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CHEMISTRY (530 journals)            First | 1 2 3 4 5 6 | Last

Journal of Heterocyclic Chemistry     Hybrid Journal   (Followers: 5)
Journal of Immunoassay and Immunochemistry     Hybrid Journal   (Followers: 3)
Journal of Inclusion Phenomena and Macrocyclic Chemistry     Hybrid Journal   (Followers: 2)
Journal of Inorganic Biochemistry     Hybrid Journal   (Followers: 3)
Journal of Labelled Compounds and Radiopharmaceuticals     Hybrid Journal   (Followers: 1)
Journal of Macromolecular Science, Part A: Pure and Applied Chemistry     Hybrid Journal   (Followers: 4)
Journal of Mass Spectrometry     Hybrid Journal   (Followers: 20)
Journal of Materials Chemistry A : Materials for Energy and Sustainability     Full-text available via subscription   (Followers: 22)
Journal of Materials Chemistry B : Materials for Biology and Medicine     Full-text available via subscription   (Followers: 5)
Journal of Materials Chemistry C : Materials for Optical, Magnetic and Electronic Devices     Full-text available via subscription   (Followers: 6)
Journal of Materials Research     Full-text available via subscription   (Followers: 9)
Journal of Mathematical Chemistry     Hybrid Journal   (Followers: 4)
Journal of Medicinal Chemistry     Full-text available via subscription   (Followers: 141)
Journal of Membrane Science     Hybrid Journal   (Followers: 9)
Journal of Modern Chemistry & Chemical Technology     Full-text available via subscription   (Followers: 1)
Journal of Molecular Catalysis A: Chemical     Hybrid Journal   (Followers: 2)
Journal of Molecular Graphics and Modelling     Hybrid Journal   (Followers: 3)
Journal of Molecular Liquids     Hybrid Journal   (Followers: 3)
Journal of Molecular Modeling     Hybrid Journal   (Followers: 3)
Journal of Molecular Recognition     Hybrid Journal  
Journal of Molecular Spectroscopy     Hybrid Journal   (Followers: 6)
Journal of Molecular Structure     Hybrid Journal   (Followers: 3)
Journal of Nanostructure in Chemistry     Open Access   (Followers: 5)
Journal of Natural Gas Chemistry     Full-text available via subscription   (Followers: 2)
Journal of Nepal Chemical Society     Open Access  
Journal of Nucleic Acids Investigation     Open Access   (Followers: 2)
Journal of Ocean University of China (English Edition)     Hybrid Journal   (Followers: 2)
Journal of Organometallic Chemistry     Hybrid Journal   (Followers: 12)
Journal of Photochemistry and Photobiology A: Chemistry     Hybrid Journal   (Followers: 4)
Journal of Photochemistry and Photobiology C: Photochemistry Reviews     Full-text available via subscription   (Followers: 4)
Journal of Polymer Science Part A: Polymer Chemistry     Hybrid Journal   (Followers: 147)
Journal of Polymers     Open Access   (Followers: 1)
Journal of Porphyrins and Phthalocyanines     Hybrid Journal   (Followers: 2)
Journal of Pure and Applied Chemistry Research     Open Access  
Journal of Raman Spectroscopy     Hybrid Journal   (Followers: 9)
Journal of Saudi Chemical Society     Open Access  
Journal of Solid State Chemistry     Hybrid Journal   (Followers: 12)
Journal of Solution Chemistry     Hybrid Journal  
Journal of Structural Chemistry     Hybrid Journal  
Journal of Sulfur Chemistry     Hybrid Journal   (Followers: 2)
Journal of Superhard Materials     Hybrid Journal   (Followers: 1)
Journal of Surfactants and Detergents     Hybrid Journal   (Followers: 5)
Journal of Systems Chemistry     Open Access   (Followers: 1)
Journal of Taibah University for Science     Open Access  
Journal of the American Chemical Society     Full-text available via subscription   (Followers: 226)
Journal of the American Society for Mass Spectrometry     Hybrid Journal   (Followers: 15)
Journal of the American Society of Brewing Chemists     Full-text available via subscription   (Followers: 1)
Journal of the Bangladesh Chemical Society     Open Access  
Journal of the Chilean Chemical Society     Open Access   (Followers: 2)
Journal of the Iranian Chemical Society     Hybrid Journal   (Followers: 1)
Journal of the Korean Society for Applied Biological Chemistry     Hybrid Journal   (Followers: 1)
