|
Chemical Science
Journal Prestige (SJR): 4.508  Citation Impact (citeScore): 9 Number of Followers: 25  Open Access journalISSN (Print) 1478-6524 - ISSN (Online) 2041-6520 Published by RSC  [43 journals]
|
- Addition of arylstannanes to alkynes giving ortho-alkenylarylstannanes
catalysed cooperatively by a rhodium complex and zinc chloride (The title
was changed)
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02459F, Edge Article
Open Access 
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jialin Ming, Qi Shi, Tamio Hayashi
The reaction of arylstannanes ArSnR3 with unfunctionalised alkynes was found to proceed in the presence of a rhodium catalyst and a catalytic amount of zinc chloride to give ortho-alkenylarylstannanes with...
The content of this RSS Feed (c) The Royal Society of Chemistry
- A Vesicle-Aggregation-Assembly Approach to Highly Ordered Mesoporous
γ-Alumina Microspheres with Shifted Double-Diamond Networks
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02967A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yang Liu, Wei Teng, Gang Chen, Zaiwang Zhao, Wei Zhang, Biao Kong, Hozzein Wael N., Al-Khalaf Areej Abdulkareem, Yonghui Deng, Dongyuan Zhao
Alumina materials have widely been used in industrial fields, such as catalysis and adsorption. However, due to the fast sol-gel process and complicated crystalline-phase transformation, the synthesis of alumina materials...
The content of this RSS Feed (c) The Royal Society of Chemistry
- A β-Diketiminate Manganese Catalyst for Alkene Hydrosilylation: Substrate
Scope, Silicone Preparation, and Mechanistic Insight
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02768D, Edge Article Open Access 
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Tufan K. Mukhopadhyay, Marco Flores, Thomas L Groy, Ryan J. Trovitch
The dimeric β-diketiminate manganese hydride compound, [(2,6-iPr2PhBDI)Mn(μ-H)]2, was prepared by treating [(2,6-iPr2Ph BDI)Mn(μ-Cl)]2 with NaEt3BH. This compound was charactized by single crystal X-ray diffraction and found to feature high-spin Mn...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Selective C-H Halogenation over Hydroxylation by Non-heme Iron(IV)-oxo
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02053A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sujoy Rana, Jyoti Prasad Biswas, Asmita Sen, Martin Clémancey, Geneviève Blondin, Jean-Marc Latour, Gopalan Rajaraman, Debabrata Maiti
Non-heme iron based halogenase enzymes promote selective halogenation of sp3-C–H bond through iron(IV)-oxo-halide active species. During halogenation, competitive hydroxylation can be prevented completely in enzymatic systems. However, synthetic iron(IV)-oxo-halide intermediates...
The content of this RSS Feed (c) The Royal Society of Chemistry
- An ultrasensitive flow cytometric immunoassay based on bead
surface-initiated template-free DNA extension
Abstract:Chem. Sci., 2018, 9,6605-6613
DOI : 10.1039/C8SC02752H, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Liping Zhu, Desheng Chen, Xiaohui Lu, Yan Qi, Pan He, Chenghui Liu, Zhengping Li
An ultrasensitive flow cytometric immunoassay (TdT-FCI) is developed based on bead surface-initiated template-free DNA extension.
The content of this RSS Feed (c) The Royal Society of Chemistry
- New Ru(II) photocages operative with near-IR light: new platform for drug
delivery in the PDT window
Abstract:Chem. Sci., 2018, 9,6711-6720
DOI : 10.1039/C8SC02094A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Malik H. Al-Afyouni, Thomas N. Rohrabaugh, Kathlyn F. Al-Afyouni, Claudia Turro
A series of Ru(II) complexes bearing the tridentate 2,6-di(quinolin-2-yl)pyridine (dqpy) ligand was designed to undergo photoinduced ligand dissociation with red/near-IR light.
The content of this RSS Feed (c) The Royal Society of Chemistry
- A photochemical layer-by-layer solution process for preparing organic
semiconducting thin films having the right material at the right place
Abstract:Chem. Sci., 2018, 9,6614-6621
DOI : 10.1039/C8SC01799A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Mitsuharu Suzuki, Yuji Yamaguchi, Kensuke Uchinaga, Katsuya Takahira, Cassandre Quinton, Shinpei Yamamoto, Naoto Nagami, Mari Furukawa, Ken-ichi Nakayama, Hiroko Yamada
A mild and versatile solution process enables the controlled preparation of multicomponent organic small-molecule thin films.
The content of this RSS Feed (c) The Royal Society of Chemistry
- A snapshot of the electrochemical reaction layer by using 3 dimensionally
resolved fluorescence mapping
Abstract:Chem. Sci., 2018, 9,6622-6628
DOI : 10.1039/C8SC02011F, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Anne de Poulpiquet, Bertrand Goudeau, Patrick Garrigue, Neso Sojic, Stéphane Arbault, Thomas Doneux, Laurent Bouffier
Fluorescence confocal laser scanning microscopy under electrochemical control allows imaging of various reaction layers revealing heterogeneous versus homogeneous reactions.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Sensitized triplet–triplet annihilation upconversion in water and its
application to photochemical transformations
Abstract:Chem. Sci., 2018, 9,6670-6678
DOI : 10.1039/C8SC01829D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Christoph Kerzig, Oliver S. Wenger
The first systems for efficient upconversion-based technologies in water have been developed and pave the way for novel green photochemistry.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Oxidative strong metal–support interactions (OMSI) of supported
platinum-group metal catalysts
Abstract:Chem. Sci., 2018, 9,6679-6684
DOI : 10.1039/C8SC01392F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hailian Tang, Yang Su, Yalin Guo, Leilei Zhang, Tianbo Li, Ketao Zang, Fei Liu, Lin Li, Jun Luo, Botao Qiao, Junhu Wang
Oxidative strong metal–support interactions of supported platinum-group metal catalysts accompanied by the encapsulation of metal nanoparticles by the support was discovered.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Silyl-mediated photoredox-catalyzed Giese reaction: addition of
non-activated alkyl bromides
Abstract:Chem. Sci., 2018, 9,6639-6646
DOI : 10.1039/C8SC02253D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Abdellatif ElMarrouni, Casey B. Ritts, Jaume Balsells
The development of a conjugate addition reaction of non-activated alkyl bromides to Michael acceptors under visible-light photoredox catalysis is disclosed. A diverse set of alkyl bromides was successfully added to α,β-unsaturated esters and amides. This transformation allowed access to a key intermediate of Vorinostat®, an HDAC inhibitor used to fight cancer and HIV.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Radical-mediated direct C–H amination of arenes with secondary
amines
Abstract:Chem. Sci., 2018, 9,6647-6652
DOI : 10.1039/C8SC01747F, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Sebastian C. Cosgrove, John M. C. Plane, Stephen P. Marsden
Direct radical-based substitution of aryl C–H bonds allows one-pot access to valuable polycyclic aryl amines from simple secondary amines.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Insights into the mechanism and aging of a noble-metal free H2-evolving
