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Open Journal of Inorganic Chemistry
Number of Followers: 1  Open Access journalISSN (Print) 2161-7406 - ISSN (Online) 2161-7414 Published by Scientific Research Publishing  [243 journals]
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- CoTe2–NiTe2 heterojunction directly grown on CoNi alloy foam for
efficient oxygen evolution reaction
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI00902H, Research ArticleYu Qi, Zhi Yang, Shuai Peng, Youcong Dong, Mingkui Wang, Xiao-Qing Bao, Hong Li, Dehua Xiong
One-step fabrication of a self-supported CoTe2–NiTe2 heterojunction electrocatalyst directly grown on CoNi foam for efficient and durable oxygen evolution reactions.
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- A new 2D layered aluminophosphate Hada 6[Al6(PO4)8](H2O)11 supported
highly uniform Ag nanoparticles for 4-nitrophenol reduction
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI00739D, Research ArticleJiang-Zhen Qiu, Long-Fei Wang, Xu-Gang Shu, Cui-Jin Li, Zhongke Yuan, Jiuxing Jiang
This work presents a new 2D aluminophosphate (ZHKU-1) with inorganic sheets containing a 4,6,12-net in AAAA-stacked sequence. Moreover, small Ag clusters supported on ZHKU-1 exhibit excellent catalytic performance in 4-nitrophenol reduction.
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- Tuning the Luminescence of Transition Metal Complexes with Acyclic
Diaminocarbene Ligands
Abstract: Inorg. Chem. Front., 2022, Accepted Manuscript
DOI : 10.1039/D1QI01288F, Review Article
Open Access 
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Mikhail A. Kinzhalov, Elena V. Grachova, Konstantin V Luzyanin
Organometallics featuring acyclic diaminocarbene (ADC) ligands have recently emerged as powerful emitters for use in OLEDs and other electroluminescent technologies. Owing to strong σ-donor properties and broad synthetic availability, ADCs...
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- Conversion of a double‐tetranuclear cluster silver helicate into a
dihelicate via a rare desulfurization process
Abstract: Inorg. Chem. Front., 2022, Accepted Manuscript
DOI : 10.1039/D1QI01308D, Research ArticleSandra Fernández-Fariña, Luis Miguel González-Barcia, María José Romero, Javier García-Tojal , Marcelino Maneiro, José Manuel Seco, Guillermo Zaragoza, Miguel Martinez-Calvo, Ana M. González-Noya, Rosa Pedrido Castiñeiras
We present the first example of a silver double‐tetranuclear cluster helicate [Ag4L2]2 obtained from a bisthiosemicarbazone ligand using electrochemical synthesis. This cluster helicate undergoes a rare desulfurization process in chloroform...
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- Highly selective ethenolysis with acyclic-aminooxycarbene ruthenium
catalysts
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01132D, Research ArticleSeunghwan Byun, Da-Ae Park, Seyong Kim, Sunghyun Kim, Ji Yeon Ryu, Junseong Lee, Sukwon Hong
Acyclic carbene–ruthenium catalysts were developed for the ethenolysis. Remarkable catalytic efficiency (turnover numbers of 100 000) and excellent α-olefin selectivity (up to 98%) were exhibited.
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- Evaporation crystallization of zero-dimensional guanidinium bismuth iodide
perovskite single crystal for X-ray detection
Abstract: Inorg. Chem. Front., 2022, Accepted Manuscript
DOI : 10.1039/D1QI01049B, Research ArticleYaxin Xu, Jiarui Hu, Xingfu Xiao, Huanfeng He, Guoliang Tong, Junnian Chen, Yunbin He
Bismuth halides hybrid perovskites have aroused intense interest in optoelectronic fields. However, develop novel bismuth halides hybrid perovskites to balance the hydrophobicity and electron transport ability is still challenging. Besides,...
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- Introducing the penicillamine moiety into a metallopeptide mimicking the
NiSOD enzyme: electronic and kinetic effects
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01025E, Research Article Open Access 
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Dóra Bonczidai-Kelemen, Giuseppe Sciortino, Nóra V. May, Eugenio Garribba, István Fábián, Norbert Lihi
The novel NiSOD related metallopeptide incorporates penicillamine moiety in the active center which alters both the electronic and kinetic features.
