|
Chemical Science
Journal Prestige (SJR): 4.508  Citation Impact (citeScore): 9 Number of Followers: 26  Open Access journalISSN (Print) 1478-6524 - ISSN (Online) 2041-6520 Published by RSC  [44 journals]
|
- Reversibility and reactivity in an acid catalyzed cyclocondensation to
give furanochromanes – A reaction at the ‘oxonium-Prins’ vs.
‘ortho-quinone methide cycloaddition’ mechanistic nexus
Abstract: Chem. Sci., 2019, Accepted Manuscript
DOI : 10.1039/C8SC04302G, Edge Article
Open Access 
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Christian Nielsen, Wouter J Mooij, David Sale, Henry S Rzepa, Jordi Burés, Alan C Spivey
Herein we report a combined experimental and computational investigation of the acid catalysed cyclocondensation reaction between styrenyl homoallylic alchohols and salicycaldehdyes to form furanochromanes. We disclose a previously unreported isomerisation...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Tailored Homo- and Hetero- Lanthanide Porphyrin Dimers: a Synthetic
Strategy for Integrating Multiple Spintronic Functionalities into a Single
Molecule
Abstract: Chem. Sci., 2019, Accepted Manuscript
DOI : 10.1039/C8SC03762K, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lapo Bogani, Jennifer Le Roy, Jonathan Cremers, Isabel Anna Thomlinson, Michael Slota, William Myers, Peter Horton, Simon Coles, Harry Laurence Anderson
We present the design, synthesis and magnetic properties of molecular magnetic systems that contain all elements necessary for spin-valve control in molecular spintronic devices in a single molecule. We investigate...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Triggering the expression of a silent gene cluster from genetically
intractable bacteria results in scleric acid discovery
Abstract:Chem. Sci., 2019, Advance Article
DOI : 10.1039/C8SC03814G, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Fabrizio Alberti, Daniel J. Leng, Ina Wilkening, Lijiang Song, Manuela Tosin, Christophe Corre
The characterisation of scleric acid, a new natural product from a silent and cryptic gene cluster from genetically intractable bacteria, and its biosynthesis are reported.
To cite this article before page numbers are assigned, use the
DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Topological Self-Template Directed Synthesis of Multi-Shelled
Intermetallic Ni3Ga Hollow Microspheres Toward Selective Hydrogenation of
Alkyne
Abstract: Chem. Sci., 2019, Accepted Manuscript
DOI : 10.1039/C8SC03178A, Edge Article Open Access 
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Mingzhen Hu, Wenjuan Yang, Shoujie Liu, Wei Zhu, Yang Li, Botao Hu, Zheng Chen, Rongan Shen, Weng-Chon Cheong, Yu Wang, Kebin Zhou, Qing Peng, Chen Chen, Yadong Li
Multi-Shelled hollow structured materials featured with large void volume and high specific surface area are very promising for a variety of applications. However, controllable synthesis of multi-shelled hollow structured intermetallic...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Mechanism of hydrogen peroxide formation by lytic polysaccharide
monooxygenase
Abstract: Chem. Sci., 2019, Accepted Manuscript
DOI : 10.1039/C8SC03980A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Octav Caldararu, Esko Oksanen, Ulf Ryde, Erik Donovan Hedegård
Lytic polysaccharide monooxygenases (LPMOs) are copper-containing metalloenzymes that can cleave the glycosidic link in polysaccharides. This could become crucial for production of energy-efficient biofuels from recalcitrant polysaccharides. Although LPMOs are...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Site-selective protein conjugation at histidine
Abstract:Chem. Sci., 2019, Advance Article
DOI : 10.1039/C8SC03355B, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Karolina Peciak, Emmanuelle Laurine, Rita Tommasi, Ji-won Choi, Steve Brocchini
Site-selective conjugation generally requires both (i) molecular engineering of the protein of interest to introduce a conjugation site at a defined location and (ii) a site-specific conjugation technology.
To cite this article before page numbers are assigned, use the
DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Counterion Influence on Dynamic Spin Properties in a V(IV) Complex
Abstract: Chem. Sci., 2019, Accepted Manuscript
DOI : 10.1039/C8SC04122A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Chun-Yi Lin, Thacien Ngendahimana, Gareth Eaton, Sandra S Eaton, Joseph Zadrozny
Using transition metal ions for spin-based applications, such as electron paramagnetic resonance imaging (EPRI) or quantum computation, requires a clear understanding of how local chemistry influences spin properties. Herein we...