dye-sensitized photocathode
Abstract:Chem. Sci., 2018, 9,6721-6738
DOI : 10.1039/C8SC00899J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Nicolas Kaeffer, Christopher D. Windle, Romain Brisse, Corinne Gablin, Didier Leonard, Bruno Jousselme, Murielle Chavarot-Kerlidou, Vincent Artero
Co-grafting of a cobalt diimine–dioxime catalyst and push–pull organic dye on NiO yields a photocathode evolving hydrogen from aqueous solution under sunlight, with equivalent performances compared to a dyad-based architecture using similar components.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Dewetting transitions coupled to K-channel activation in cytochrome c
oxidase
Abstract:Chem. Sci., 2018, 9,6703-6710
DOI : 10.1039/C8SC01587B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shreyas Supekar, Ville R. I. Kaila
Cytochrome c oxidase (CcO) drives aerobic respiratory chains in all organisms by transducing the free energy from oxygen reduction into an electrochemical proton gradient across a biological membrane.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Acceleration of CO2 insertion into metal hydrides: ligand, Lewis acid, and
solvent effects on reaction kinetics
Abstract:Chem. Sci., 2018, 9,6629-6638
DOI : 10.1039/C8SC02535E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jessica E. Heimann, Wesley H. Bernskoetter, Nilay Hazari, James M. Mayer
Kinetic studies of CO2 insertion into transition metal hydrides provide evidence about the nature of the rate-determining transition state.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Photocatalytic reverse polarity Povarov reaction
Abstract:Chem. Sci., 2018, 9,6653-6658
DOI : 10.1039/C8SC01704B, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jamie A. Leitch, Angel L. Fuentes de Arriba, Joanne Tan, Oskar Hoff, Carlos M. Martínez, Darren J. Dixon
A reverse polarity photocatalysed Povarov reaction of imines and electron deficient alkenes is described.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Programmable one-pot synthesis of heparin pentasaccharides enabling access
to regiodefined sulfate derivatives
Abstract:Chem. Sci., 2018, 9,6685-6691
DOI : 10.1039/C8SC01743C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Supriya Dey, Chi-Huey Wong
We report the design of building blocks with optimized reactivities for the programmable one-pot synthesis of heparin pentasaccharides with regiodefined sulfation patterns.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Engineering a bifunctional copper site in the cupredoxin fold by
loop-directed mutagenesis
Abstract:Chem. Sci., 2018, 9,6692-6702
DOI : 10.1039/C8SC01444B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Andrés Espinoza-Cara, Ulises Zitare, Damián Alvarez-Paggi, Sebastián Klinke, Lisandro H. Otero, Daniel H. Murgida, Alejandro J. Vila
Loop directed mutagenesis leads to a cupredoxin withthe strongest copper–thiolate bond known to date, high reduction potential and imidazole binding properties.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Theory for polariton-assisted remote energy transfer
Abstract:Chem. Sci., 2018, 9,6659-6669
DOI : 10.1039/C8SC00171E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Matthew Du, Luis A. Martínez-Martínez, Raphael F. Ribeiro, Zixuan Hu, Vinod M. Menon, Joel Yuen-Zhou
A comprehensive theory is presented to mechanistically elucidate the long-range energy transfer between molecules strongly coupled to electromagnetic fields.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Understanding the Visible-light Photocatalytic Activity of GaN:ZnO Solid
Solution: the Role of Rh2-yCryO3 Cocatalyst and Charge Carrier Lifetimes
Over Tens of Seconds
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02348D, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Robert Godin, Takashi Hisatomi, Kazunari Domen, James Durrant
A persistent challenge for the widespread deployment of solar fuels is the development of high efficiency photocatalysts combined with a low-cost preparation and implementation route. Since its discovery in 2005,...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Facile room temperature synthesis of large graphene sheets from simple
molecules
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02818D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lais C Lopes, Lidya C Silva, Boniek Gontijo Vaz, Alfredo Ricardo Marques de Oliveira, Marcela M. Oliveira, Maria Luiza Rocco, Elisa S Orth, Aldo J.G. Zarbin
The largest graphene sample obtained through a chemical reaction under ambient conditions (temperature and pressure), using simple molecules such as benzene or n-hexane as precursors, is reported. Starting from a...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Tailor-made Janus lectin with dual avidity assembles glycoconjugate
multilayers and crosslinks protocells
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02730G, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Joao P. Ribeiro, Sarah Villringer, David Goyard, Liliane Guerente, Manuela Höferlin, Olivier Renaudet, Winfried Römer, Anne Imberty
We engineered the first chimeric, bispecific lectin, with two rationally oriented and distinct recognition surfaces. This lectin, coined Janus lectin in allusion to the two-faced roman god, is able to...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Biocatalyst – artificial metalloenzyme cascade based on alcohol
dehydrogenase
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02371A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Simone Morra, Anca Pordea
Chemo-enzymatic cascades of enzymes with transition metal catalysts can offer efficient synthetic strategies, but their development is challenging due to the incompatibility between proteins and transition metal complexes. Rhodium catalysts...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Reversible π-system switching of thiophene-fused thiahexaphyrins by
solvent and oxidation/reduction
Abstract:Chem. Sci., 2018, Advance Article
DOI : 10.1039/C8SC02448K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Tomohiro Higashino, Atsushi Kumagai, Shigeyoshi Sakaki, Hiroshi Imahori
The dithieno[3,4-b:3′,4′-d]thiophene unit is a new effective motif to realize the π-system switching of expanded porphyrins.
To cite this article before page numbers are assigned, use the
DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
- The effect of iron binding on uranyl(V) stability
Abstract:Chem. Sci., 2018, Advance Article
DOI : 10.1039/C8SC02099J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Radmila Faizova, Sarah White, Rosario Scopelliti, Marinella Mazzanti
The tripodal heptadentate Schiff base trensal3− ligand allowed the synthesis and characterization of stable uranyl(V) complexes presenting UO2+⋯K+ or UO2+⋯Fe2+ cation–cation interactions. The presence of Fe2+ bound to the uranyl(V) oxygen leads to increased stability with respect to proton induced disproportionation and to an increased range of stability of the uranyl(V) species with respect both to oxidation and reduction reactions.
