Subjects -> CHEMISTRY (Total: 928 journals)
    - ANALYTICAL CHEMISTRY (59 journals)
    - CHEMISTRY (661 journals)
    - CRYSTALLOGRAPHY (23 journals)
    - ELECTROCHEMISTRY (28 journals)
    - INORGANIC CHEMISTRY (45 journals)
    - ORGANIC CHEMISTRY (47 journals)
    - PHYSICAL CHEMISTRY (65 journals)

CHEMISTRY (661 journals)                  1 2 3 4 | Last

Showing 1 - 200 of 735 Journals sorted alphabetically
Accounts of Materials Research     Hybrid Journal  
Accreditation and Quality Assurance: Journal for Quality, Comparability and Reliability in Chemical Measurement     Hybrid Journal   (Followers: 30)
ACS Applied Polymer Materials     Hybrid Journal   (Followers: 8)
ACS Catalysis     Hybrid Journal   (Followers: 52)
ACS Chemical Neuroscience     Hybrid Journal   (Followers: 23)
ACS Combinatorial Science     Hybrid Journal   (Followers: 21)
ACS Environmental Au     Open Access   (Followers: 8)
ACS Macro Letters     Hybrid Journal   (Followers: 25)
ACS Materials Letters     Open Access   (Followers: 2)
ACS Medicinal Chemistry Letters     Hybrid Journal   (Followers: 42)
ACS Nano     Hybrid Journal   (Followers: 181)
ACS Photonics     Hybrid Journal   (Followers: 14)
ACS Symposium Series     Full-text available via subscription   (Followers: 3)
ACS Synthetic Biology     Hybrid Journal   (Followers: 30)
Acta Chemica Malaysia     Open Access  
Acta Chimica Slovaca     Open Access   (Followers: 2)
Acta Chimica Slovenica     Open Access   (Followers: 2)
Acta Chromatographica     Full-text available via subscription   (Followers: 7)
Acta Metallurgica Sinica (English Letters)     Hybrid Journal   (Followers: 8)
Acta Scientifica Naturalis     Open Access   (Followers: 2)
adhäsion KLEBEN & DICHTEN     Hybrid Journal   (Followers: 7)
Adhesion Adhesives & Sealants     Hybrid Journal   (Followers: 9)
Adsorption Science & Technology     Open Access   (Followers: 7)
Advanced Electronic Materials     Hybrid Journal   (Followers: 7)
Advanced Functional Materials     Hybrid Journal   (Followers: 71)
Advanced Journal of Chemistry, Section A     Open Access   (Followers: 3)
Advanced Journal of Chemistry, Section B     Open Access   (Followers: 1)
Advanced Science Focus     Free   (Followers: 6)
Advanced Theory and Simulations     Hybrid Journal   (Followers: 2)
Advanced Therapeutics     Hybrid Journal   (Followers: 1)
Advances in Chemical Engineering and Science     Open Access   (Followers: 109)
Advances in Chemical Science     Open Access   (Followers: 51)
Advances in Chemistry     Open Access   (Followers: 34)
Advances in Colloid and Interface Science     Full-text available via subscription   (Followers: 16)
Advances in Environmental Chemistry     Open Access   (Followers: 10)
Advances in Enzyme Research     Open Access   (Followers: 10)
Advances in Heterocyclic Chemistry     Full-text available via subscription   (Followers: 8)
Advances in Materials Physics and Chemistry     Open Access   (Followers: 33)
Advances in Nanoparticles     Open Access   (Followers: 17)
Advances in Organometallic Chemistry     Full-text available via subscription   (Followers: 18)
Advances in Polymer Science     Hybrid Journal   (Followers: 51)
Advances in Protein Chemistry and Structural Biology     Full-text available via subscription   (Followers: 18)
Advances in Quantum Chemistry     Full-text available via subscription   (Followers: 6)
Advances in Sample Preparation     Open Access   (Followers: 5)
Advances in Science and Technology     Full-text available via subscription   (Followers: 16)
Aerosol Science and Engineering     Hybrid Journal  
African Journal of Chemical Education     Open Access   (Followers: 5)
African Journal of Pure and Applied Chemistry     Open Access   (Followers: 6)
Aggregate     Open Access  
Agrokémia és Talajtan     Full-text available via subscription   (Followers: 2)
Al-Kimia : Jurnal Penelitian Sains Kimia     Open Access  
Alchemy : Journal of Chemistry     Open Access   (Followers: 4)
Alchemy : Jurnal Penelitian Kimia     Open Access  
Alotrop     Open Access  
AMB Express     Open Access   (Followers: 1)
Ambix     Hybrid Journal   (Followers: 3)
American Journal of Biochemistry and Biotechnology     Open Access   (Followers: 43)
American Journal of Biochemistry and Molecular Biology     Open Access   (Followers: 19)
American Journal of Chemistry     Open Access   (Followers: 37)
American Journal of Plant Physiology     Open Access   (Followers: 8)
Analyst     Hybrid Journal   (Followers: 35)
Analytical Science Advances     Open Access   (Followers: 1)
Angewandte Chemie     Hybrid Journal   (Followers: 150)
Angewandte Chemie International Edition     Hybrid Journal   (Followers: 227)
Annales Universitatis Mariae Curie-Sklodowska, sectio AA – Chemia     Open Access   (Followers: 1)
Annals of Clinical Chemistry and Laboratory Medicine     Open Access   (Followers: 6)
Annual Reports in Computational Chemistry     Full-text available via subscription   (Followers: 4)
Annual Reports Section A (Inorganic Chemistry)     Full-text available via subscription   (Followers: 5)
Annual Review of Chemical and Biomolecular Engineering     Full-text available via subscription   (Followers: 12)
Annual Review of Food Science and Technology     Full-text available via subscription   (Followers: 13)
Antiviral Chemistry and Chemotherapy     Open Access   (Followers: 1)
Applied Organometallic Chemistry     Hybrid Journal   (Followers: 7)
Applied Spectroscopy     Full-text available via subscription   (Followers: 24)
Applied Surface Science     Hybrid Journal   (Followers: 31)
Arabian Journal of Chemistry     Open Access   (Followers: 4)
ARKIVOC     Open Access   (Followers: 1)
Asian Journal of Applied Chemistry Research     Open Access   (Followers: 1)
Asian Journal of Biochemistry     Open Access   (Followers: 2)
Asian Journal of Chemical Sciences     Open Access  
Asian Journal of Chemistry and Pharmaceutical Sciences     Open Access  
Asian Journal of Physical and Chemical Sciences     Open Access   (Followers: 2)
Australian Journal of Chemistry     Hybrid Journal   (Followers: 7)
Autophagy     Hybrid Journal   (Followers: 7)
Biochemical Pharmacology     Hybrid Journal   (Followers: 11)
Biochemistry     Hybrid Journal   (Followers: 200)
Biochemistry Insights     Open Access   (Followers: 6)
Biochemistry Research International     Open Access   (Followers: 5)
BioChip Journal     Hybrid Journal  
Bioinorganic Chemistry and Applications     Open Access   (Followers: 5)
Biointerface Research in Applied Chemistry     Open Access  
Biointerphases     Open Access   (Followers: 1)
Biology, Medicine, & Natural Product Chemistry     Open Access   (Followers: 2)
Biomacromolecules     Hybrid Journal   (Followers: 23)
Biomass Conversion and Biorefinery     Partially Free   (Followers: 10)
Biomedical Chromatography     Hybrid Journal   (Followers: 6)
Biomolecular NMR Assignments     Hybrid Journal   (Followers: 3)
BioNanoScience     Partially Free   (Followers: 3)
Bioorganic & Medicinal Chemistry     Hybrid Journal   (Followers: 90)
Bioorganic & Medicinal Chemistry Letters     Hybrid Journal   (Followers: 66)
Bioorganic Chemistry     Hybrid Journal   (Followers: 9)
Biopolymers     Hybrid Journal   (Followers: 15)
Biosensors     Open Access   (Followers: 3)
Biotechnic and Histochemistry     Hybrid Journal   (Followers: 3)
Bitácora Digital     Open Access  
Boletin de la Sociedad Chilena de Quimica     Open Access  
Bulletin of Institute of Chemistry and Chemical Technology, Mongolian Academy of Sciences     Open Access  
Bulletin of the Chemical Society of Ethiopia     Open Access   (Followers: 1)
Bulletin of the Chemical Society of Japan     Full-text available via subscription   (Followers: 24)
Bulletin of the Korean Chemical Society     Hybrid Journal   (Followers: 1)
C - Journal of Carbon Research     Open Access   (Followers: 5)
Cakra Kimia (Indonesian E-Journal of Applied Chemistry)     Open Access  
Canadian Association of Radiologists Journal     Full-text available via subscription   (Followers: 1)
Canadian Journal of Chemistry     Hybrid Journal   (Followers: 12)
Canadian Mineralogist     Full-text available via subscription   (Followers: 5)
Carbohydrate Polymer Technologies and Applications     Open Access  
Carbohydrate Polymers     Hybrid Journal   (Followers: 9)
Carbohydrate Research     Hybrid Journal   (Followers: 24)
Carbon     Hybrid Journal   (Followers: 65)
Carbon Capture Science & Technology     Open Access  
Carbon Trends     Open Access   (Followers: 3)
Catalysis Reviews: Science and Engineering     Hybrid Journal   (Followers: 9)
Catalysis Science and Technology     Hybrid Journal   (Followers: 9)
Catalysis Surveys from Asia     Hybrid Journal   (Followers: 4)
Catalysts     Open Access   (Followers: 11)
Cell Reports Physical Science     Open Access  
Cellulose     Hybrid Journal   (Followers: 7)
Cereal Chemistry     Full-text available via subscription   (Followers: 4)
Chem     Hybrid Journal  
Chem Catalysis     Hybrid Journal  
ChemBioEng Reviews     Full-text available via subscription   (Followers: 3)
ChemCatChem     Hybrid Journal   (Followers: 8)
Chemical and Engineering News     Free   (Followers: 22)
Chemical Bulletin of Kazakh National University     Open Access  
Chemical Communications     Hybrid Journal   (Followers: 81)
Chemical Engineering Research and Design     Hybrid Journal   (Followers: 26)
Chemical Physics Impact     Full-text available via subscription  
Chemical Research in Chinese Universities     Hybrid Journal   (Followers: 4)
Chemical Research in Toxicology     Hybrid Journal   (Followers: 22)
Chemical Reviews     Hybrid Journal   (Followers: 168)
Chemical Science     Open Access   (Followers: 39)
Chemical Science International Journal     Open Access  
Chemical Technology     Open Access   (Followers: 75)
Chemical Thermodynamics and Thermal Analysis     Open Access   (Followers: 2)
Chemical Vapor Deposition     Hybrid Journal   (Followers: 4)
Chemie in Unserer Zeit     Hybrid Journal   (Followers: 54)
Chemie-Ingenieur-Technik (Cit)     Hybrid Journal   (Followers: 22)
ChemInform     Hybrid Journal   (Followers: 5)
Chemistry     Open Access  
Chemistry & Biodiversity     Hybrid Journal   (Followers: 7)
Chemistry & Industry     Full-text available via subscription   (Followers: 6)
Chemistry - A European Journal     Hybrid Journal   (Followers: 121)
Chemistry - An Asian Journal     Hybrid Journal   (Followers: 19)
Chemistry Africa : A Journal of the Tunisian Chemical Society     Hybrid Journal  
Chemistry and Materials Research     Open Access   (Followers: 18)
Chemistry Central Journal     Open Access   (Followers: 4)
Chemistry Education Research and Practice     Free   (Followers: 6)
Chemistry Education Review     Open Access   (Followers: 1)
Chemistry in Education     Open Access   (Followers: 3)
Chemistry Letters     Full-text available via subscription   (Followers: 44)
Chemistry of Heterocyclic Compounds     Hybrid Journal   (Followers: 4)
Chemistry of Materials     Hybrid Journal   (Followers: 161)
Chemistry of Natural Compounds     Hybrid Journal   (Followers: 10)
Chemistry World     Hybrid Journal   (Followers: 20)
Chemistry-Didactics-Ecology-Metrology     Open Access  
ChemistryOpen     Open Access   (Followers: 1)
ChemistrySelect     Hybrid Journal  
Chemistry–Methods     Open Access   (Followers: 1)
Chemkon - Chemie Konkret, Forum Fuer Unterricht Und Didaktik     Hybrid Journal  
ChemNanoMat     Hybrid Journal   (Followers: 1)
Chemoecology     Hybrid Journal   (Followers: 2)
Chemometrics and Intelligent Laboratory Systems     Hybrid Journal   (Followers: 13)
Chemosensors     Open Access   (Followers: 1)
ChemPhotoChem     Hybrid Journal  
ChemPhysChem     Hybrid Journal   (Followers: 12)
ChemPhysMater     Full-text available via subscription  
ChemPlusChem     Hybrid Journal   (Followers: 2)
Chempublish Journal     Open Access  
ChemSystemsChem     Hybrid Journal   (Followers: 1)
ChemTexts     Hybrid Journal   (Followers: 1)
CHIMIA International Journal for Chemistry     Open Access   (Followers: 2)
Chinese Journal of Chemistry     Hybrid Journal   (Followers: 6)
Chinese Journal of Polymer Science     Hybrid Journal   (Followers: 9)
Chromatographia     Hybrid Journal   (Followers: 22)
Chromatography     Open Access   (Followers: 2)
Chromatography Research International     Open Access   (Followers: 4)
Ciencia     Open Access  
Clay Minerals     Hybrid Journal   (Followers: 8)
Cogent Chemistry     Open Access   (Followers: 3)
Colloid and Interface Science Communications     Open Access  
Colloid and Polymer Science     Hybrid Journal   (Followers: 6)
Colloids and Interfaces     Open Access  
Colloids and Surfaces B: Biointerfaces     Hybrid Journal   (Followers: 8)
Combinatorial Chemistry & High Throughput Screening     Hybrid Journal   (Followers: 2)
Combustion Science and Technology     Hybrid Journal   (Followers: 26)
Comments on Inorganic Chemistry: A Journal of Critical Discussion of the Current Literature     Hybrid Journal   (Followers: 1)
Communications Chemistry     Open Access   (Followers: 2)
Communications Materials     Open Access  
Composite Interfaces     Hybrid Journal   (Followers: 6)
Comptes Rendus : Chimie     Open Access  
Comptes Rendus : Physique     Open Access   (Followers: 2)

