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  Subjects -> CHEMISTRY (Total: 844 journals)
    - ANALYTICAL CHEMISTRY (51 journals)
    - CHEMISTRY (594 journals)
    - CRYSTALLOGRAPHY (21 journals)
    - ELECTROCHEMISTRY (25 journals)
    - INORGANIC CHEMISTRY (41 journals)
    - ORGANIC CHEMISTRY (45 journals)
    - PHYSICAL CHEMISTRY (67 journals)

CHEMISTRY (594 journals)                  1 2 3 | Last

Showing 1 - 200 of 735 Journals sorted alphabetically
2D Materials     Hybrid Journal   (Followers: 8)
Accreditation and Quality Assurance: Journal for Quality, Comparability and Reliability in Chemical Measurement     Hybrid Journal   (Followers: 26)
ACS Catalysis     Full-text available via subscription   (Followers: 34)
ACS Chemical Neuroscience     Full-text available via subscription   (Followers: 18)
ACS Combinatorial Science     Full-text available via subscription   (Followers: 23)
ACS Macro Letters     Full-text available via subscription   (Followers: 24)
ACS Medicinal Chemistry Letters     Full-text available via subscription   (Followers: 39)
ACS Nano     Full-text available via subscription   (Followers: 244)
ACS Photonics     Full-text available via subscription   (Followers: 12)
ACS Synthetic Biology     Full-text available via subscription   (Followers: 23)
Acta Chemica Iasi     Open Access   (Followers: 2)
Acta Chimica Sinica     Full-text available via subscription   (Followers: 1)
Acta Chimica Slovaca     Open Access   (Followers: 1)
Acta Chimica Slovenica     Open Access  
Acta Chromatographica     Full-text available via subscription   (Followers: 9)
Acta Facultatis Medicae Naissensis     Open Access  
Acta Metallurgica Sinica (English Letters)     Hybrid Journal   (Followers: 5)
Acta Scientifica Naturalis     Open Access   (Followers: 2)
adhäsion KLEBEN & DICHTEN     Hybrid Journal   (Followers: 5)
Adhesion Adhesives & Sealants     Hybrid Journal   (Followers: 8)
Adsorption Science & Technology     Full-text available via subscription   (Followers: 5)
Advanced Functional Materials     Hybrid Journal   (Followers: 51)
Advanced Science Focus     Free   (Followers: 3)
Advances in Chemical Engineering and Science     Open Access   (Followers: 56)
Advances in Chemical Science     Open Access   (Followers: 13)
Advances in Chemistry     Open Access   (Followers: 15)
Advances in Colloid and Interface Science     Full-text available via subscription   (Followers: 18)
Advances in Drug Research     Full-text available via subscription   (Followers: 22)
Advances in Enzyme Research     Open Access   (Followers: 9)
Advances in Fluorine Science     Full-text available via subscription   (Followers: 8)
Advances in Fuel Cells     Full-text available via subscription   (Followers: 16)
Advances in Heterocyclic Chemistry     Full-text available via subscription   (Followers: 9)
Advances in Materials Physics and Chemistry     Open Access   (Followers: 21)
Advances in Nanoparticles     Open Access   (Followers: 15)
Advances in Organometallic Chemistry     Full-text available via subscription   (Followers: 15)
Advances in Polymer Science     Hybrid Journal   (Followers: 41)
Advances in Protein Chemistry     Full-text available via subscription   (Followers: 17)
Advances in Protein Chemistry and Structural Biology     Full-text available via subscription   (Followers: 20)
Advances in Quantum Chemistry     Full-text available via subscription   (Followers: 5)
Advances in Science and Technology     Full-text available via subscription   (Followers: 12)
African Journal of Bacteriology Research     Open Access  
African Journal of Chemical Education     Open Access   (Followers: 2)
African Journal of Pure and Applied Chemistry     Open Access   (Followers: 7)
Agrokémia és Talajtan     Full-text available via subscription   (Followers: 2)
Al-Kimia : Jurnal Penelitian Sains Kimia     Open Access  
Alkaloids: Chemical and Biological Perspectives     Full-text available via subscription   (Followers: 3)
AMB Express     Open Access   (Followers: 1)
Ambix     Hybrid Journal   (Followers: 3)
American Journal of Biochemistry and Biotechnology     Open Access   (Followers: 66)
American Journal of Biochemistry and Molecular Biology     Open Access   (Followers: 15)
American Journal of Chemistry     Open Access   (Followers: 27)
American Journal of Plant Physiology     Open Access   (Followers: 14)
American Mineralogist     Hybrid Journal   (Followers: 14)
Analyst     Full-text available via subscription   (Followers: 40)
Angewandte Chemie     Hybrid Journal   (Followers: 225)
Angewandte Chemie International Edition     Hybrid Journal   (Followers: 222)
Annales UMCS, Chemia     Open Access   (Followers: 1)
Annals of Clinical Chemistry and Laboratory Medicine     Open Access   (Followers: 4)