Journal of the Mexican Chemical Society     Open Access   (Followers: 1)
Journal of Theoretical and Computational Chemistry     Hybrid Journal   (Followers: 7)
Journal of Theoretical Chemistry     Open Access  
Journal of Wood Chemistry and Technology     Hybrid Journal   (Followers: 7)
JPC - Journal of Planar Chromatography - Modern TLC     Full-text available via subscription   (Followers: 6)
Jurnal Penelitian Sains (JPS)     Open Access  
Jurnal Teknologi Informasi     Open Access   (Followers: 3)
Kinetics and Catalysis     Hybrid Journal   (Followers: 4)
Korea-Australia Rheology Journal     Hybrid Journal  
Langmuir     Full-text available via subscription   (Followers: 35)
Latvian Journal of Chemistry     Open Access   (Followers: 1)
Lebensmittelchemie     Hybrid Journal   (Followers: 1)
Lipid Insights     Open Access   (Followers: 1)
Luminescence     Hybrid Journal   (Followers: 1)
Macromolecular Materials & Engineering     Hybrid Journal   (Followers: 4)
Macromolecular Rapid Communications     Hybrid Journal   (Followers: 4)
Macromolecular Research     Hybrid Journal  
Macromolecular Symposia     Hybrid Journal  
Macromolecular Theory and Simulations     Hybrid Journal  
Macromolecules     Full-text available via subscription   (Followers: 31)
Magnetic Resonance in Chemistry     Hybrid Journal   (Followers: 4)
Main Group Chemistry     Hybrid Journal  
Marine Chemistry     Hybrid Journal   (Followers: 4)
Marine Drugs     Open Access   (Followers: 4)
MATEC Web of Conferences     Open Access  
Materials Characterization     Hybrid Journal   (Followers: 21)
Materials Horizons     Full-text available via subscription  
Materials Research Bulletin     Hybrid Journal   (Followers: 15)
Materials Science Monographs     Full-text available via subscription   (Followers: 1)
Materials Science-Poland     Hybrid Journal  
Materials Sciences and Applications     Open Access   (Followers: 4)
MedChemComm     Full-text available via subscription   (Followers: 4)
Medicinal Chemistry Research     Hybrid Journal   (Followers: 10)
Metallography, Microstructure, and Analysis     Hybrid Journal   (Followers: 1)
Metallomics     Full-text available via subscription  
Micro and Nano Systems Letters     Open Access   (Followers: 1)
Microchimica Acta     Hybrid Journal   (Followers: 1)
Microporous and Mesoporous Materials     Hybrid Journal   (Followers: 3)
Modern Research in Catalysis     Open Access   (Followers: 2)
Molbank     Open Access  
Molecules     Open Access   (Followers: 3)
Molecules and Cells     Hybrid Journal   (Followers: 1)
Monatshefte für Chemie - Chemical Monthly     Hybrid Journal   (Followers: 3)
Moscow University Chemistry Bulletin     Hybrid Journal   (Followers: 2)
MRS Bulletin     Full-text available via subscription   (Followers: 5)
MRS Online Proceedings     Full-text available via subscription   (Followers: 1)
Nachrichten aus der Chemie     Full-text available via subscription   (Followers: 1)
Nano Reviews     Open Access   (Followers: 15)
Nanomaterials and the Environment     Open Access  

  First | 1 2 3 4 5 6 | Last

Journal Cover Kinetics and Catalysis
   [6 followers]  Follow    
   Hybrid Journal Hybrid journal (It can contain Open Access articles)
     ISSN (Print) 1608-3210 - ISSN (Online) 0023-1584
     Published by Springer-Verlag Homepage  [2209 journals]   [SJR: 0.25]   [H-I: 19]
  • Anti-Markovnikov hydration of α-olefins and the other pathways to
    • Abstract: Three possible mechanisms of the direct hydration of α-olefins under conditions of catalysis with metal complexes in solution are considered, and information that confirms the possible realization of the reaction steps of various types is presented. Factors determining the regioselectivity of reaction steps are considered in the framework of various mechanisms, and the available published data about catalytic systems capable of ensuring the direct hydration of α-olefins are analyzed. New approaches to organization of the synthesis of n-alcohols from olefins and dienes are discussed, which are based on the systems of consecutive reactions, conjugated, and combined (associated) processes.