To cite this article before page numbers are assigned, use the
DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Adhesion analysis of single circulating tumor cell on base layer of
endothelial cells using open microfluidics
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03027H, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sifeng Mao, Qiang Zhang, Haifang Li, Wanling Zhang, Qiushi Huang, Mashooq Khan, Jin-Ming Lin
Circulating Tumor Cell (CTC) adhesion is essential in understanding the mechanism of metastasis. Although conventional methods to measure adhesion strength have performed well on cell population, deeper insight into cell...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Dihydrogen contacts observed by through-space indirect NMR coupling
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02859A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Martin Dracinsky, Michal Buchta, Milos Budesinsky, Jana Vacek Chocholoušová, Irena G Stará, I. Stary, Olga L. Malkina
“Through-space” indirect spin-spin couplings between hydrogen atoms formally separated by up to 18 covalent bonds have been detected by NMR experiments in model helical molecules. It is demonstrated that this...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Ultrafast Interligand Electron Transfer in
cis-[Ru(4,4'-dicarboxylate-2,2'-bipyridine)2(NCS)2]4- and Implications for
Electron Injection Limitations in Dye Sensitized Solar Cells
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC00274F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Belinda Pettersson-Rimgard, Jens Föhlinger, Jonas Petersson, Marcus Lundberg, Burkhard Zietz, Ann Marie Woys, Stephen A. Miller, Michael R Wasielewski, Leif Hammarström
Interligand electron transfer (ILET) of the lowest metal-to-ligand charge transfer (MLCT) state of N712 (cis-[Ru(dcb)2 (NCS)2 ]4− , where dcb=4,4’-dicarboxylate-2,2’-bipyridine) in a deuterated acetonitrile solution has been studied by means...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Four-coordinate Triarylborane Synthesis via Cascade B-Cl/C-B
Cross-Metathesis and C-H Bond Borylation
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02281J, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kai Yang, Guan Zhang, Qiuling Song
To develop simple and efficient synthetic method of four-coordinate triarylboranes, we herein describe a tandem highly selective B-Cl/C-B cross-metathesis of two same or different arylboranes and C-H bond borylation to...
The content of this RSS Feed (c) The Royal Society of Chemistry
- RAFT polymer cross-coupling with boronic acids
Abstract:Chem. Sci., 2018, Advance Article
DOI : 10.1039/C8SC01862F, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Hartwig Golf, Riley O'Shea, Carl Braybrook, Oliver Hutt, David W. Lupton, Joel F. Hooper
A one step modification of RAFT polymers to give functionalised materials.
To cite this article before page numbers are assigned, use the
DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Phosphorescent Cationic Iridium(III) Complexes Dynamically Bound to
Cyclodextrin Vesicles: Applications in Live Cell Imaging
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02875C, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Frauke Schibilla, Anna Holthenrich, Boyi Song, Anna Livia Linard Matos, David Grill, Diego Rota Martir, Volker Gerke, Eli Zysman-Colman, Bart Jan Ravoo
We report cationic Ir(III) complexes functionalized with adamantyl groups designed to bind to β cyclodextrin vesicles (CDV) with high affinity (Ka = 1∙106 M-1). The emission of the complexes is...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Annulative π-Extension of Indoles and Pyrroles with Diiodobiaryls by Pd
Catalysis: Rapid Synthesis of Nitrogen-Containing Polycyclic Aromatic
Compounds
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02802H, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Hiroyuki Kitano, Wataru Matsuoka, Hideto Ito, Kenichiro Itami
A palladium-catalyzed one-step annulative π-extension (APEX) reaction of indoles and pyrroles that allows rapid access to nitrogen-containing polycyclic aromatic compounds is described. In the presence of palladium pivalate and silver...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Synthetic biology approaches and combinatorial biosynthesis towards
heterologous lipopeptide production
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02046A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Fu Yan, Christian Burgard, Alexander Popoff, Nestor Zaburannyi, Gregor Zipf, Josef Maier, Hubert S. Bernauer, Silke C. Wenzel, Rolf Müller
Synthetic biology techniques coupled with heterologous secondary metabolite production offers opportunities for the discovery and optimisation of natural products. Here we developed a new assembly strategy based on type IIS...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Oxidative Dehalogenation and Denitration by a Flavin-dependent
Monooxygenase is Controlled by Substrate Deprotonation
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC01482E, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Panu Pimviriyakul, Panida Surawatanawong, Pimchai Chaiyen
Enzymes that are capable of detoxifying halogenated phenols (HPs) and nitrophenols (NPs) are valuable for bioremediation and waste biorefinery. HadA monooxygenase was found to have dual activities of oxidative dehalogenation...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Tricarbocyanine N-triazoles: the scaffold-of-choice for long-term
near-infrared imaging of immune cells in vivo
Abstract:Chem. Sci., 2018, Advance Article
DOI : 10.1039/C8SC00900G, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Richard J. Mellanby, Jamie I. Scott, Iris Mair, Antonio Fernandez, Louise Saul, Jochen Arlt, Monica Moral, Marc Vendrell
Tricarbocyanine N-triazoles are first described as rationally-designed structures to overcome the limitations of NIR dyes for long-term in vivo imaging.
To cite this article before page numbers are assigned, use the
DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Capturing intracellular oncogenic microRNAs with self-assembled DNA
nanostructures for microRNA-based cancer therapy
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03039A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Qian Liu, Dong Wang, Ming Yuan, Bingfeng He, Jin Li, Chengde Mao, Guansong Wang, Hang Qian
Aberrantly overexpressed oncogenic microRNAs (miRNAs, miRs) are excellent targets for therapeutic interventions. Nevertheless, thus far, little progress has been made in developing miRNA-based drugs and techniques for clinical applications, especially...