Annual Reports in Computational Chemistry     Full-text available via subscription   (Followers: 3)
Annual Reports Section A (Inorganic Chemistry)     Full-text available via subscription   (Followers: 4)
Annual Reports Section B (Organic Chemistry)     Full-text available via subscription   (Followers: 8)
Annual Review of Chemical and Biomolecular Engineering     Full-text available via subscription   (Followers: 12)
Annual Review of Food Science and Technology     Full-text available via subscription   (Followers: 16)
Anti-Infective Agents     Hybrid Journal   (Followers: 3)
Antiviral Chemistry and Chemotherapy     Hybrid Journal  
Applied Organometallic Chemistry     Hybrid Journal   (Followers: 7)
Applied Spectroscopy     Full-text available via subscription   (Followers: 23)
Applied Surface Science     Hybrid Journal   (Followers: 28)
Arabian Journal of Chemistry     Open Access   (Followers: 6)
ARKIVOC     Open Access   (Followers: 2)
Asian Journal of Biochemistry     Open Access   (Followers: 1)
Atomization and Sprays     Full-text available via subscription   (Followers: 4)
Australian Journal of Chemistry     Hybrid Journal   (Followers: 7)
Autophagy     Hybrid Journal   (Followers: 2)
Avances en Quimica     Open Access   (Followers: 1)
Biochemical Pharmacology     Hybrid Journal   (Followers: 10)
Biochemistry     Full-text available via subscription   (Followers: 313)
Biochemistry Insights     Open Access   (Followers: 6)
Biochemistry Research International     Open Access   (Followers: 6)
BioChip Journal     Hybrid Journal  
Bioinorganic Chemistry and Applications     Open Access   (Followers: 9)
Bioinspired Materials     Open Access   (Followers: 5)
Biointerface Research in Applied Chemistry     Open Access   (Followers: 2)
Biointerphases     Open Access   (Followers: 1)
Biology, Medicine, & Natural Product Chemistry     Open Access   (Followers: 1)
Biomacromolecules     Full-text available via subscription   (Followers: 19)
Biomass Conversion and Biorefinery     Partially Free   (Followers: 10)
Biomedical Chromatography     Hybrid Journal   (Followers: 6)
Biomolecular NMR Assignments     Hybrid Journal   (Followers: 3)
BioNanoScience     Partially Free   (Followers: 5)
Bioorganic & Medicinal Chemistry     Hybrid Journal   (Followers: 121)
Bioorganic & Medicinal Chemistry Letters     Hybrid Journal   (Followers: 89)
Bioorganic Chemistry     Hybrid Journal   (Followers: 10)
Biopolymers     Hybrid Journal   (Followers: 18)
Biosensors     Open Access   (Followers: 2)
Biotechnic and Histochemistry     Hybrid Journal   (Followers: 1)
Bitácora Digital     Open Access  
Boletin de la Sociedad Chilena de Quimica     Open Access  
Bulletin of the Chemical Society of Ethiopia     Open Access   (Followers: 2)
Bulletin of the Chemical Society of Japan     Full-text available via subscription   (Followers: 24)
Bulletin of the Korean Chemical Society     Hybrid Journal   (Followers: 1)
C - Journal of Carbon Research     Open Access   (Followers: 3)
Cakra Kimia (Indonesian E-Journal of Applied Chemistry)     Open Access  
Canadian Association of Radiologists Journal     Full-text available via subscription   (Followers: 3)
Canadian Journal of Chemistry     Hybrid Journal   (Followers: 10)
Canadian Mineralogist     Full-text available via subscription   (Followers: 5)
Carbohydrate Research     Hybrid Journal   (Followers: 26)
Carbon     Hybrid Journal   (Followers: 66)
Catalysis for Sustainable Energy     Open Access   (Followers: 7)
Catalysis Reviews: Science and Engineering     Hybrid Journal   (Followers: 8)
Catalysis Science and Technology     Free   (Followers: 7)
Catalysis Surveys from Asia     Hybrid Journal   (Followers: 3)
Catalysts     Open Access   (Followers: 8)
Cellulose     Hybrid Journal   (Followers: 7)
Cereal Chemistry     Full-text available via subscription   (Followers: 4)
ChemBioEng Reviews     Full-text available via subscription   (Followers: 1)
ChemCatChem     Hybrid Journal   (Followers: 8)
Chemical and Engineering News     Free   (Followers: 15)
Chemical Bulletin of Kazakh National University     Open Access  
Chemical Communications     Full-text available via subscription   (Followers: 72)
Chemical Engineering Research and Design     Hybrid Journal   (Followers: 25)
Chemical Research in Chinese Universities     Hybrid Journal   (Followers: 3)
Chemical Research in Toxicology     Full-text available via subscription   (Followers: 20)
Chemical Reviews     Full-text available via subscription   (Followers: 179)
Chemical Science     Open Access   (Followers: 22)
Chemical Technology     Open Access   (Followers: 16)
Chemical Vapor Deposition     Hybrid Journal   (Followers: 5)
Chemical Week     Full-text available via subscription   (Followers: 8)