        1 2 3 4 | Last

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Chemical Science
Journal Prestige (SJR): 4.508
Citation Impact (citeScore): 9
Number of Followers: 39  

  This is an Open Access Journal Open Access journal
ISSN (Print) 2041-6520 - ISSN (Online) 2041-6539
Published by RSC Homepage  [50 journals]
  • Robust dicopper(I) µ-boryl complexes supported by a dinucleating
           naphthyridine-based ligand

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC00848C, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Pablo Ríos, Matthew S. See, Rex Handford, Simon Teat, T Don Tilley
      Copper boryl species have been widely invoked as reactive intermediates in Cu-catalysed C−H borylation reactions, but their isolation and study have been challenging. Use of the robust dinucleating ligand DPFN...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Visualizing the Mode of Action and Supramolecular Assembly of Teixobactin
           Analogues in Bacillus subtilis

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01388F, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Michael A Morris, Alexander Vallmitjana, Fabian Grein, Tanja Schneider, Melina Arts, Chelsea R. Jones, Betty T. Nguyen, Mohammad H. Hashemian, Melody Malek, Enrico Gratton, James S Nowick
      Teixobactin has been the source of intensive study and interest as a promising antibiotic, because of its excellent activity against drug-resistant Gram-positive pathogens and its novel but not yet fully...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • A MXene-derived redox homeostasis regulator perturbs the Nrf2 antioxidant
           program for reinforced sonodynamic therapy

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D1SC07073H, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Huan Wang, Xinchen Liu, Xiangyu Yan, Jiawen Fan, Daowei Li, Jinsong Ren, Xiaogang Qu
      Ultrasound (US)-mediated sonodynamic therapy (SDT) has been emerged as a spatiotemporally controllable therapeutic modality in combating cancer because of its high tissue-penetration depth and minimal invasiveness. However, the elevated nuclear...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Tantalum, Easy as Pi: Understanding Differences in Metal-Imido Bonding
           Towards Improving Ta/Nb Separations

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01926D, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Alexander B. Weberg, Eric J. Schelter, Patrick Carroll, Michael Gau, Pragati Pandey, Ekaterina Lapsheva, George C Schatz, Thibault Cheisson, Subhajyoti Chaudhuri, Christian Uruburo
      The separation and purification of niobium and tantalum, which co-occur in natural sources, is difficult due to their similar physical and chemical properties. The current industrial method for separating Ta/Nb...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Nickel-catalyzed cross-electrophile allylation of vinyl bromides and the
           modification of anti-tumour natural medicine β-elemene