The content of this RSS Feed (c) The Royal Society of Chemistry
- High electrical conductivity and high porosity in a Guest@MOF material:
evidence of TCNQ ordering within Cu3BTC2 micropores
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02471E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Christian Schneider, Dardan Ukaj, Raimund Koerver, A. Alec Talin, Gregor Kieslich, Sidharam Pundlik Pujari, Han Zuilhof, Juergen Janek, Mark D. Allendorf, Roland A. Fischer
The host-guest system TCNQ@Cu3BTC2 (TCNQ = 7,7,8,8-tetracyanoquinodimethane, BTC = 1,3,5-benzenetricarboxylate) is a striking example of how semiconductivity can be introduced by guest incorporation in an otherwise insulating parent material. Exhibiting...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Performing DNA nanotechnology operations on a zebrafish
Abstract:Chem. Sci., 2018, Advance Article
DOI : 10.1039/C8SC01771A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jian Yang, Zhuojun Meng, Qing Liu, Yasuhito Shimada, René C. L. Olsthoorn, Herman P. Spaink, Andreas Herrmann, Alexander Kros
Nanoscale engineering of biological surfaces is becoming an indispensable technique to modify membranes and, thus cellular behaviour.
To cite this article before page numbers are assigned, use the
DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Exploring a new ligand binding site of G protein-coupled receptors
Abstract:Chem. Sci., 2018, 9,6480-6489
DOI : 10.1039/C8SC01680A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.H. C. Stephen Chan, Jingjing Wang, Krzysztof Palczewski, Slawomir Filipek, Horst Vogel, Zhi-Jie Liu, Shuguang Yuan
A new binding pocket of the endogenous ligand has been discovered by MD simulations.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Slow magnetic relaxation in octahedral low-spin Ni(III) complexes
Abstract:Chem. Sci., 2018, 9,6564-6571
DOI : 10.1039/C7SC04482H, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Indrani Bhowmick, Andrew J. Roehl, James R. Neilson, Anthony K. Rappé, Matthew P. Shores
Low-spin (S = 1/2) Ni(III) cyclam complex salts can show SMM-type properties depending on the axial ligand donor atom identity.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Biomass-mediated ZSM-5 zeolite synthesis: when self-assembly allows to
cross the Si/Al lower limit
Abstract:Chem. Sci., 2018, 9,6532-6539
DOI : 10.1039/C8SC01675E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Marcelo Maciel Pereira, Elisa Silva Gomes, Alessandra Vieira Silva, Ana Belen Pinar, Marc-Georg Willinger, Sangaraju Shanmugam, Céline Chizallet, Guillaume Laugel, Pit Losch, Benoît Louis
Biomass-mediated syntheses of ZSM-5 zeolites allowed crossing low Si/Al barrier, inducing high acidity, hence remarkably improving catalyst performance.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Prediction of disulfide dihedral angles using chemical shifts
Abstract:Chem. Sci., 2018, 9,6548-6556
DOI : 10.1039/C8SC01423J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.David A. Armstrong, Quentin Kaas, K. Johan Rosengren
Chemical shifts can be used to predict the conformation of disulfide bonds, greatly improving resolution of solution NMR structures.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Identifying site-dependent reactivity in oxidation reactions on single Pt
particles
Abstract:Chem. Sci., 2018, 9,6523-6531
DOI : 10.1039/C8SC01956H, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shahar Dery, Suhong Kim, David Haddad, Albano Cossaro, Alberto Verdini, Luca Floreano, F. Dean Toste, Elad Gross
IR nanospectroscopy measurements revealed the influence of oxidizing reaction conditions on the reactivity of different surface sites on Pt particles.
The content of this RSS Feed (c) The Royal Society of Chemistry
- A new structure–activity relationship for cyanine dyes to improve
photostability and fluorescence properties for live cell imaging
Abstract:Chem. Sci., 2018, 9,6557-6563
DOI : 10.1039/C8SC01574K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Christian Schwechheimer, Franziska Rönicke, Ute Schepers, Hans-Achim Wagenknecht
A new set of cyanine-indole dyes was synthesized, characterized by optical and cytotoxic properties and subsequently applied for live cell imaging.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Antibody drug conjugates (ADCs) charged with HDAC inhibitor for targeted
epigenetic modulation
Abstract:Chem. Sci., 2018, 9,6490-6496
DOI : 10.1039/C7SC05266A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Elena Cini, Valentina Faltoni, Elena Petricci, Maurizio Taddei, Laura Salvini, Giuseppe Giannini, Loredana Vesci, Ferdinando Maria Milazzo, Anna Maria Anastasi, Gianfranco Battistuzzi, Rita De Santis
A new weapon is added to the ADC arsenal, a thiol based HDAC inhibitor. Low toxic, hits the target and stops tumor growth in many mouse models.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Mononuclear complexes of a tridentate redox-active ligand with sulfonamido
groups: structure, properties, and reactivity
Abstract:Chem. Sci., 2018, 9,6540-6547
DOI : 10.1039/C7SC05445A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Sarah A. Cook, Justin A. Bogart, Noam Levi, Andrew C. Weitz, Curtis Moore, Arnold L. Rheingold, Joseph W. Ziller, Michael P. Hendrich, A. S. Borovik
Enhancing the redox properties of FeII with a bis(sulfonamido)amine pincer ligand leads to catalytic cyclic amination reactivity.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Diastereo- and enantioselective copper catalyzed hydroallylation of
disubstituted cyclopropenes
Abstract:Chem. Sci., 2018, 9,6503-6508
DOI : 10.1039/C8SC02085J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Heiko Sommer, Ilan Marek
A highly diastereo- and enantioselective protocol for the hydroallylation of 1,1- and 1,2-disubstituted cyclopropenes has been developed utilizing an in situ formed copper hydride.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Tunable stiffness of graphene oxide/polyacrylamide composite scaffolds
regulates cytoskeleton assembly
Abstract:Chem. Sci., 2018, 9,6516-6522
DOI : 10.1039/C8SC02100G, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yupeng Sun, Kaixiang Zhang, Ruijie Deng, Xiaojun Ren, Can Wu, Jinghong Li
Graphene oxide/polyacrylamide composite scaffolds with tunable stiffness are designed and fabricated to investigate the effect of extracellular matrix (ECM) stiffness on cytoskeleton assembly and specific gene expression during cell growth.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Exploration of biocompatible AIEgens from natural resources
Abstract:Chem. Sci., 2018, 9,6497-6502
DOI : 10.1039/C8SC01635F, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yuan Gu, Zheng Zhao, Huifang Su, Pengfei Zhang, Junkai Liu, Guangle Niu, Shiwu Li, Zhaoyang Wang, Ryan T. K. Kwok, Xin-Long Ni, Jingzhi Sun, Anjun Qin, Jacky W. Y. Lam, Ben Zhong Tang
In this contribution, we propose natural resources as a new source to acquire biocompatible AIEgens.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Size-dependent rate acceleration in the silylation of secondary alcohols:
the bigger the faster
Abstract:Chem. Sci., 2018, 9,6509-6515
DOI : 10.1039/C8SC01889H, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Marta Marin-Luna, Benjamin Pölloth, Fabian Zott, Hendrik Zipse
Relative rates for the reaction of secondary alcohols carrying large aromatic moieties with silyl chlorides carrying equally large substituents have been determined in organic solvents.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Synthesis and reactivity of a nickel(II) thioperoxide complex:
demonstration of sulfide-mediated N2O reduction
Abstract:Chem. Sci., 2018, 9,6580-6588
DOI : 10.1039/C8SC02536C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Nathaniel J. Hartmann, Guang Wu, Trevor W. Hayton
The “masked” terminal nickel sulfide [K(18-crown-6)][LtBuNiII(S)] mediates the reduction of N2O by CO, via the thioperoxide complex [K(18-crown-6)][LtBuNiII(η2-SO)].