Chemie in Unserer Zeit     Hybrid Journal   (Followers: 58)
Chemie-Ingenieur-Technik (Cit)     Hybrid Journal   (Followers: 26)
ChemInform     Hybrid Journal   (Followers: 8)
Chemistry & Biodiversity     Hybrid Journal   (Followers: 6)
Chemistry & Biology     Full-text available via subscription   (Followers: 30)
Chemistry & Industry     Hybrid Journal   (Followers: 5)
Chemistry - A European Journal     Hybrid Journal   (Followers: 151)
Chemistry - An Asian Journal     Hybrid Journal   (Followers: 15)
Chemistry and Materials Research     Open Access   (Followers: 20)
Chemistry Central Journal     Open Access   (Followers: 4)
Chemistry Education Research and Practice     Free   (Followers: 5)
Chemistry in Education     Open Access   (Followers: 9)
Chemistry International     Hybrid Journal   (Followers: 2)
Chemistry Letters     Full-text available via subscription   (Followers: 44)
Chemistry of Materials     Full-text available via subscription   (Followers: 227)
Chemistry of Natural Compounds     Hybrid Journal   (Followers: 9)
Chemistry World     Full-text available via subscription   (Followers: 22)
Chemistry-Didactics-Ecology-Metrology     Open Access   (Followers: 1)
ChemistryOpen     Open Access   (Followers: 2)
Chemkon - Chemie Konkret, Forum Fuer Unterricht Und Didaktik     Hybrid Journal  
Chemoecology     Hybrid Journal   (Followers: 4)
Chemometrics and Intelligent Laboratory Systems     Hybrid Journal   (Followers: 15)
Chemosensors     Open Access  
ChemPhysChem     Hybrid Journal   (Followers: 9)
ChemPlusChem     Hybrid Journal   (Followers: 2)
ChemTexts     Hybrid Journal  
CHIMIA International Journal for Chemistry     Full-text available via subscription   (Followers: 2)
Chinese Journal of Chemistry     Hybrid Journal   (Followers: 6)
Chinese Journal of Polymer Science     Hybrid Journal   (Followers: 10)
Chromatographia     Hybrid Journal   (Followers: 24)
Clay Minerals     Full-text available via subscription   (Followers: 10)
Cogent Chemistry     Open Access  
Colloid and Interface Science Communications     Open Access  
Colloid and Polymer Science     Hybrid Journal   (Followers: 10)
Colloids and Surfaces B: Biointerfaces     Hybrid Journal   (Followers: 7)
Combinatorial Chemistry & High Throughput Screening     Hybrid Journal   (Followers: 4)
Combustion Science and Technology     Hybrid Journal   (Followers: 18)
Comments on Inorganic Chemistry: A Journal of Critical Discussion of the Current Literature     Hybrid Journal   (Followers: 2)
Composite Interfaces     Hybrid Journal   (Followers: 6)
Comprehensive Chemical Kinetics     Full-text available via subscription   (Followers: 2)
Comptes Rendus Chimie     Full-text available via subscription  
Comptes Rendus Physique     Full-text available via subscription   (Followers: 1)
Computational and Theoretical Chemistry     Hybrid Journal   (Followers: 9)
Computational Biology and Chemistry     Hybrid Journal   (Followers: 12)
Computational Chemistry     Open Access   (Followers: 2)
Computers & Chemical Engineering     Hybrid Journal   (Followers: 9)
Coordination Chemistry Reviews     Full-text available via subscription   (Followers: 3)
Copernican Letters     Open Access   (Followers: 1)
Critical Reviews in Biochemistry and Molecular Biology     Hybrid Journal   (Followers: 5)
Croatica Chemica Acta     Open Access  
Crystal Structure Theory and Applications     Open Access   (Followers: 4)
CrystEngComm     Full-text available via subscription   (Followers: 13)
Current Catalysis     Hybrid Journal   (Followers: 2)
Current Metabolomics     Hybrid Journal   (Followers: 5)
Current Opinion in Colloid & Interface Science     Hybrid Journal   (Followers: 9)
Current Opinion in Molecular Therapeutics     Full-text available via subscription   (Followers: 17)
Current Research in Chemistry     Open Access   (Followers: 8)
Current Science     Open Access   (Followers: 62)
Dalton Transactions     Full-text available via subscription   (Followers: 23)
Detection     Open Access   (Followers: 2)
Developments in Geochemistry     Full-text available via subscription   (Followers: 2)
Diamond and Related Materials     Hybrid Journal   (Followers: 12)
Dislocations in Solids     Full-text available via subscription  
Doklady Chemistry     Hybrid Journal  
Drying Technology: An International Journal     Hybrid Journal   (Followers: 4)
Eclética Química     Open Access   (Followers: 1)
Ecological Chemistry and Engineering S     Open Access   (Followers: 3)
Ecotoxicology and Environmental Contamination     Open Access  
Educación Química     Open Access   (Followers: 1)
Education for Chemical Engineers     Hybrid Journal   (Followers: 5)
EJNMMI Radiopharmacy and Chemistry     Open Access  
Elements     Full-text available via subscription   (Followers: 3)

