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  Subjects -> CHEMISTRY (Total: 908 journals)
    - ANALYTICAL CHEMISTRY (56 journals)
    - CHEMISTRY (642 journals)
    - CRYSTALLOGRAPHY (21 journals)
    - ELECTROCHEMISTRY (28 journals)
    - INORGANIC CHEMISTRY (43 journals)
    - ORGANIC CHEMISTRY (47 journals)
    - PHYSICAL CHEMISTRY (71 journals)

CHEMISTRY (642 journals)                  1 2 3 4 | Last

Showing 1 - 200 of 735 Journals sorted alphabetically
2D Materials     Hybrid Journal   (Followers: 14)
Accreditation and Quality Assurance: Journal for Quality, Comparability and Reliability in Chemical Measurement     Hybrid Journal   (Followers: 30)
ACS Catalysis     Hybrid Journal   (Followers: 53)
ACS Chemical Neuroscience     Hybrid Journal   (Followers: 23)
ACS Combinatorial Science     Hybrid Journal   (Followers: 23)
ACS Macro Letters     Hybrid Journal   (Followers: 27)
ACS Medicinal Chemistry Letters     Hybrid Journal   (Followers: 44)
ACS Nano     Hybrid Journal   (Followers: 328)
ACS Photonics     Hybrid Journal   (Followers: 15)
ACS Symposium Series     Full-text available via subscription  
ACS Synthetic Biology     Hybrid Journal   (Followers: 25)
Acta Chemica Iasi     Open Access   (Followers: 6)
Acta Chimica Slovaca     Open Access   (Followers: 2)
Acta Chimica Slovenica     Open Access   (Followers: 1)
Acta Chromatographica     Full-text available via subscription   (Followers: 8)
Acta Facultatis Medicae Naissensis     Open Access  
Acta Metallurgica Sinica (English Letters)     Hybrid Journal   (Followers: 7)
Acta Scientifica Naturalis     Open Access   (Followers: 2)
adhäsion KLEBEN & DICHTEN     Hybrid Journal   (Followers: 8)
Adhesion Adhesives & Sealants     Hybrid Journal   (Followers: 9)
Adsorption Science & Technology     Open Access   (Followers: 7)
Advanced Functional Materials     Hybrid Journal   (Followers: 62)
Advanced Science Focus     Free   (Followers: 5)
Advances in Chemical Engineering and Science     Open Access   (Followers: 77)
Advances in Chemical Science     Open Access   (Followers: 21)
Advances in Chemistry     Open Access   (Followers: 27)
Advances in Colloid and Interface Science     Full-text available via subscription   (Followers: 20)
Advances in Drug Research     Full-text available via subscription   (Followers: 26)
Advances in Environmental Chemistry     Open Access   (Followers: 7)
Advances in Enzyme Research     Open Access   (Followers: 11)
Advances in Fluorine Science     Full-text available via subscription   (Followers: 9)
Advances in Fuel Cells     Full-text available via subscription   (Followers: 17)
Advances in Heterocyclic Chemistry     Full-text available via subscription   (Followers: 12)
Advances in Materials Physics and Chemistry     Open Access   (Followers: 27)
Advances in Nanoparticles     Open Access   (Followers: 17)
Advances in Organometallic Chemistry     Full-text available via subscription   (Followers: 17)
Advances in Polymer Science     Hybrid Journal   (Followers: 45)
Advances in Protein Chemistry     Full-text available via subscription   (Followers: 19)
Advances in Protein Chemistry and Structural Biology     Full-text available via subscription   (Followers: 20)
Advances in Quantum Chemistry     Full-text available via subscription   (Followers: 6)
Advances in Science and Technology     Full-text available via subscription   (Followers: 12)
African Journal of Bacteriology Research     Open Access  
African Journal of Chemical Education     Open Access   (Followers: 4)
African Journal of Pure and Applied Chemistry     Open Access   (Followers: 8)
Agrokémia és Talajtan     Full-text available via subscription   (Followers: 2)
Al-Kimia : Jurnal Penelitian Sains Kimia     Open Access  
Alchemy : Journal of Chemistry     Open Access   (Followers: 3)
Alkaloids: Chemical and Biological Perspectives     Full-text available via subscription   (Followers: 2)
AMB Express     Open Access   (Followers: 1)
Ambix     Hybrid Journal   (Followers: 3)
American Journal of Biochemistry and Biotechnology     Open Access   (Followers: 68)
American Journal of Biochemistry and Molecular Biology     Open Access   (Followers: 22)
American Journal of Chemistry     Open Access   (Followers: 34)
American Journal of Plant Physiology     Open Access   (Followers: 13)
American Mineralogist     Hybrid Journal   (Followers: 15)
Anadolu University Journal of Science and Technology A : Applied Sciences and Engineering     Open Access  
Analyst     Full-text available via subscription   (Followers: 37)
Angewandte Chemie     Hybrid Journal   (Followers: 187)
Angewandte Chemie International Edition     Hybrid Journal   (Followers: 273)
Annales Universitatis Mariae Curie-Sklodowska, sectio AA – Chemia     Open Access   (Followers: 1)
Annals of Clinical Chemistry and Laboratory Medicine     Open Access   (Followers: 4)
Annual Reports in Computational Chemistry     Full-text available via subscription   (Followers: 3)
Annual Reports Section A (Inorganic Chemistry)     Full-text available via subscription   (Followers: 4)
Annual Reports Section B (Organic Chemistry)     Full-text available via subscription   (Followers: 9)
Annual Review of Chemical and Biomolecular Engineering     Full-text available via subscription   (Followers: 12)
Annual Review of Food Science and Technology     Full-text available via subscription   (Followers: 15)
Antiviral Chemistry and Chemotherapy     Open Access   (Followers: 2)
Applied Organometallic Chemistry     Hybrid Journal   (Followers: 9)
Applied Spectroscopy     Full-text available via subscription   (Followers: 26)
Applied Surface Science     Hybrid Journal   (Followers: 34)
Arabian Journal of Chemistry     Open Access   (Followers: 6)
ARKIVOC     Open Access   (Followers: 1)
Asian Journal of Biochemistry     Open Access   (Followers: 3)
Asian Journal of Chemistry and Pharmaceutical Sciences     Open Access  
Atomization and Sprays     Full-text available via subscription   (Followers: 4)
Australian Journal of Chemistry     Hybrid Journal   (Followers: 7)
Autophagy     Hybrid Journal   (Followers: 4)
Avances en Quimica     Open Access  
Biochemical Pharmacology     Hybrid Journal   (Followers: 11)
Biochemistry     Hybrid Journal   (Followers: 382)
Biochemistry Insights     Open Access   (Followers: 7)
Biochemistry Research International     Open Access   (Followers: 7)
BioChip Journal     Hybrid Journal  
Bioinorganic Chemistry and Applications     Open Access   (Followers: 11)
Bioinspired Materials     Open Access   (Followers: 5)
Biointerface Research in Applied Chemistry     Open Access   (Followers: 2)
Biointerphases     Open Access   (Followers: 1)
Biology, Medicine, & Natural Product Chemistry     Open Access   (Followers: 2)
Biomacromolecules     Hybrid Journal   (Followers: 24)
Biomass Conversion and Biorefinery     Partially Free   (Followers: 10)
Biomedical Chromatography     Hybrid Journal   (Followers: 6)
Biomolecular NMR Assignments     Hybrid Journal   (Followers: 3)
BioNanoScience     Partially Free   (Followers: 5)
Bioorganic & Medicinal Chemistry     Hybrid Journal   (Followers: 143)
Bioorganic & Medicinal Chemistry Letters     Hybrid Journal   (Followers: 93)
Bioorganic Chemistry     Hybrid Journal   (Followers: 10)
Biopolymers     Hybrid Journal   (Followers: 20)
Biosensors     Open Access   (Followers: 2)
Biotechnic and Histochemistry     Hybrid Journal   (Followers: 1)
Bitácora Digital     Open Access  
Boletin de la Sociedad Chilena de Quimica     Open Access  
Bulletin of the Chemical Society of Ethiopia     Open Access   (Followers: 1)
Bulletin of the Chemical Society of Japan     Full-text available via subscription   (Followers: 25)
Bulletin of the Korean Chemical Society     Hybrid Journal   (Followers: 1)
C - Journal of Carbon Research     Open Access   (Followers: 3)
Cakra Kimia (Indonesian E-Journal of Applied Chemistry)     Open Access  
Canadian Association of Radiologists Journal     Full-text available via subscription   (Followers: 2)
Canadian Journal of Chemistry     Hybrid Journal   (Followers: 12)
Canadian Mineralogist     Full-text available via subscription   (Followers: 7)
Carbohydrate Research     Hybrid Journal   (Followers: 25)
Carbon     Hybrid Journal   (Followers: 70)
Catalysis for Sustainable Energy     Open Access   (Followers: 10)
Catalysis Reviews: Science and Engineering     Hybrid Journal   (Followers: 10)
Catalysis Science and Technology     Hybrid Journal   (Followers: 10)
Catalysis Surveys from Asia     Hybrid Journal   (Followers: 3)
Catalysts     Open Access   (Followers: 14)
Cellulose     Hybrid Journal   (Followers: 13)
Cereal Chemistry     Full-text available via subscription   (Followers: 5)
ChemBioEng Reviews     Full-text available via subscription   (Followers: 2)
ChemCatChem     Hybrid Journal   (Followers: 8)
Chemical and Engineering News     Free   (Followers: 23)
Chemical Bulletin of Kazakh National University     Open Access  
Chemical Communications     Full-text available via subscription   (Followers: 75)
Chemical Engineering Research and Design     Hybrid Journal   (Followers: 28)
Chemical Physics Letters : X     Open Access  
Chemical Research in Chinese Universities     Hybrid Journal   (Followers: 3)
Chemical Research in Toxicology     Hybrid Journal   (Followers: 22)
Chemical Reviews     Hybrid Journal   (Followers: 218)
Chemical Science     Open Access   (Followers: 29)
Chemical Technology     Open Access   (Followers: 36)
Chemical Vapor Deposition     Hybrid Journal   (Followers: 5)
Chemie in Unserer Zeit     Hybrid Journal   (Followers: 57)
Chemie-Ingenieur-Technik (Cit)     Hybrid Journal   (Followers: 21)
ChemInform     Hybrid Journal   (Followers: 8)
Chemistry     Open Access  
Chemistry & Biodiversity     Hybrid Journal   (Followers: 7)
Chemistry & Biology     Full-text available via subscription   (Followers: 33)
Chemistry & Industry     Full-text available via subscription   (Followers: 9)
Chemistry - A European Journal     Hybrid Journal   (Followers: 183)
Chemistry - An Asian Journal     Hybrid Journal   (Followers: 16)
Chemistry and Materials Research     Open Access   (Followers: 21)
Chemistry Central Journal     Open Access   (Followers: 4)
Chemistry Education Research and Practice     Free   (Followers: 5)
Chemistry in Education     Open Access   (Followers: 9)
Chemistry International     Open Access   (Followers: 3)
Chemistry Letters     Full-text available via subscription   (Followers: 46)
Chemistry of Materials     Hybrid Journal   (Followers: 281)
Chemistry of Natural Compounds     Hybrid Journal   (Followers: 10)
Chemistry World     Full-text available via subscription   (Followers: 21)
Chemistry-Didactics-Ecology-Metrology     Open Access   (Followers: 1)
ChemistryOpen     Open Access   (Followers: 1)
Chemkon - Chemie Konkret, Forum Fuer Unterricht Und Didaktik     Hybrid Journal  
Chemoecology     Hybrid Journal   (Followers: 3)
Chemometrics and Intelligent Laboratory Systems     Hybrid Journal   (Followers: 15)
Chemosensors     Open Access  
ChemPhysChem     Hybrid Journal   (Followers: 12)
ChemPlusChem     Hybrid Journal   (Followers: 2)
ChemTexts     Hybrid Journal  
CHIMIA International Journal for Chemistry     Full-text available via subscription   (Followers: 2)
Chinese Journal of Chemistry     Hybrid Journal   (Followers: 6)
Chinese Journal of Polymer Science     Hybrid Journal   (Followers: 11)
Chromatographia     Hybrid Journal   (Followers: 22)
Chromatography     Open Access   (Followers: 3)
Chromatography Research International     Open Access   (Followers: 5)
Cogent Chemistry     Open Access   (Followers: 2)
Colloid and Interface Science Communications     Open Access  
Colloid and Polymer Science     Hybrid Journal   (Followers: 11)
Colloids and Interfaces     Open Access  
Colloids and Surfaces B: Biointerfaces     Hybrid Journal   (Followers: 7)
Combinatorial Chemistry & High Throughput Screening     Hybrid Journal   (Followers: 4)
Combustion Science and Technology     Hybrid Journal   (Followers: 23)
Comments on Inorganic Chemistry: A Journal of Critical Discussion of the Current Literature     Hybrid Journal   (Followers: 2)
Communications Chemistry     Open Access   (Followers: 2)
Composite Interfaces     Hybrid Journal   (Followers: 7)
Comprehensive Chemical Kinetics     Full-text available via subscription   (Followers: 1)
Comptes Rendus Chimie     Full-text available via subscription  
Comptes Rendus Physique     Full-text available via subscription   (Followers: 1)
Computational and Theoretical Chemistry     Hybrid Journal   (Followers: 9)
Computational Biology and Chemistry     Hybrid Journal   (Followers: 13)
Computational Chemistry     Open Access   (Followers: 2)
Computers & Chemical Engineering     Hybrid Journal   (Followers: 10)
Coordination Chemistry Reviews     Full-text available via subscription   (Followers: 4)
Copernican Letters     Open Access   (Followers: 1)
Corrosion Series     Full-text available via subscription   (Followers: 7)
Critical Reviews in Biochemistry and Molecular Biology     Hybrid Journal   (Followers: 8)
Croatica Chemica Acta     Open Access  
Crystal Structure Theory and Applications     Open Access   (Followers: 4)
CrystEngComm     Full-text available via subscription   (Followers: 13)
Current Catalysis     Hybrid Journal   (Followers: 2)
Current Chromatography     Hybrid Journal  
Current Green Chemistry     Hybrid Journal   (Followers: 2)
Current Metabolomics     Hybrid Journal   (Followers: 6)
Current Microwave Chemistry     Hybrid Journal  
Current Opinion in Colloid & Interface Science     Hybrid Journal   (Followers: 9)
Current Opinion in Molecular Therapeutics     Full-text available via subscription   (Followers: 14)
Current Research in Chemistry     Open Access   (Followers: 9)
Current Science     Open Access   (Followers: 77)
Current Topics in Medicinal Chemistry     Hybrid Journal   (Followers: 9)
Current Trends in Biotechnology and Chemical Research     Open Access   (Followers: 2)
Dalton Transactions     Full-text available via subscription   (Followers: 26)