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- CsCu3SbS4: rational design of a two-dimensional layered material with
giant birefringence derived from Cu3SbS4
Abstract: Inorg. Chem. Front., 2022, Accepted Manuscript
DOI : 10.1039/D1QI01318A, Research ArticleChang Liu, Shenghua Zhou, Chao Zhang, Yaying Shen, Xiao-Yan Liu, Hua Lin, Yi Liu
It is an important and challenging task to develop new infrared (IR) birefringent materials to promote the development of laser technology. In this work, a novel thioantimonate with the highest...
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- 2D WO3 nanosheets for high-performance electrochromic-supercapacitor
Abstract: Inorg. Chem. Front., 2022, Accepted Manuscript
DOI : 10.1039/D1QI01289D, Research ArticleShen Wang, Hongbo Xu, Jiupeng Zhao, Yao Li
In our article, 2D WO3 nanosheet arrays with (101) preferential orientation facets (WO3 NSHs) were successfully assembled on fluorine-doped tin oxide (FTO) electrode through a simple solvothermal method. The physicochemical...
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- Controlling the band structure and photocatalytic performance of single
atom Ag/C3N4 catalysts by variation of silver concentration
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01138C, Research ArticleJiayu Xin, Fei Li, Zhen Li, Jiaqi Zhao, Yu Wang
We have investigated the effect of the concentration of single Ag atoms on the electronic structure of C3N4, and the relationship between the energy band structure and photocatalytic performance has been analysed in depth as well.
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- Bottom-up Synthesis Strategy of a Two-dimensional {Fe5} Cluster-Based
Coordination Polymer: Stepwise Formation of {Fe5} Cluster and Its
Dimension Augmentation
Abstract: Inorg. Chem. Front., 2022, Accepted Manuscript
DOI : 10.1039/D1QI01333E, Research ArticleYe Tao, Huang-Fei Qin, Zhi-Rong Hu, Zhao-Ting Pan, Peng-Fei Yao, He-Dong Bian, Di Yao, Xiao-Huan Qin, Fu-Ping Huang
Sophisticated aggregation assembly is challenging in assembly chemistry. Monitoring the assembly process helps to understand the assembly mechanism and the create new building blocks. A two-dimensional (2D) cluster-based coordination polymer...
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- Distinct nonlinear optical responses in three pairs of 2D homochiral Ag(I)
enantiomers modulated by dicarboxylic acid ligands
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01321A, Research ArticleCongli Gao, Jianya Zhou, Minghui Cui, Diming Chen, Liming Zhou, Fengcai Li, Xi-Li Li
Based on three pairs of 2D homochiral Ag(I) enantiomers, we demonstrate that both the symmetry and degree of π-conjugation of the ligands have a significant effect on the type and intensity of their NLO responses.
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- Self-templating synthesis of heteroatom-doped large-scalable carbon anodes
for high-performance lithium-ion batteries
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01105G, Research ArticleGhulam Yasin, Muhammad Arif, Jiameng Ma, Shumaila Ibraheem, Donglin Yu, Lipeng Zhang, Dong Liu, Liming Dai
We design a simple and cost-effective strategy to construct a large–scalable nitrogen-rich sulfur-doped porous carbon material as a high-performance anode material for lithium-ion batteries.
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- Extended anisotropic phonon dispersion and optical properties of
two-dimensional ternary SnSSe
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01141C, Research ArticleMuhammad Usman, Zahir Muhammad, Ghulam Dastgeer, Natalia Zawadzka, Yijie Niu, Muhammad Imran, Maciej R. Molas, Hu Rui
The phonon dispersion and optical properties of mechanically exfoliated SnSSe were investigated with the aid of high-resolution Raman scattering and photoluminescence (PL) spectroscopies along with first-principles calculations.
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- Photoactive iron complexes: more sustainable, but still a challenge
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01112J, Review ArticlePhilipp Dierks, Yannik Vukadinovic, Matthias Bauer
With the “Criticality Score” used as a benchmark for sustainability – potentials, strategies and challenges are discussed to replace noble metal compounds in photosensitizers by the sustainable alternative iron.
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- New iron(II) spin-crossover metallomesogen with long aliphatic chain
terminated by a CC bond
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01181B, Research ArticleShuting Liu, Zhenhua Zhu, Xiao-Lei Li, Jinkui Tang
A new Fe(II) complex with long aliphatic chains and terminal CC bonds exhibits SCO behavior and liquid-crystalline properties.