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC02054H, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yang Ye, Xiang Qi, Bing Xu, Ying Lin, Huan Xiang, Liang Zou, Xiang-Yang Ye, Tian Xie
      Herein, we present a facile and efficient allylation method via Ni-catalyzed cross-electrophile coupling of readily available allylic acetates with a variety of substituted alkenyl brimides using zinc as the terminal...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Customising excitation properties of polycyclic aromatic hydrocarbons by
           rational positional heteroatom doping: the peri-xanthenoxanthene (PXX)
           case

    • Abstract: Chem. Sci., 2022, Advance Article

      DOI : 10.1039/D2SC01038K, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Cataldo Valentini, Duncan Gowland, C. Grazia Bezzu, Deborah Romito, Nicola Demitri, Nicola Bonini, Davide Bonifazi
      In this paper we tackle the challenge of gaining control of the photophysical properties of PAHs through a site-specific N-doping within the structural aromatic framework.
      To cite this article before page numbers are assigned, use the
      DOI form of citation above.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Modular Synthesis of α-Arylated Carboxylic Acids, Esters and Amides via
           Photocatalyzed Triple C−F Bond Cleavage of Methyltrifluorides

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01905A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sifan Li, Paul Davies, Wei Shu
      α-Arylated carboxylic acids and amides are widespread motifs in bioactive molecules and important building blocks in chemical synthesis. Thus, straightforward and rapid access to such structures is highly desirable. Here...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Cell surface photoengineering enables modeling of glycocalyx shedding
           dynamics

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC00524G, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sean C Purcell, Michelle H Zhang, Daniel Honigfort, Hans Jefferson C Ng, Austen L Michalak, Kamil Godula
      The cellular glycocalyx, composed of membrane associated glycoproteins and glycolipids, is a complex and dynamic interface that facilitates interactions between cells and their environment. The glycocalyx composition is continuously changing...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Covalent labeling of a chromatin reader domain using proximity-reactive
           cyclic peptides

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC00555G, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Meng Yao Zhang, Hyunjun Yang, Gloria Ortiz, Michael J Trnka, Nektaria Petronikolou, A. L. Burlingame, Bill DeGrado, Danica Fujimori
      Chemical probes for chromatin reader proteins are valuable tools for investigating epigenetic regulatory mechanisms and evaluating whether the target of interest holds therapeutic potential. Developing potent inhibitors for plant homeodomain...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Bioinspired hollow g-C3N4-CuPc heterostructure with remarkable SERS
           enhancement and photosynthesis-mimicking property for theranostic
           applications

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01534J, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jun-Jie Zhu, Yu Su, Baozhen Yuan, Yaowen Jiang, Xiaolin Huang, Ping Wu, Li-Ping Jiang
      Surface-enhanced Raman scattering (SERS) based on chemical mechanism (CM) is of great potential for superior stability and selectivity. Moreover, the bioinspired CM-Raman substrate-Raman reporter system with charge separation and electron...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Catalytic Intramolecular Aminoarylation of Unactivated Alkenes with Aryl
           Sulfonamides

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01228F, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Efrey Noten, Rory C. McAtee, Corey Stephenson
      Arylethylamines are abundant motifs in myriad natural products and pharmaceuticals, so efficient methods to synthesize them are valuable in drug discovery. In this work, we disclose an intramolecular alkene aminoarylation...
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  • An Electric Field–Based Approach for Quantifying Effective Volumes and
           Radii of Chemically Affected Space

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC00780K, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Austin M. Mroz, Audrey Davenport, Jasper Sterling, Joshua Davis, Christopher H. Hendon
      Chemical shape and size play a critical role in chemistry. The van der Waals (vdW) radii, a familiar manifold used to quantify size by assuming overlapping spheres, provides rapid estimates...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Accessing the triplet state of perylenediimide by radical-enhanced
           intersystem crossing

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01899C, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Maximilian Maylaender, Peter Gilch, Michael R Wasielewski, Yunfan Qiu, Laura Bancroft, Sabine Richert, Michael Franz, Oliver Nolden, Su Chen
      Owing to their exceptional photophysical properties and high photostability, perylene diimide (PDI) chromophores have found various applications as building blocks of materials for organic electronics. In many light-induced processes in...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Halogen Bonding and Chalcogen Bonding Mediated Sensing

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01800D, Review ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Robert Hein, Paul D. Beer
      Sigma-hole interactions, in particular halogen bonding (XB) and chalcogen bonding (ChB), have become indispensible tools in supramolecular chemistry, with wide-ranging applications in crystal engineering, catalysis and materials chemistry as well...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Predicting Reaction Conditions from Limited Data through Active Transfer
           Learning

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D1SC06932B, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Eunjae Shim, Joshua Kammeraad, Ziping Xu, Ambuj Tewari, Tim Cernak, Paul Zimmerman
      Transfer and active learning have the potential to accelerate the development of new chemical reactions, using prior data and new experiments to inform models that adapt to the target area...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Biohybrid photosynthetic charge accumulation detected by flavin
           semiquinone formation in ferredoxin-NADP+ reductase

    • Abstract: Chem. Sci., 2022, Advance Article

      DOI : 10.1039/D2SC01546C, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lisa M. Utschig, Udita Brahmachari, Karen L. Mulfort, Jens Niklas, Oleg G. Poluektov
      One electron at a time, photosynthetic biohybrids enable charge accumulation via the flavin semiquinone of ferredoxin-NADP+ reductase.
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  • 3D vs. turbostratic: controlling metal-organic framework dimensionality
           via N-heterocyclic carbene chemistry

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01041K, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ilia Kochetygov, Anita Justin, Mehrdad Asgari, Shuliang Yang, Vikram V. Karve, Till Schertenleib, Dragos Stoian, Emad Oveisi, Mounir Mensi, Wendy Lee Queen
      Using azolium-based ligands for the construction of metal-organic frameworks (MOFs) is a viable strategy to immobilize catalytically active N-heterocyclic carbenes (NHC) or NHC-derived species inside MOF pores. Thus, in the...
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  • Understanding of chiral site-dependent enantioselective identification on
           plasmon-free semiconductor based SERS substrate

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01938H, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jing Xu, Yuanfei Xue, Xiaoxia Jian, Yue Zhao, Zhenqing Dai, Jingwen Xu, Zhida Gao, Ye Mei, Yan-Yan Song
      Chiral differentiation is an important topic in diverse fields ranging from pharmaceutics to chiral synthesis. Improvement of sensitivity and elucidation of mechanism of chiral recognition are still the two main...
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  • C2-ketonylation of carbohydrates via excited-state palladium-catalyzed
           1,2-spin-center shift

    • Abstract: Chem. Sci., 2022, Advance Article

      DOI : 10.1039/D2SC01042A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Gaoyuan Zhao, Upasana Mukherjee, Lin Zhou, Yue Wu, Wang Yao, Jaclyn N. Mauro, Peng Liu, Ming-Yu Ngai
      The excited-state palladium-catalyzed 1,2-spin-center shift process streamlines the synthesis of C2-ketonyl sugars. This step-economic reaction has a broad scope and allows late-stage functionalization of natural product- and drug-glycoconjugates.
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  • Advancing global chemical education through interactive teaching tools

    • Abstract: Chem. Sci., 2022, Advance Article

      DOI : 10.1039/D2SC01881K, PerspectiveOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Francesca M. Ippoliti, Jason V. Chari, Neil K. Garg
      This perspective highlights the development of interactive chemical education resources for worldwide usage. We hope to promote a spirit of innovation in chemical education and spur the development of new chemical education resources.
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  • Dysfunction of vesicular storage in young-onset Parkinson’s
           patient-derived dopaminergic neurons and organoids revealed by single cell
           electrochemical cytometry

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC00809B, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Wanying Zhu, Mengdan Tao, Yuan Hong, Shanshan Wu, Chu Chu, Zhilong Zheng, Xiao Han, Qian Zhu, Min Xu, Andrew Ewing, Xing Guo, Yan Liu
      Electrochemical cytometry based on nano-tip microelectrodes was used to quantify the vesicular storage at the single-cell level in human neurons and midbrain organoids which acted as disease models of young-onset...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • An economical approach for peptide synthesis via regioselective C–N
           bond cleavage of lactams