        1 2 3 4 | Last

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Chemical Science
Journal Prestige (SJR): 4.508
Citation Impact (citeScore): 9
Number of Followers: 29  

  This is an Open Access Journal Open Access journal
ISSN (Print) 1478-6524 - ISSN (Online) 2041-6520
Published by RSC Homepage  [46 journals]
  • Palladium-catalyzed enantioselective decarboxylative allylic alkylation of
           fully substituted N-acyl indole-derived enol carbonates

    • Abstract: Chem. Sci., 2019, Advance Article

      DOI : 10.1039/C9SC01726G, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Eric J. Alexy, Tyler J. Fulton, Haiming Zhang, Brian M. Stoltz
      The first enantioselective Pd-catalyzed decarboxylative allylic alkylation of fully substituted N-acyl indole-derived enol carbonates generates acyclic all-carbon quaternary stereocenters in excellent yields (up to 99%) and enantioselectivities (up to 98% ee) using a new electron-deficient phosphinoxazoline (PHOX) ligand.
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  • Synergetic interaction between neighboring platinum and ruthenium monomers
           boosts CO oxidation

    • Abstract: Chem. Sci., 2019, Advance Article

      DOI : 10.1039/C9SC00658C, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Peng Zhou, Xingang Hou, Yuguang Chao, Wenxiu Yang, Weiyu Zhang, Zijie Mu, Jianping Lai, Fan Lv, Kuan Yang, Yuxi Liu, Jiong Li, Jingyuan Ma, Jun Luo, Shaojun Guo
      The synergetic effect between neighboring Pt and Ru monomers supported on N vacancy-rich g-C3N4 promotes the catalytic CO oxidation.
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      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Vinylphosphonites for Staudinger-induced chemoselective peptide
           cyclization and functionalization

