liang Wang
  Octadecanethiol-modified Pd metallene was fabricated for electrochemical synthesis of ammonia with high ammonia production and Faraday efficiency.
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Zeolite-templated carbon-supported Ru-based catalysts for efficient
alkaline hydrogen evolution reaction
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  Abstract: Chem. Commun., 2023, 59,6544-6547
  
  DOI : 10.1039/D3CC01874A, CommunicationXin Wang, Xiaoli Yang, Junwei Sun, Mingyu Guo, Zhihao Cao, Haoxi Ben, Wei Jiang, Shujun Ming, Lixue Zhang
  Zeolite-templated carbon (ZTC) has a uniform porous structure that confines the Ru clusters, and also has a high graphitization, which enables the Ru/ZTCs catalysts to exhibit excellent activity and stability in HER process.
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Li10GeP2S12 solid electrolytes synthesised via liquid-phase methods
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  Abstract: Chem. Commun., 2023, 59,6564-6567
  
  DOI : 10.1039/D3CC01018J, CommunicationKazuhiro Hikima, Kaito Ogawa, Hirotada Gamo, Atsunori Matsuda
  Li10GeP2S12 solid electrolytes for all-solid-state batteries were synthesised rapidly through liquid-phase method in 7.5 h.
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Surface termination passivation of imidazole-based diiodide enabling
efficient inverted perovskite solar cells
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  Abstract: Chem. Commun., 2023, 59,6580-6583
  
  DOI : 10.1039/D3CC01379K, CommunicationYu Wang, Jiaxing Song, Jingchuan Ye, Yingzhi Jin, Xinxing Yin, Zhen Su, Lin Hu, Yan Wu, Chufeng Qiu, Hao Wang, Wensheng Yan, Zaifang Li
  Efficient and stable Cs/FA-based inverted PSCs were developed by introducing imidazole diiodide (APDI) for surface termination passivation.
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A P-doped PtNi alloy supported on N,C-doped TiO2 nanosheets as a stable
electrocatalyst for the oxygen reduction reaction in an acidic electrolyte
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  Abstract: Chem. Commun., 2023, 59,6525-6528
  
  DOI : 10.1039/D3CC00859B, CommunicationChen Lu, Chao Xu, Peng-Peng Guo, Kun-Zu Yang, Ying Xu, Hua-Min Chi, Ping-Jie Wei, Jin-Gang Liu
  A non-carbon-supported catalyst P–PtNi@N,C–TiO2 in which P-doped PtNi alloy was loaded on N,C-doped TiO2 nanosheets exhibited much superior ORR activity and durability compared to a commercial Pt/C catalyst in a strongly acidic electrolyte.
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Ag-doped Cu nanosheet arrays for efficient hydrogen evolution reaction
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  Abstract: Chem. Commun., 2023, 59,6533-6535
  
  DOI : 10.1039/D3CC01365K, CommunicationLing-Jie Kong, Ya-Meng Xie, Xing-Yu Chen, Cong Xi, Fei-Fei Zhang, Min Wang, Long Shang, Yuan Huang, Xi-Wen Du, Sergei A. Kulinich
  A zinc-infiltration process was adopted to prepare silver-doped copper nanosheet arrays.
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Photochemical generation and reactivity of a new
phthalocyanine-manganese–oxo intermediate
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  Abstract: Chem. Commun., 2023, 59,6540-6543
  
  DOI : 10.1039/D3CC01275A, CommunicationTristan Skipworth, Seth Klaine, Rui Zhang
  A novel phthalocyanine-manganese–oxo intermediate was photo-generated, and its reactivity was kinetically probed and compared with the related porphyrin-metal–oxo intermediates.
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Iodanes as multi-tools for the total synthesis of complex natural products
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  Abstract: Chem. Commun., 2023, 59,6495-6508
  