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- Oxygen vacancy distributions and electron localization in a CeO2(100)
nanocube
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01179K, Research ArticleWeihua Ji, Na Wang, Qiang Li, He Zhu, Kun Lin, Jinxia Deng, Jun Chen, Hongjie Zhang, Xianran Xing
Oxygen vacancy distributions in a 5 nm CeO2 nanocube were determined using the Reverse Monte Carlo method. The oxygen vacancies tend to be located on the surface of the CeO2 nanocube, with far fewer in subsurface and internal regions.
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- Room temperature synthesis of UO2+x nanocrystals and thin films via
hydrolysis of uranium(IV) complexes
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01248G, Research ArticleJesse Murillo, Debiprasad Panda, Subhananda Chakrabarti, Alex Hattori, Leonel Griego, Venkata S. N. Chava, Sreeprasad T. Sreenivasan, Chintalapalle V. Ramana, Skye Fortier
Methods for the straightforward, room temperature synthesis of UO2+x nanoparticles and thin films using solution processable, molecular uranium(IV) compounds is described.
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- Heterometallic Re/Mo and Re/W cubane-type cluster complexes
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01230D, Research ArticleAleksei S. Pronin, Yakov M. Gayfulin, Taisiya S. Sukhikh, Alexander N. Lavrov, Vadim V. Yanshole, Yuri V. Mironov
A series of heterometallic Re/Mo and Re/W cubane-type cluster complexes were obtained. New cluster anions demonstrate a regular change in geometric characteristics and redox potentials depending on the composition of the cluster core.
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- The modification effect of Fe2O3 nanoparticles on ZnO nanorods improves
the adsorption and detection capabilities of TEA
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01339D, Research ArticleXiao Liang, Jing Zhang, Kewei Zhang, Xiaodong Yang, Mingzhe Zhang
The depletion layer and more active sites are the key factors for improving the gas sensitivity of an Fe2O3/ZnO sensor.
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- Regulating the lattice strain of platinum–copper catalysts for enhancing
collaborative electrocatalysis
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01348C, Research ArticleFangfang Chang, Yongpeng Liu, Qing Zhang, Zhichao Jia, Xiaolei Wang, Lin Yang, Zhengyu Bai
PtnCu100−n alloy nanostellates showed the high catalytic activity for both the oxygen reduction and alcohol oxidation reactions.
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- Self-reconstruction of cationic activated Ni-MOFs enhanced the intrinsic
activity of electrocatalytic water oxidation
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI00857A, Research ArticleXuemin Wang, Xixi Wang, Lin Zhao, Hanyu Zhang, Ming Liu, Cui Zhang, Shuangxi Liu
Here, the cation modified Ni-MOFs catalysts was cleverly designed. And the multilayer FeNi-LDH with enrich active sites derived by in-situ self-reconstruction in alkali solution was considered to be the decisive factor driving the OER reaction.
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- Tuning of spin-crossover behavior in two cyano-bridged mixed-valence
FeIII2FeII trinuclear complexes based on a TpR ligand
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01086G, Research ArticleArshia Sulaiman, Yi-Zhan Jiang, Mohammad Khurram Javed, Shu-Qi Wu, Zhao-Yang Li, Xian-He Bu
With the use of TpR derivatives, we have demonstrated the modulation in the SCO behavior in two analogous trinuclear complexes. Moreover, a change in the spin transition temperature via solvent loss is observed.
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- The rational construction of diamond-like dysprosium–hexacyanometallate
frameworks featuring dynamic magnetic behaviour
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01173A, Research ArticleAi-Huan Sun, Xi-Xi Liu, Rong Sun, Jin Xiong, Hao-Ling Sun, Song Gao
Four novel diamond-like dysprosium–hexacyanometallate frameworks featuring slow magnetic relaxation have been rationally constructed by a feasible building block strategy using hexacyanometallate to link superparamagnetic dimeric units.
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- Mind the gap! tailoring sol–gel ceramic mesoporous coatings on labile
metal–organic frameworks through kinetic control
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01128F, Research ArticleElisa Bindini, Tanja Lüdtke, Dorleta Otaegui, Marco Möller, Ryma Haddad, Cédric Boissière, Sergio E. Moya
Kinetic control allows for the synthesis of mesoporous silica shells on top of labile ZIF-8 cores without compromising MOF stability.