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01345H, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Marc-André Kasper, Maria Glanz, Andreas Oder, Peter Schmieder, Jens Peter von Kries, Christian Hackenberger
      In this paper, we introduce vinylphosphonites for chemoselective Staudinger-phosphonite reactions (SPhR) with azides to form vinylphosphonamidates for the subsequent modification of cysteine residues in peptides and proteins. An electron-rich alkene...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • H-Bond donor parameters for cations

    • Abstract: Chem. Sci., 2019, Advance Article

      DOI : 10.1039/C9SC00721K, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Sarah J. Pike, Ennio Lavagnini, Lisa M. Varley, Joanne L. Cook, Christopher A. Hunter
      Parameters that provide a quantitative description of the free energy of interaction of cations with any H-bond acceptor in any solvent have been experimentally determined.
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  • Targeting extracellular glycans: tuning multimeric boronic acids for
           pathogen-selective killing of Mycobacterium tuberculosis

    • Abstract: Chem. Sci., 2019, Advance Article

      DOI : 10.1039/C9SC00415G, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Collette S. Guy, Matthew I. Gibson, Elizabeth Fullam
      Innovative chemotherapeutic agents that are active against Mycobacterium tuberculosis (Mtb) are urgently required to control the tuberculosis (TB) epidemic.
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  • Stretching of cis-Formic Acid: Warm-Up and Cool-Down As Molecular Work-Out

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01555H, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Katharina A. E. Meyer, Martin A. Suhm
      A new technique to rotationally simplify and Raman-probe conformationally and vibrationally excited small molecules is applied to the cis-trans isomerism of formic acid. It quintuples the previously available gas phase...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Regioselectivity Switch in Pd-Catalyzed Hydroallylation of Alkynes

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01527B, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Ding-Wei Ji, Yan-Cheng Hu, Hao Zheng, Chao-Yang Zhao, Qing-An Chen, Vy Dong
      By exploiting the reactivity of a vinyl-Pd species, we control the regioselectivity in hydroallylation of alkynes under Pd-hydride catalysis. A monophosphine ligand and carboxylic acid combination promotes 1,5-dienes by a...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Two non-identical twins in one unit cell: characterization of 34π
           aromatic core-modified octaphyrins, their structural isomers and anion
           bound complexes

    • Abstract: Chem. Sci., 2019, Advance Article

      DOI : 10.1039/C9SC01633C, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Arindam Ghosh, Syamasrit Dash, A. Srinivasan, Cherumuttathu H. Suresh, Tavarekere K. Chandrashekar
      Two inseparable isomers A and B (non-identical twins) crystallize in a single unit cell. However, replacement of middle thiophene ring by selenophene ring results in crystallization of two molecules of isomer A (identical twins).
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  • Correction: Mechanism unravelling for ultrafast and selective 99TcO4−
           uptake by a radiation-resistant cationic covalent organic framework: a
           combined radiological experiment and molecular dynamics simulation study

    • Abstract: Chem. Sci., 2019, 10,5183-5184

      DOI : 10.1039/C9SC90094B, CorrectionOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Linwei He, Shengtang Liu, Long Chen, Xing Dai, Jie Li, Mingxing Zhang, Fuyin Ma, Chao Zhang, Zaixing Yang, Ruhong Zhou, Zhifang Chai, Shuao Wang
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Generalizing metallocene mechanochemistry to ruthenocene mechanophores

    • Abstract: Chem. Sci., 2019, 10,4959-4965

      DOI : 10.1039/C9SC01347D, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ye Sha, Yudi Zhang, Enhua Xu, C. Wayne McAlister, Tianyu Zhu, Stephen L. Craig, Chuanbing Tang
      This work establishes ruthenocene as new metallocene-based mechanophores that exhibit an intriguing combination of force-free thermal stability and mechanical lability.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Highly regioselective complexation of tungsten with Eu@C82/Eu@C84:
           interplay between endohedral and exohedral metallic units induced by
           electron transfer

    • Abstract: Chem. Sci., 2019, 10,4945-4950

      DOI : 10.1039/C9SC01479A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lipiao Bao, Pengyuan Yu, Ying Li, Changwang Pan, Wangqiang Shen, Peng Jin, Shuquan Liang, Xing Lu
      Interplay between inner and outer metallic units induced by charge transfer is observed in tungsten complexes of Eu@C2(5)-C82 and Eu@C2(13)-C84.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Solid-solution alloy nanoparticles of a combination of immiscible Au and
           Ru with a large gap of reduction potential and their enhanced oxygen
           evolution reaction performance

    • Abstract: Chem. Sci., 2019, 10,5133-5137

      DOI : 10.1039/C9SC00496C, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Quan Zhang, Kohei Kusada, Dongshuang Wu, Naoki Ogiwara, Tomokazu Yamamoto, Takaaki Toriyama, Syo Matsumura, Shogo Kawaguchi, Yoshiki Kubota, Tetsuo Honma, Hiroshi Kitagawa
      AuxRu1−x with whole compositions were synthesized and showed an enhanced catalytic performance for OER.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • The antioxidant activity of polysulfides: it's radical!

    • Abstract: Chem. Sci., 2019, 10,4999-5010

      DOI : 10.1039/C9SC00276F, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jean-Philippe R. Chauvin, Markus Griesser, Derek A. Pratt
      Sulfurized olefins (polysulfides) containing four (or more) sulfur atoms react efficiently with peroxyl radicals by homolytic substitution, accounting for their primary antioxidant activity.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Guest recognition enhanced by lateral interactions

    • Abstract: Chem. Sci., 2019, 10,5114-5123

      DOI : 10.1039/C9SC00591A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Tianyu Jiao, Kang Cai, Zhichang Liu, Guangcheng Wu, Libo Shen, Chuyang Cheng, Yuanning Feng, Charlotte L. Stern, J. Fraser Stoddart, Hao Li
      Lateral interactions enhance the guest inclusion and peripheral complexation within a highly charged covalent cage.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Threading-gated photochromism in [2]pseudorotaxanes

    • Abstract: Chem. Sci., 2019, 10,5104-5113

      DOI : 10.1039/C9SC00913B, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Giorgio Baggi, Lorenzo Casimiro, Massimo Baroncini, Serena Silvi, Alberto Credi, Stephen J. Loeb
      Photochromic axles bearing a bis(thienyl)ethene moiety exhibit threading-gated photochromism, where formation of a [2]pseudorotaxane with crown ether rings significantly enhances the photochromic properties of the axles.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Ionic liquid cations as methylation agent for extremely weak chalcogenido
           metalate nucleophiles

    • Abstract: Chem. Sci., 2019, Advance Article

      DOI : 10.1039/C9SC01358J, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Bertram Peters, Silke Santner, Carsten Donsbach, Pascal Vöpel, Bernd Smarsly, Stefanie Dehnen
      Imidazolium-based ionic liquids served to selectively methylate terminal chalcogenide ligands of chalcogenidometalate clusters [Sn10S16O4(SMe)4]4−, [Mn4Sn4Se13(SeMe)4]6−, and [Hg6Te10(TeMe)2]6−.
      To cite this article before page numbers are assigned, use the
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  • NosL is a dedicated copper chaperone for assembly of the CuZ center of
           nitrous oxide reductase

    • Abstract: Chem. Sci., 2019, 10,4985-4993

      DOI : 10.1039/C9SC01053J, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Sophie P. Bennett, Manuel J. Soriano-Laguna, Justin M. Bradley, Dimitri A. Svistunenko, David J. Richardson, Andrew J. Gates, Nick E. Le Brun
      The Cu(I)-binding protein NosL functions specifically as an assembly factor for the unique CuZ centre of nitrous oxide reductase (N2OR).
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Scrutinizing metal–ligand covalency and redox non-innocence via nitrogen
           K-edge X-ray absorption spectroscopy