      PubDate: 2014-03-01
  • Nickel, cobalt, and Ni-Co alloy nanopowders prepared by plasma-assisted
           milling: Catalytic activity in the carbon dioxide reforming of methane
    • Abstract: The nanopowders of Ni and Co metals and their alloy were prepared by plasma-assisted milling, and the activity of catalysts on their basis was studied in the carbon dioxide reforming of methane (CDRM) at atmospheric pressure. It was found that the catalytic activity of Ni nanopowder rapidly decreased because of the blocking of its surface by coking products. Co powder exhibited lower but stable activity, which gradually decreased as a result of coking only 300 h after the onset of reaction. A Ni-Co alloy (1: 1, by weight) is an active and selective catalyst for CDRM. Its catalytic activity appeared at 400°C; at 870°C, conversion reached 90% and remained unchanged for 500 h. The initial activity was restored by the regeneration of a catalyst based on the Ni-Co alloy with molecular hydrogen for several hours at 400°C.
      PubDate: 2014-03-01
  • Effect of preparation conditions on the formation of the active phase of
           carbon fiber catalytic systems for the low-temperature oxidation of carbon
    • Abstract: We studied the effects of the composition of impregnating solution and heat treatment conditions on the activity of catalytic systems for the low-temperature oxidation of CO obtained by the impregnation of Busofit carbon-fiber cloth with aqueous solutions of palladium, copper, and iron salts. The formation of an active phase in the synthesized catalysts at different stages of their preparation was examined with the use of differential thermal and thermogravimetric analyses, X-ray diffraction analysis, X-ray photoelectron spectroscopy, and elemental spectral analysis. The catalytic system prepared by the impregnation of electrochemically treated Busofit with the solutions of PdCl2, FeCl3, CuBr2, and Cu(NO3)2 and activated under optimum conditions ensured 100% CO conversion under a respiratory regime at both low (0.03%) and high (0.5%) carbon monoxide contents of air. It was found that the activation of a catalytic system at elevated temperatures (170–180°C) leads to the conversion of Pd(II) into Pd(I), which was predominantly localized in a near-surface layer. The promoting action of copper nitrate consists in the formation of a crystalline phase of the rhombic atacamite Cu2Cl(OH)3. The catalyst surface is finally formed under the conditions of a catalytic reaction, when a joint Pd(I)-Cu(I) active site is formed.
      PubDate: 2014-03-01
  • On the activation of Mo       class="a-plus-plus">2B and MoB catalysts in
           oct-1-ene epoxidation with        class="a-plus-plus">tert-butyl hydroperoxide
    • Abstract: The activation of Mo2B and MoB catalyst in the epoxidation of oct-1-ene with tert-butyl hydroperoxide is reported. The activation process is described by the Avraami-Erofeev topokinetic equation and includes two successive steps, viz., the nucleation and formation of a new active phase. The epoxide is produced only when the activated form of the catalyst is involved. The effective and topochemical constants of the process have been determined.
      PubDate: 2014-03-01
  • Kinetics of the liquid-phase hydrochlorination of methanol
    • Abstract: The kinetics of the liquid-phase hydrochlorination of methanol with hydrogen chloride in the absence of a catalyslt is reported. A kinetic equation is suggested for the reaction. The values of the preexponential factor, activation energy, and empiric coefficients characterizing the influence of the hydration of the chlorine anion on the rate of hydrochlorination have been.