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- Phosphomolybdic acid encapsulated in ZIF-8-based porous ionic liquids for
reactive extraction desulfurization of fuels
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01255J, Research ArticleNing Yang, Linjie Lu, Linhua Zhu, Peiwen Wu, Duanjian Tao, Xiaowei Li, Jiahong Gong, Linlin Chen, Yanhong Chao, Wenshuai Zhu
Phosphomolybdic acid was encapsulated within a ZIF-8-based porous ionic liquid (HPMo@ZIF-8-PIL) for ultradeep reactive extraction desulfurization.
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- Oxygen vacancy enriched Cu-WO3 hierarchical structures for the thermal
decomposition of ammonium perchlorate
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01027A, Research ArticleJing Shi, Xiangying Xing, Huixiang Wang, Lin Ge, Haizhen Sun, Baoliang Lv
Cu-WO3 hierarchical structures are rapidly prepared and they exhibit excellent catalytic activity in AP decomposition due to their rich oxygen vacancies and Lewis acid sites.
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- Ion cross-linking assisted synthesis of ZIF-8/chitosan/melamine sponge
with anti-biofouling activity for enhanced uranium recovery
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01203G, Research ArticleXuejie Guo, Haocheng Yang, Jun Wang
A ZIF-8/chitosan/melamine sponge (CMZ8) uranium adsorbent was prepared using chitosan and zinc ions as adjuvants to achieve the integration of anti-fouling, adsorption and separation properties.
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- In situ construction of FeNi2Se4-FeNi LDH heterointerfaces with electron
redistribution for enhanced overall water splitting
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01185E, Research ArticleHanzhi Yu, Yaoyi Xie, Liming Deng, Hongjiao Huang, Junnan Song, Deshuang Yu, Linlin Li, Shengjie Peng
The abundant heterogeneous interfaces between the FeNi2Se4 and FeNi LDH can provide enriched active sites and accelerate reaction kinetics, which improves the overall water splitting performance.
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- Fluoride-free synthesis of high-silica, medium-pore zeolites PST-22 and
PST-30
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01213D, Research ArticleDonghui Jo, Suk Bong Hong
High-silica, medium-pore zeolites PST-22 and PST-30, which were recently discovered via the excess fluoride approach, have been synthesized using two pyrazolium-based dications as organic structure-directing agents, respectively, in hydroxide media.
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- Enhanced thermal stability and afterglow performance in
Sr2Ga2−xAlxSiO7:Ce3+ phosphors via band gap tailoring
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01152A, Research ArticleRongfu Zhou, Fengkai Ma, Yunlin Yang, Tingting Deng, Jingwei Li, Hongting Zhao, Jie Sheng, Qi Peng
Due to the change of band gap, the photoluminescence and persistent luminescence performances of Ce3+ in Sr2(Ga,Al)2SiO7 have been optimized by the regulation of Al3+/Ga3+.
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- Highly red-emissive salen–indium complexes: impact of
4-amino-substitution on the photophysical properties
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01337H, Research ArticleSang Woo Kwak, Hanif Mubarok, Ji Hye Lee, Hyonseok Hwang, Kang Mun Lee, Min Hyung Lee, Myung Hwan Park
4-NR2-appended salen–indium complexes were prepared via a one-pot synthetic pathway. The complexes exhibited narrow-bandwidth red emissions with high photoluminescence quantum yields that are the highest among the reported salen-based luminophores.
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- UiO-67-derived bithiophene and bithiazole MIXMOFs for luminescence sensing
and removal of contaminants of emerging concern in wastewater
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01184G, Research ArticleGiorgio Mercuri, Marco Moroni, Simona Galli, Clara Piccirillo, Agostina-Lina Capodilupo, Giulia Tuci, Giuliano Giambastiani, Andrea Rossin
The UiO-67-type MIXMOF [Zr6O4(OH)4(PhPh)5(TzTz)], containing a blue-emitting bithiazole linker, is a potential multifunctional material for environmental remediation, being both a luminescent sensor and an adsorbent for diclofenac in aqueous solutions.
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- Construction of brown mesoporous carbon nitride with a wide spectral
response for high performance photocatalytic H2 evolution
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01137E, Research ArticleJinzhou Chen, Xianglin Zhu, Zhifeng Jiang, Wei Zhang, Haiyan Ji, Xingwang Zhu, Yanhua Song, Zhao Mo, Huaming Li, Hui Xu
A novel brown mesoporous carbon nitride photocatalyst is synthesized by a doping strategy. The excellent visible light response and stable mesoporous structure lead to an efficient hydrogen evolution activity.