    • Abstract: Chem. Sci., 2019, 10,5044-5055

      DOI : 10.1039/C8SC03350A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.James T. Lukens, Ida M. DiMucci, Takashi Kurogi, Daniel J. Mindiola, Kyle M. Lancaster
      A series of nitrogen K-edge XAS data obtained for coordination complexes of diverse transition metals is used to calibrate computational pre-edge peak energies and to afford estimates of metal–ligand covalencies. The approach is extended to probe an inner-sphere aminyl radical ligand.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Brønsted acid and Pd–PHOX dual-catalysed enantioselective addition of
           activated C-pronucleophiles to internal dienes

    • Abstract: Chem. Sci., 2019, 10,5176-5182

      DOI : 10.1039/C9SC00633H, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Sangjune Park, Nathan J. Adamson, Steven J. Malcolmson
      We describe the development of Pd–PHOX-catalysed enantioselective couplings of internal dienes with malononitrile and other activated C-pronucleophiles.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Surface-mediated assembly, polymerization and degradation of
           thiophene-based monomers

    • Abstract: Chem. Sci., 2019, 10,5167-5175

      DOI : 10.1039/C8SC05267K, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.G. Galeotti, F. De Marchi, T. Taerum, L. V. Besteiro, M. El Garah, J. Lipton-Duffin, M. Ebrahimi, D. F. Perepichka, F. Rosei
      Temperature mapping of the different molecular phases of tribromoterthienobenzene on (111) coinage metals.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Probing N-glycoprotein microheterogeneity by lectin affinity
           purification-mass spectrometry analysis

    • Abstract: Chem. Sci., 2019, 10,5146-5155

      DOI : 10.1039/C9SC00360F, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Di Wu, Jingwen Li, Weston B. Struwe, Carol V. Robinson
      A lectin affinity purification-mass spectrometry approach to characterize lectin-reactive glycoproteoforms and elucidate lectin specificities at the intact protein level.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Photocatalytic carbanion generation – benzylation of aliphatic
           aldehydes to secondary alcohols

    • Abstract: Chem. Sci., 2019, 10,5162-5166

      DOI : 10.1039/C9SC01356C, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Karsten Donabauer, Mitasree Maity, Anna Lucia Berger, Gregory S. Huff, Stefano Crespi, Burkhard König
      We present a redox-neutral method for the photocatalytic generation of carbanions.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Synthesis of α-heterosubstituted ketones through sulfur mediated
           difunctionalization of internal alkynes

    • Abstract: Chem. Sci., 2019, 10,5156-5161

      DOI : 10.1039/C9SC00568D, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Zhong Zhang, Yuzheng Luo, Hongguang Du, Jiaxi Xu, Pingfan Li
      Synthesis of α-heterosubstituted ketones and related heterocyclic structures was achieved through sulfur mediated difunctionalization of internal alkynes in one pot.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Synthesis and characterization of an unnatural boron and
           nitrogen-containing tryptophan analogue and its incorporation into
           proteins

    • Abstract: Chem. Sci., 2019, 10,4994-4998

      DOI : 10.1039/C8SC05167D, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Katherine Boknevitz, James S. Italia, Bo Li, Abhishek Chatterjee, Shih-Yuan Liu
      A boron and nitrogen containing unnatural analogue of tryptophan is synthesized and incorporated into proteins.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Cyclometalated iridium–BODIPY ratiometric O2 sensors

    • Abstract: Chem. Sci., 2019, 10,5124-5132

      DOI : 10.1039/C9SC00696F, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Ku Sun Choung, Karen Marroquin, Thomas S. Teets
      Cyclometalated iridium–BODIPY conjugates are prepared by a simple strategy and are effective ratiometric sensors for molecular oxygen.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Exploring the thermodynamic criteria for responsive adsorption processes

    • Abstract: Chem. Sci., 2019, 10,5011-5017

      DOI : 10.1039/C9SC01299K, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jack D. Evans, Simon Krause, Stefan Kaskel, Martin B. Sweatman, Lev Sarkisov
      A general thermodynamic model to investigate responsive adsorption processes in flexible porous materials.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Quantum tunnelling of the magnetisation in single-molecule magnet
           isotopologue dimers

    • Abstract: Chem. Sci., 2019, 10,5138-5145

      DOI : 10.1039/C9SC01062A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Eufemio Moreno-Pineda, Gheorghe Taran, Wolfgang Wernsdorfer, Mario Ruben
      Low-temperature magnetic studies of two isotopologues dimers, with and without nuclear spins, reveal that, at very low temperatures, the nuclear spin facilitates the coupling to the phonon bath enhancing the direct relaxation process; observation reflected in the temperature and field dependence of the relaxation rates, whilst at higher temperatures the effect of the nuclear spins is less relevant.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Efficient development of stable and highly functionalised peptides
           targeting the CK2α/CK2β protein–protein interaction

    • Abstract: Chem. Sci., 2019, 10,5056-5063

      DOI : 10.1039/C9SC00798A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jessica Iegre, Paul Brear, David J. Baker, Yaw Sing Tan, Eleanor L. Atkinson, Hannah F. Sore, Daniel H. O' Donovan, Chandra S. Verma, Marko Hyvönen, David R. Spring
      This work describes the efficient development of functionalised, cell-permeable, and stable peptide inhibitors of the protein–protein interaction of CK2.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Photoredox Ni-catalyzed peptide C(sp2)–O cross-coupling: from
           intermolecular reactions to side chain-to-tail macrocyclization

    • Abstract: Chem. Sci., 2019, 10,5073-5078

      DOI : 10.1039/C9SC00694J, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hyelee Lee, Nicolas C. Boyer, Qiaolin Deng, Hai-Young Kim, Tomi K. Sawyer, Nunzio Sciammetta
      Ni/photoredox (4DPAIPN) dual catalysis enabled challenging peptide C(sp2)–O coupling reactions.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Triperyleno[3,3,3]propellane triimides: achieving a new generation of
           quasi-D3h symmetric nanostructures in organic electronics

    • Abstract: Chem. Sci., 2019, 10,4951-4958

      DOI : 10.1039/C9SC00849G, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lingling Lv, Josiah Roberts, Chengyi Xiao, Zhenmei Jia, Wei Jiang, Guowei Zhang, Chad Risko, Lei Zhang
      A novel propellane rylene imide is synthesized. It serves as a versatile building block for quasi-D3h symmetric nanostructures.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Crystallization kinetics of amorphous calcium carbonate in confinement

    • Abstract: Chem. Sci., 2019, 10,5039-5043

      DOI : 10.1039/C8SC05634J, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jack Cavanaugh, Michael L. Whittaker, Derk Joester
      In situ observation of amorphous calcium carbonate (ACC) confined in ∼500 pL emulsion droplets allows determination of the timing of individual crystal nucleation events. Statistical analysis of events in hundreds of droplets establishes an upper limit for the steady-state nucleation rate of 1.2 cm−3 s−1 for the crystallization from ACC.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Enhancing singlet oxygen generation in semiconducting polymer
           nanoparticles through fluorescence resonance energy transfer for tumor
           treatment

    • Abstract: Chem. Sci., 2019, 10,5085-5094

      DOI : 10.1039/C8SC05501G, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jiayang Jiang, Yuanyuan Qian, Zihan Xu, Zhuang Lv, Peng Tao, Mingjuan Xie, Shujuan Liu, Wei Huang, Qiang Zhao
      We have developed semiconducting polymer nanoparticle-based photosensitizers for O2 mapping and enhanced the PDT effect by using fluorescence resonance energy transfer.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Localization of ligands within human carbonic anhydrase II using 19F
           pseudocontact shift analysis

    • Abstract: Chem. Sci., 2019, 10,5064-5072

      DOI : 10.1039/C8SC05683H, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kaspar Zimmermann, Daniel Joss, Thomas Müntener, Elisa S. Nogueira, Marc Schäfer, Livia Knörr, Fabien W. Monnard, Daniel Häussinger
      Unraveling the native structure of protein–ligand complexes in solution enables rational drug design.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Direct population of triplet excited states through singlet–triplet
           transition for visible-light excitable organic afterglow

    • Abstract: Chem. Sci., 2019, 10,5031-5038

      DOI : 10.1039/C8SC05198D, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jie Yuan, Runfeng Chen, Xingxing Tang, Ye Tao, Shen Xu, Lu Jin, Cailin Chen, Xinhui Zhou, Chao Zheng, Wei Huang
      Direct population of triplet states via singlet-to-triplet absorption red-shifts the excitation wavelength and improves the organic afterglow efficiency under ambient conditions.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Diacetyl as a “traceless” visible light photosensitizer in metal-free
           cross-dehydrogenative coupling reactions