      PubDate: 2014-03-01
  • New approaches to studying the kinetics of the radical reaction of        class="a-plus-plus">N-phenyl-1,4-benzoquinone
           monoimine with 2-mercaptobenzothiazole
    • Abstract: The kinetics of the reaction of N-phenyl-1,4-benzoquinone monoimine with 2-mercaptobenzothiazole in chlorobenzene at 298 and 343 K under argon has been studied by kinetic spectrophotometry. The reaction orders have been determined. The influence of tetraphenylhydrazine and azobisisobutyronitrile initiators has been investigated. An accelerating effect of one of the reaction products, 4-hydroxydiphenylamine, has been discovered. The accelerating effect strenthens with an increasing 2-mercaptobenzothiazole concentration. Two methods are proposed for determination of the kinetic parameters of the reaction. The first method uses data on the consumption rate of quinoneimine in the noninitiated reaction in the presence of 4-hydroxydiphenylamine. In the second method, the accumulation of quinone monoimine is studied during initiator decomposition in the presence of mixtures of 4-hydroxydiphenylamine and 2-mercaptobenzothiazole and parameters are estimated from the dependences of the limiting concentration of accumulated quinone monoimine on the initiation rate and on the concentrations of the reactants Using the proposed approaches, the numerical values of a number of kinetic parameters of the radical reactions of the quinone compounds with thiols have been determined for the first time for the reaction studied.
      PubDate: 2014-03-01
  • Localization of the copper-containing component in the pore volume of
           zeolite ZSM-5
    • Abstract: The distribution of the copper-containing component in the pore volume of zeolite ZSM-5 has been investigated by H2 and N2 adsorption at 77 K and IR spectroscopy. Samples were synthesized by ion exchange and incipient wetness impregnation. Copper-containing clusters are mostly located on the surface of the mesopores formed by packed zeolite nanocrystallites. This causes partial blocking of the volume of microporous channels for N2 molecules, but these channels remain accessible for H2 molecules. It has been deduced that no considerable amount of copper located in the structural channels of the zeolite. According to IR spectroscopic data, the sorption of copper ions in the Cu/ZSM-5 catalysts takes place on extraframe-work aluminum, which forms Al-OH-Al bridges and terminal Al-OH groups, and on terminal Si-OH groups located on the zeolite crystal surface.
      PubDate: 2014-03-01
  • Ni-based catalyst derived from Ni/Mg/Al hydrotalcite-like compounds and
           its activity in the methanation of carbon monoxide
    • Abstract: The supported Ni-based catalyst is widely used in the methanation process. Nevertheless, the major disadvantages of this catalyst are a poor behavior in the water-gas-shift (WGS) reaction and the deactivation at higher temperatures. A new kind of catalyst, nickel-containing oxides catalyst (NiMgAl), obtained from thermal treatment of hydrotalcite-like compounds (HTlcs) was prepared using the co-precipitation method. The performance of this catalyst was systematically investigated and compared with that of the Ni/Al2O3 catalyst. It was found that the NiMgAl catalyst shows an enhanced methanation activity compared to that of the Ni/Al2O3 catalyst and the former catalyst shows a better performance for the methanation especially at temperature over 550°C. Three NiMgAl catalysts with different nickel content were prepared and tested in the methanation operated at a GHSV of 15000 h−1 and n(H2)/n(CO) of 1.5. The results indicate that with the NiMg8 catalyst a higher activity and stability could be achieved than with the NiMg5 and NiMg6 samples, the effect mainly attributed to a higher extent of Ni dispersion was confirmed by XRD results.
      PubDate: 2014-03-01
  • Hydrodesulfurization catalysts P-Mo-W/γ-Al       class="a-plus-plus">2O       class="a-plus-plus">3: Characterization and
           catalytic activity
    • Abstract: P-Mo-W/γ-Al2O3 catalysts with various Mo and W contents have been synthesized. The parameters of the porous structure of their sulfide and oxide forms have been determined. The geometric parameters of the active phase of the sulfide catalysts have been calculated using high-resolution transmission electron microscopy data. The catalytic activity has been estimated in dibenzothiophene (DBT) hydrodesulfurization (HDS). The reaction under the conditions examined proceeds mainly as direct hydrodesulfurization. The catalytic activity has been correlated with the Mo/W molar ratio and with the proportions of edge and corner sites.
      PubDate: 2014-03-01
  • Photocatalytic oxidation of pharmaceuticals on thin nanostructured Zinc
           Oxide films
    • Abstract: The photocatalytic activity of thin ZnO films in the photocatalytic oxidation of the pharmaceuticals, paracetamol and chloramphenicol (Levomycetin) is reported. The films annealed at 500°C exhibit the highest activity. They have a wurtzite-like structure and consist of conducting branches, which are the spinodal decomposition products.
