| Publisher: Geological Society of America
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Geology
Journal Prestige (SJR): 3.114  Citation Impact (citeScore): 4 Number of Followers: 54  Subscription journalISSN (Print) 0091-7613 - ISSN (Online) 1943-2682 Published by Geological Society of America  [4 journals]
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- The volatile record of volcanic apatite and its implications for the
formation of porphyry copper deposits-
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Abstract: AbstractVolatile saturation influences the physicochemical behavior of magmas and is essential for the sequestration of metals in porphyry copper deposits. Tracking the evolution of volatile components (F, Cl, H2O, S) in arc systems is complicated by their mobility and tendency to rapidly re-equilibrate with late-stage melts. We demonstrate that accurate measurements of volatile concentrations in apatite offer a reliable method for identifying the occurrence of volatile saturation. Fluorine, Cl, S, and calculated OH concentrations in apatite obtained by scanning electron microscope–energy-dispersive X-ray spectroscopy and electron microprobe analysis were used to compare two end-member volcanic systems in the West Luzon Arc (Philippines): Pinatubo (a fluid-saturated analogue for porphyry copper deposits) and Taal (a barren and fluid-undersaturated comparator). Apatites from Pinatubo are S-rich (0.04–0.64 wt%) and show a progressive decrease in XCl/XOH (0.6–0.25) and an increase in XF/XCl (1.5–8) and XF/XOH (0.75–1.2) during crystallization. Modeling indicates that these changes result from efficient partitioning of Cl into a continuously saturated H2O-rich fluid, while high regions of S in apatite reflect episodic flushing by a separate S-rich flux. Little S is evident in apatites from Taal (<300 ppm), which show increasing XCl/XOH and XF/XOH together with constant XF/XCl during crystallization. This cannot be explained using an H2O-saturated model, and instead reflects fluid-undersaturated crystallization and cooling in a reduced and/or S-depleted system. Measured volatiles in apatite therefore effectively discriminate volatile-saturated and undersaturated magmatic systems, providing an important ‘fertility’ filter for porphyry exploration.
PubDate: Thu, 05 Oct 2023 00:00:00 GMT
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- Seafloor spreading and the delivery of sulfur and metals to Earth’s
oceans-
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Abstract: AbstractCirculating fluids within Earth’s mid-ocean ridge system cool and alter the oceanic crust, contribute distinct chemistry to the ocean, and generate economically and geologically important metal-sulfide deposits at the seafloor. Yet, we have few constraints on the characteristics of these fluids at peak subseafloor pressure and temperature conditions or how the primary variable, seafloor spreading, affects these fluids’ delivery of metals and sulfur to seawater. Here, we develop a new, robust technique for estimating the peak endowment of heat and dissolved sulfur, iron, and copper in subseafloor hydrothermal fluids and determining their fate as these superheated fluids rise to the seafloor. Calculations using this technique indicate that >20%–70% of sulfur, iron, and copper dissolved at peak subseafloor conditions are lost during upflow due to cooling and concomitant decreases in sulfide mineral solubility. The interpretation of these estimates within the geologic context of vent fields allows us to demonstrate a strong inverse relationship between seafloor spreading rate and peak pressure-temperature conditions, subseafloor heat loss, and the magnitude of subseafloor sulfide mineralization. Our results demonstrate the extent to which the secular variation of Earth’s mid-ocean ridge system over geologic time has impacted sulfide deposition rates and hydrothermal fluxes of sulfur and metals to the ocean.