    • Abstract: Chem. Sci., 2022, Advance Article

      DOI : 10.1039/D2SC01466A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Wataru Muramatsu, Hisashi Yamamoto
      An economical, solvent-free, and metal-free method for peptide synthesis via C–N bond cleavage using lactams has been developed.
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      DOI form of citation above.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Porous liquids – the future is looking emptier

    • Abstract: Chem. Sci., 2022, 13,5042-5054

      DOI : 10.1039/D2SC00087C, PerspectiveOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Benjamin D. Egleston, Austin Mroz, Kim E. Jelfs, Rebecca L. Greenaway
      The realisation of permanent microporosity in liquids transforms the way functional porosity may be implemented. Considering recent advances, we explore the developing theory of porous liquids and delve into the discovery process and applications.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • A chiral phosphazane reagent strategy for the determination of
           enantiomeric excess of amines

    • Abstract: Chem. Sci., 2022, 13,5398-5412

      DOI : 10.1039/D2SC01692C, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Andrew J. Peel, Alexandros Terzopoulos, Rajesh B. Jethwa, Dipanjana Choudhury, Hao-Che Niu, Andrew D. Bond, Jonathan Slaughter, Dominic S. Wright
      The simple inorganic cyclodiphosph(III)azane chiral derivatisation agent ClP(μ-tBuN)2POBorn (Born = endo-(1S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl) is shown to be effective in the measurement of ee’s of chiral amines using 31P NMR spectroscopy.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • A sustainable approach for the synthesis of recyclable cyclic CO2-based
           polycarbonates

    • Abstract: Chem. Sci., 2022, Advance Article

      DOI : 10.1039/D2SC01387H, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xi Liao, Feng-Chao Cui, Jiang-Hua He, Wei-Min Ren, Xiao-Bing Lu, Yue-Tao Zhang
      It is highly desirable to reduce the environmental pollution related to the disposal of end-of-life plastics.
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      DOI form of citation above.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Simultaneous tracking of autophagy and oxidative stress during stroke with
           an ICT-TBET integrated ratiometric two-photon platform

    • Abstract: Chem. Sci., 2022, 13,5363-5373

      DOI : 10.1039/D1SC06805A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Wei Hu, Taotao Qiang, Li Chai, Tianyu Liang, Longfang Ren, Fei Cheng, Chunya Li, Tony D. James
      Ratiometric simultaneous tracking of autophagy and oxidative stress was achieved using an ICT-TBET integrated platform. Mito-ONOO exhibited excellent selectivity, good chemical stability, and non-overlapping ratiometric signals.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Selective radical cascade (4+2) annulation with olefins towards the
           synthesis of chroman derivatives via organo-photoredox catalysis

    • Abstract: Chem. Sci., 2022, Advance Article

      DOI : 10.1039/D2SC00903J, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Zhipeng Guan, Xingxing Zhong, Yayu Ye, Xiangwei Li, Hengjiang Cong, Hong Yi, Heng Zhang, Zhiliang Huang, Aiwen Lei
      We have developed a (4 + 2) radical annulation approach for the synthesis of diverse chromans. This method is complementary to the traditional Diels–Alder [4 + 2] annulation of ortho-quinone methides and electron-rich dienophiles.
      To cite this article before page numbers are assigned, use the
      DOI form of citation above.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • A photoresponsive antibody–siRNA conjugate for activatable
           immunogene therapy of cancer

    • Abstract: Chem. Sci., 2022, 13,5345-5352

      DOI : 10.1039/D2SC01672A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xingxing Wang, Xiao Xiao, Yi Feng, Jinbo Li, Yan Zhang
      A photoresponsive antibody–siRNA conjugate (PARC) enables tumor-targeted siRNA delivery and photoactivatable gene silencing for cancer immunotherapy.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Asymmetric addition of Grignard reagents to ketones: culmination of the
           ligand-mediated methodology allows modular construction of chiral tertiary
           alcohols

    • Abstract: Chem. Sci., 2022, Advance Article

      DOI : 10.1039/D1SC06350B, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Claudio Monasterolo, Ryan O'Gara, Saranna E. Kavanagh, Sadbh E. Byrne, Bartosz Bieszczad, Orla Murray, Michael Wiesinger, Rebecca A. Lynch, Kirill Nikitin, Declan G. Gilheany
      Easily applied enantioselective addition of aliphatic and aromatic Grignard reagents to ketones provides modular and universal access to challenging chiral tertiary alcohols, enabling the straightforward preparation of natural products and APIs.
      To cite this article before page numbers are assigned, use the
      DOI form of citation above.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Metastable doubly threaded [3]rotaxanes with a large macrocycle

    • Abstract: Chem. Sci., 2022, 13,5333-5344

      DOI : 10.1039/D2SC01486F, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jerald E. Hertzog, Vincent J. Maddi, Laura F. Hart, Benjamin W. Rawe, Phillip M. Rauscher, Katie M. Herbert, Eric P. Bruckner, Juan J. de Pablo, Stuart J. Rowan
      Multiple metastable doubly threaded [3]rotaxanes using a large 46 atom ring were prepared and fully characterized. Varying the stopper group size gave a range of interlocked stabilities in CDCl3 from a half-life of <1 minute to ca. 6 months.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Single-component nanodiscs via the thermal folding of amphiphilic graft
           copolymers with the adjusted flexibility of the main chain

    • Abstract: Chem. Sci., 2022, 13,5243-5251

      DOI : 10.1039/D2SC01674E, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Tomoki Nishimura, Yusuke Hatatani, Mitsuru Ando, Yoshihiro Sasaki, Kazunari Akiyoshi
      A strategy for the fabrication of nanodiscs via the self-assembly of thermoresponsive amphiphilic graft copolymers is demonstrated.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Exciton decay mechanism in DNA single strands: back-electron transfer and
           ultrafast base motions

    • Abstract: Chem. Sci., 2022, 13,5230-5242

      DOI : 10.1039/D1SC06450A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Benjamin Bauer, Rahul Sharma, Majed Chergui, Malte Oppermann
      Despite its key role in DNA photochemistry, the decay mechanism of excitons in stacked bases has remained difficult to resolve. Ultrafast polarization spectroscopy now reveals a back-electron transfer and ultrafast base motions in adenosine strands.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Thermodynamic equilibrium between locally excited and charge-transfer
           states through thermally activated charge transfer in
           1-(pyren-2′-yl)-o-carborane

    • Abstract: Chem. Sci., 2022, 13,5205-5219

      DOI : 10.1039/D1SC06867A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lei Ji, Stefan Riese, Alexander Schmiedel, Marco Holzapfel, Maximillian Fest, Jörn Nitsch, Basile F. E. Curchod, Alexandra Friedrich, Lin Wu, Hamad H. Al Mamari, Sebastian Hammer, Jens Pflaum, Mark A. Fox, David J. Tozer, Maik Finze, Christoph Lambert, Todd B. Marder
      Reversible conversion between excited-states is key to many photophysical phenomena. We studied the equilibrium between LE and CT states by time-resolved and temperature-dependent fluorescence, fs- and ns-transient absorption, and LR-TDDFT calculations.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Multi-component self-assembled molecular-electronic films: towards new
           high-performance thermoelectric systems

    • Abstract: Chem. Sci., 2022, 13,5176-5185

      DOI : 10.1039/D2SC00078D, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Troy L. R. Bennett, Majed Alshammari, Sophie Au-Yong, Ahmad Almutlg, Xintai Wang, Luke A. Wilkinson, Tim Albrecht, Samuel P. Jarvis, Lesley F. Cohen, Ali Ismael, Colin J. Lambert, Benjamin J. Robinson, Nicholas J. Long
      Through an experimental and theoretical study, cross-plane thermoelectricity in Self-Assembled Monolayers (SAMs) was enhanced by adding extra molecular layers, presenting a new strategy towards the design of high thermoelectric materials.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Unravelling the pore network and gas dynamics in highly adaptive rubbery
           organic frameworks

    • Abstract: Chem. Sci., 2022, 13,5141-5147

      DOI : 10.1039/D2SC01355J, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Romain Dupuis, Mihail Barboiu, Guillaume Maurin
      Structure and gas transport molecular insight into the intriguing rubbery organic frameworks characterized by unique adaptative behavior owing to the reversible connections between their constitutive building units and their non-permanent porosity.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Gram-scale synthesis of a covalent nanocage that preserves the redox
           properties of encapsulated fullerenes