      PubDate: 2014-03-01
  • Sulfonated carbon nanocage as a catalyst for the per-O-acetylation of
    • Abstract: We report an efficient per-O-acetylation of carbohydrates. The use was made of the sulfonated carbon nanocage with high specific surface area and uniform mesoporous structure as a recyclable heterogeneous catalyst. This protocol eliminates the need to involve pyridine and provides products in good to excellent yields.
      PubDate: 2014-03-01
  • Kinetics of ethylbenzene oxy-chemiluminescence in the presence of
           antioxidants from tissues of the marine invertebrate        class="a-plus-plus">Eupentacta fraudatrix:
           Estimating the concentration and reactivity of the natural antioxidants
    • Abstract: Extracts from tissues of the holothuria Eupentacta fraudatrix suppress the oxy-chemiluminescence of ethylbenzene in chlorobenzene initiated by azobisisobutyronitrile thermolysis and enhanced by energy transfer to 9,10-dibromoanthracene. The decrease of the chemiexcitation rate in the reaction between peroxyl radicals is caused by radical interception by the antioxidants contained in the extracts. The concentrations of the antioxidants in the extracts and the rate constants of their reactions with peroxyl radicals have been estimated from chemiluminescence kinetics.
      PubDate: 2014-03-01
  • Optimal process conditions for zeolite catalyzed acylation of anisole
    • Abstract: Acylation of anisole is a commercially important reaction in the production of various fine chemicals, agrochemicals, pharmaceuticals and fragrances. Conventionally, it is carried out using the catalysts like AlCl3, FeCl3, ZnCl3, HF, which suffer from major drawbacks such as larger consumption, corrosion and safety issues, waste disposal and the material handling. Hence the conventional catalysts are being replaced with solid acid catalysts like H-Beta, H-ZSM5 to overcome the above drawbacks. In this work, liquid phase acylation of anisole has been carried out employing H Beta, H ZSM-5 and HY catalysts and the process standardization at a macrolevel has been done with reference to parameters like temperature, reaction time, molar ratio of reactants, catalyst nature, Si/Al ratio of catalyst and the catalyst quantity. In addition, catalyst stability was investigated.
      PubDate: 2014-03-01
  • Mathematical modeling of styrene and butyl acrylate homopolymerization via
           the reversible addition-fragmentation mechanism
    • Abstract: A mathematical model is suggested for the kinetics of the controlled free-radical polymerization of two monomers—styrene and butyl acrylate—via the reversible addition-fragmentation chain transfer (RAFT) mechanism (with 2,2′-azobisisobutyronitrile as the initiator and dibenzyl trithiocarbonate as the RAFT agent). A comparison of experimental molecular weight characteristics of polystyrene and poly(butyl acrylate) with those calculated using the model indicates that the model is valid. The effects of the process control parameters (temperature and the initial concentrations of the initiator, monomer, and RAFT agent) have been elucidated by a computational experiment.
      PubDate: 2014-03-01
  • Reaction space organization effect on propane pyrolysis in the presence of
           a nickel-copper catalyst
    • Abstract: Propane pyrolysis at atmospheric pressures and temperatures of 500–700°C in the presence of a bimetallic catalyst containing 50 wt % Ni, 40 wt % Cu, and a silicon dioxide textural promoter has been investigated. It has been established experimentally that the reactor geometry and the way the reactants are let in and out exert an effect on the catalytic pyrolysis. The overall process rate is mainly determined by the heterogeneous reaction occurring on the catalyst surface. The homogeneous constituent of the process has an effect on the propane conversion at the early stages of the reaction.
      PubDate: 2014-01-01
  • Effect of ketones on the equilibrium between peroxy radicals carrying the
           chains of cyclohexanol oxidation with molecular oxygen
    • Abstract: The influence of methyl phenyl ketone and diphenyl ketone on the kinetics of cyclohexanol oxidation initiated by cumyl peroxide at 373 K was studied. The ratio of the chain propagation rate constant involving the 1-hydroxy-1-phenylethylperoxy radical to the equilibrium constant of radical dissociation into methyl phenyl ketone and hydroperoxy radical (k 2.3/K′2 = 900 L2 mol−2 s−1) was determined by the selective inhibition method.