PubDate: Thu, 05 Oct 2023 00:00:00 GMT
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- Relationships between fluvial dune cross-set thickness, planview width,
and trough geometry-
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Abstract: AbstractSedimentary structures provide critical information for the reconstruction of ancient environments of Earth and other planets. Fluvial dune cross sets, structures that record dune migration via the filling of leading troughs along ancient riverbeds, are particularly useful. Most quantitative methods for interpreting cross sets require thickness measurements, but the growth of planview imaging of sedimentary rocks on Earth and Mars has introduced a need for methods to interpret planview exposures of cross sets. Here, we measured 359 cross-set widths exposed along ancient channel belts of the Cretaceous Cedar Mountain Formation exposed in Utah, USA, and compared these widths to published thicknesses (n = 350). We found that the mean cross-set width was 1.29 m, 9.3 times the mean thickness. The normalized distributions of widths and thicknesses were statistically similar and thus contained similar paleoenvironmental information. Numerical experiments representing a series of trough cut-and-fill structures show that cross-set reworking is equally important in setting width as thickness and that the observed cross-set widths could be explained by a gamma-distributed range of trough widths with a mean of 2.96 ± 0.25 m, ~2.3 times cross-set width. Given the similarity of dune-field geometries across depositional settings and planetary boundary conditions, we suggest this cross-set width-to-thickness relationship could be useful for interpreting other cross sets exposed in planview.
PubDate: Thu, 05 Oct 2023 00:00:00 GMT
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- Identifying plutons associated with long-lived volcanism by thermal
modeling of contact metamorphic aureoles-
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Abstract: AbstractA compilation of the thicknesses of contact metamorphic aureoles (CMAs) developed around intermediate to felsic plutons shows many CMAs are far broader than expected by commonly used thermal models for pluton emplacement. Shortfalls in the amount of heat potentially provided based on pluton size, compared to that needed to form the observed CMA, can be accounted for if some hot magma has been lost by volcanic eruption after passing through the pluton domain and replaced by new hot magma. A high ambient temperature may also contribute to broad CMA formation. However, the presence of coeval pairs of both narrow and broad CMAs in the same area requires contrasting types of pluton growth history. Our thermal modeling, constrained by the peak metamorphic temperature, shows the broad CMA of a well-developed pair of CMAs in the Hongusan area of Japan is due to a magmatic history, including magma tapping and replenishment. A global compilation of CMAs suggests more than 30% of plutons are associated with broad CMAs and fed contemporaneous volcanic eruption.
PubDate: Wed, 04 Oct 2023 00:00:00 GMT
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- Lithospheric-scale dynamics during continental subduction: Evidence from a
frozen-in plate interface-
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Abstract: AbstractContinental subduction and collision are not merely follow-ups of oceanic subduction but mark the transition from lithospheric-scale deformation localized along the subduction interface to crustal-scale deformation distributed across the orogen. In order to unravel the processes typifying the dynamic changes from oceanic subduction to collision, we have characterized the pressure-temperature (P-T) and spatio-temporal evolution of rocks on each side of the tectonic contact (Briançonnais–Liguro-Piemont [Br-LP] contact) separating the subducted oceanic remnants from the subducted continental fragments along the Western Alps.Results indicate that the maximum temperature and pressure difference on each side of the contact is generally <30 °C and <0.3 GPa, evidencing that no significant metamorphic gap exists. The preservation of similar P-T conditions on both sides of the Br-LP contact is interpreted as resulting from offscraping of the Liguro-Piemont and later Briançonnais units at similar depths, as supported by the ~10 m.y. gap between peak burial ages of both zones. The similar depth range reached by the various units reflects systematic variations of slicing and mechanical coupling along the plate interface suggesting that (1) similar slicing mechanisms and strain localization prevailed during both oceanic and continental subduction and (2) the Br-LP contact represents a frozen-in subduction interface. The end of high-pressure and low-temperature metamorphism and continental subduction at ca. 33 Ma would mark the stalling of subduction interface dynamics and the onset of strain distribution across the plate interface and into the lower plate.