        1 2 3 | Last

Journal Cover Chemical Research in Chinese Universities
  [SJR: 0.255]   [H-I: 17]   [3 followers]  Follow
    
   Hybrid Journal Hybrid journal (It can contain Open Access articles)
   ISSN (Print) 1005-9040 - ISSN (Online) 2210-3171
   Published by Springer-Verlag Homepage  [2354 journals]
  • Mechanical and thermal properties of waterborne polyurethane films
           modified by CaCO 3 @TiO 2 particles with UV absorption activity
    • Authors: Tiechao Jiang; Qingqiu Fan; Chunying Huang; Zhen Li; Lijie Guo; Bing Zhou
      Abstract: CaCO3@TiO2 particles were synthesized through a direct carbonation method, which can be used as the substitutes of TiO2 in pigments and coatings. To improve the dispersion in waterborne polyurethane(WPU) suspen-sions, CaCO3@TiO2 particles were modified by stearic acid. SEM tests of the fractured surfaces of the composites films showed that the CaCO3@TiO2 particles were well embedded in the WPU matrix. And the mechanical properties, thermal stability and water resistance of the composites films were improved by the introduction of CaCO3@TiO2 particles.
      PubDate: 2017-11-15
      DOI: 10.1007/s40242-017-7088-8
       
  • Morphology effect of metal-organic framework HKUST-1 as a catalyst on
           benzene oxidation
    • Authors: Yanfeng Liu; Boliang Liu; Qingfeng Zhou; Tianyong Zhang; Wubin Wu
      Abstract: An attempt was made to study whether the morphology effect of metal-organic frameworks HKUST-1 could significantly influence the chemical reaction of benzene oxidation. Four representative cupric salts, CuSO4·5H2O, Cu(OAc)2·H2O, CuCl2·2H2O and Cu(NO3)2·3H2O, were treated with 1,3,5-benzenetricarboxylic acid under ultrasound or with static method at room temperature to prepare metal-organic frameworks(12 types of HKUST-1 samples). And the as-prepared HKUST-1 materials were comprehensively investigated by X-ray diffraction, scanning electron microscopy and N2 adsorption-desorption. The HKUST-1 samples with different morphologies and characterisitcs were employed as catalysts for benzene oxidation with H2O2 as oxidant at 60 °C in acetonitrile to achieve the aromatic oxygenates and test their yields. In all the HKUST-1 samples, the HKUST-1/SA, HKUST-1/SA0 and HKUST-1/UN had the higher catalytic activities with the yields of benzene oxygenates of 15.9%, 16.6% and 11.7%, respectively, which can be ascribed to the larger pore volume, the stronger benzene adsorption and the smaller fine crystal particles. Comparatively, the HKUST-1/SN0 and HKUST-1/SC0 with more intact crystal, larger surface area, lower pore volume and weaker benzene adsorption had the lower catalytic activities with the yields of benzene oxygenates not more than 4%. Therefore, our results confirmed that employing various cupric precursors to prepare the HKUST-1 samples with different morphologies and characteristics can be considered as a worth strategy to design many more powerful heterogeneous catalysts.
      PubDate: 2017-11-15
      DOI: 10.1007/s40242-017-6468-4
       
  • Synthesis of (Ph 3 P) 2 PdX 2 complexes and their catalytic activity for
           Heck reaction involving aryl halide and acrylate
    • Authors: Chengxin Liu; Fangwai Han; Guiyan Liu; Hongkun Zhao
      Abstract: Two palladium complexes, (Ph3P)2PdBr2 and (Ph3P)2PdI2, were synthesized by a new method and their structures were confirmed by NMR, elemental analysis and X-ray crystallography. The catalytic activity of the two palladium complexes was evaluated in Mizoroki-Heck cross-coupling reaction of aryl halide with acrylate, the results show that they all have high catalytic activity to many different substrates.
      PubDate: 2017-11-15
      DOI: 10.1007/s40242-017-7125-7
       
  • Improving the performance of TIPS-pentacene thin film transistors via
           interface modification
    • Authors: Xiaofei Zhu; Xiaodong Zhang; Lizhen Huang; Zi Wang; Lifeng Chi
      Abstract: Understanding the structure-performance relationship is crucial for optimizing the performance of organic thin film transistors. Here, two interface modification methods were applied to modulate the thin film morphology of the organic semiconductor, 6,13-bis(triisopropylsilylethynyl)pentacene(TIPS-pentacene). The resulting different film morphologies and packing structures led to distinct charge transport abilities. A substantial 40-fold increase in charge carrier mobility was observed on the octadecyltrichlorosilane(OTS)-modified sample compared to that of the transis-tor on the bare substrate. A better charge mobility greater than 1 cm2·V‒1·s‒1 is realized on the p-sexiphenyl(p-6P)-modified transistors due to the large grain size, good continuity and, importantly, the intimate π-π packing in each domain.
      PubDate: 2017-11-15
      DOI: 10.1007/s40242-017-7122-x
       