    • Abstract: Chem. Sci., 2019, 10,5018-5024

      DOI : 10.1039/C8SC05631E, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Chia-Yu Huang, Jianbin Li, Wenbo Liu, Chao-Jun Li
      Minisci alkylation is of prime importance for its applicability in functionalizing diverse heteroarenes, which are core structures in many bioactive compounds.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Regiodivergent hydrosilylation, hydrogenation, [2π + 2π]-cycloaddition
           and C–H borylation using counterion activated earth-abundant metal
           catalysis

    • Abstract: Chem. Sci., 2019, 10,5079-5084

      DOI : 10.1039/C8SC05391J, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Riaz Agahi, Amy J. Challinor, Joanne Dunne, Jamie H. Docherty, Neil B. Carter, Stephen P. Thomas
      Low oxidation-state iron- and cobalt catalysis has been enabled using tetrafluoroborate activation across 5 reaction classes and seven ligand frameworks using a single catalysis protocol.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Synthesis and reduction chemistry of mixed-Lewis-base-stabilised
           chloroborylenes

    • Abstract: Chem. Sci., 2019, 10,5095-5103

      DOI : 10.1039/C9SC01039D, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Merle Arrowsmith, Julia I. Schweizer, Myron Heinz, Marcel Härterich, Ivo Krummenacher, Max C. Holthausen, Holger Braunschweig
      Mixed-base-stabilised chloroborylenes are easily accessed by twofold reduction of a cyclic (alkyl)(amino)carbene-supported trichloroborane in the presence of a second Lewis base, thus enabling fine-tuning of the electronic properties of the electron-rich borylene centre.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Single-step multivalent capture assay for nucleic acid detection with
           dual-affinity regulation using mutation inhibition and allosteric
           activation

    • Abstract: Chem. Sci., 2019, 10,5025-5030

      DOI : 10.1039/C9SC01199D, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xing Lu, Guobao Zhou, Yanbo Zeng, Zhengzhi Yin, Zulei Zhang, Liping Guo, Yunyun Zhai, Yiwen Yang, Hailong Wang, Lei Li
      A single-step electrocatalytic biosensor with dual-affinity regulation enables a tunable dynamic range and tunable single nucleotide resolution for nucleic acid detection.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Mapping binary copolymer property space with neural networks

    • Abstract: Chem. Sci., 2019, 10,4973-4984

      DOI : 10.1039/C8SC05710A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Liam Wilbraham, Reiner Sebastian Sprick, Kim E. Jelfs, Martijn A. Zwijnenburg
      We map the property space of binary copolymers to understand how copolymerisation can be used to tune the optoelectronic properties of polymers.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • A sulfonium tethered peptide ligand rapidly and selectively modifies
           protein cysteine in vicinity

    • Abstract: Chem. Sci., 2019, 10,4966-4972

      DOI : 10.1039/C9SC00034H, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Dongyuan Wang, Mengying Yu, Na Liu, Chenshan Lian, Zhanfeng Hou, Rui Wang, Rongtong Zhao, Wenjun Li, Yixiang Jiang, Xiaodong Shi, Shuiming Li, Feng Yin, Zigang Li
      A unique peptide stabilization method provides a tethered sulfonium that can rapidly and selectively modify protein cysteine in close vicinity.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Ultra-High Molecular Weight Linear Coordination Polymers with Terpyridine
           Ligands

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01115C, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Reece Lewis, Nino Malic, Kei Saito, Richard A Evans, Neil R Cameron
      Ultra-high molecular weight (UHMW, Mn > 1000 kDa) polymeric drift control adjuvants (DCAs) for agricultural spraying are prone to mechanical degradation and rapidly lose performance. To overcome this, we have...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Formation of Trigons in a Metal-Organic Framework: The Role of
           Metal-Organic Polyhedron Subunits as Meta-Atoms

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC00513G, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jiyoung Lee, Jae Sun Choi, Nak Cheon Jeong, Wonyoung Choe
      Shape control of metal-organic materials in meso- and macroscale has been an important theme due to emerging properties. Especially, chemical etching has been useful to create various forms such as...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • s-Block cooperative catalysis: alkali metal magnesiate-catalysed
           cyclisation of alkynols

    • Abstract: Chem. Sci., 2019, Advance Article

      DOI : 10.1039/C9SC01598A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Michael Fairley, Laia Davin, Alberto Hernán-Gómez, Joaquín García-Álvarez, Charles T. O'Hara, Eva Hevia
      Through mixed metal cooperativity, alkali metal magnesiates efficiently catalyse the cyclisation of alkynols.
      To cite this article before page numbers are assigned, use the
      DOI form of citation above.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Identification of potential sialic acid binding proteins on cell membrane
           by proximity chemical labeling

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01360A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Qiongyu Li, Yixuan Xie, Gege Xu, Carlito B Lebrilla
      The cell membrane contains a highly interactive glycan surface on a scaffold of proteins and lipids. Sialic acids are negatively charged monosaccharides, and the proteins that bind to sialic acids...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Leoligin-inspired synthetic lignans with selectivity for cell-type and
           bioactivity relevant for cardiovascular disease

    • Abstract: Chem. Sci., 2019, Advance Article

      DOI : 10.1039/C9SC00446G, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Thomas Linder, Rongxia Liu, Atanas G. Atanasov, Yuanfang Li, Sophie Geyrhofer, Stefan Schwaiger, Hermann Stuppner, Michael Schnürch, Verena M. Dirsch, Marko D. Mihovilovic
      The first total synthesis of the edelweiss constituent leoligin is reported, together with the first pharmacological evaluation of the parent compound and some of its analogs.
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      DOI form of citation above.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Correction: Identification of selective protein–protein interaction
           inhibitors using efficient in silico peptide-directed ligand design

    • Abstract: Chem. Sci., 2019, Advance Article

      DOI : 10.1039/C9SC90088H, CorrectionOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Andrew M. Beekman, Marco M. D. Cominetti, Samuel J. Walpole, Saurabh Prabhu, Maria A. O’Connell, Jesus Angulo, Mark Searcey
      To cite this article before page numbers are assigned, use the
      DOI form of citation above.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Impact of charge switching stimuli on supramolecular perylene monoimide
           assemblies

    • Abstract: Chem. Sci., 2019, Advance Article

      DOI : 10.1039/C8SC05595E, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Adam Dannenhoffer, Hiroaki Sai, Dongxu Huang, Benjamin Nagasing, Boris Harutyunyan, Daniel J. Fairfield, Taner Aytun, Stacey M. Chin, Michael J. Bedzyk, Monica Olvera de la Cruz, Samuel I. Stupp
      A switchable perylene monoimide which undergoes reversible morphological and electronic changes controlled by the ionization state of the phenolic oxygen.
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      DOI form of citation above.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Molecular mechanism of polyketide shortening in anthraquinone biosynthesis
           of Photorhabdus luminescens

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC00749K, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Qiuqin Zhou, Alois Bräuer, Helene Adihou, Maximilian Schmalhofer, Patricia Saura, Gina Grammbitter, Ville R Kaila, Michael Groll, Helge Bode
      Anthraquinones, a widely distributed class of aromatic natural products, are produced by a type II polyketide synthase system in the Gram-negative bacterium Photorhabdus luminescens. Heterologous expression of the antABCDEFGHI anthraquinone...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Controlling preferential motion of chiral molecular walkers at a surface

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01135H, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.David Abbasi Perez, Hongqian Sang, Lluisa Perez-Garcia, Andrea Floris , rasmita raval, David B Amabilino, J. Manuel Recio, lev Kantorovich
      Molecular walkers standing on two or more “feet” on an anisotropic periodic potential of a crystal surface may perform a one-dimensional Brownian motion at the surface-vacuum interface along a particular...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Temperature-dependent Interchromophoric Interaction in a Fluorescent
           Pyrene-based Metal–organic Framework