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- Photoactive perylenediimide metal–organic framework for boosting
iodoperfluoroalkylation of alkenes and oxidative coupling of amines
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01206A, Research ArticleZhengfen Liu, Chao Li, Jian Chen, Xiaobo Li, Fumang Luo, Feixiang Cheng, Jian-Jun Liu
A novel photoactive MOF was prepared based on an electron-deficient perylenediimide derivative, which exhibits excellent photocatalytic activities towards the iodoperfluoroalkylation of alkenes and the oxidation of amines to imines.
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- Electronic configuration modulation of tin dioxide by phosphorus dopant
for pathway change in electrocatalytic water oxidation
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01169C, Research ArticleHao Wan, Xue Xiao, Wei Ma, Ying Zhang, Xiaohe Liu, Yanyu Liu, Gen Chen, Ning Zhang, Yijun Cao, Renzhi Ma
Electronic configuration modulation of SnO2 nanoparticles was realized using a phosphorus dopant, contributing to the reaction pathway change of water oxidation.
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- Controlled assembly and reversible transformation of tuneable luminescent
Mo8-R6G hybrids
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01014J, Research ArticleHui-Min Zeng, Wei-Hong Wu, Chao Wang, Zhan-Guo Jiang, Cai-Hong Zhan
This work reports that two new assemblies based on POM and AIE-quenched R6G display tuneable fluorescence intensity; furthermore two hybrids can be controllably synthesized and reversible transformation can also be achieved.
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- Solvent-dependent textural properties of defective UiO-66 after acidic and
basic treatment
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI00226K, Research ArticleDaniele Cartagenova, Fabio A. Peixoto Esteves, Nathan T. Fischer, Jeroen A. van Bokhoven, Marco Ranocchiari
We report the effect of inorganic and organic acids and bases, in combination with different solvents, on the crystallinity and porosity of defective UiO-66 MOFs.
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- Construction of In2S3@ZIF-8@ZnIn2S4 hierarchical nanoflower
heterostructures to promote photocatalytic reduction activity
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI00973G, Research ArticleChengyuan Yang, Rong Wang, Wenxin Zhu, Jing Wang, Liang Zhang, Ting Du, Zhaoli Liu, Linxuan Xie, Jing Sun, Jianlong Wang
A ZIF-8 interface (as an electron donor–acceptor) is fabricated to achieve ultrahigh photoreduction efficiency by optimizing the hierarchical heterostructures.
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- Intramolecular π-conjugated channel expansion achieved by doping
cross-linked dopants into carbon nitride frameworks for propelling
photocatalytic hydrogen evolution and mechanism insight
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01122G, Research ArticleChunmei Li, Tingxu Zhou, Ming Yan, Shasha Cheng, Yun Wang, Jingxue Sun, Gang Chen, Hongjun Dong
PYM as a cross-linked bridge in CN frameworks via a multi-bonding mode expedites the transfer and separation of intramolecular photoproduced electron–hole pairs by π-conjugated channel expansion to improve the PHE activity.
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- Introducing ytterbium acetate to luminescent CsPbCl3 nanocrystals for
enhanced sensitivity of Cu2+ detection
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01235E, Research ArticleXiufeng Wu, Songtao Hu, He Shao, Lifang Li, Wenda Chen, Biao Dong, Lin Xu, Wen Xu, Donglei Zhou, Zhennan Wu, Hongwei Song, Xue Bai
The Yb(OAc)3 promoted the formation of CsPbCl3 nanowires (NWs). The NWs exhibited boost in conductivity and the adsorbed AcO− on the surface of NWs enhanced the adsorption capacity of Cu2+, which enabled NWs with high detection sensitivity of Cu2+.
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- Mo6+–P5+ co-doped Li2ZnTi3O8 anode for Li-storage in a wide temperature
range and applications in LiNi0.5Mn1.5O4/Li2ZnTi3O8 full cells
Abstract:Inorg. Chem. Front., 2022, Advance Article
DOI : 10.1039/D1QI01077H, Research ArticleZhongxue Zhang, Lianjing Feng, Huanhuan Liu, Lijuan Wang, Song Wang, Zhiyuan Tang
LZM7TP3O co-doped with Mo6+ and P5+, with excellent electrochemical performance at 0–55 °C, has been synthesized using a simple solid-state method. The LiNi0.5Mn1.5O4/LZM7TP3O full cell can power LED bulbs that emit different colors of light.
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