    • Abstract: Chem. Sci., 2022, 13,5325-5332

      DOI : 10.1039/D2SC00445C, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Daniel A. Rothschild, William P. Kopcha, Aaron Tran, Jianyuan Zhang, Mark C. Lipke
      This report describes the first gram-scale synthesis of a nanocage that can host fullerenes (C60 and C70). The redox properties of the fullerenes are preserved in this host, enabling characterization of complexes with fulleride anions and dianions.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Asymmetrically bridged aroyl-S,N-ketene acetal-based multichromophores
           with aggregation-induced tunable emission

    • Abstract: Chem. Sci., 2022, 13,5374-5381

      DOI : 10.1039/D2SC00415A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lukas Biesen, Julius Krenzer, Nithiya Nirmalananthan-Budau, Ute Resch-Genger, Thomas J. J. Müller
      A library of 23 asymmetrically linked aroyl-S,N-ketene acetal solid-state emissive multichromophores accessed by one-pot multicomponent reactions exhibits AIE- and AIEE-active behavior as well as dual emission and potential energy transfer.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Machine learning potential era of zeolite simulation

    • Abstract: Chem. Sci., 2022, 13,5055-5068

      DOI : 10.1039/D2SC01225A, PerspectiveOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sicong Ma, Zhi-Pan Liu
      The machine learning atomic simulation will usher the research of zeolite, as other complex materials, into a new era featuring the easy access to zeolite functionalities predicted from theory.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Variable control of the electronic states of a silver nanocluster via
           protonation/deprotonation of polyoxometalate ligands

    • Abstract: Chem. Sci., 2022, Advance Article

      DOI : 10.1039/D2SC01156E, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kentaro Yonesato, Seiji Yamazoe, Soichi Kikkawa, Daisuke Yokogawa, Kazuya Yamaguchi, Kosuke Suzuki
      The electronic states of Ag nanoclusters were reversibly controlled driven by protonation/deprotonation of polyoxometalate ligands.
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      DOI form of citation above.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Site-selective coupling of remote C(sp3)–H/meta-C(sp2)–H bonds enabled
           by Ru/photoredox dual catalysis and mechanistic studies

    • Abstract: Chem. Sci., 2022, 13,5382-5389

      DOI : 10.1039/D2SC00764A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hong-Chao Liu, Xiangtao Kong, Xiao-Ping Gong, Yuke Li, Zhi-Jie Niu, Xue-Ya Gou, Xue-Song Li, Yu-Zhao Wang, Wei-Yu Shi, Yan-Chong Huang, Xue-Yuan Liu, Yong-Min Liang
      A novel photoinduced Ru/photocatalyst-cocatalyzed regioselective cross-dehydrogenative coupling of dual remote C–H bonds, including inert γ-C(sp3)–H bonds in amides and meta-C(sp2)–H bonds in arenes, to construct meta-alkylated arenes has been accomplished.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Rational design of a promising oxychalcogenide infrared nonlinear optical
           crystal

    • Abstract: Chem. Sci., 2022, 13,5305-5310

      DOI : 10.1039/D2SC00099G, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yansong Cheng, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu
      Based on heteroanionic structure engineering, the first heteroanionic thiostannate has been successfully synthesized. It is a promising IR-NLO material exhibiting moderate second-harmonic generation and wide IR transmission.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • [Ni30S16(PEt3)11]: an open-shell nickel sulfide nanocluster with a
           “metal-like” core

    • Abstract: Chem. Sci., 2022, 13,5171-5175

      DOI : 10.1039/D2SC00960A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Alexander J. Touchton, Guang Wu, Trevor W. Hayton
      The atomically-precise nanocluster, [Ni30S16(PEt3)11], features a compact “metal-like” core indicative of a high degree of Ni–Ni bonding, along with an open-shell ground state.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Highly efficient C(CO)–C(alkyl) bond cleavage in ketones to access
           esters over ultrathin N-doped carbon nanosheets

    • Abstract: Chem. Sci., 2022, 13,5196-5204

      DOI : 10.1039/D2SC00579D, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Manli Hua, Jinliang Song, Xin Huang, Honglei Fan, Tianbin Wu, Qinglei Meng, Zhanrong Zhang, Buxing Han
      Ultrathin and metal-free N-doped carbon nanosheets showed high activity and selectivity for oxidative esterification of ketones via C(CO)–C bond cleavage to access methyl esters.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Unmasking the constitution and bonding of the proposed lithium nickelate
           “Li3NiPh3(solv)3”: revealing the hidden C6H4 ligand

    • Abstract: Chem. Sci., 2022, 13,5268-5276

      DOI : 10.1039/D2SC01244H, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Rosie J. Somerville, Andryj M. Borys, Marina Perez-Jimenez, Ainara Nova, David Balcells, Lorraine A. Malaspina, Simon Grabowsky, Ernesto Carmona, Eva Hevia, Jesús Campos
      We disclose the actual octanuclear nature of the major compound from reacting Ni(COD)2 and PhLi, assigned for more than four decades as ‘Li3NiPh3(solv)3’. We provide a thorough bonding analysis and discuss its potential implications in catalysis.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Sulfur(IV)-mediated umpolung α-heterofunctionalization of
           2-oxazolines

    • Abstract: Chem. Sci., 2022, 13,5164-5170

      DOI : 10.1039/D2SC00476C, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Qifeng Zhang, Yuchen Liang, Ruiqi Li, Ziyi Huang, Lichun Kong, Peng Du, Bo Peng
      Aryl sulfonium salts serving as a new type of carbonyl umpolung reagent enable direct α-heterofunctionalization of 2-oxazolines.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Extended phenothiazines: synthesis, photophysical and redox properties,
           and efficient photocatalytic oxidative coupling of amines

    • Abstract: Chem. Sci., 2022, 13,5252-5260

      DOI : 10.1039/D2SC01086K, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jun Zhou, Lijun Mao, Meng-Xiang Wu, Zhiyong Peng, Yiming Yang, Manfei Zhou, Xiao-Li Zhao, Xueliang Shi, Hai-Bo Yang
      Herein, we successfully developed a ring-fusion approach to extend the conjugation length of phenothiazines that were demonstrated to be efficient photocatalysts for visible-light-driven oxidative coupling reactions of amines under an air atmosphere.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Precisely synthesized segmented polyurethanes toward block
           sequence-controlled drug delivery

    • Abstract: Chem. Sci., 2022, 13,5353-5362

      DOI : 10.1039/D1SC06457F, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yuanqing Song, Chuandong Sun, Chenxu Tian, Hao Ming, Yanjun Wang, Wenkai Liu, Nan He, Xueling He, Mingming Ding, Jiehua Li, Feng Luo, Hong Tan, Qiang Fu
      Polyurethanes (PUs) with different segment sequence orders are prepared using a precise synthetic platform, and the sequence order of functional segments plays a crucial role in regulating the surface charges and performance of nano-drug carriers.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Highly selective synthesis and near-infrared photothermal conversion of
           metalla-Borromean ring and [2]catenane assemblies

    • Abstract: Chem. Sci., 2022, 13,5130-5140

      DOI : 10.1039/D2SC00437B, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Li-Long Dang, Ting-Ting Li, Ting-Ting Zhang, Ying Zhao, Tian Chen, Xiang Gao, Lu-Fang Ma, Guo-Xin Jin
      The selective synthesis of three kinds of supermolecular topologies, molecular Borromean ring, [2]catenane and metallarectangle based on two alkynyl ligands is presented. Remarkably, the NIR photothermal conversion efficiency was found to improve as the π–π stacking increases.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Catalytic electron drives host–guest recognition

    • Abstract: Chem. Sci., 2022, 13,5261-5267

      DOI : 10.1039/D2SC01342H, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yoshihiro Owatari, Shuta Iseki, Daiji Ogata, Junpei Yuasa
      The reactants of AQH–CH2CN are converted into AQ and CH3CN in sustainable electrocatalytic chain reactions, successfully achieving catalytic electron-triggered charge-transfer (CT) complex formation.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Extending conceptual DFT to include external variables: the influence of
           magnetic fields

    • Abstract: Chem. Sci., 2022, 13,5311-5324

      DOI : 10.1039/D1SC07263C, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Robin Francotte, Tom J. P. Irons, Andrew M. Teale, Frank de Proft, Paul Geerlings
      An extension of conceptual DFT to include the influence of an external magnetic field is proposed in the context of a program set up to cope with the ever increasing variability of reaction conditions and concomitant reactivity.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Energetics of a protein disorder–order transition in small molecule
           recognition