PubDate: Wed, 04 Oct 2023 00:00:00 GMT
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- Strength of the winter North Atlantic jet stream has deviated from its
natural trend under anthropogenic warming-
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Abstract: AbstractThe North Atlantic jet stream (NAJ) has a profound impact on the climate of the North Atlantic–European sector, especially in winter. Observations show that the winter NAJ (NAJw) has strengthened over the past ~140 yr. However, it remains unclear whether this long-term trend has deviated from the natural variability. Here, we present a 2500-yr-long reconstruction of NAJw strength using high-quality stalagmite δ18O records from southeastern Europe. Our results show that the NAJw weakened during both the Roman Warm Period (300 B.C.–A.D. 200) and the Medieval Warm Period (A.D. 900–1250) but that it has strengthened under anthropogenic warming (since A.D. 1850). This indicates that its current trend has already deviated from the natural variability. The best explanation for this present anomalous trend of NAJw strength is that it was triggered by the appearance of the North Atlantic warming hole under anthropogenic forcing. This anomalous trend suggests that continued global warming may further strengthen the NAJw in the future.
PubDate: Tue, 03 Oct 2023 00:00:00 GMT
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- ERRATUM: Microbial sulfate reduction plays an important role at the
initial stage of subseafloor sulfide mineralization-
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Abstract: ORIGINAL ARTICLE: 2021, v. 49, no. 6, p. 222–227, https://doi.org/10.1130/G47943.1. First published 7 October 2020.
PubDate: Tue, 03 Oct 2023 00:00:00 GMT
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- Ammonium “nutrient capacitor” model for δ 15 N signatures associated
with marine anoxic events-
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Abstract: AbstractGeochemical records of ancient periods of warm climate can be useful to help understand the looming effects of modern anthropogenic warming, including changes to biogeochemical nutrient cycles. Stable nitrogen isotope compositions of marine sediments archive the balance of processes in the global nitrogen cycle. However, the unusual isotopic signals of Mesozoic oceanic anoxic events (OAEs) remain enigmatic, thus hindering our understanding of nitrogen cycle processes and dynamics under conditions of ocean deoxygenation. Here, we present an ammonium “nutrient capacitor” model of the water-column nitrogen cycle to explain the anomalously negative isotopic compositions seen in Mesozoic OAE sediments. Our model applies isotopic inferences derived from high-resolution records of Lake Kivu sediments to show how periodic chemocline overturning of redox-stratified water columns during Mesozoic OAEs may have delivered ammonium to the photic zone in excess of primary producer requirements. Smoothed, stochastic sampling of the changing fluxes within the nitrogen cycle across these events can simulate OAE nitrogen isotope records.
PubDate: Thu, 28 Sep 2023 00:00:00 GMT
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- Mantle metasomatism induced by water-fluxed melting of subducted
continental crust at ultrahigh pressures-
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Abstract: AbstractMantle metasomatism under ultrahigh-pressure (UHP) conditions is widely recognized in orogenic peridotites and pyroxenites from UHP terranes. However, the processes by which the deeply subducted continental crust reacts with the mantle remain obscure. To investigate the metasomatic regime under UHP conditions, we conducted layered reaction experiments between gneiss and peridotite at 5 GPa and 800–1100 °C, with free water added in some of the experiments. At temperatures below the gneiss solidus, the major metasomatic agent is aqueous fluid, with the main reaction products being orthopyroxene + phlogopite + K-richterite. At temperatures above the gneiss solidus, hydrous melt becomes the major metasomatic agent, and the major reaction products vary from orthopyroxene + phlogopite to orthopyroxene + garnet with increasing degree of melting. The transformation from phlogopite to garnet occurred between 1000 °C and 1100 °C for runs without water added and between 800 °C and 900 °C for runs with water added. Pyroxenites in UHP terranes are mainly characterized by the metasomatic growth of orthopyroxene and garnet at 4–6 GPa and 750–1000 °C. Only experiments with water added reproduced the metasomatic assemblage at similar pressure-temperature conditions, indicating that mantle metasomatism in UHP terranes is probably mainly induced by water-fluxed melting of the continental crust under UHP conditions.