  DOI : 10.1039/D3CC01603J, Feature ArticleCamille Rocq, Maxime Denis, Sylvain Canesi
  Hypervalent iodine reagents as efficient tools for the total synthesis of complex natural products.
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Nanophase-Photocatalysis: Loading, Storing, and Release of H2O2 using
Graphitic Carbon Nitride
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC01442H, Communication Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Akalya Karunakaran, Katie J Francis, Chris Bowen, Richard J Ball, Yuanzhu Zhao, Lina Wang, Neil B. McKeown, Mariolino Carta, Philip J Fletcher, Remi Castaing, Mark Andrew Isaacs, Laurence J. Hardwick, Gema Cabello, Igor V. Sazanovich, Frank Marken
  A blue light mediated photochemical process using solid graphitic carbon nitride (g-C3N4) in ambient air/isopropanol vapour is suggested to be linked to “nanophase” water inclusions and is shown to produce...
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Olefin hydroboration catalyzed by an Iron-borane complex
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC00494E, Communication Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Laura A Grose, Darren Willcox
  The well-defined iron(0) complex [(iPrDPBPh)Fe2-(μ-1,2-N2)] (A) reacts with HBPin affords the complex [iPrDBPPh](μ-H)Fe(H)(BPin)2 via oxidative addition of the H-B bond. Complex A is an effective pre-catalyst for the hydroboration of...
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Excitonic coupling of RNA-templated merocyanine dimer studied by
higher-order transient absorption spectroscopy
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC02024J, CommunicationJulia Dietzsch, Ajay Jayachandran, Stefan Mueller, Claudia Höbartner, Tobias Brixner
  We report the synthesis and spectroscopic analysis of RNA containing the barbituric acid merocyanine rBAM2 as a nucleobase surrogate. Incorporation into RNA strands by solid-phase synthesis leads to fluorescence enhancement...
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Switching the chemoselectivity of perakine reductase for selective
reduction of α,β-unsaturated ketones by Arg127 mutation
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC00850A, CommunicationZehao Zhang, Yun Zhou, Hong Zhao, Yihang Wu, Lianli Sun
  The chemoselectivity of perakine reductase (PR) was engineered through rational design. We identified Arg127 as a control site of chemoselectivity. Mutation of Arg127 switched the chemoselectivity of PR between C=O...
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Plasmonic Nanomaterials for Solar-Driven Photocatalysis
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC01512B, Feature ArticleQingzhe Zhang, Zhihong Zuo, Dongling Ma
  Plasmonic nanomaterials have spurred significant research interest in enhanced solar-driven photocatalysis due to their strong localized surface plasmon resonance (LSPR). As this rapid-developing research area begun to raise and answer...
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Long-term heat-storage materials based on λ-Ti3O5 for green
transformation (GX)
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC00641G, Feature Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Shin-ichi Ohkoshi, Marie Yoshikiyo, Jessica Grace MacDougall, Yusuke Ikeda, Hiroko Tokoro
  Effective reuse of waste heat energy is an important energy savings issue for green transformation. In general, phase-change heat storage materials cannot store energy for a prolonged period. If a...
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Complexation with pagoda[n]arene (n=4, 5) protects ferrocenium from
oxidation
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC01202F, CommunicationGui-Hua Chen, Yi-Meng Duan, Ying Li, Xiao-Ni Han, Kun-Peng Wang, Zhi-Qiang Hu, Chuan-Feng Chen
  The complexation behaviors of pagoda[n]arenes (n=4, 5) with ferrocene, ferrocenium and analogues cobaltocenium were studied. The inclusion complexes of pagoda[n]arenes can protect ferrocenium from oxidation in organic solvents and improve...
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Chloroacetyl boronate N-tosylhydrazone as a versatile synthetic building
block
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  Abstract: Chem. Commun., 2023, Accepted Manuscript
  
  DOI : 10.1039/D3CC02086J, Communication Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ryuya Miyazaki, Kei Muto, Junichiro Yamaguchi
  Chloroacetyl boronate N-tosylhydrazone (CABT) has been synthesized as a reagent to generate a diverse range of molecular skeletons. CABT can undergo a series of transformations involving nucleophilic substitution of the...
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