The content of this RSS Feed (c) The Royal Society of Chemistry
- High-temperature magnetic blocking and magneto-structural correlations in
a series of dysprosium(III) metallocenium single-molecule magnets
Abstract: Chem. Sci., 2019, Accepted Manuscript
DOI : 10.1039/C8SC03907K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kenneth Randall McClain, Colin Alexander Gould, Khetpakorn Chakarawet, Simon Teat, Thomas J Groshens, Jeffrey R. Long, Benjamin Grant Harvey
A series of dysprosium(III) metallocenium salts, [Dy(CpiPr4R)2][B(C6F5)4] (R = H (1), Me (2), Et (3), iPr (4)), was synthesized by reaction of DyI3 with the corresponding known NaCpiPr4R (R =...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Divergent Synthetic Pathway for Pyrimidine-Embedded Medium-Sized Azacycles
through N-quaternizing Strategy
Abstract: Chem. Sci., 2019, Accepted Manuscript
DOI : 10.1039/C8SC04061C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yoona Choi, Heejun Kim, Seung Bum Park
Medium-sized heterocycles have recently received significant attention because of their potential roles as modulators of protein–protein interactions, but their molecular diversity and synthetic availability are still inadequate to meet the...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Unusual fcc-Structured Ag10 Kernel Trapped in Ag70 Nanocluster
Abstract: Chem. Sci., 2019, Accepted Manuscript
DOI : 10.1039/C8SC03396J, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yanmin SU, Zhi Wang, Gui-lin Zhuang, Quanqin Zhao, Xing-Po Wang, Chen-Ho Tung, Di Sun
Controlled trapping atom-precise ultrasmall silver nanoparticles into silver nanoclusters is challenging thus only limited progress has been made in this area. We are therefore inspired to isolate two novel silver...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Folding of Unstructured Peptoids and Formation of Hetero-Bimetallic
Peptoid Complexes upon Side-Chain-to-Metal Coordination
Abstract: Chem. Sci., 2019, Accepted Manuscript
DOI : 10.1039/C8SC03616K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Maria Baskin, Hui Zhu, Zheng-wang Qu, Jordan H Chill, Stefan Grimme, Galia Maayan
Helices are key structural features in biopolymers, enabling a variety of biological functions. Mimicking these secondary structure motifs has a wide potential in the development of biomimetic materials. Peptoids, N-substituted...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Streptavidin interfacing as a general strategy to localize fluorescent
membrane tension probes in cells
Abstract:Chem. Sci., 2018, Advance Article
DOI : 10.1039/C8SC03620A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Antoine Goujon, Karolína Straková, Naomi Sakai, Stefan Matile
Site-specific labeling with biotinylated mechanophores is probed to address the next challenge toward the imaging of forces in cells.
To cite this article before page numbers are assigned, use the
DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Bismuth Oxide/Graphene Oxide Nanocomposite Membrane Showing Super Proton
Conductivity and Low Methanol Permeability
Abstract: Chem. Sci., 2019, Accepted Manuscript
DOI : 10.1039/C8SC03726D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Bailing Liu, Dongming Cheng, Hao-Tian Zhu, Jing Du, Ke Li, Hong-Ying Zang, Huaqiao Tan, Yong-Hui Wang, Wei Xing, Yang-Guang Li
Proton exchange membrane fuel cells usually suffer from severe power loss and even damage under harsh working conditions, which restricts their practical use in cold areas. One effective solution to...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Correction: A robust iron catalyst for the selective hydrogenation of
substituted (iso)quinolones
Abstract: Chem. Sci., 2018, 9,7882-7882
DOI : 10.1039/C8SC90188K, Correction Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Basudev Sahoo, Carsten Kreyenschulte, Giovanni Agostini, Henrik Lund, Stephan Bachmann, Michelangelo Scalone, Kathrin Junge, Matthias Beller
The content of this RSS Feed (c) The Royal Society of Chemistry
- Anion identification using silsesquioxane cages
Abstract:Chem. Sci., 2018, 9,7753-7765
DOI : 10.1039/C8SC02959H, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Supphachok Chanmungkalakul, Vuthichai Ervithayasuporn, Patcharaporn Boonkitti, Alisa Phuekphong, Nicha Prigyai, Sumana Kladsomboon, Suda Kiatkamjornwong
Anthracene-conjugated octameric silsesquioxane cages thermodynamically display intramolecular excimer formation, which can be used to identify anions through the change of fluorescence.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Charge carrier injection and transport engineering in two-dimensional
transition metal dichalcogenides
Abstract:Chem. Sci., 2018, 9,7727-7745
DOI : 10.1039/C8SC02609B, Minireview Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.José Ramón Durán Retamal, Dharmaraj Periyanagounder, Jr-Jian Ke, Meng-Lin Tsai, Jr-Hau He
This review intertwines current engineering strategies tailoring the carrier injection and carrier transport of two-dimensional transition metal dichalcogenides toward efficient electronic devices.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Alternating oligo(o,p-phenylenes) via ruthenium catalyzed diol–diene
benzannulation: orthogonality to cross-coupling enables de novo
nanographene and PAH construction