PubDate: Wed, 27 Sep 2023 00:00:00 GMT
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- Controls on upstream-migrating bed forms in sandy submarine channels
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Abstract: AbstractSubmarine channels parallel river channels in their ability to transport sediment. However, in contrast to rivers, sediment transport and bed-form development in submarine channels are less well understood. Many steep (>1°), sandy submarine channels are dominated by upstream-migrating bed forms. The flow conditions required to form these upstream-migrating bed forms remain debated because the interactions between turbidity currents and active bed forms are difficult to measure directly. Consequently, we used a depth-resolved numerical model to test the role of flow parameters that are hypothesized to control the formation of upstream-migrating bed forms in submarine channels. While our modeling results confirmed the importance of previously identified flow parameters (e.g., densiometric Froude number), we found that basal sediment concentration in turbidity currents is the strongest predictor of upstream-migrating bed-form formation. Our model shows how locally steep gradients enable high sediment concentrations (average >5 vol%) in the basal parts of flows, which allow the development of cyclic step instabilities and their associated bed forms. This new insight explains the previously puzzling observation that upstream-migrating bed forms are abundant in proximal, steep, sandy reaches of submarine channels, while their occurrence becomes more intermittent downslope.
PubDate: Wed, 27 Sep 2023 00:00:00 GMT
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- “Wrecking the rocks”: Continental weathering by groundwater
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Abstract: AbstractGroundwater solute mass flux discharged from the continents to the oceans is between 56% and 63% of particulate sediment transport mass flux. Herein we utilized newly developed continental geospatial groundwater concentration estimates that were multiplied by groundwater volumetric recharge flux to provide a continental-scale discharge mass flux to the oceans of 7.3 Pg DS/yr (petagrams dissolved solutes per year). This mass flux was evaluated from six continental ecosystems: direct ocean discharge (0.28 Pg DS/yr), endorheic basins (0.59 Pg DS/yr), cold-wet exorheic basins (0.55 Pg DS/yr), cold-dry exorheic basins (1.1 Pg DS/yr), warm-dry exorheic basins (0.82 Pg DS/yr), and warm-wet exorheic basins (4.0 Pg DS/yr), thus providing insight into the role of rainfall and temperature on continental weathering and denudation. A new, robust molar silicate/carbonate ratio of 0.42 was calculated for weathering of continental rocks, which is important in the Urey model of climate change. We estimate that rock weathering accounts for ~50% of the total solute mass flux discharged from the continents, the remainder being from externally derived marine aerosols and organic-derived bicarbonate.
PubDate: Wed, 27 Sep 2023 00:00:00 GMT
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- Insights into initial continental rifting of marginal seas from seismic
evidence for slab relics in the mid-mantle of the Woodlark rift,
southwestern Pacific-
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Abstract: AbstractThe initiation and evolution of marginal seas, especially those developing under a convergent setting, is one of the more enigmatic aspects of plate tectonics. Here, we report the presence of slab relics in the mid-mantle of the Woodlark rift in the southwestern Pacific based on a new map of the topography of the mantle discontinuities from a receiver function analysis and evidence from body-wave tomography. The widespread mantle transition-zone thickening rules out active mantle upwelling, and the revealed slab relics in both the upper and middle mantle may hydrate the upper mantle, which can be expected to further weaken the overlying lithosphere. Such a process can then promote initial continental rifting when this lithosphere is exposed to tensional stress like slab-pull stretching originating from the nearby active subduction.