  • Enhanced visible-light-driven photocatalytic performance of In 2 O 3
           -loaded TiO 2 nanocubes with exposed (001) facet
    • Authors: Bifen Gao; Jianfeng Wan; Desheng Hu; Yilin Chen; Bizhou Lin
      Abstract: The heterostructures of In2O3 nanoparticle loaded on anatase TiO2 nanocube with exposed (001) facet (In2O3/TiO2-nanocube) were fabricated via a two-step hydrothermal process. The crystal phase, morphology, mi-cro-structure and photo-absorption property of the products were characterized by FESEM, TEM, XRD, and UV-Vis diffuse reflectance spectroscopy. The results showed that the percentage of exposed (001) facet of TiO2 nanocube was about 33%. In2O3 nanoparticles were successfully decorated on the surface of TiO2 nanocube to form the In2O3/TiO2 heterojunction. Photocurrent measurements confirmed that (001) faceted surface was advantageous for the charge carrier migration and separation in the composites. In comparison with bare TiO2 nanocube and In2O3/TiO2-nanoparticle, the In2O3/TiO2-nanocube heterostructures exhibited enhanced activity toward the degrada-tion of rhodamine B and tetracycline under visible light irradiation, which was attributed to the synergic effect of In2O3/TiO2 heterojunction and the exposure of (001) facet.
      PubDate: 2017-11-15
      DOI: 10.1007/s40242-017-7133-7
       
  • Morphology and properties of PP in-reactor alloys prepared with a MgCl 2
           /TiCl 4 /diisobutyl phthalate/phosphate tris-methylphenyl ester catalyst
           system
    • Authors: Chunyu Zhang; Bo Dong; Hexin Zhang; Yanming Hu; Xuequan Zhang
      Abstract: A series of polypropylene(PP)/poly(ethylene-co-propylene) in-reactor alloys with different ethylene con-tents was prepared through a two-stage polymerization process using a MgCl2/TiCl4/diisobutyl phthalate/phosphate tris-methylphenyl ester catalyst system. The ethylene content, particle shape, fractured surface, and glass-transition temperature(T g) of the obtained PP in-reactor alloys were characterized by means of nuclear magnetic resonance, scanning electron microscopy(SEM), and dynamic mechanical analysis(DMA). The ethylene content of the PP alloys increased from 2.34% to 26.69% when the propylene/ethylene feed ratio was increased from 66/34 to 54/46(molar ratio). Morevoer, the increment in ethylene content increased the notched Izod impact strength of the resulting PP al-loys. The impact strength of the PP alloy with an ethylene content of 26.69% was 55.8 kJ/m2, which is 12.7 times that of isotactic polypropylene. The results of DMA and SEM analysis reveal that ethylene-propylene random copoly-mer(EPR) in the PP alloy has a low T g of ca.‒50 °C and a high interface compatibility with the PP matrix. The ex-cellent impact performance of the PP alloy can be attributed to the uniform dispersal of EPR in the alloy particles and PP matrix.
      PubDate: 2017-11-15
      DOI: 10.1007/s40242-017-7140-8
       
  • Influence of fluoride ions on the structure-directing effect of organic
           amine in the synthesis of aluminophosphate open-frameworks
    • Authors: Ye Tian; Jun Xu; Zi Wang; Feng Deng; Ruren Xu; Wenfu Yan
      Abstract: The crystallization behavior of the initial mixture with the composition of Al2O3:4.0P2O5:3.0 diethylene-triamine(DETA):xHF:153H2O was investigated at 180 °C, where 0≤x≤3. If x≤1.8, three-dimensional open- framework aluminophosphate AlPO-CJ31 was obtained. If 2≤x≤3, a chain-like aluminophosphate(1) was obtained. The crystallization process of both compounds was investigated by means of powder X-ray diffraction(XRD) and the concentrations of Al and P in the liquid product during the crystallization process were analysed by means of induc-tively coupled plasma atomic emission spectroscopy(ICP-AES). The evolution of the coordination state of Al, P and F during the crystallization was monitored with 27Al, 31P and 19F MAS NMR technique. The influence of the fluoride ions and the source of fluoride ions on the structure-directing effect of DETA was discussed. It was found that the fluoride ions changed the crystallization direction of the initial mixture, i.e., the structure-directing effect of DETA, via altering the distribution or micro-structure of the inorganic fragments.
      PubDate: 2017-11-15
      DOI: 10.1007/s40242-017-7131-9
       
  • Preparation of polyclonal antibody and development of a
           biotin-streptavidin-based ELISA method for detecting kanamycin in milk and
           honey
    • Authors: Ping Su; Xiaonan Chen; Zhangjing He; Yi Yang
      Abstract: Kanamycin is an aminoglycoside antibiotic used increasingly in human and veterinary medicine. However, kanamycin residues in food can cause serious side effects. Here we reported the preparation of polyclonal antibody and the development of an indirect competitive biotin-streptavidin-amplified-based enzyme-linked immunosorbent assay(BA-ELISA) that can sensitively and specifically detect kanamycin residues in milk and honey. The immunogen and coating antigen were synthesized by covalently linking kanamycin to carrier proteins using the carbodiimide me-thod. The anti-kanamycin polyclonal antibodies were obtained from immunized rabbits. The key assay parameters were investigated and optimized. The results show that under optimum conditions, the limit of detection for kanamy-cin is 0.07 ng/mL and the IC50 is 6.48 ng/mL. Cross-reactivity values of the antibody with four kanamycin analogues are all <1%. Trace amounts of kanamycin in milk and honey samples can be detected by this novel BA-ELISA method successfully with satisfactory recoveries of 91.0%—103.3%. The developed protocol was also validated against liquid chromatography-mass spectrometry, returning a significant correlation. These results indicate that BA-ELISA is a viable option for monitoring kanamycin residues in milk and honey.
      PubDate: 2017-11-15
      DOI: 10.1007/s40242-017-7168-9
       