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01422E, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Andrzej Gladysiak, Tu Ngoc Nguyen, Richard Bounds, Anna Zacharia, Grigorios Itskos, Jeffrey Reimer, Kyriakos Stylianou
      Compounds exhibiting tuneable fluorescence emission upon heating or cooling are considered smart materials as their optical properties can be exquisitely controlled by adjusting the external temperature. Herein, we report such...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Measuring proteins in H2O with 2D-IR spectroscopy

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01590F, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Samantha Hume, Gordon Hithell, Gregory M Greetham, Paul Donaldson, Michael Towrie, Anthony William Parker, Matthew J Baker, Neil Hunt
      The amide I infrared band of proteins is highly sensitive to secondary structure, but studies under physiological conditions are prevented by strong, overlapping water absorptions, motivating the widespread use of...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Reactive Coordinatively Saturated Mo(III) Complex: Exploiting the Adaptive
           Hapticity of Tris(tert-butoxy)silanolate Ligands

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01955C, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Margherita Pucino, Florian Allouche, Christopher P Gordon, Michael Wörle, Victor Mougel, Christophe Coperet
      Coordinatively unsaturated Mo(III) complexes have been identified as highly reactive species able to activate dinitrogen without the need of a sacrificial reducing agent. Here, we report a coordinatively saturated octahedral...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Continuous nonenzymatic cross-replication of DNA strands with in situ
           activated DNA oligonucleotides

    • Abstract: Chem. Sci., 2019, Advance Article

      DOI : 10.1039/C9SC00770A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Evgeniia Edeleva, Annalena Salditt, Julian Stamp, Philipp Schwintek, Job Boekhoven, Dieter Braun
      A nonenzymatic DNA cross-replicator uses temperature cycling to overcome product inhibition and thus survives exponential dilution conditions.
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      DOI form of citation above.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Laser illumination-induced dramatic catalytic activity change on Au
           nanospheres

    • Abstract: Chem. Sci., 2019, Advance Article

      DOI : 10.1039/C9SC01666J, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Zhongju Ye, Lin Wei, Lehui Xiao, Jianfang Wang
      In this work, the distinct catalytic properties of a single gold nanoparticle (GNP) after symmetry breaking were disclosed at the single-particle level for the first time.
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      DOI form of citation above.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Catalase-like metal–organic framework nanoparticles to enhance
           radiotherapy in hypoxic cancer and prevent cancer recurrence

    • Abstract: Chem. Sci., 2019, Advance Article

      DOI : 10.1039/C9SC00747D, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yuanyuan Chen, Hui Zhong, Jianbo Wang, Xiuyan Wan, Yanhua Li, Wei Pan, Na Li, Bo Tang
      Tumor hypoxia typically occurs inside a solid tumor with an inadequate oxygen supply, sharply reducing the therapeutic efficiency of radiotherapy and significantly increasing the risk of local tumor recurrence.
      To cite this article before page numbers are assigned, use the
      DOI form of citation above.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Stable radical versus reversible σ-bond formation of
           (porphyrinyl)dicyanomethyl radicals

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01631G, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Atsuhiro Osuka, Daiki Shimizu, Ko Furukawa, Bellamkonda Adinarayana
      (Porphyrinyl)dicyanomethyl radicals were produced by oxidation of dicyanomethyl-substituted porphyrins with PbO2. These radicals constitute a rare example displaying stable radical versus dynamic covalent chemistry (DCC) depending upon the substitution position...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Borohydride-containing coordination polymers: synthesis, air stability and
           dehydrogenation

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC00731H, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kentaro Kadota, Nghia Tuan Duong, Yusuke Nishiyama, Easan Sivaniah, Susumu Kitagawa, Satoshi Horike
      Control of the reactivity of hydride (H−) in crystal structures has been a challenge because of its strong electron-donating ability and reactivity with protic species. For metal borohydrides, the dehydrogenation...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Direct Triplet Sensitization of Oligothiophene by Quantum Dots

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01648A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Zihao Xu, Tao Jin, Yiming Huang, Karimulla Mulla, Francesco A Evangelista, Eilaf Egap, Tianquan Lian
      Effective sensitization of triplet states is essential to many applications, including triplet-triplet annihilation based photon upconversion schemes. This work demonstrates successful triplet sensitization of a CdSe quantum dot (QD)–bound oligothiophene...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • An oxygen self-sufficient NIR-responsive nanosystem for enhanced PDT and
           chemotherapy against hypoxic tumors

    • Abstract: Chem. Sci., 2019, Advance Article

      DOI : 10.1039/C9SC00985J, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Guoliang Yang, Jia Tian, Chao Chen, Dawei Jiang, Yudong Xue, Chaochao Wang, Yun Gao, Weian Zhang
      An oxygen self-sufficient NIR-responsive nanoplatform enhances the efficiency of synergistic treatments between PDT and chemotherapy in hypoxic tumors.
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  • Multiple local σ-aromaticity of nonagermanide clusters

    • Abstract: Chem. Sci., 2019, Advance Article

      DOI : 10.1039/C9SC00929A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Nikolay V. Tkachenko, Alexander I. Boldyrev
      A new chemical bonding picture of various nonagermanide species were presented. The stability of Ge9 fragments could be well described via the concept of multiple local σ-aromaticity.
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  • Finding intersections between electronic excited state potential energy
           surfaces with simultaneous ultrafast X-ray scattering and spectroscopy

    • Abstract: Chem. Sci., 2019, Advance Article

      DOI : 10.1039/C8SC04023K, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kasper S. Kjær, Tim B. Van Driel, Tobias C. B. Harlang, Kristjan Kunnus, Elisa Biasin, Kathryn Ledbetter, Robert W. Hartsock, Marco E. Reinhard, Sergey Koroidov, Lin Li, Mads G. Laursen, Frederik B. Hansen, Peter Vester, Morten Christensen, Kristoffer Haldrup, Martin M. Nielsen, Asmus O. Dohn, Mátyás I. Pápai, Klaus B. Møller, Pavel Chabera, Yizhu Liu, Hideyuki Tatsuno, Cornelia Timm, Martin Jarenmark, Jens Uhlig, Villy Sundstöm, Kenneth Wärnmark, Petter Persson, Zoltán Németh, Dorottya Sárosiné Szemes, Éva Bajnóczi, György Vankó, Roberto Alonso-Mori, James M. Glownia, Silke Nelson, Marcin Sikorski, Dimosthenis Sokaras, Sophie E. Canton, Henrik T. Lemke, Kelly J. Gaffney
      Combined X-ray free-electron laser techniques pinpoints loci of intersections between potential energy surfaces of a photo-excited 3d transition-metal centered molecule.
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  • Broadband NIR photostimulated luminescence nanoprobes based on
           CaS:Eu2+,Sm3+ nanocrystals

    • Abstract: Chem. Sci., 2019, Advance Article

      DOI : 10.1039/C9SC01321K, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yu Gao, Renfu Li, Wei Zheng, Xiaoying Shang, Jiaojiao Wei, Meiran Zhang, Jin Xu, Wenwu You, Zhuo Chen, Xueyuan Chen
      A broadband NIR photostimulated luminescence nanoprobe with an ultralow power density threshold is developed based on CaS:Eu2+,Sm3+ nanocrystals.
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  • Ferroelectric metallomesogens composed of achiral spin crossover molecules

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01229J, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ryohei Akiyoshi, Yuma Hirota, Daisuke Kosumi, Mayu Tsutsumi, Masaaki Nakamura, Leonard F Lindoy, Shinya Hayami
      Ferroelectric liquid crystals (FLCs) are fascinating functional materials that have a remnant and electrically invertible polarization. To date, typical FLCs have been mainly realized by molecular design such as the...
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  • Organocopper Cross-coupling Reaction for C–C Bond Formation on Highly
           Sterically Hindered Structures

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC00891H, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Miku Oi, Ryo TAKITA, Junichiro Kanazawa, Atsuya Muranaka, Chao Wang, Masanobu Uchiyama
      We describe a powerful, broadly applicable cross-coupling protocol that enables carbon–carbon bond formation at highly sterically hindered carbon centers (both sp2 and sp3) by employing organocopper reagents under palladium catalysis....
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Ionization of Gold (gamma-Methoxy)vinyl Complexes Generates Reactive Gold
           Vinyl Carbene Complexes