Abstract:Chem. Sci., 2018, 9,7866-7873
DOI : 10.1039/C8SC03236J, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zachary A. Kasun, Hiroki Sato, Jing Nie, Yasuyuki Mori, Jon A. Bender, Sean T. Roberts, Michael J. Krische
Ruthenium(0) catalyzed diol–diene benzannulation enables formation of p-bromo-terminated alternating oligo(o,p-phenylenes) and, therefrom, diverse PAH materials.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Activity-based ubiquitin-protein probes reveal target protein specificity
of deubiquitinating enzymes
Abstract:Chem. Sci., 2018, 9,7859-7865
DOI : 10.1039/C8SC01573B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ping Gong, Gregory A. Davidson, Weijun Gui, Kun Yang, William P. Bozza, Zhihao Zhuang
Activity-based Ub-PCNA probes identify deubiquitinating enzymes (DUBs) specific for PCNA and demonstrate site-specific deubiquitination by DUBs.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Double layer 3D codes: fluorescent supramolecular polymeric gels allowing
direct recognition of the chloride anion using a smart phone
Abstract:Chem. Sci., 2018, 9,7746-7752
DOI : 10.1039/C8SC03463J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xiaofan Ji, Wei Chen, Lingliang Long, Feihe Huang, Jonathan L. Sessler
The top layer of a two-layer 3D code can be delaminated and removed by exposure to a chloride anion source.
The content of this RSS Feed (c) The Royal Society of Chemistry
- A chemical reporter facilitates the detection and identification of lysine
HMGylation on histones
Abstract:Chem. Sci., 2018, 9,7797-7801
DOI : 10.1039/C8SC02483A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xiucong Bao, Ying Xiong, Xin Li, Xiang David Li
Chemical reporter, HMGAM-yne, facilitates the detection and identification of lysine HMGylation on histones.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Luminescent mesoporous nanorods as photocatalytic enzyme-like peroxidase
surrogates
Abstract:Chem. Sci., 2018, 9,7766-7778
DOI : 10.1039/C8SC03112F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.M. Carmen Ortega-Liebana, Jose L. Hueso, Rodrigo Fernandez-Pacheco, Silvia Irusta, Jesus Santamaria
One-step synthesis of luminescent mesoporous rods with enhanced photocatalytic response as novel metal-free peroxidase-like nanozymes.
The content of this RSS Feed (c) The Royal Society of Chemistry
- High yield accelerated reactions in nonvolatile microthin films: chemical
derivatization for analysis of single-cell intracellular fluid
Abstract:Chem. Sci., 2018, 9,7779-7786
DOI : 10.1039/C8SC03382J, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zhenwei Wei, Xiaochao Zhang, Jinyu Wang, Sichun Zhang, Xinrong Zhang, R. Graham Cooks
The identification of trace components from an individual cell can require derivatization under mild conditions for successful analysis by mass spectrometry (MS).
The content of this RSS Feed (c) The Royal Society of Chemistry
- Rational design of red AIEgens with a new core structure from non-emissive
heteroaromatics
Abstract:Chem. Sci., 2018, 9,7829-7834
DOI : 10.1039/C8SC02810A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Ming Chen, Xianglong Hu, Junkai Liu, Baixue Li, Nelson L. C. Leung, Lucia Viglianti, Tsz Shing Cheung, Herman H. Y. Sung, Ryan T. K. Kwok, Ian D. Williams, Anjun Qin, Jacky W. Y. Lam, Ben Zhong Tang
This work provides a new strategy to design heterocycle-containing AIEgens from non-emissive heteroaromatics and promotes their applications for long-term lysosome imaging.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Live-cell labeling of endogenous proteins with nanometer precision by
transduced nanobodies
Abstract:Chem. Sci., 2018, 9,7835-7842
DOI : 10.1039/C8SC02910E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.A. Klein, S. Hank, A. Raulf, E. F. Joest, F. Tissen, M. Heilemann, R. Wieneke, R. Tampé
Using engineered nanobodies with bright organic dyes (fluorescent nanobodies) and subsequent microfluidic cell manipulation, controlled nanobody delivery was achieved, allowing the multiplexed imaging and super-resolution of endogenous protein networks in living cells.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Understanding complex supramolecular landscapes: non-covalent
macrocyclization equilibria examined by fluorescence resonance energy
transfer
Abstract:Chem. Sci., 2018, 9,7809-7821
DOI : 10.1039/C8SC03229G, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.María J. Mayoral, David Serrano-Molina, Jorge Camacho-García, Eva Magdalena-Estirado, Marina Blanco-Lomas, Elham Fadaei, David González-Rodríguez
Energy transfer between FRET pairs is employed herein to reveal novel intermolecular interactions between self-assembled macrocycles, built via Watson–Crick pairing between complementary dinucleosides, and mononucleoside competitors.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Chemically stable ionic viologen-organic network: an efficient scavenger
of toxic oxo-anions from water
Abstract:Chem. Sci., 2018, 9,7874-7881
DOI : 10.1039/C8SC02456A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Partha Samanta, Priyanshu Chandra, Subhajit Dutta, Aamod V. Desai, Sujit K. Ghosh
Dual capture of hazardous oxo-anions was demonstrated with a viologen based cationic organic network via an anion exchange process.