  • Facile synthesis of mesoporous Co 3 O 4 nanoflowers for catalytic
           combustion of ventilation air methane
    • Authors: Shankui Liu; Pengcheng Liu; Ruyue Niu; Shuang Wang; Jinping Li
      Abstract: Flower-like Co3O4 hierarchical microspheres composed of self-assembled porous nanoplates were pre-pared by employing Pluronic F127 block-copolymer as template. The samples were characterized by powder X-ray diffraction(PXRD), scanning/transmission electron microscopy(SEM/TEM), and nitrogen adsorption-desorption at 77 K. The results show that the catalytic activity of Co3O4 nanoflowers for the combustion of ventilation air methane is higher than that of commercial Co3O4. The superior catalytic performance of this material can be related to its dominantly exposed {112} crystal planes and higher content of surface Co3+.
      PubDate: 2017-11-15
      DOI: 10.1007/s40242-017-7047-4
       
  • Nd 3-x AE x Fe 5 O 12 : hydrothermal synthesis, structure and magnetic
           properties
    • Authors: Jie Wu; Long Yuan; Shan Wang; Changmin Hou
      Abstract: Rare-earth ferrite garnet is one of the most important materials applied in microwave transducer and infrared magneto-optical devices, etc. Nd3-x AE x Fe5O12(AE=Ca, Sr) crystals, which have cubic structure with the space group of Ia 3 d and lattice constants over 1.26 nm, were prepared via the mild hydrothermal method. The structural, morhpology and magnetic properties were characterized by means of powder X-ray diffraction, scanning electronic microscopy, as well as vibrating sample magnetometer and Mössbauer spectroscopy, respectively. Mössbauer spectroscopy demonstrates the coexistence of Sr2+, Ca2+ and Nd3+ at the C sites of the dodecahedrons for different substituted garnets. The crystal shape is dodecahedron, and the particle sizes are decreased with increasing the Ca and Sr doping concentrations. By recording the magnetic hysteresis loops and M-T curves at different temperatures, it can be seen that with the increasing x, the saturation magnetization values decrease while the coercive forces increase under the condition of high temperatures.
      PubDate: 2017-11-15
      DOI: 10.1007/s40242-017-7069-y
       
  • Thermodynamics on sulfur migration in CaSO 4 oxygen carrier reduction by
           CO
    • Authors: Simei Zhong; Min Zheng; Sixu Pu; Yanbin Xing; Kongzhai Li; Hua Wang
      Abstract: CaSO4 is an attractive oxygen carrier for chemical looping combustion(CLC) because of its high oxygen capacity and low price. The utilization of a CaSO4 oxygen carrier suffers the problems of sulfur release, and deactivation caused by sulfur loss. With respect to the fact that partial sulfur release could be recaptured and then recycled to CaSO4 by CaO sorbent, the mixture of CaSO4-CaO can be treated as an oxygen carrier. Thermodynamics of CaSO4 and CaSO4-CaO reduction by CO have been investigated in this study. The sulfur migrations, including the sulfur migration from CaSO4 to gas phase, mutual transformation of sulfur-derived gases and sulfur migration from gas phase to solid phase, were focused and elucidated. The results show that the releases of S2, S8, COS and CS2 from CaSO4 oxygen carrier are spontaneous, while SO2 can be released at high reaction temperatures above 884 °C. SO2 is the major emission source of sulfur at low CO/CaSO4 molar ratios, and COS is the major part of the byproducts as soon as the ratio exceeds 4 at 900 °C. Under CO atmosphere, all the sulfur-derived gases, SO2, S2, S8 and CS2, involved are thermodynamically favored to be converted into COS substance, and are spontaneously absorbed and solidified by CaO additive just into CaS species, which may be recycled to CaSO4 as oxygen carrier in the air reactor. But high reaction temperatures and high CO2 concentrations are adverse to sulfur capture.
      PubDate: 2017-11-15
      DOI: 10.1007/s40242-017-6457-7
       