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01574D, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ross Widenhoefer, Nana Kim
      Cationic gold vinyl carbene/allylic cation complexes of the form (E)-[(L)AuC(H)C(H)CAr2]+ OTf– {L = IPr, Ar = Ph [(E)-5a], L = IPr, Ar = 4-C6H4OMe [(E)-5b], L = P(t-Bu)2o-biphenyl, Ar =...
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  • Ruthenium(II)-Catalyzed C-H Allenylation-Based Approach to Allenoic Acids

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC00603F, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xiaoyan Wu, Junjie Fan, Chunling Fu, Shengming Ma
      A Ru(II)-catalyzed direct access to various functionalized allenoic acids via C-H allenylation of readily available aryl carboxylic acid with propargylic acetates is reported. Axially chiral allenoic acids could be obtained...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Widely applicable background depletion step enables transaminase evolution
           through solid-phase screening

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C8SC05712E, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Matteo Planchestainer, Eimear Hegarty, Christian Heckmann, Louise Gourlay, Francesca Paradisi
      Directed evolution of transaminases is a widespread technique in the development of highly sought-after biocatalysts for industrial applications. This process, however, is challenged by the limited availability of effective high-throughput...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • β-Strand Inspired Bifacial π-Conjugated Polymers

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01724K, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Saikat Chaudhuri, Manikandan Mohanan, Andreas V Willems, Jeffery A. Bertke, Nagarjuna Gavvalapalli
      Access to diverse, relatively high molecular weight soluble linear polymers without pendant solubilizing chains is the key to solution state synthesis of structurally diverse nanoribbons of conjugated materials. However, realizing...
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  • Synthesis of aminyl biradicals by base-induced Csp3–Csp3 coupling of
           cationic azo dyes

    • Abstract: Chem. Sci., 2019, Advance Article

      DOI : 10.1039/C9SC01502G, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yizhu Liu, Paul Varava, Alberto Fabrizio, Léonard Y. M. Eymann, Alexander G. Tskhovrebov, Ophélie Marie Planes, Euro Solari, Farzaneh Fadaei-Tirani, Rosario Scopelliti, Andrzej Sienkiewicz, Clémence Corminboeuf, Kay Severin
      Deprotonation of cationic azo dyes results in the formation of aminyl biradicals.
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  • Cysteinylprolyl Imide (CPI) Peptide: A Highly Reactive and Easily
           Accessible Crypto-thioester for Chemical Protein Synthesis

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC00646J, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Masafumi Yanase, Koki Nakatsu, Charlane Joy Cardos, Yoshiki Konda, Gosuke Hayashi, Akimitsu Okamoto
      Native chemical ligation (NCL) between the C-terminal peptide thioester and the N-terminal cysteinyl-peptide revolutionized the field of chemical protein synthesis. The difficulty of direct synthesis of the peptide thioester in...
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  • Effect of oxygen deficiency on the excited state kinetics of WO3 and
           implications for photocatalysis

    • Abstract: Chem. Sci., 2019, Advance Article

      DOI : 10.1039/C9SC00693A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Michael Sachs, Ji-Sang Park, Ernest Pastor, Andreas Kafizas, Anna A. Wilson, Laia Francàs, Sheraz Gul, Min Ling, Chris Blackman, Junko Yano, Aron Walsh, James R. Durrant
      Using WO3 as a model material, we investigate how different oxygen vacancy concentrations affect trapping of photogenerated charges and photocatalytic reactions in metal oxides.
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  • Quo vadis niobium' Divergent coordination behavior of early-transition
           metals towards MOF-5

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01553A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Maciej Damian Korzyński, Luca Braglia, Elisa Borfecchia, Kirill A. Lomachenko, Amgalanbaatar Baldansuren, Christopher H. Hendon, Carlo Lamberti, Mircea Dinca
      Treatment of MOF-5 with NbCl4(THF)2 in acetonitrile leads to incorporation of Nb(IV) centers in a fashion that diverges from the established cation metathesis reactivity of this iconic material. A combination...
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  • Energy Storage. Pseudocapacitance in Prospect.

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01662G, PerspectiveOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Cyrille Costentin, Jean-Michel Saveant
      The two main types of charge storage devices -batteries and double layer charging capacitors- can be unambiguously distinguished from one another by the shape and scan rate dependence of their...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Quantitative insights into charge-separated states from one- and two-pulse
           laser experiments relevant for artificial photosynthesis

    • Abstract: Chem. Sci., 2019, Advance Article

      DOI : 10.1039/C9SC01381D, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Svenja Neumann, Christoph Kerzig, Oliver S. Wenger
      Quantitative laser flash photolysis experiments with several excitation wavelengths provided unprecedented insights into the charge-separated state photochemistry of molecular triads.
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  • Correction: Gold–carbonyl group interactions in the electrochemistry of
           anthraquinone thiols self-assembled on Au(111)-surfaces

    • Abstract: Chem. Sci., 2019, Advance Article

      DOI : 10.1039/C9SC90101A, CorrectionOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Michal Wagner, Katrine Qvortrup, Katja E. Grier, Mikkel R. Ottosen, Jonas O. Petersen, David Tanner, Jens Ulstrup, Jingdong Zhang
      To cite this article before page numbers are assigned, use the
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  • Diiron Oxo Reactivity in a Weak-Field Environment

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC00605B, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Theodore Betley, Elizabeth J Johnson, Claudia Kleinlein, Rebecca A Musgrave
      Concomitant deprotonation and metalation of a dinucleating cofacial Pacman dipyrrin ligand platform tBudmxH2 with Fe2(Mes)4 results in isolation of a diiron complex (tBudmx)Fe2(Mes)2. Treatment of (tBudmx)Fe2(Mes)2 with one equivalent of...
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  • Digital quantum simulation of molecular vibrations

    • Abstract: Chem. Sci., 2019, Advance Article

      DOI : 10.1039/C9SC01313J, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sam McArdle, Alexander Mayorov, Xiao Shan, Simon Benjamin, Xiao Yuan
      We investigate how digital quantum computers may be used to calculate molecular vibrational properties, such as energy levels and spectral information.
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  • Main-Chain Scission of Individual Macromolecules Induced by Solvent
           Swelling

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01639B, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Daniel Messmer, Oscar Bertran, Reinhard Kissner, Carlos Aleman, A. Dieter Schlüter
      We present a comprehensive investigation of main-chain scission processes affecting peripherally charged and neutral members of a class of dendronized polymers (DPs) studied in our laboratory. In these thick, sterically...
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  • On the Encapsulation and Assembly of Anticancer Drugs in a Cooperative
           Fashion

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01380F, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Weikun Wang, Han Wang, Lei Zhiquan, Han Xie, Honggang Cui, Jovica D. Badjic
      In this study, we report on the remarkable recognition and assembly characteristics of D3hsymmetric basket 16-containing two adjoining and nonpolar cavities with six biocompatible GABA residues at their northern and southern termini....
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  • Optimal coordination-site exposure engineering in porous platinum for
           outstanding oxygen reduction performance

    • Abstract: Chem. Sci., 2019, Advance Article

      DOI : 10.1039/C9SC01078E, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Han Cheng, Si Liu, Zikai Hao, Jingyu Wang, Bojun Liu, Guangyao Liu, Xiaojun Wu, Wangsheng Chu, Changzheng Wu, Yi Xie
      Optimal coordination-site exposure engineering in porous platinum brings ultrahigh activity and durability for the fuel cell oxygen reduction reaction.
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  • Revisiting a classical redox process on gold electrode by operando
           ToF-SIMS: where does gold go'

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC00956F, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xin Hua, Hai-Lun Xia, Yi-Tao Long
      Electrochemical redox conversion between ferricyanide and ferrocyanide on gold electrode is one of the most classical reactions in electrochemistry. In textbooks, gold electrode is seen as chemically inert on which...
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  • Energy-storage covalent organic frameworks: Improving performance via
           engineering polysulfide chains on walls

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C8SC04518F, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Donglin Jiang, Fei Xu, Shuhao Yang, Hongqiang Wang, Hejun Li, Bingqing Wei, Xiong Chen, qianhui Liu
      The aligned one-dimensional channels found in covalent organic frameworks offer a unique space for energy storage. However, physical isolation of sulfur in the channels is not sufficient to prevent the...
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  • Mechanochemistry allows carrying out sensitive organometallic reactions in
           air: Glove-box-and-Schlenk-line-free synthesis of oxidative addition
           complexes from aryl halides and palladium(0)