The content of this RSS Feed (c) The Royal Society of Chemistry
- Brønsted/Lewis acid sites synergistically promote the initial C–C bond
formation in the MTO reaction
Abstract:Chem. Sci., 2018, 9,6470-6479
DOI : 10.1039/C8SC02302F, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yueying Chu, Xianfeng Yi, Chengbin Li, Xianyong Sun, Anmin Zheng
The Lewis acid site combined with a Brønsted acid site in zeolite catalysts facilitates first C–C bond formation in the initiation step of the MTO reaction.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Characterisation of redox states of metal–organic frameworks by growth
on modified thin-film electrodes
Abstract:Chem. Sci., 2018, 9,6572-6579
DOI : 10.1039/C8SC00803E, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Tamoghna Mitra, Florian Moreau, Adam Nevin, Carlo U. Perotto, Alex Summerfield, E. Stephen Davies, Elizabeth A. Gibson, Timothy L. Easun, Martin Schröder
Two different SURMOF films have been grown on a transparent conducting surface for spectro-electrochemical characterisation of radical species.
The content of this RSS Feed (c) The Royal Society of Chemistry
- A fluorescent methylation-switchable probe for highly sensitive analysis
of FTO N6-Methyladenosine demethylase activity in cells
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02163E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Adeline Cheong, Joanne Low, Andrea Lim, Paul Yen, Esther C. Y. Woon
N 6-Methyladenosine (m6A) is one of the most abundant epigenetic modifications on mRNA. It is dynamically regulated by the m6A demethylases FTO and ALKBH5, which are currently attracting intense medical interest...
The content of this RSS Feed (c) The Royal Society of Chemistry
- De novo coiled-coil peptides as scaffolds for disrupting protein-protein
interactions
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02643B, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jordan M. Fletcher, Katherine A. Horner, Gail J Bartlett, Guto R. Rhys, Andrew Wilson, Derek Woolfson
Protein-protein interactions (PPIs) play pivotal roles in the majority of biological processes. Therefore, improved approaches to target and disrupt PPIs would provide tools for chemical biology and leads for therapeutic...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Conformational selectivity and high-affinity binding in the complexation
of N-phenyl amides in water by a phenyl extended calix[4]pyrrole
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03034K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Luis Escobar, Alejandro Diaz-Moscoso, Pablo Ballester
We described the synthesis of a tetrapyridinium phenyl extended calix[4]pyrrole that is soluble in neutral water solution at mM concentrations. We show that, in pure water, the synthesized calix[4]pyrrole receptor...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Multiplex MicroRNAs Imaging in Living Cell Using DNA-Capped-Au Assembled
Hydrogels
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02858C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xiangdan Meng, Kai Zhang, Wenhao Dai, Yu Cao, Fan Yang, Haifeng Dong, Xueji Zhang
Non-invasively imaging multiplex microRNAs (miRNAs) in living cells is pivotal to understand the physiological functions and pathological development due to key regulator roles of miRNAs in gene expression. However, smart...
The content of this RSS Feed (c) The Royal Society of Chemistry
- A General One-pot Strategy for the Synthesis of Au@multi-oxides Yolk@shell
Nanospheres with Enhanced Catalytic Performance
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC01520A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jian Li, Shuyan Song, Yan Long, Shuang Yao, Xin Ge, Lanlan Wu, Yibo Zhang, Xiao Wang, Xiangguang Yang, Hongjie Zhang
By integrating redox self-assembly and redox etching process, we report a general one-pot strategy for the synthesis of Au@multi-MxOy (M = Co, Ce, Fe, Sn) yolk@shell nanospheres. Without any additional...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Length-Independent Charge Transport of Well-Separated Single-Crystal TiO2
Long Nanowire Arrays
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02335B, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xinjian Feng, Jie Liu, Xia Sheng, Fengying Guan, ke Li, Dandan Wang, Liping Chen
Long, well-separated single crystal TiO2 nanowire (NW) arrays with rapid charge tranpsort properties hold great promise in photoelectrochemical and energy storage devices. Synthesis variations to increase the nanowire length generally...
The content of this RSS Feed (c) The Royal Society of Chemistry
- A Soft Phosphorus Atom to “Harden” an Erbium(III) Single-Ion
Magnet
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC01626G, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shiming Chen, Yi-Quan Zhang, Jin Xiong, Qiong Yuan, Bingwu Wang, Song Gao
Beyond the well-performed lanthanide organometallic single-ion magnet (SIM) (Cp*)Er(COT)1 ([Cp*]‒ = pentamethylcyclopentadienide; COT2‒ = cyclooctatetraenide), we managed to replace one coordinated carbon atom on [Cp*]‒ ring by a soft phosphorus...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Between Single Ion Magnets and macromolecules: polymer/transition
metal–based semi–solid solution
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02277A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Anna Małgorzata Majcher, Pawel Dąbczyński, Mateusz M Marzec, Magdalena Ceglarska, Jakub Rysz, Andrzej Bernasik, Shin-ichi Ohkoshi, Olaf Stefańczyk
Creation of functional magnetic materials for application in high–density memory storage or in the new field of molecular spintronics is a matter of widespread interest among the material research community....
The content of this RSS Feed (c) The Royal Society of Chemistry
- Enantioselective fluorination of homoallylic alcohols enabled by the
tuning of non-covalent interactions
Abstract:Chem. Sci., 2018, Advance Article
DOI : 10.1039/C8SC02223B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jaime A. S. Coelho, Akira Matsumoto, Manuel Orlandi, Margaret J. Hilton, Matthew S. Sigman, F. Dean Toste
Multivariate correlation analysis, including designer π-interaction derived parameters, was applied to the study of the enantioselective fluorination of homoallylic alcohols via chiral anion phase transfer (CAPT) catalysis.