PubDate: Tue, 26 Sep 2023 00:00:00 GMT
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- Oceanic serpentinites: A potentially critical reservoir for deep nitrogen
recycling-
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Abstract: AbstractSerpentinized oceanic peridotites might be an important reservoir delivering volatile elements including nitrogen (N) into the mantle via subduction. To determine N sources and estimate the budget of alteration-added secondary N in the oceanic mantle peridotite reservoir, we examined oceanic serpentinites from four Ocean Drilling Program (ODP) sites in the Pacific and Atlantic Oceans. Our results showed that, despite large variation in serpentinization condition (high temperatures up to >350 °C at Holes 895D, 1271B, and 920D; low temperatures <150 °C at Hole 1274A), serpentinites from all sites displayed ubiquitous and similar magnitude of N enrichment (3.2–18.6 ppm) from sediments/seawater sources (δ15N = –3.3‰ to +4.4‰), and these values were significantly elevated relative to the low N concentration (0.04–2.0 ppm) and δ15N value (−5‰ ± 2‰) of the depleted mantle. Based on these data, the serpentinized oceanic mantle is estimated to contribute 0.4 ± 0.2–14.7 ± 6.9 × 109 mol N annually to global subduction zones. Although this flux is smaller than that of subducting sediments (57 × 109 mol·yr–1), comparison between oceanic serpentinites and meta-serpentinites from subduction zones suggests that N can be effectively retained in serpentinites during prograde metamorphism. This implies that the serpentinized slab mantle could be a critical reservoir to deliver N enriched in 15N to the mantle (at least 70 km depth) and potentially to the deepest portions of the mantle sampled by deep-rooted mantle plumes.
PubDate: Thu, 21 Sep 2023 00:00:00 GMT
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- Ongoing fragmentation of the subducting Cocos slab, Central America
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Abstract: AbstractFundamental to plate tectonics is the subduction of cold and mechanically strong oceanic plates. While the subducted plates are conventionally regarded to be impermeable to mantle flow and separate the mantle wedge and the subslab region, isolated openings have been proposed. By combining new shear wave splitting measurements with results from geodynamic modeling and recent seismic tomography and geochemical observations, we show that the upper ~200 km of the Cocos slab in northern Central America is intensively fractured. The slab there is strong enough to produce typical arc volcanoes and Benioff Zone earthquakes but allows mantle flow to traverse from the subslab region to the mantle wedge. Upwelling of hot subslab mantle flow through the slab provides a viable explanation for the behind-the-volcanic-front volcanoes that are geochemically distinct from typical arc volcanoes, and for the puzzling high heat flow, high elevation, and low Bouguer gravity anomalies observed in northern Central America.
PubDate: Thu, 21 Sep 2023 00:00:00 GMT
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- Formation of lower arc crust by magmatic underplating revealed by
high-precision geochronology-
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Abstract: AbstractIn modern plate tectonic regimes, continental crust is generated above subduction zones in magmatic island arcs. Models for continental growth—largely based on the modeling of geochemical processes that can transform mantle melts into the intermediate composition of bulk continental crust—have been hampered by a lack of definitive geochronology, which could clarify the temporal emplacement of igneous rocks at the base of island arc crust. The Kohistan Arc Complex (KAC) of Pakistan is a rare window into a nearly complete section of lower arc crust, revealing a sequence of igneous rocks representing discrete batches of magma underplated along the base of the arc crust. We present high-precision isotope dilution–thermal ionization mass spectrometry U-Pb geochronological data from zircon, and Lu-Hf and Sm-Nd isochron data from several mafic lower crustal cumulates within the KAC. These data establish a clear downward-younging age trend throughout this succession of cumulate complexes, demonstrating a total magmatic duration of ~20 m.y., corresponding to a rate of lower crust formation of up to 200–260 km3 km–1 Ma–1. These results provide the first direct evidence of a sequential process of underplating, revealing a fundamental mechanism responsible for building the root of island arc crust.