    • Abstract: Chem. Sci., 2022, 13,5220-5229

      DOI : 10.1039/D2SC00028H, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Cesar Mendoza-Martinez, Michail Papadourakis, Salomé Llabrés, Arun A. Gupta, Paul N. Barlow, Julien Michel
      Molecular simulations and biophysical measurements elucidate why the ligand AM-7209 orders a disordered region of the protein MDM2 on binding. This work expands strategies available to medicinal chemists for targeting disordered proteins.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Metal binding and interdomain thermodynamics of mammalian
           metallothionein-3: enthalpically favoured Cu+ supplants entropically
           favoured Zn2+ to form Cu4+ clusters under physiological conditions

    • Abstract: Chem. Sci., 2022, 13,5289-5304

      DOI : 10.1039/D2SC00676F, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Matthew R. Mehlenbacher, Rahma Elsiesy, Rabina Lakha, Rhiza Lyne E. Villones, Marina Orman, Christina L. Vizcarra, Gabriele Meloni, Dean E. Wilcox, Rachel N. Austin
      Metallothioneins (MTs) are a ubiquitous class of small metal-binding proteins involved in metal homeostasis and detoxification.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Recent advances in noble metal complex based photodynamic therapy

    • Abstract: Chem. Sci., 2022, 13,5085-5106

      DOI : 10.1039/D1SC05478C, Review ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yanping Wu, Shumeng Li, Yuncong Chen, Weijiang He, Zijian Guo
      This minireview summarizes recent developments of noble metal photosensitizers based on Ru, Ir, and Pt. Molecular design strategies to overcome shallow tissue penetration depth, O2-dependence and the limited therapeutic effect are introduced.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • A structure determination protocol based on combined analysis of 3D-ED
           data, powder XRD data, solid-state NMR data and DFT-D calculations reveals
           the structure of a new polymorph of L-tyrosine

    • Abstract: Chem. Sci., 2022, 13,5277-5288

      DOI : 10.1039/D1SC06467C, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Christopher J. H. Smalley, Harriet E. Hoskyns, Colan E. Hughes, Duncan N. Johnstone, Tom Willhammar, Mark T. Young, Christopher J. Pickard, Andrew J. Logsdail, Paul A. Midgley, Kenneth D. M. Harris
      A new polymorph of L-tyrosine is reported, with the crystal structure determined by combined analysis of 3D-ED data and powder XRD data, augmented by information from periodic DFT-D calculations and solid-state 13C NMR data.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • A dynamic DNA nanosponge for triggered amplification of gene-photodynamic
           modulation

    • Abstract: Chem. Sci., 2022, 13,5155-5163

      DOI : 10.1039/D2SC00459C, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Dan Luo, Xue Lin, Yun Zhao, Jialing Hu, Fengye Mo, Gege Song, Zhiqiao Zou, Fuan Wang, Xiaoqing Liu
      Oligonucleotide drug delivery approach is provided with a biomimetic, dynamic DNA nanomaterial, which enables disease gene regulation and auxiliary therapy in a controllable and self-boosting manner.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Bioinspired superwettable electrodes towards electrochemical biosensing

    • Abstract: Chem. Sci., 2022, 13,5069-5084

      DOI : 10.1039/D2SC00614F, Review ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Qinglin Zhu, Yuemeng Yang, Hongxiao Gao, Li-Ping Xu, Shutao Wang
      The recent progress of superhydrophilic/phobic electrodes, superaerophilic/phobic electrodes, superwettable patterned electrodes, Janus wettability electrodes and wettability switchable electrodes in electrochemical biosensing is reviewed.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • The Janus face of high trans-effect carbenes in olefin metathesis: gateway
           to both productivity and decomposition

    • Abstract: Chem. Sci., 2022, 13,5107-5117

      DOI : 10.1039/D2SC00855F, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Giovanni Occhipinti, Daniel L. Nascimento, Marco Foscato, Deryn E. Fogg, Vidar R. Jensen
      In ruthenium catalysts for olefin metathesis, carbene ligands of high trans influence/effect suppress decomposition via β-H elimination, but increase susceptibility to bimolecular decomposition.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Predicting biomolecule adsorption on MoS2 nanosheets with high structural
           fidelity

    • Abstract: Chem. Sci., 2022, 13,5186-5195

      DOI : 10.1039/D1SC06814H, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Le Nhan Pham, Tiffany R. Walsh
      Benchmarked van der Waals density functional theory calculations are used to create a force-field to describe biomolecule interactions at the aqueous MoS2 interface, which can recover interfacial biomolecule adsorption with high structural fidelity.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Triazolinedione protein modification: from an overlooked off-target effect
           to a tryptophan-based bioconjugation strategy

    • Abstract: Chem. Sci., 2022, 13,5390-5397

      DOI : 10.1039/D1SC06942J, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Klaas W. Decoene, Kamil Unal, An Staes, Olivier Zwaenepoel, Jan Gettemans, Kris Gevaert, Johan M. Winne, Annemieke Madder
      A new strategy for selective tryptophan modification using triazolinedione (TAD) chemistry at pH 4 is shown on peptides and proteins. Additionally, off-target modification of tryptophan residues during the classical TAD-Y click reaction is uncovered.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Site-specific doping of silver atoms into a Au25 nanocluster as directed
           by ligand binding preferences

    • Abstract: Chem. Sci., 2022, 13,5148-5154

      DOI : 10.1039/D2SC00012A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Wan-Qi Shi, Zong-Jie Guan, Jiao-Jiao Li, Xu-Shuang Han, Quan-Ming Wang
      For the first time site-specific doping of silver into a spherical Au25 nanocluster has been achieved in [Au19Ag6(MeOPhS)17(PPh3)6] (BF4)2. It is a 6e system showing quite a different absorption spectrum from [Au25(SR)18]−.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Can a Wanzlick-like equilibrium exist between dicoordinate borylenes and
           diborenes'

    • Abstract: Chem. Sci., 2022, 13,5118-5129

      DOI : 10.1039/D1SC05988B, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Felipe Fantuzzi, Yinchun Jiao, Rian D. Dewhurst, Frank Weinhold, Holger Braunschweig, Bernd Engels
      The ground-state multiplicity of dicoordinate borylenes, which dictates their reactivity, is tuned by the nature of the stabilising carbene ligand.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Metal-free Deoxygenative Coupling of Alcohol-Derived Benzoates and
           Pyridines for Small Molecules and DNA-Encoded Libraries Synthesis

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01621D, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Sai Rohini Narayanan Kolusu, Manuel Nappi
      Alcohols are among the most widely occurring functional groups found in naturally abundant, biologically-relevant organic compounds, which in many cases are considered feedstock chemicals. Herein, we report a metal-free method...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Enhanced Catalysis of LIS3· Radical-to-Polysulfide Interconversion via
           Increased Sulfur Vacancies in Lithium–Sulfur Batteries

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01353C, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Rui Xu, Hong An Tang, Yuanyuan Zhou, Fangzheng Wang, Hongrui Wang, Minhua Shao, Cunpu Li, Zidong Wei
      The practical application of lithium-sulfur (Li-S) batteries is seriously hindered by severe lithium polysulfide (LiPS) shuttling and sluggish electrochemical conversions. Herein, the Co9S8/MoS2 heterojunction as a model cathode host material...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Reversible Tuning of Luminescence and Magnetism in a Structurally Flexible
           Erbium-Anilato MOF

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC00769J, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Noemi N. Monni, José J. Baldoví, Víctor García-López, Mariangela M. Oggianu, enzo cadoni, Francesco Quochi, Miguel Clemente Leon, Maria Laura Mercuri, Eugenio Coronado
      By combining 3,6-N-ditriazolyl-2,5-dihydroxy-1,4-benzoquinone (H2trz2An) with NIR-emitting ErIII ion, two different 3D neutral polymorphic frameworks (1a and 1b), differing for the number of uncoordinated water molecules, formulated as [Er2(trz2An)3(H2O)4]n·xH2O (x =...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Design and synthesis of TiO2/C nanosheets with a directional cascade
           carriers transfer

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01872A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Si-Ming Wu, Yi-Tian Wang, Shi-Tian Xiao, Yan-Xiang Zhang, Ge Tian, Jiang-Bo Chen, Xiao-Fang Zhao, Christoph Janiak, Menny Shalom, Detlef W. Bahnemann, Liying Wang, Xiao-Yu Yang
      Directed transfer of carriers, akin to excited charges in photosynthesis, in semiconductors by structure design is challenging. Here, TiO2 nanosheets with interlayered sp2 carbon and titanium vacancies are obtained by...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • CO reductive oligomerization by a divalent thulium complex and CO2-induced
           functionalization