The content of this RSS Feed (c) The Royal Society of Chemistry
- A DNA nanowire based localized catalytic hairpin assembly reaction for
microRNA imaging in live cells
Abstract:Chem. Sci., 2018, 9,7802-7808
DOI : 10.1039/C8SC02943A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Qiaomei Wei, Jin Huang, Jing Li, Jiaoli Wang, Xiaohai Yang, Jianbo Liu, Kemin Wang
Here, we have developed a localized catalytic hairpin assembly (LCHA) strategy for intracellular miR-21 imaging by using DNA nanowires confining both hairpin probes in a compact space.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Conformation of intrazeolitic choline ions and the framework topology of
zeolite hosts
Abstract:Chem. Sci., 2018, 9,7787-7796
DOI : 10.1039/C8SC02581A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Juna Bae, Suk Bong Hong
A close relationship between the conformation of choline and the structure type of zeolites crystallized using this organic species was found.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Selective C–H halogenation over hydroxylation by non-heme
iron(IV)-oxo
Abstract:Chem. Sci., 2018, 9,7843-7858
DOI : 10.1039/C8SC02053A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sujoy Rana, Jyoti Prasad Biswas, Asmita Sen, Martin Clémancey, Geneviève Blondin, Jean-Marc Latour, Gopalan Rajaraman, Debabrata Maiti
Synthetic non-heme iron-oxo and iron-halide complexes promote selective halogenation of the sp3-C–H bonds via hydrogen atom abstraction and halide rebound phenomenon.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Phosphorescent cationic iridium(III) complexes dynamically bound to
cyclodextrin vesicles: applications in live cell imaging
Abstract:Chem. Sci., 2018, 9,7822-7828
DOI : 10.1039/C8SC02875C, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Frauke Schibilla, Anna Holthenrich, Boyi Song, Anna Lívia Linard Matos, David Grill, Diego Rota Martir, Volker Gerke, Eli Zysman-Colman, Bart Jan Ravoo
Cyclodextrin vesicles decorated with luminescent Ir(III)-complexes are used as contrast agents for cell imaging.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Three to Tango Requires a Site-Specific Substitution: Heterotrimetallic
Molecular Precursors for High-Voltage Rechargeable Batteries
Abstract: Chem. Sci., 2019, Accepted Manuscript
DOI : 10.1039/C8SC03816C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Haixiang Han, Zheng Wei, Alexander S Filatov, Jesse C. Carozza, Melisa Alkan, Andrey Yu Rogachev, Andrey Shevtsov, Artem Abakumov, Chongin Pak, Michael Shatruk, Yu-Sheng Chen, Evgeny V. Dikarev
Design of heterotrimetallic molecules, especially those containing at least two different metals with close atomic numbers, radii, and the same coordination number/environment is a challenging task. This quest is greatly...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Selective Deoxygenation of Nitrate to Nitrosyl using Trivalent Chromium
and the Mashima Reagent: Reductive Silylation
Abstract: Chem. Sci., 2019, Accepted Manuscript
DOI : 10.1039/C8SC02979B, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Junghee Seo, Alyssa Cabelof, Chun-Hsing Chen, Kenneth G Caulton
1,4-Bis(trimethylsilyl)-1,4-diaza-2,5-cyclohexadiene is an effective silyl transfer reagent towards oxygen of nitrate coordinated to Cr(III) in a pincer complex. Two nitrate oxygens are removed to give the 17 valence electron octahedral...
The content of this RSS Feed (c) The Royal Society of Chemistry
- A cheap metal for a challenging task: nickel-catalyzed highly diastereo-
and enantioselective hydrogenation of tetrasubstituted fluorinated
enamides
Abstract:Chem. Sci., 2018, Advance Article
DOI : 10.1039/C8SC04002H, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yu-Qing Guan, Zhengyu Han, Xiuxiu Li, Cai You, Xuefeng Tan, Hui Lv, Xumu Zhang
Nickel-catalyzed stereospecific syn-selective asymmetric hydrogenation of challenging tetrasubstituted fluorinated enamides has been achieved. This protocol provides an efficient access to chiral α-fluoro-β-amino esters.