  • Design of L -cysteine functionalized Au@SiO 2 @Fe 3 O 4 /nitrogen-doped
           graphene nanocomposite and its application in electrochemical detection of
           Pb 2+
    • Authors: Jing Nie; Bin He; Yanmei Cheng; Wei Yin; Changjun Hou; Danqun Huo; Linlin Qian; Yunan Qin; Huanbao Fa
      Abstract: A novel magnetic electrochemical sensor was designed for determination of lead ions based on gold na-noparticles(AuNPs)@SiO2@Fe3O4/nitrogen-doped graphene(NG) composites functionalized with L-cysteine. The Au@SiO2@Fe3O4/NG was synthesized by the electrostatic adsorption between AuNPs and SiO2-coated Fe3O4 NPs(SiO2@Fe3O4) and the amide bond between Au@SiO2@Fe3O4 and NG. L-Cysteine was successfully functiona-lized on the surface of Au@SiO2@Fe3O4/NG nanocomposites via the S―Au bond between L-cysteine and AuNPs. Owing to numerous active sites in L-cysteines and high conductivity of Au@SiO2@Fe3O4/NG composites, the pro-posed electrochemical sensor exhibited a well-distributed nanostructure and high responsivity toward Pb(II). The sensor linearly responded to Pb2+ concentration in the range of 5―80 μg/L with a detection limit of 0.6 μg/L, indi-cating that this L-cysteine functionalized Au@SiO2@Fe3O4/NG composite could be a promising candidate material for the detection of Pb2+.
      PubDate: 2017-11-15
      DOI: 10.1007/s40242-017-7101-2
       
  • Enhanced antibacterial activities of La/Zn-doped BiNbO 4 nanocomposites
    • Authors: Yanhui Hou; Huili Yuan; Hang Chen; Yan Ding; Liangchao Li
      Abstract: Bi1‒xLaxNbO4 and Bi1‒xLaxNbO4 nanocomposites were prepared by a simple coprecipitation method, and their composition, structure and morphology were characterized by modern testing techniques. The antibacterial ac-tivities of the as-prepared samples against Staphylococcus aureus, Escherichia coli and Candida albicans were measured by the experiments of powder inhibition zone, inhibition zone diameter and minimum inhibitory concentra-tion under the irradiation of sunlight. The results show that the antibacterial activities of BiNbO4 doped with La and Zn are superior to that of the parent, and the composition of antibacterial agent and their mass ratio have a great in-fluence on the antibacterial activities. Among these, the antibacterial activity of Bi0.96La0.04NbO4 against three bacte-ria was best and its antibacterial activity to Candida albicans was better than those to the other two kinds.
      PubDate: 2017-11-15
      DOI: 10.1007/s40242-017-7113-y
       
  • Total synthesis and biological evaluation of Wewakazole
    • Authors: Bohua Long; Jingzhao Zhang; Xueyan Wang; Xudong Tang; Zhengzhi Wu
      Abstract: The total synthesis of Wewakazole was achieved on a gram scale, unambiguously confirming its structure. Three different substituted oxazoles present in this natural product were prepared efficiently. Biological evaluation indicated that Wewakazole significantly inhibited cancer cell proliferation in a dose-dependent manner.
      PubDate: 2017-11-08
      DOI: 10.1007/s40242-017-7129-3
       
  • Double-lipase catalyzed synthesis of kojic dipalmitate in organic solvents
    • Authors: Zhiyuan Wang; Wen Luo; Junying Fu; Zhibing Li; Zhongming Wang; Pengmei Lü
      Abstract: Kojic dipalmitate(KDP) was synthesized by the way of esterification of palmitic and kojic acids in organic solvent, with double-lipase as the biocatalyst. Four commercially available lipases(Amano PS, Novozym 435, Lipozyme TL IM and Lipozyme RM IM) were used to group six double-lipase combinations. These combinations were studied and Amano PS-Novozym 435 was found to have the best efficiency and was selected for optimizing the reaction conditions. The optimal reaction conditions were that the mass ratio of Amano PS to Novozyme 435 1:1.5, stirring speed of 500 r/min, substrates molar ratio of 1:2, 50 °C, 5%(mass fraction) catalyst dosage of kojic acid quantity and using acetone as co-solvent. Under these conditions, the diesterification of C5 and C7 hydroxyl groups of kojic acid molecule could be well catalyzed by double-lipase and realize a high KDP yield of 85%.
      PubDate: 2017-11-08
      DOI: 10.1007/s40242-017-7048-3
       
  • Design, synthesis and insecticidal evaluation of novel N
           -pyridylpyrazolecarboxamide derivatives containing isoxazole, isoxazoline
           and 1, 3, 4-thiadiazole rings
    • Authors: Xuewen Hua; Chen Liu; Sha Zhou; Minggui Chen; Lixia Xiong; Yongqiang Li; Zhengming Li
      Abstract: With the introduction of various heterocyclic rings at the benzene part of anthranilic diamides, a series of N-pyridylpyrazolecarboxamide derivatives containing isoxazole, isoxazoline and 1,3,4-thiadiazole rings was designed, synthesized and evaluated for their insecticidal activities. The structures of the obtained novel target compounds were confirmed by means of 1H NMR, 13C NMR and HRMS. The bioassay results indicated that most of the target com-pounds displayed moderate or good insecticidal activities against oriental armyworm and diamondback moth at the adopted concentrations compared with chlorantraniliprole, especially compounds Ii and Il, of which the LC50 and LC95 values against oriental armyworm were further measured. The structure-activity relationship demonstrated that the introduction of chlorine in benzene ring, bromomethyl and acetoxyl substituents in 4,5-dihydroisoxazole part was more advantageous to improve the corresponding insecticidal activities than the introduction of other substituents and heterocycles.
      PubDate: 2017-11-08
      DOI: 10.1007/s40242-017-7147-1
       