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01798A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Thomas Simler, Karl Nael McCabe, Laurent Maron, Grégory Nocton
      The divalent thulium complex [Tm(Cpttt)2] (Cpttt = 1,2,4-tris(tert-butyl)cyclopentadienyl) reacts with CO to afford selective CO reductive dimerization and trimerization into ethynediolate (C2) and ketenecarboxylate (C3) complexes, respectively. DFT calculations were...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • The Oxidation State in Low-Valent Beryllium and Magnesium Compounds

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01401G, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Diego M Andrada, Pedro Salvador Sedano, Ines Corral, Anukul Jana, Sergi Danés, Martí Gimferrer, Eva Vos, Cem Burak Yildiz
      Low-valent group 2 (E = Be and Mg) stabilized compounds have been long preparatively pursued. Here we discuss the electronic structure on a series of Lewis base-stabilized Be and Mg...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Linker Engineering in Metal-Organic Frameworks for Dark Photocatalysis

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D1SC06785K, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yating Pan, Jingxue Wang, Shengyi Chen, Weijie Yang, Chunmei Ding, Amir Wasim, Hai-Long Jiang
      Dark reaction featuring continuous activity under light off conditions plays a critical role in natural photosynthesis. However, most of artificial photocatalysts are inactive upon the removal of light source, and...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Regulating the excited state chirality to fabricate
           high-performance-solid-state circularly polarized luminescence materials

    • Abstract: Chem. Sci., 2022, Advance Article

      DOI : 10.1039/D2SC01846B, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jianlei Han, Yonghong Shi, Xue Jin, Xuefeng Yang, Pengfei Duan
      In situ instant crystallization significantly boosts the CPL performance in which both large circular polarization and high luminescence efficiency are achieved due to the chiral supramolecular arrangement of chromophores in the crystalline state.
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      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Water molecular bridge-induced selective dual polarization in crystals for
           stable multi-emitters

    • Abstract: Chem. Sci., 2022, Advance Article

      DOI : 10.1039/D2SC00908K, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yi Xing, Zhongyu Li, Glib V. Baryshnikov, Shen Shen, Danfeng Ye, Hans Ågren, Liangliang Zhu
      In the solid state, the molecular polarization of donor–acceptor (D–A) molecules can be implemented by internal chemical polarization approaches.
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      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Material design and surface chemistry for advanced rechargeable
           zinc–air batteries

    • Abstract: Chem. Sci., 2022, Advance Article

      DOI : 10.1039/D1SC07212A, Review ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Soobeom Lee, Jinyeong Choi, Minsoo Kim, Jihan Park, Minjoon Park, Jaephil Cho
      This work reviews latest research on the bifunctional electrocatalysts for air cathodes, introducing the advanced zinc–air batteries with the full-temperature range operation, all-solid-states, and newly reported non-alkaline electrolytes.
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      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Progress and prospects of electrolyte chemistry of calcium batteries

    • Abstract: Chem. Sci., 2022, Advance Article

      DOI : 10.1039/D2SC00267A, Review ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Qianshun Wei, Liping Zhang, Xiaohua Sun, T. Leo Liu
      Chemical designs, electrochemical performance, and solution and interfacial chemistry of calcium battery electrolytes are comprehensively reviewed and discussed.
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      DOI form of citation above.
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  • Ultrafast coherent photoexcited dynamics in a trimeric dendrimer probed by
           X-ray stimulated-Raman signals

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC00601D, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Victor Manuel Freixas Lemus, Daniel Keefer, Sergei Tretiak, Sebastian Fernandez-Alberti, S. Mukamel
      The photoinduced ultrafast coherent inter-chromophore energy redistribution in a triarylamine trimer is explored using nonadiabatic excited state molecular dynamics followed by simulations of X-ray Raman signals. The nitrogencentered system ensures...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Operando acoustic analysis: a valuable method for investigating reaction
           mechanisms in mechanochemistry

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01496C, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.César Leroy, Sébastien Mittelette, Gautier Félix, Nicolas Fabregue, Jessica Špačková, Philippe Gaveau, Thomas-Xavier Métro, Danielle Laurencin
      We present a new operando approach for following reactions taking place in mechanochemistry, relying on the analysis of the evolution of the sound during milling. We show that differences in...
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  • Chemical Synthesis of Human Selenoprotein F and Elucidation of Its
           Thiol-Disulfide Oxidoreductase Activity

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC00492E, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Peisi Liao, Hongmei Liu, Chunmao He
      Selenoprotein F (SelF) is an endoplasmic reticulum-residing eukaryotic protein that contains a selenocysteine (Sec) residue. It has been suggested to be involved in a number of physiological processes by acting...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Functional amyloids from bacterial biofilms - structural properties and
           interaction partners

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC00645F, Review ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ümit Akbey, Maria Andreasen
      aggregation and amyloid formation have historically been linked with various diseases such as Alzheimer’s and Parkinson’s disease but recently functional amyloids have gained a great deal of interest in not...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • General electrochemical Minisci alkylation of N-heteroarenes with alkyl
           halides

    • Abstract: Chem. Sci., 2022, Advance Article

      DOI : 10.1039/D2SC01799G, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Roberto del Río-Rodríguez, Lorena Fragoso-Jarillo, Alberto F. Garrido-Castro, M. Carmen Maestro, Jose A. Fernández-Salas, José Alemán
      Herein, we report, a general, facile and environmentally friendly Minisci-type alkylation of N-heteroarenes under simple and straightforward electrochemical conditions using widely available alkyl halides as radical precursors.
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      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Regioselective Synthesis of Spirocyclic Pyrrolines via a
           Palladium-Catalyzed Narasaka-Heck/C-H Activation/[4+2] Annulation Cascade
           Reaction

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01887J, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Wan-Xu Wei, Xiangtao Kong, Rui-Qiang Jiao, Xue-Song Li, Cui-Tian Wang, Yuke Li, Yong-Min Liang
      A novel palladium-catalyzed spirocyclization through sequential Narasaka-Heck, C-H activation and [4+2] annulation has been developed. In this reaction, cheap and readily available 2-chlorobenzoic acid or ethyl phenylpropiolate was employed as...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Engineering lanmodulin's selectivity for actinides over lanthanides by
           controlling solvent coordination and second-sphere interactions

    • Abstract: Chem. Sci., 2022, Advance Article

      DOI : 10.1039/D2SC01261H, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Joseph A. Mattocks, Joseph A. Cotruvo, Gauthier J.-P. Deblonde
      Nature’s most potent protein for f-elements, lanmodulin, relies on subtle first-sphere/second-sphere interactions to bind metal ions. Dissecting lanmodulin’s binding mechanism yielded variants with enhanced actinide/lanthanide selectivity.
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      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Similarity based enzymatic retrosynthesis

    • Abstract: Chem. Sci., 2022, Advance Article

      DOI : 10.1039/D2SC01588A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Karthik Sankaranarayanan, Esther Heid, Connor W. Coley, Deeptak Verma, William H. Green, Klavs F. Jensen
      Using a large database of enzymatic transformations, similarity based enzymatic retrosynthesis search algorithm takes a holistic approach to enzymatic synthesis planning to yield a diverse set of single-step suggestions.
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      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Prediction and realisation of high mobility and degenerate p-type
           conductivity in CaCuP thin films

    • Abstract: Chem. Sci., 2022, Advance Article

      DOI : 10.1039/D2SC01538B, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Joe Willis, Ivona Bravić, Rekha R. Schnepf, Karen N. Heinselman, Bartomeu Monserrat, Thomas Unold, Andriy Zakutayev, David O. Scanlon, Andrea Crovetto
      We synthesize air-stable, p-type CaCuP thin films with high hole concentration and high hole mobility as potential p-type transparent conductors. We study their optoelectronic properties in detail by advanced experimental and computational methods.
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  • Heterometallic nanomaterials: activity modulation, sensing, imaging and
           therapy

    • Abstract: Chem. Sci., 2022, Advance Article

      DOI : 10.1039/D2SC00460G, Review ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shan-Shan Li, Ai-Jun Wang, Pei-Xin Yuan, Li-Ping Mei, Lu Zhang, Jiu-Ju Feng
      Heterometallic nanomaterials display wide applications in the fields of catalysis, sensing, imaging and therapy due to synergistic effects between the multi-metals.
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      DOI form of citation above.
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  • One-electron Bonds in Copper-Aluminum and Copper-Gallium Complexes