To cite this article before page numbers are assigned, use the
DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Glucose/O2 Fuel Cell-Based Self-Powered Biosensor for Probing Drug
Delivery Model with Self-Diagnosis and Self-Evaluation
Abstract: Chem. Sci., 2019, Accepted Manuscript
DOI : 10.1039/C8SC04019B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Linlin Wang, Haohua Shao, Xuanzhao Lu, Wenjing Wang, Jian-Rong Zhang, Rong-Bin Song, Jun-Jie Zhu
Extending the application self-powered biosensor (SPB) into the drug delivery field is highly desirable. Herein, a robust glucose/O2 fuel cell-based biosensor is successfully integrated with targeting drug delivery system to...
The content of this RSS Feed (c) The Royal Society of Chemistry
- The effect of particle size, morphology and support on the formation of
palladium hydride in commercial catalysts
Abstract: Chem. Sci., 2019, Accepted Manuscript
DOI : 10.1039/C8SC03766C, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Stewart Parker, Helen Walker, Samantha K Callear, Elena Grünewald, Tina Petzold, Dorit Wolf, Konrad Möbus, Julian Adam, Stefan D Wieland, Monica Jimenez-Ruiz, PETER w Albers
The relative amounts of hydrogen retained by a range of supported palladium catalysts have been investigated by a combination of electron microscopy and spectroscopic techniques, including incoherent inelastic neutron scattering....
The content of this RSS Feed (c) The Royal Society of Chemistry
- Facile chemoenzymatic synthesis of a novel stable mimic of NAD+
Abstract: Chem. Sci., 2019, Accepted Manuscript
DOI : 10.1039/C8SC03899F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Zhefu Dai, Xiao-Nan Zhang, Fariborz Nasertorabi, Qinqin Cheng, Hua Pei, Stan G. Louie, Raymond C Stevens, Yong Zhang
Nicotinamide adenine dinucleotide (NAD+) is an essential cofactor participating in a variety of important enzyme-catalyzed physiological and pathophysiological processes. Analogues of NAD+ provide key and valuable agents for investigating NAD+-dependent...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Organic core–shell-shaped micro/nanoparticles from twisted
macrocycles in Schiff base reaction
Abstract: Chem. Sci., 2019, Accepted Manuscript
DOI : 10.1039/C8SC03824D, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xin-Long Ni, Huaiyu Chen, Chao Huang, Yazhou Ding, Qi-Long Zhang, Bixue Zhu
Functional self-assemblies derived from noncovalent interactions such as lipid vesicle and DNA chiral double helix are a typical feature of natural life activity. Because of this phenomenon, a self-assembly approach...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Carved Nanoframes of Cobalt-Iron Bimetal Phosphide as a Bifunctional
Electrocatalyst for Efficient Overall Water splitting
Abstract: Chem. Sci., 2019, Accepted Manuscript
DOI : 10.1039/C8SC03877E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yuebin Lian, Hao Sun, Xuebin Wang, Pengwei Qi, Qiaoqiao Mu, Yujie Chen, Jing Ye, Xiaohui Zhao, Zhao Deng, Yang Peng
Water electrolysis for hydrogen production has been long regarded as an ideal tactic for renewable energy conversion and storage, but impeded by the sluggish kinetics of both the hydrogen and...