      PubDate: 2014-01-01
  • Solvent effect on the kinetics of the free-radical polymerization of
           styrene in the presence of fullerene C       class="a-plus-plus">60
    • Abstract: The induction period in the kinetic curves of styrene polymerization in the presence of fullerene C60 was found to increase significantly at a solvent (benzene, toluene, ortho-dichlorobenzene, CCl4) concentration of ≥50 mol %. The free-radical polymerization rates of styrene in the presence of fullerene C60 and solvents, the ratio of chain propagation and termination rate constants k p /k 0 1/2 , and the stoichiometric inhibition coefficient were determined.
      PubDate: 2014-01-01
  • Isoparametricity phenomenon and kinetic enthalpy-entropy compensation
           effect: Experimental evidence obtained by investigating pyridine-catalyzed
           reactions of phenyloxirane with benzoic acids
    • Abstract: The joint effect of structure and temperature on the rate and free activation energy of reactions between phenyloxirane and substituted benzoic acids catalyzed by substituted pyridines in acetonitrile has been investigated. A correlation analysis of the results of a multifactor kinetic experiment indicates the additivity of the joint effects of structural factors (substituents X in pyridines and substituents Y in benzoic acids) and of the effects of the substituents Y and temperature. Intensive interaction (nonadditivity) is observed between the effects of the substituents X and temperature. This fact has provided experimental evidence for the existence of the enthalpy-entropy compensation aspect of the isoparametricity phenomenon: at the isoparametric temperature point (isokinetic temperature), the rate (free activation energy) of the process is independent of the structure of the substituent X because of the existence of an enthalpy-entropy compensation effect; on passing through this point, an inversion of the effect of X on the catalytic activity of pyridines takes place (isoparametricity paradox). At the isoparametric point with respect to the substituent X constant, there is no temperature effect on the reaction rate because of the activation enthalpy being close to zero. The isoparametric properties of a cross series of reactions are used to describe the mechanism of the pyridine-catalyzed opening of the oxirane ring.
      PubDate: 2014-01-01
  • Partial oxidation of toluene with nitrous oxide under supercritical
    • Abstract: The partial oxidation of toluene with nitrous oxide over the H-ZSM-5 catalyst under supercritical conditions at temperatures of 370–420°C and pressures of 70–160 atm has been investigated for the first time. The maximum cresol selectivity under these conditions is 32%. The amounts of the resulting cresol isomers form the following decreasing sequence: m-cresol > o-cresol > p-cresol. The partial oxidation of toluene is accompanied by disproportionation and biphenyl formation.
      PubDate: 2014-01-01
  • Dissociation energy of N-H bonds in diatomic aromatic amines
    • Abstract: The dissociation energies of N-H bonds (D, kJ/mol) were calculated by the intersecting parabolas method using the kinetic data for the following aromatic diamines: para-phenylenediamine (359.8), N,N′-dimethyl-para-phenylenediamine (348.9), N-dimethyl-N′-methyl-para-phenylenediamine (342.4), N,N′-diphenyl-para-phenylenediamine (352.8), N,N′-diphenylethylenediamine (372.7), N,N′-diheptylethylenediamine (373.3), N,N′-di-(4,4′-ethoxyphenyl)ethylenediamine (363.3), N,N′-di-(4,4′-diisopropylphenyl)-para-phenylenediamine (344.6), 4-{[dimethyl(4-phenylamino)phenoxy)silyl]oxy}-N-phenylaniline (353.4), N,N′-di-β-naphthyl-para-phenylenediamine (354.6), N,N′-di-β-naphthoxy-para-phenylenediamine (353.7), 1,1′-dinaphthyl-2,2′-bis-N,N′-phenyldiamine (372.9), 1,1′-dinaphthyl-2,2′-bis-N,N′-β-naphthyldiamine (384.2), and 2,6-bis[(1E)-1-(2-phenylhydrazin-1-ylidene)ethyl]pyridine (367.9). Individual dissociation energies for the two N-H bonds were determined in N-phenyl-N′-isopropyl-para-phenylenediamine: D(PhN-H) = 352.5 and D(Me2CHN-H) = 348.7 kJ/mol.
      PubDate: 2014-01-01
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