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01998A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Connie Lu, Michael Dorantes, Matthew Vollmer, Thais Scott, Brendan Graziano, Victor Young, Jr., Bill Eckhard, Laura Gagliardi
      Odd-electron bonds have unique electronic structures and are often encountered as transiently stable, homonuclear species. In this study, a pair of copper complexes supported by Group 13 metalloligands, M[N((o-C6H4)NCH2PiPr2)3] (M...
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  • Dual electrochemical and chemical control in atom transfer radical
           polymerization with copper electrodes

    • Abstract: Chem. Sci., 2022, Advance Article

      DOI : 10.1039/D2SC01982E, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Francesco De Bon, Francesca Lorandi, Jorge F. J. Coelho, Armenio C. Serra, Krzysztof Matyjaszewski, Abdirisak A. Isse
      The use of a Cu cathode in eATRP allows exploiting the synergistic effect between electrochemical and chemical stimuli to halt or accelerate polymerizations, reduce energy consumption and achieve control in challenging systems.
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  • Insights into Electrochemiluminescence Dynamics by Synchronizing Real-Time
           Electrical, Luminescent, and Mass Spectrometric Measurements

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01317G, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.xuemeng zhang, Weifeng Lu, Cheng Ma, Tao Wang, Jun-Jie Zhu, Richard N. Zare, Qianhao Min
      Electrochemiluminescence (ECL) comprises a sophisticated cascade of reactions. Despite advances in mechanistic studies by electrochemistry and spectroscopy, lack of the access to dynamic molecular information renders many plausible ECL pathways...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Direct in situ spectroscopic evidence of the crucial role played by
           surface oxygen vacancies in the O2-sensing mechanism of SnO2

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01738E, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Stefan Kucharski, Pilar Ferrer, Federica Venturini, G. Held, Alex Walton, Conor Byrne, James A Covington, Sai Kiran Ayyala, Andrew Michael Beale, Christopher S Blackman
      Conductometric gas sensors (CGS) provide a reproducible gas response at a low cost, but their operation mechanisms are not yet well understood. In this paper, we elucidate the nature of...
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  • Lithium achieves sequence selective ring-opening terpolymerisation
           (ROTERP) of ternary monomer mixtures

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01776H, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Alex Johannes Plajer, Patrick Pröhm, Susanne M. Rupf
      Heteroatom-containing degradable polymers have strong potential as sustainable replacements for petrochemically derived materials. However, to accelerate and broaden their uptake greater structural diversity and new synthetic methodologies are required. Here...
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  • Cagearenes: synthesis, characterization, and application for programmed
           vapor release

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01782B, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shuai Fang, Mengbin Wang, Yating Wu, Qing-Hui Guo, Errui Li, Hao Li, Feihe Huang
      Here, we announce the establishment of a new family of organic molecular cages, named cagearenes, by taking advantage of a versatile strategy. That is precursors grafted by 1,4-dimethoxybenzene groups are...
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  • Arsolyl-Supported Intermetallic Dative Bonding

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01200F, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Ryan M. Kirk, Anthony Hill
      The first examples of late transition metal η5-arsolyls [Co(CO)(L)(η5-AsC4R2R’2)] (L = CO, P(OMe)3; R = Ph, Me, Et, SiMe3; R’ = Ph, H, Me, Et, Me) serve as ditopic donors...
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  • Dynamic Kinetic Resolution of Transient Hemiketals: A Strategy for the
           Desymmetrisation of Prochiral Oxetanols

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01547A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Alexander Sandvoß, Henning Maag, Constantin Gabriel Daniliuc, Dieter Schollmeyer, Johannes M Wahl
      Identification of an electron poor trifluoroacetophenone allows the formation of uniquely stable hemiketals from prochiral oxetanols. When exposed to a cobalt(II) catalyst, efficient ring-opening to densely functionalized dioxolanes is observed....
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  • Why Heterogeneous Single-Atom Catalysts Preferentially Produce CO in the
           Electrochemical CO2 Reduction Reaction

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01593E, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yu Wang, Tianyang Liu, Yafei Li
      Formate and CO are competing products in the two-electron CO2 reduction reaction (2e CO2RR), and they are produced via *OCHO and *COOH intermediates, respectively. However, the factors governing CO/formate selectivity...
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  • Silicon functionalization expands the repertoire of Si-rhodamine
           fluorescent probes

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01821G, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Stephen Miller, Desaboini Nageswara Rao, Xincai Ji
      Fluorescent dyes such as rhodamines are widely used to assay the activity and image the location of otherwise invisible molecules. Si-rhodamines, in which the bridging oxygen of rhodamines is replaced...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Docking Rings in a Solid: Reversible Assembling of Pseudorotaxanes inside
           a Zirconium Metal–Organic Framework

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01497A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xia Li, Jialin Xie, Zhenglin Du, Long Jiang, Guangqin Li, Sanliang Ling, Kelong Zhu
      An unprecedented Zirconium Metal–organic framework featuring a T-shaped benzimidazole strut was constructed and employed as a sponge-like material for selective absorption of macrocyclic guests. The neutral benzimidazole domain of the...
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  • Enhancing Cell Membrane Phase Separation for Inhibiting Cancer Metastasis
           with a Stimuli-responsive DNA Nanodevice

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC00371F, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Di Li, Yingying Su, Xiaoqing Chen, Hui Wang, Lele Sun, YIng Xu
      Phase separation at cell membranes promotes the assembly of transmembrane receptors to initiate signal transduction in response to environmental cues. Many cellular behaviors are manipulated by promoting membrane phase separation...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Autophagy and evasion of immune system by SARS-CoV-2. Structural features
           of the Non-structural protein 6 from Wild Type and Omicron viral strains
           interacting with a model lipid bilayer

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC00108J, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Emmanuelle Bignon, Marco Marazzi, Stéphanie Grandemange, Antonio Monari
      The viral cycle of SARS-CoV-2 is based on a complex interplay with the cellular machinery, which is mediated by specific proteins eluding or hijacking the cellular defense mechanisms. Among the...
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  • A proximity labeling method for protein-protein interactions on cell
           membrane

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D1SC06898A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Qiongyu Li, Yixuan Xie, Rachel Rice, E. Maverakis, Carlito B Lebrilla
      Antibodies targeting specific antigens are widely utilized in biological research to investigate protein interactions or to quantify target antigens. Here, we introduce antigen-antibody proximity labeling (AAPL), a novel method to...
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  • Correction: Ultrasensitive recognition of AP sites in DNA at the
           single-cell level: one molecular rotor sequentially self-regulated to form
           multiple different stable conformations

    • Abstract: Chem. Sci., 2022, Advance Article

      DOI : 10.1039/D2SC90066A, CorrectionOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Beidou Feng, Kui Wang, Yonggang Yang, Ge Wang, Hua Zhang, Yufang Liu, Kai Jiang
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  • Standard-Free Single Magnetic Bead Evaluation: A Stable Nanoplatform for
           Prostate Disease Differentiation

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC00928E, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zili Huang, Xiaobo Xie, Bei Xu, Rui Liu, Jianyu Hu, Yi Lv
      Explicit interpretation of heterogeneity between prostate-specific antigen (PSA) subtypes is essential for prostate cancer differentiation during different disease courses, whereas the universal protocol with uniform criteria is still lacking across...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • A Bioorthogonal Chemical Reporter for the Detection and Identification of
           Protein Lactylation

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC00918H, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yanan Sun, Yanchi Chen, Tao Peng
      L-Lactylation is a recently discovered post-translational modification occurring on histone lysine residues to regulate gene expression. However, the substrate scope of lactylation, especially that in non-histone proteins, remains unknown, largely...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • A Dysprosium Single Molecule Magnet outperforming current pseudocontact
           shift agents

    • Abstract: Chem. Sci., 2022, Accepted Manuscript

      DOI : 10.1039/D2SC01619B, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Francielli Santana, Mauro Perfetti, Matteo Briganti, Francesca Sacco, Giordano Poneti, Enrico Ravera, Jaisa Fernandes Soares, Roberta Sessoli
      A common criterion for designing performant Single Molecule Magnets and Pseudocontact shift tags is a large magnetic anisotropy. In this article we present a Dysprosium complex chemically designed to exhibit...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
 
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