To cite this article before page numbers are assigned, use the
DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Phosphorescent Iridium(III) Complexes Capable of Imaging and
Distinguishing between Exogenous and Endogenous Analytes in Living Cells
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02984A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kenneth Yin Zhang, Taiwei Zhang , Huanjie Wei, Qi Wu , Shu-Juan Liu, Qiang Zhao, Wei Huang
Many luminescent probes have been developed for intracellular imaging and sensing. During cellular luminescence sensing, it is difficult to distinguish species generated inside cells from those internalized from extracellular environments...
The content of this RSS Feed (c) The Royal Society of Chemistry
- O 2-3-Aminopropyl diazeniumdiolates suppress progression of highly
metastatic triple-negative breast cancer by inhibition of microvescile
formation via nitric oxide-based epigenetic regulation
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC00167G, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.fenghua Kang, Jiayi Zhu, Jianbing Wu, Tian Lv, Hua Xiang, Jide Tian, Yihua Zhang, Zhangjian Huang
Currently, there is no effective therapy for treatment of highly metastatic triple-negative breast cancer (TNBC). Microvesicle (MV) formation is crucial for metastasis of TNBC. Here we report a novel strategy...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Tetrazine-mediated bioorthogonal prodrug–prodrug activation
Abstract:Chem. Sci., 2018, Advance Article
DOI : 10.1039/C8SC02610F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kevin Neumann, Alessia Gambardella, Annamaria Lilienkampf, Mark Bradley
Prodrug–prodrug activation describes the simultaneous, traceless and bioorthogonal activation of two drugs.
To cite this article before page numbers are assigned, use the
DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Photocatalytic Barbier Reaction – Visible-Light induced Allylation and
Benzylation of Aldehydes and Ketones
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02038H, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Anna Lucia Berger, Karsten Donabauer, Burkhard Koenig
We report a photocatalytic version of the Barbier type reaction using readily available allyl or benzyl bromides and aromatic aldehydes or ketones as starting materials to generate allylic or benzylic...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Overcoming Conservation in TALE-DNA Interactions: A Minimal Repeat
Scaffold Enables Selective Recognition of an Oxidized 5-Methylcytosine
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC01958D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sara Maurer, Benjamin Buchmuller, Christiane Ehrt, Julia Jasper, Oliver Koch, Daniel Summerer
Transcription-activator-like effectors (TALEs) are repeat-based proteins featuring programmable DNA binding. The repulsion of TALE repeats by 5-methylcytosine (5mC) and its oxidized forms makes TALEs potential probes for their programmable analysis....
The content of this RSS Feed (c) The Royal Society of Chemistry
- Can percolation theory explain the gelation behavior of diblock copolymer
worms'
Abstract:Chem. Sci., 2018, Advance Article
DOI : 10.1039/C8SC02406E, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Joseph R. Lovett, Matthew J. Derry, Pengcheng Yang, Fiona L. Hatton, Nicholas J. Warren, Patrick W. Fowler, Steven P. Armes
Physical gelation by block copolymer worms can be explained in terms of multiple inter-worm contacts using percolation theory, suggesting that worm entanglements are irrelevant in this context.
To cite this article before page numbers are assigned, use the
DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Spin-reorientation-induced magnetodielectric coupling effects in two
layered perovskite magnets
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02917B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Bo Huang, Jianyu Zhang, Rui-Kang Huang, Ming-Kun Chen, Wei Xue, Wei-Xiong Zhang, Ming-Hua Zeng, Xiao-Ming Chen
Spin-reorientation-induced magnetodielectric coupling effects were disclosed in two layered perovskite magnets, [C6H5CH2CH2NH3]2[MCl4] (M = Mn2+, Cu2+), by isothermally magnetodielectric measurements on single-crystal samples. Specifically, peak-like dielectric anomaly and spin-flop transition...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Metal-free alkene oxy- and amino-perfluoroalkylations via carbocation
formation by using perfluoro acid anhydrides: unique reactivity between
styrenes and perfluoro diacyl peroxides
Abstract:Chem. Sci., 2018, Advance Article
DOI : 10.1039/C8SC02547A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Elena Valverde, Shintaro Kawamura, Daisuke Sekine, Mikiko Sodeoka
A practical metal-free perfluoroalkylation using acid anhydrides with unique reaction mode via carbocation has been developed.
To cite this article before page numbers are assigned, use the
DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Fluorogenic thiazole orange TOTFO probes stabilise parallel DNA triplexes
at pH 7 and above
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02418A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sarah Walsh, Afaf Helmy El-Sagheer, Tom Brown
The instability of DNA triplexes particularly at neutral pH and above severely limits their applications. Here, we demonstrate that the introduction of a thiazole orange (TO) intercalator onto a thymine...
The content of this RSS Feed (c) The Royal Society of Chemistry
- The coordination chemistry of CmIII, AmIII, and AcIII in nitrate
solutions: an actinide L3-edge EXAFS study
Abstract:Chem. Sci., 2018, Advance Article
DOI : 10.1039/C8SC02270D, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Maryline G. Ferrier, Benjamin W. Stein, Sharon E. Bone, Samantha K. Cary, Alexander S. Ditter, Stosh A. Kozimor, Juan S. Lezama Pacheco, Veronika Mocko, Gerald T. Seidler
CmIII, AmIII, and AcIII have been characterized by solution L3-edge X-ray absorption spectroscopy as a function of nitric acid concentration. This enabled the first experimental determination of Cm and Ac nitrate distances.