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01711A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Koji Kubota, Rina Takahashi, Hajime Ito
      Organic reactions that employ moisture- and/or oxygen-sensitive reagents or intermedaites usually involve the use of glove-box or Schlenk-line techniques as well as dry and degassed solvents. Unfortunately, these requirements may...
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  • Radical cyanomethylation via vinyl azide cascade-fragmentation

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01370A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.James R Donald, Sophie L. Berrell
      Herein, a novel methodology for radical cyanomethylation is described. The process is initiated by radical addition to the vinyl azide reagent 3-azido-2-methylbut-3-en-2-ol which triggers a cascade-fragmentation mechanism driven by the...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Photoelectric Effect Accelerated Electrochemical Corrosion and Nanoimprint
           Processes on Gallium Arsenide Wafer

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01978B, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Chengxin Guo, Lin Zhang, Matthew Sartin, Lianhuan Han, Zhaowu Tian, Zhong-qun Tian, Dongping Zhan
      Here we report photoelectric-effect-enhanced interfacial charge transfer reactions. The elecrochemical corrosion rate of n-type gallium arsenide (n-GaAs) induced by the contact potential at the platinum (Pt) and GaAs boudaries can...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Symmetry-guided syntheses of mixed-linker Zr metal-organic frameworks with
           precise linker locations

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01301F, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hyehyun Kim, Dongwook Kim, Dohyun Moon, Yong Nam Choi, Seung Bin Baek, Myoung Soo Lah
      While the one-pot reaction of zirconium metal ion with a mixture of two dicarboxylate heterolinkers yield-ed a 12-c fcu Zr MOF with randomly distributed linkers, the symmetry-guided stepwise reaction produced...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Chemically modified nanofoci unifying plasmonics and catalysis

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC00403C, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yueliang Wang, Lingling Fang, Ming Gong, Zhaoxiang Deng
      Plasmonic nanofocus, often in the form of a nanogap, is capable of concentrating light in a nanomeric volume. The greatly enhanced electromagnetic field offers many opportunities in physics and chemistry....
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • The Effect of Water on the Validity of Löwenstein’s Rule

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC00725C, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Christopher J. Heard, Lukáš Grajciar, Petr Nachtigall
      The common understanding of zeolite acidity is based on Löwenstein’s rule, which states that Al-O-Al aluminium pairs are forbidden in zeolites. This rule is generally accepted to be inviolate in...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Trifluoromethylthiolation-Arylation of Diazocarbonyl Compounds by Modified
           Hooz Multicomponent Coupling

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC00829B, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Marvin Luebcke, Dina Bezhan, Kalman J. Szabo
      A new Zn-mediated trifluoromethylthiolation-based bifunctionalization reaction is developed. In this process, simultaneous C-SCF3 and C-C bond formation takes place in a multicomponent reaction, in which an aryl and a SCF3...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Cyano-Borrowing Reaction: Nickel-Catalyzed Direct Conversion of
           Cyanohydrins and Aldehydes/Ketones to β-Cyano Ketone

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC00640K, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zhao-Feng Li, Qian Li, Li-Qing Ren, Qing-Hua Li, Yungui Peng, Tang-Lin Liu
      A direct nickel-catalyzed, high atom- and step-economical reaction of cyanohydrins with aldehydes or ketones via an unprecedented “cyano-borrowing reaction” has been developed. Cleavage of the C-CN bond of cyanohydrins, aldol...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Probing and Regulating the Activity of Cellular Enzyme by DNA Tetrahedron
           Nanostructures

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01912J, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yi Zhang, Yingnan Deng, Congshan Wang, Lidan Li, Lida Xu, Yingjie Yu, Xin Su
      Given the essential role of apurinic/apyrimidinic endonuclease (APE1) in gene repair and cancer progression, we report a novel approach for probing and regulating cellular APE1 activity by using DNA tetrahedron....
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • On the absence of a phonon bottleneck in strongly-confined CsPbBr3
           perovskite nanocrystals

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01339C, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yulu Li, Runchen Lai, Xiao Luo, Xue Liu, Tao Ding, Xin Lu, Kaifeng Wu
      In traditional solar cells, photogenerated energetic carriers (so-called hot carriers) rapidly relax to band edges via emission of phonons, prohibiting the extraction of their excessive energy above the band gap....
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Unusual Confinement Property of a Water Insoluble Small Peptide Hydrogel

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01754B, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Nilotpal Singha, Arpita Srivastava, Bapan Pramanik, Sahnawaz Ahmed, Payel Dowari, sumit Chowdhury, Basab Kanti Das, Ananya Debnath, Debapratim Das
      Unlike polymeric hydrogels, in case of supramolecular hydrogels, the cross-linked network formation is governed by non-covalent forces. Hence, in these cases, the gelator molecules inside the network retain their characteristic...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Acid-durable Electride with Layered Ruthenium for Ammonia Synthesis:
           Boosting the Activity via Selective Etching

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01539F, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jiang Li, Jiazhen Wu, Hiayun Wang, Yangfan Lu, Tiannan Ye, Masato Sasase, Xiaojun Wu, Masaaki Kitano, Takeshi Inoshita, Hideo Hosono
      Ruthenium (Ru) loaded catalysts are of significant interest for ammonia synthesis under mild reaction conditions. The B5 sites have been reported as the active sites for ammonia formation, i.e., Ru...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Substrate Specificity-Enabled Terminal Protection for Direct
           Quantification of Circulating MicroRNA in Patient Serums

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C8SC05240A, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zhihui Dai, Junyao Li, Wenxin Fu, Zhaoyin Wang
      Currently, reported affinity pairings are still lack in diversity, thus terminal protection relying on steric hindrance is restricted in designing nucleic acids-based analytical systems. In this work, resistance to exonuclease...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Development of 68Ga-labelled Ultrasound Microbubbles for Whole-body PET
           Imaging

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC00684B, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Javier Hernandez-Gil, Marta Braga, Bethany Harriss, Laurence Stephen Carroll, Cheong Leow, Mengxing Tang, Eric O. Aboagye, Nicholas J Long
      Microbubble (MB) contrast agents have revolutionised the way we understand ultrasound (US) imaging. Contrast-enhanced US offers improvements in soft-tissue contrast, as well as the ability to visualise disease processes at...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Diketopyrrolopyrrole-based fluorescence probes for the imaging of
           lysosomal Zn2+ and identification of prostate cancer in human tissue

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01153F, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Chenchen Du, Shibo Fu, Xiaohua Wang, Adam C Sedgwick, zhen Wei, Minjie Li, Xinqiang Li, Juan Zhou, Zhong Wang, Hong-Yu Wang, Jonathan L. Sessler
      A series of diketopyrrolopyrrole-based fluorescent probes (DPP-C2, LysoDPP-C2, LysoDPP-C3, and LysoDPP-C4) have been developed for the detection of low pH and Zn2+ in an AND logic fashion. The chelation of...
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  • Automated Glycan Assembly of Lewis Type I and II Oligosaccharide Antigens

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC00768G, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Mónica Guberman, Maria Bräutigam, Peter Seeberger
      Human blood group related glycan antigens are fucosylated (neo-)lactoseries oligosaccharides that play crucial roles in pathogenic processes. Lewis type-II-chain antigens mark the surface of cancer cells, but also are also...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Highly-Chemoselective Step-Down Reduction of Carboxylic Acids to Aromatic
           Hydrocarbons via Palladium Catalysis

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC00892F, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Chengwei Liu, Zhi-Xin Qin, Chong-Lei Ji, Xin Hong, Michal Szostak
      Aryl carboxylic acids are among the most abundant substrates in chemical synthesis and represent a perfect example of a traceless directing group that is central to many processes in the...
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  • Salting-in species induced self-assembly of stable MOFs

    • Abstract: Chem. Sci., 2019, Accepted Manuscript

      DOI : 10.1039/C9SC01447K, Edge ArticleOpen Access Open Access Creative Commons Licence  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ke Li, Jian Yang, Jinlou Gu
      Metal-organic frameworks (MOFs) are attracting immense research interest while their synthesis usually proceeds in organic media or under harsh conditions dependent on specific cases. Herein, Hofmeister effect was firstly introduced...
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