  • Tuning shell thickness of MnO/C core-shell nanowires for optimum
           performance of lithium-ion batteries
    • Authors: Dan Zhang; Guangshe Li; Jianming Fan; Baoyun Li; Liping Li
      Abstract: MnO/C core-shell nanowires with varying carbon shell thickness were synthesized via calcining resorci-nol-formaldehyde resin(RF) with different amounts of hydrothermally synthesized MnO2 nanowires. The relationship between the carbon shell thickness and the anode performance of the MnO/C materials was discussed. With a suitable carbon shell thickness(6.8 nm), the MnO/C core-shell nanowires exhibit better cycling and rate performance than those with a smaller or larger thickness. The TEM results show that after 50 cycles, the core-shell structure with this thickness can be retained, which leads to superior performance. This contribution provides a significant guiding model for optimizing the electrochemical performance of MnO/C core-shell materials by controlling the thickness of carbon shells.
      PubDate: 2017-11-07
      DOI: 10.1007/s40242-017-7223-6
       
  • Preparation of β -cyclodextrin/Fe 3 O 4 /polyvinylpyrrolidone composite
           magnetic microspheres for the adsorption of methyl orange
    • Authors: Qingbo Si; Qian Wen; Qingbiao Yang; Yan Song; Yaoxian Li
      Abstract: Magnetic microspherical β-cyclodextrin(CD)/Fe3O4@polyvinylpyrrolidone(PVP) particles, in which embedded Fe3O4 particles were coated by β-CD/glutaraldehyde crosslinked PVP, were synthesized via electrostatic spray and thermal crosslinking technologies. The magnetic microspheres were characterized by infrared spectroscopy, X-ray diffraction, scanning electron microscopy(SEM) and magnetic measurements, and the adsorption performance of the β-CD/Fe3O4@PVP composite nanoparticles for methyl orange was studied. The results show that the β-CD/Fe3O4@PVP microspheres could be quickly separated from the adsorption system under an external magnetic field within 30 s and that the adsorption capacity of the microspheres for methyl orange reaches greater than 90%, with a maximum adsorption quantity of 47.62 mg/g.
      PubDate: 2017-11-07
      DOI: 10.1007/s40242-017-7083-0
       
  • Physicochemical properties of Bi-containing ionic liquid analogs based on
           choline chloride
    • Authors: Luxia Bu; Daying Liu; Zhen Wei; Zhanlin Ma
      Abstract: The preparation and characterization of homogeneous and colorless ionic liquid analogs(ILAs) containing choline chloride(ChCl), malonic acid and bismuth chloride were investigated. The structure of the above mixture was preliminarily analyzed, and then the physicochemical properties including viscosity, conductivity and density were investigated as functions of temperature and composition. Additionally, the thermal stability of the ILAs and the electrochemical behavior of Bi3+ ions in the medium were studied. Structure analysis reveals that the synthesis of deep eutectic solvents(DESs) is closely related to the formation of hydrogen bonds between malonic acid and ChCl, with their viscosity, conductivity and density being greatly dependent on the temperature and composition. Thermo-gravimetric analysis demonstrates that the ILAs are very stable between room temperature and 398.15 K. And the electrochemical experiments indicate that the bismuth films can be successfully deposited from this ILAs and the deposition mechanism of bismuth is a rather irreversible process. The surface morphology of bismuth films deposited on Cu substrates was very compact and smooth. Thus, ChCl-malonic acid DESs were shown to be a good alternative to aqueous solvents for various deposition-related applications.
      PubDate: 2017-11-07
      DOI: 10.1007/s40242-017-7170-2
       
  • PVA/PEG hybrid hydrogels prepared by freeze-thawing and high energy
           electron beam irradiation
    • Authors: Chunming Zhao; Xueting Lu; Qianqian Hu; Shuai Liu; Shuang Guan
      Abstract: In this paper, poly(vinyl alcohol)(PVA) and PVA/poly(ethylene glycol)(PEG) hybrid hydrogels were syn-thesized by freeze-thawing or freeze-thawing followed by high energy electron beam irradiation. The influence of PEG molecular weight, mass ratios of PVA to PEG, thawing temperature and number of freeze-thawing(FT) cycles on the mechanical strength of PVA/PEG hydrogel was investigated. Also, the thermal behaviors were examined by dif-ferential scanning calorimetry(DSC) and the microstructures were observed with scanning electron microscopy(SEM). The results suggest that the addition of PEG improves the mechanical strength of PVA hydrogel and the irradiation reduces both the strength of PVA/PEG hydrogel slightly and the degree of crystallinity. The improved properties suggest that PVA/PEG hydrogel can be a good candidate for the application in the biomedical.
      PubDate: 2017-11-07
      DOI: 10.1007/s40242-017-7107-9
       
 
 
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