To cite this article before page numbers are assigned, use the
DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Facile and Systematic Access to the Least-coordinating WCA
[(RFO)3Al−F−Al(ORF)3]− and its more Lewis-Basic Brother
[F−Al(ORF)3]− (RF = C(CF3)3)
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02591F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Arthur Martens, Philippe Weis, Michael Krummer, Marvin Kreuzer, Andreas Meierhöfer, Stefan Clemens Meier, Jan Bohnenberger, Harald Scherer, Ian Riddlestone, Ingo Krossing
By reaction of the Lewis acid Me3Si−F−Al(ORF)3 with a series of [PF6]− salts, gaseous PF5 and Me3Si-F are liberated and salts of the anion [F−Al(ORF)3]− ([f−al]−; RF = C(CF3)3) can...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Combined reversible switching of ECD and quenching of CPL with chiral
fluorescent macrocycles
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02935K, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Alexandre Homberg, Elodie Brun, Francesco Zinna, Simon Pascal, Marcin Górecki , Luc Monnier, Céline Besnard, Gennaro Pescitelli, Lorenzo Di Bari, Jerome Lacour
Straightforward synthesis and resolution of a series of chiral fluorescent macrocycles are presented, together with their electronic circular dichroism (ECD), strong excimer fluorescence (EF, λ 300 to 650 nm) and...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Carrier-doping as a tool to probe the electronic structure and
multi-carrier recombination dynamics in heterostructured colloidal
nanocrystals
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC01926F, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Tao Ding, Guijie Liang, Junhui Wang, Kaifeng Wu
Heterostructured colloidal nanocrystals, such as core/shells and dot-in-rods, enable new spectral and dynamic properties otherwise unachievable with single-component nanocrystals or quantum dots (QDs). For example, the electron and hole wavefunctions...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Supercooling of functional alkyl-π molecular liquids
Abstract:Chem. Sci., 2018, Advance Article
DOI : 10.1039/C8SC02723D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Fengniu Lu, Keumhee Jang, Izabela Osica, Keita Hagiwara, Michito Yoshizawa, Masashi Ishii, Yoshiaki Chino, Kazuchika Ohta, Kinga Ludwichowska, Krzysztof Jan Kurzydłowski, Shinsuke Ishihara, Takashi Nakanishi
The formation of a metastable supercooled alkyl-π molecular liquid was prohibited by subtle alteration of the molecular structure.
To cite this article before page numbers are assigned, use the
DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Metal-Ligand Pair Anisotropy in a Series of Mononuclear Er-COT Complexes
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC01361F, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jeremy Hilgar, Maximilian Gordon Bernbeck, Brandon S Flores, Jeffrey D Rinehart
Synthetic control of the crystal field has elevated lanthanides to the forefront of single-molecule magnet (SMM) research, yet the resultant strong, predictable single-ion anisotropy has thus far not translated into...
The content of this RSS Feed (c) The Royal Society of Chemistry
- The Hydrogen Atom Transfer Reactivity of Sulfinic Acids
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02400F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Markus Griesser, Jean-Philippe R Chauvin, Derek Andrew Pratt
Sulfinic acids (RSO2H) have a reputation for being difficult reagents due to their facile autoxidation. Nevertheless, they have recently been employed as key reagents in a variety of useful radical...
The content of this RSS Feed (c) The Royal Society of Chemistry
- ZrMOF nanoparticles as quencher to conjugate DNA aptamer for
target-induced bioimaging and photodynamic therapy
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02210K, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yuan Liu, Weijia Hou, Lian Xia, Cheng Cui, Shuo Wan, Ying Jiang, Yu Yang, Qiong Wu, Liping Qiu, Weihong Tan
Porphyrinic metal-organic framework (MOF) nanoparticles for photodynamic therapy solve the photosensitizer problems of poor solubility, self-quenching and aggregation. However, the low selectivity towards malignant tissues is an obstacle for bioimaging...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Correlated dynamics in aqueous proton diffusion
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC01253A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Sean A. Fischer, Brett I. Dunlap, Lennart Daniel Gunlycke
The aqueous proton displays an anomalously large diffusion coefficient that is up to 7 times that of similarly sized cations. There is general consensus that the proton achieves its high...
The content of this RSS Feed (c) The Royal Society of Chemistry
- “All-in-One” Antitumor and Anti-Recurrence/Metastasis Nanomedicine
with Multi-Drug Co-Loading and Burst Drug Release for Multi-Modality
Therapy
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02305K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jichun Yang, Yue Shang, Yu-Hao Li, Yu Cui, Xue-Bo Yin
Drug-loading often suffers from tedious procedure, limited loading efficiency, slow release, and therefore low curative effect. Cancer is easily recurred and metastasized even solid tumor is removed. Herein, we reported...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Boosting the thermoelectric performance of p-type heavily Cu-doped
polycrystalline SnSe via inducing intensive crystal imperfections and
defect phonon scattering
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02397B, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xiaolei Shi, Kun Zheng, Min Hong, Weidi Liu, Raza Moshwan, Yuan Wang, Xianlin Qu, Zhi-Gang Chen, Jin Zou
In this study, we, for the first time, report a high Cu solubility of 11.8 % in single crystal SnSe microbelts synthesized via a facile solvothermal route. The pellets sintered...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Hierarchiral Tandem Assembly of Planar [3×3] Building Units into
{3×[3×3]} Oligomers: Mixed-Valency, Electrical Conductivity and
Magnetism
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02851F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Fei Yu, Mohamedally Kurmoo, Gui-lin Zhuang, Jing-Lin Zuo
A hierarchiral tandem assembly – coordination, oligomerisation and supramolecular organization – is recognized using MALDI-TOF of the solid products of the solvothermal reaction of 5,5'-pyridyl-3,3'-bi-1H-pyrazole with CuSO4.5H2O in CH3OH-CH3CN. The...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Direct evidence for heme-assisted solid-state electronic conduction in
multi-heme c-type cytochromes
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC01716F, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kavita Garg, Miihir Ghosh, Tamar Eilash, Jessica H. van wonderen, Julea Butt, Liang Shi, Xiuyun Jiang, Zdeněk Futera, Jochen Blumberger, Israel Pecht, Mordechai Sheves, David Cahen
Multi-heme cytochrome c (CytC) proteins are key for transferring electrons out of cells, to enable intracellular oxidation to proceed, also in the absence of O2. In these proteins most of...
The content of this RSS Feed (c) The Royal Society of Chemistry
- pH / Hypoxia Programmable Triggered Cancer Photo-Chemotherapy Based on
Semiconducting Polymer dot hybridized Mesoporous Silica Framework
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02408A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Da Zhang, Zhixiong Cai, Naishun Liao, Shanyou Lan, Ming Wu, Haiyan Sun, Zuwu Wei, Juan Li, Xiaolong Liu
Although photothermal therapy (PTT) has become compelling strategy for cancer therapy, few studies concern in the physiological consequences of PTT ablation. Herein, we discover that PTT-induced hyperthermia can aggravate tumor...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Microwave-assisted functionalization of the Aurivillius phase Bi2SrTa2O9:
diol grafting and amine insertion vs. alcohol grafting
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC01754A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Y Wang, Maria Nikolopoulou, Emilie Delahaye, Cédric LEUVREY, Fabrice Leroux, Pierre Rabu, Guillaume Rogez
Microwave-assisted functionalization of the layered Aurivillius phase Bi2SrTa2O9 by alcohols is thoroughly investigated. The grafting of linear aliphatic and bulky alcohols is studied as a function of the starting material,...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Probing cytoplasmic and nuclear microRNAs in single living cells via
plasmonic affinity sandwich assay
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02533A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jia Liu, Yanrong Wen, Hui He, Hong-Yuan Chen, Zhen Liu
MicroRNAs (miRNAs) regulate the expression of mRNAs in cells. The determination of subcellular miRNAs in single living cells is essential for understanding the subcellular localizations and functions of miRNAs as...