The content of this RSS Feed (c) The Royal Society of Chemistry
- MoS2-Quantum Dots Triggered Reactive Oxygen Species Generation and
Depletion: Responsible for Enhanced Chemiluminescence
Abstract: Chem. Sci., 2019, Accepted Manuscript
DOI : 10.1039/C8SC03511C, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xiangnan Dou, Qiang Zhang, Syed Niaz Ali Shah, Mashooq Khan, Katsumi Uchiyama, Jin-Ming Lin
Reactive oxygen species (ROS) generation is of intense interest because of its crucial role in many fields. Here we demonstrate MoS2-QDs exhibits a promising capability for generation of reactive oxygen...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Colloidal Tectonics for Tandem Synergistic Pickering Interfacial
Catalysis: Oxidative Cleavage of Cyclohexene Oxide into Adipic Acid
Abstract: Chem. Sci., 2019, Accepted Manuscript
DOI : 10.1039/C8SC03345E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Bingyu Yang, Loic Leclercq, Veronique Schmitt, Marc Pera-Titus, Véronique Nardello-Rataj
Supramolecular preorganization and interfacial recognition can provide useful architectures for colloidal building. To this aim, a novel approach, based on colloidal tectonics involving two surface-active particles containing both recognition and...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Penetration depth tunable BODIPY derivatives for pH triggered enhanced
photothermal/photodynamic synergistic therapy
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02443J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xiao-Chen Dong, Jianhua Zou, peng wang, Ya Wang, Gongyuan Liu, Yewei Zhang, Qi Zhang, Jinjun Shao, Weili Si, Wei Huang
Improving the deep-tissue phototherapy (PDT) efficiency in the near-infrared (NIR) region has become one of the major challenges in clinic for cancer treatment. Developing intelligent photosensitizers (PSs) responding to tumor-specific...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Correction: Ligand design for Rh(III)-catalyzed C–H activation: an
unsymmetrical cyclopentadienyl group enables a regioselective synthesis of
dihydroisoquinolones
Abstract: Chem. Sci., 2018, Advance Article
DOI : 10.1039/C8SC90195C, Correction Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Todd K. Hyster, Derek M. Dalton, Tomislav Rovis
To cite this article before page numbers are assigned, use the
DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Host-guest selectivity in a series of isoreticular metal-organic
frameworks: observation of acetylene-to-alkyne and carbon dioxide-to-amide
interactions
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03622E, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jack Humby, Oguarabau Benson, Gemma Smith, Stephen Argent, Ivan da Silva, Yongqiang Cheng, Svemir Rudic, Pascal Manuel, Mark Frogley, Gianfelice Cinque, Lucy K Saunders, Inigo Vitorica-Yrzebal, George F S Whitehead, Timothy Easun, William Lewis, Alexander J. Blake, Anibal Javier Ramirez-Cuesta, Sihai Yang, Martin Schroder
In order to develop new porous materials for applications in gas separations such as natural gas upgrading, landfill gas processing and acetylene purification it is vital to gain understanding of...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Bisulfite-free, single base-resolution analysis of 5-hydroxymethylcytosine
in genomic DNA by chemical-mediated mismatch
Abstract: Chem. Sci., 2019, Accepted Manuscript
DOI : 10.1039/C8SC04272A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xiang Zhou, Yafen Wang, Xiong Zhang, Fan Wu, Zonggui Chen
5-hydroxymethylcytosine (5hmC) is known as one of the vital players in nuclear reprogramming and the process of active DNA demethylation. Although the development of whole-genome sequencing methods for modified cytosine...
The content of this RSS Feed (c) The Royal Society of Chemistry
- A versatile synthetic strategy to macromolecular cages: Intramolecular
consecutive cyclization of star-shaped polymers
Abstract: Chem. Sci., 2019, Accepted Manuscript
DOI : 10.1039/C8SC04006K, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yoshinobu Mato, Kohei Honda, Kenji Tajima, Takuya Yamamoto, Takuya Isono, Toshifumi Satoh
Cage-shaped polymers, or “macromolecular cages”, are of great interest as the macromolecular analogues of molecular cages because of their various potential applications in supramolecular chemistry and materials science. However, the...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Rational design of super-contrast NIR-II fluorophore affords
high-performance NIR-II molecular imaging guided microsurgery
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03751E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Rui Tian, Huilong Ma, Qinglai Yang, Hao Wan, Shoujun Zhu, Swati Chandra, Haitao Sun, Dale Kiesewetter, Gang Niu, Yongye Liang, Xiaoyuan Shawn Chen
In vivo molecular imaging in the “transparent” near-infrared II (NIR-II) window has demonstrated impressive benefits in reaching millimeter penetration depths with high specificity and imaging quality. Previous NIR-II molecular imaging...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Dissolving uptake-hindering surface defects in metal–organic
frameworks
Abstract:Chem. Sci., 2018, Advance Article
DOI : 10.1039/C8SC03735C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kai Müller, Nina Vankova, Ludger Schöttner, Thomas Heine, Lars Heinke
Performance-limiting surface defects in metal–organic frameworks caused by exposure to a humid environment can be dissolved by exposure to ethanol.
To cite this article before page numbers are assigned, use the
DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Origin of the low-temperature endotherm of acid-doped ice VI: New
hydrogen-ordered phase of ice or deep glassy states'
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03647K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Alexander Rosu-Finsen, Christoph G. Salzmann
On the basis of a low-temperature endotherm, it has recently been argued that cooling acid-doped ice VI at high pressures leads to a new hydrogen-ordered phase. We show that the...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Luminescent ruffled iridium(III) porphyrin complexes containing
N-heterocyclic carbene ligands: structures, spectroscopies and potent
antitumor activities under dark and light irradiation conditions
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02920B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Tsz Lung Lam, Tong Ka Chung, Chen Yang, Wai-Lun Kwong, Xiangguo Guan, Ming-De Li, Vanessa Kar-Yan Lo, Sharon Lai-Fung Chan, David Lee Phillips, Chun-Nam Lok, Chi-Ming Che
A panel of iridium(III) porphyrin complexes containing axial N-heterocyclic carbene (NHC) ligand(s) were synthesized and characterized. X-ray crystal structures of the bis-NHC complexes [IrIII(ttp)(IMe)2]+ (2a), [IrIII(oep)(BIMe)2]+ (2d), [IrIII(oep)(IiPr)2]+ (2e) and...