PubDate: Thu, 21 Sep 2023 00:00:00 GMT
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- Westward underthrusting of thick North American crust: The dominant
thickening process that built the Cordilleran orogenic plateau-
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Abstract: AbstractQuantification of the crustal thickening processes that construct orogenic plateaus is essential for interpreting their genesis. In the North American Cordillera, a 2.75–3.5-km-elevation, 200–250-km-wide plateau was constructed to the west of the Cretaceous–Paleogene Sevier fold-and-thrust belt (SFTB). The SFTB deformed a Mesoproterozoic to Mesozoic sedimentary package that thickened westward from a 2–3-km-thick platform section that was deposited above the ~40-km-thick craton to a 15–25-km-thick continental margin section that was deposited above middle to lower crust that had been significantly thinned during Neoproterozoic rifting. Shortening in the SFTB translated this thick sedimentary package as much as 265 km eastward, which resulted in the relative westward underthrusting of an equivalent length of thick cratonic basement beneath the hinterland region. Measurement of components of thickening with respect to the initial and final crustal thickness above and below the basal thrust décollement demonstrates that thickening accommodated by underthrusting outweighed thickening in the overlying SFTB by a factor of 1.5–3 and was likely the dominant thickening mechanism that constructed the broad hinterland plateau. In eastern Nevada, the reconstructed western edge of the underthrusted craton underlies the western limit of 2.75–3.5 km paleoelevations, which supports this interpretation. This analysis provides an important case study for underthrusting as a first-order thickening process in fold-and-thrust systems that deform sedimentary packages with a high pre-orogenic taper.
PubDate: Wed, 20 Sep 2023 00:00:00 GMT
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- Calcite-aragonite seas as a driver of echinoderm evolution' Experimental
insight and deep-time decoupling-
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Abstract: AbstractSeawater magnesium (Mg) and calcium (Ca) have undergone secular fluctuations throughout the Phanerozoic, controlling whether the dominant calcium carbonate precipitant is calcite or aragonite + high-Mg calcite. Although these oscillations in seawater Mg/Ca ratios have been implicated as an important control on Phanerozoic diversification of calcifying marine organisms, determining the degree to which Mg/Ca ratios affected different clades requires integration of experimental data with historical patterns of biodiversity from the fossil record. We explore short-term and long-term responses of echinoderms to shifting calcite-aragonite seas by combining experimental and deep-time biodiversity investigations. While experimental results support a strong relationship between Mg/Ca ratios and short-term echinoderm regeneration rates, patterns of Phanerozoic echinoderm diversification dynamics show no correspondence with Mg/Ca ratios or calcite-aragonite sea transitions. This decoupling between short- and long-term responses of echinoderms to seawater Mg/Ca ratios suggests echinoderms were relatively unaffected by seawater chemistry throughout their evolutionary history, possibly due to their ability to alter skeletal Mg fractionation and/or adapt to gradual shifts in seawater chemistry. Notably, our results indicate a strict uniformitarian extrapolation of experimental results over geological time scales may not be appropriate for many calcifying marine invertebrates. Instead, the effect of seawater Mg/Ca ratios should be evaluated for individual clades using both experimental and deep-time biodiversity data in a time series.
PubDate: Tue, 12 Sep 2023 00:00:00 GMT
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- Icy thermometers: Quantifying the impact of volcanic heat on glacier
elevation-
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Abstract: AbstractWe present a continentwide study of 600 glaciers located on and near 37 ice-clad volcanoes in South America. Results demonstrate glacier sensitivity to volcanic heat. We distinguished between “volcanic glaciers” (≤1 km from volcanic centers; n = 74), and “proximal glaciers” (1–15 km; n = 526) and calculated their equilibrium line altitudes (ELAs). For each ice-clad volcano, we compared the ELAs of its volcanic glaciers to those of its proximal glaciers, which showed that the ELAs of the former are higher than the ELAs of the latter. ΔELAmean, defined as the offset between the mean ELA of the volcanic glaciers compared with that of the proximal glaciers, was calculated for each ice-clad volcano. ΔELAmean was positive for 92% of the 37 volcanoes, and a quantitative relationship between ΔELAmean and volcanic thermal anomaly was established. Results highlight the impact of volcanic heat on glacier elevation; emphasize the need to exclude glaciers on, or near, volcanoes from glacier-climate investigations; and demonstrate the first-order potential for glaciers as “volcanic thermometers.” Volcanic-glacier monitoring could contribute to our understanding of magmatic and thermal activity, with changes in glacier geometries potentially reflecting long-term fluctuations in volcanic heat and unrest.
PubDate: Thu, 31 Aug 2023 00:00:00 GMT
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