The content of this RSS Feed (c) The Royal Society of Chemistry
- A Mild Light-Induced Cleavage of S-O Bond of Aryl Sulfonate Esters Enables
Efficient Sulfonylation of Vinylarenes
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02769B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Maxim Ratushnyy, Monika Kamenova, Vladimir Gevorgyan
A new mode of S-O bond activation has been discovered, which constitutes novel reactivity of easily available and bench stable arylsulfonate phenol esters. This novel protocol enables access to putative...
The content of this RSS Feed (c) The Royal Society of Chemistry
- meta-C–H Arylation of fluoroarenes via traceless directing group
relay strategy
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02417K, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Marc Font, Andrew Spencer, Igor Larrosa
While several methods are now available for the ortho and selective arylation of fluoroarenes, meta-functionalisation has never been achieved. We report a new methodology, based on the traceless directing group...
The content of this RSS Feed (c) The Royal Society of Chemistry
- A Synergistic LUMO Lowering Strategy Using Lewis Acid Catalysis in Water
to Enable Photoredox Catalytic, Functionalizing C-C Cross-Coupling of
Styrenes
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02106F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Elisabeth Speckmeier, Patrick j. w. Fuchs, Kirsten Zeitler
Easy available α-carbonyl acetates serve as convenient alkyl radical source for an efficient, photocatalytic cross-coupling with a great variety of styrenes. Activation of electronically different α-acetylated acetophenone derivatives could be...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Multi-omics and temporal dynamics profiling reveal disruption of central
metabolism in Helicobacter pylori on bismuth treatment
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC01668B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Bingjie Han, Zhen Zhang, Yanxuan Xie, Xuqiao Hu, Haibo Wang, Wei Xia, Yulan Wang, Hongyan Li, Yuchuan Wang, Hongzhe Sun
Integration of multi-omics enables uncovering cellular responses to stimuli or mechanism of action of a drug at system levels. Bismuth drugs have long been used for the treatment of Helicobacter...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Tuning the reactivity of nitriles using Cu(II) catalysis – potentially
prebiotic activation of nucleotides
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02513D, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Ziwei Liu, Angelica Mariani, Longfei Wu, Dougal J Ritson, Andrea Folli, Damien M. Murphy, John Sutherland
During the transition from prebiotic chemistry to biology, a period of solution-phase, non-enzymatic activation of (oligo)nucleotides must have occurred, and accordingly, a mechanism for phosphate activation must have existed. Herein,...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Adaptive Responses of Sterically Confined Intramolecular Chalcogen Bonds
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC01943F, Perspective Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Karuthapandi Selvakumar, Harkesh B Singh
The responsive behavior of an entity towards its immediate surrounding is referred as an adaptive response. The adaptive responses of a noncovalent interaction at molecular scale are reflected from it’s...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Catalyst-Dependent Selectivity in Sulfonium Ylide Cycloisomerization
Reactions
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02815J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Rik Oost, James Neuhaus, Antonio Misale, Ricardo Meyrelles, Luis Filipe F. Veiros, Nuno Maulide
Divergent catalysis is an emerging field whereby access to structurally diverse compounds from a common precursor is achieved through controlled reaction pathways. Herein we present an unusual example of π-acid...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Switchable gate-opening effect in metal–organic polyhedra assemblies
through solution processing
Abstract:Chem. Sci., 2018, Advance Article
DOI : 10.1039/C8SC02263A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Gavin A. Craig, Patrick Larpent, Shinpei Kusaka, Ryotaro Matsuda, Susumu Kitagawa, Shuhei Furukawa
Assemblies of lantern-type metal–organic polyhedra are found to show gate-opening gas adsorption depending on how they are treated with solvents.
To cite this article before page numbers are assigned, use the
DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Correction: The intramolecular hydrogen bonded–halogen bond: a new
strategy for preorganization and enhanced binding
Abstract: Chem. Sci., 2018, Advance Article
DOI : 10.1039/C8SC90145G, Correction Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Asia Marie S. Riel, Daniel A. Decato, Jiyu Sun, Casey J. Massena, Morly J. Jessop, Orion B. Berryman
To cite this article before page numbers are assigned, use the
DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Antibody-nucleotide conjugate as a substrate for DNA polymerases
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC01839A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jana Balintova, Moritz Welter, Andreas Marx
Here we report on the development of an antibody-modified nucleotide and its sequence-selective incorporation into nascent DNA catalysed by DNA polymerases. Although the modification of the nucleotide is several orders...
The content of this RSS Feed (c) The Royal Society of Chemistry
- OH formation and H2 adsorption at the liquid water-Pt(111) interface
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02495B, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Henrik Høgh Kristoffersen, Tejs Vegge, Heine Anton Hansen
The liquid water-Pt(111) interface is studied with constant temperature ab initio molecular dynamics to explore the importance of liquid water dynamics on catalytic reactions such as the oxygen reduction reaction...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Shape-Memory and Self-Healing Functions of DNA-Based Carboxymethyl
Cellulose Hydrogels Driven by Chemical or Light Triggers
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02411A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Chen Wang, Michael Fadeev, Junji Zhang, Margarita Vázquez-González, Gilad Davidson-Rozenfeld, He Tian, Itamar Willner
Photoresponsive nucleic acid-based carboxymethyl cellulose hydrogels are synthesized, and their application as shape-memory and self-healing functional matrices are discussed. One system involves the preparation of a carboxymethyl cellulose hydrogel crosslinked...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Achieving Convenient Tandem of CO2 Electroreduction and Photovoltage Using
Potential-Insensitive Disordered Ag Nanoparticles
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02576B, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Wanyu Deng, Lei Zhang, Hao Dong, Xiaoxia Chang, Tuo Wang, Jinlong Gong
Photovoltaic-electrochemical (PV-EC) system can not only take full use of solar energy, but also transform CO2 into organic molecules. However, it is difficult to achieve PV-EC system since most CO2...
The content of this RSS Feed (c) The Royal Society of Chemistry