The content of this RSS Feed (c) The Royal Society of Chemistry
- The biosynthetic implications of late-stage condensation domain
selectivity during glycopeptide antibiotic biosynthesis
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03530J, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Melanie Schoppet, Madeleine Peschke, Anja Kirchberg, Vincent Wiebach, Roderich D. Süssmuth, Evi Stegmann, Max Cryle
Non-ribosomal peptide synthesis is a highly important biosynthetic pathway for the formation of many secondary metabolites of medical relevance. Due to the challenges associated with the chemical synthesis of many...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Cell Membrane-Anchored Fluorescent Probe for Monitoring Carbon Monoxide
Released out of Living Cells
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03584A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shuai Xu, Hongwen Liu, Xia Yin, Lin Yuan, Shuangyan Huan, Xiaobing Zhang
Carbon monoxide (CO) acts as an important gasotransmitter in delivering intramolecular and intermolecular signals to regulate a variety of physiological processes. This lipid-soluble gas can freely pass through cell membrane...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Effects of coordination sphere on unusually large zero field splitting and
slow magnetic relaxation in trigonally symmetric molecules
Abstract:Chem. Sci., 2018, Advance Article
DOI : 10.1039/C8SC02820F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kelsey A. Schulte, Kuduva R. Vignesh, Kim R. Dunbar
Coordination of a water molecule results in drastic effects on the magnetic behavior of a series of trigonal monopyramidal and bipyramidal compounds.
To cite this article before page numbers are assigned, use the
DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
- van der Waals forces control ferroelectric–antiferroelectric ordering in
CuInP2S6 and CuBiP2Se6 laminar materials
Abstract:Chem. Sci., 2018, 9,7620-7627
DOI : 10.1039/C8SC01274A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jeffrey R. Reimers, Sherif Abdulkader Tawfik, Michael J. Ford
We show how van der Waals (vdW) forces outcompete covalent and ionic forces to control ferroelectric ordering in CuInP2S6 nanoflakes as well as in CuInP2S6 and CuBiP2Se6 crystals.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Visualization of oxidative injury in the mouse kidney using selective
superoxide anion fluorescent probes
Abstract:Chem. Sci., 2018, 9,7606-7613
DOI : 10.1039/C8SC03308K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yun Lv, Dan Cheng, Dongdong Su, Mei Chen, Bin-Cheng Yin, Lin Yuan, Xiao-Bing Zhang
Drug-induced acute kidney injury (AKI), caused by renal drug metabolism, has been regarded as a main problem in clinical pharmacology and practice.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Rational synthesis of benzimidazole[3]arenes by CuII-catalyzed
post-macrocyclization transformation
Abstract:Chem. Sci., 2018, 9,7614-7619
DOI : 10.1039/C8SC03086C, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Shohei Tashiro, Tsutomu Umeki, Ryou Kubota, Mitsuhiko Shionoya
A new series of calix[n]arene analogues, benzimidazole[3]arenes, was rationally synthesized by CuII-catalyzed post-macrocyclization transformation of a tris(o-phenylenediamine) macrocycle, and fully characterized by NMR, MS, and single-crystal X-ray diffraction (XRD) analyses.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Chimera: enabling hierarchy based multi-objective optimization for
self-driving laboratories
Abstract:Chem. Sci., 2018, 9,7642-7655
DOI : 10.1039/C8SC02239A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Florian Häse, Loïc M. Roch, Alán Aspuru-Guzik
Chimera enables multi-target optimization for experimentation or expensive computations, where evaluations are the limiting factor.
The content of this RSS Feed (c) The Royal Society of Chemistry
- The mechanism of the triple aryne–tetrazine reaction cascade: theory
and experiment
Abstract:Chem. Sci., 2018, 9,7688-7693
DOI : 10.1039/C8SC01796D, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Sung-Eun Suh, Shuming Chen, K. N. Houk, David M. Chenoweth
This article describes an experimental and computational investigation on the possible aryne reactivity modes in the course of the reaction of two highly energetic molecules, an aryne and a 1,2,4,5-tetrazine.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Preventing the coffee-ring effect and aggregate sedimentation by in situ
gelation of monodisperse materials
Abstract:Chem. Sci., 2018, 9,7596-7605
DOI : 10.1039/C8SC03302A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Huaiguang Li, Darren Buesen, Rhodri Williams, Joerg Henig, Stefanie Stapf, Kallol Mukherjee, Erik Freier, Wolfgang Lubitz, Martin Winkler, Thomas Happe, Nicolas Plumeré
Microscale uniformity and long-range cohesion in multi-functional films assembled through drop-casting is realized by in situ gelation of monodisperse building blocks.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Addition of arylstannanes to alkynes giving ortho-alkenylarylstannanes
catalysed cooperatively by a rhodium complex and zinc chloride
Abstract:Chem. Sci., 2018, 9,7700-7704
DOI : 10.1039/C8SC02459F, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jialin Ming, Qi Shi, Tamio Hayashi
A Rh complex and ZnCl2 cooperatively catalyse the reaction of arylstannanes with alkynes giving ortho-alkenylarylstannanes.
The content of this RSS Feed (c) The Royal Society of Chemistry
- A vesicle-aggregation-assembly approach to highly ordered mesoporous
γ-alumina microspheres with shifted double-diamond networks
Abstract:Chem. Sci., 2018, 9,7705-7714
DOI : 10.1039/C8SC02967A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yang Liu, Wei Teng, Gang Chen, Zaiwang Zhao, Wei Zhang, Biao Kong, Wael N. Hozzein, Areej Abdulkareem Al-Khalaf, Yonghui Deng, Dongyuan Zhao
Highly ordered mesoporous γ-alumina microspheres with a shifted double-diamond mesostructure have been synthesized via a vesicle-aggregation-assembly approach.
The content of this RSS Feed (c) The Royal Society of Chemistry
- A β-diketiminate manganese catalyst for alkene hydrosilylation: substrate
scope, silicone preparation, and mechanistic insight
Abstract:Chem. Sci., 2018, 9,7673-7680
DOI : 10.1039/C8SC02768D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Tufan K. Mukhopadhyay, Marco Flores, Thomas L. Groy, Ryan J. Trovitch
A (BDI)Mn catalyst has been found to hydrosilylate olefins and the observed selectivity can be attributed to alkene insertion.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Tailor-made Janus lectin with dual avidity assembles glycoconjugate
multilayers and crosslinks protocells
Abstract:Chem. Sci., 2018, 9,7634-7641
DOI : 10.1039/C8SC02730G, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.João P. Ribeiro, Sarah Villringer, David Goyard, Liliane Coche-Guerente, Manuela Höferlin, Olivier Renaudet, Winfried Römer, Anne Imberty
The double-faced Janus lectin, designed by assembling sialic acid and fucose-specific lectin, organize multivalent heteroglyco compounds in mulitlayered material, and glycosylated protocells in prototissues.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Adhesion analysis of single circulating tumor cells on a base layer of
endothelial cells using open microfluidics
Abstract:Chem. Sci., 2018, 9,7694-7699
DOI : 10.1039/C8SC03027H, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sifeng Mao, Qiang Zhang, Haifang Li, Wanling Zhang, Qiushi Huang, Mashooq Khan, Jin-Ming Lin
We present a microfluidic method for adhesion strength analysis of single CTCs on endothelial cells to reveal tumor metastasis.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Four-coordinate triarylborane synthesis via cascade B–Cl/C–B
cross-metathesis and C–H bond borylation
Abstract:Chem. Sci., 2018, 9,7666-7672
DOI : 10.1039/C8SC02281J, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kai Yang, Guan Zhang, Qiuling Song
We herein describe a tandem highly selective B–Cl/C–B cross-metathesis of two same or different arylboranes and C–H bond borylation to synthesize four-coordinate triarylboranes with broad substrate scope.
The content of this RSS Feed (c) The Royal Society of Chemistry
- De novo coiled-coil peptides as scaffolds for disrupting
protein–protein interactions
Abstract:Chem. Sci., 2018, 9,7656-7665
DOI : 10.1039/C8SC02643B, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jordan M. Fletcher, Katherine A. Horner, Gail J. Bartlett, Guto G. Rhys, Andrew J. Wilson, Derek N. Woolfson
Homo- and hetero-dimeric coiled coils as scaffolds for the presentation of α-helical protein-binding motifs.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Fluorogenic thiazole orange TOTFO probes stabilise parallel DNA triplexes
at pH 7 and above
Abstract:Chem. Sci., 2018, 9,7681-7687
DOI : 10.1039/C8SC02418A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sarah Walsh, Afaf Helmy El-Sagheer, Tom Brown
Multiple additions of thiazole orange forms TOTFO probes stable for dsDNA detection and also expands the triplex target range.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Diastereoselective C–H carbonylative annulation of aliphatic amines: a
rapid route to functionalized γ-lactams
Abstract:Chem. Sci., 2018, 9,7628-7633
DOI : 10.1039/C8SC02855A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zhuang Mao Png, Jaime R. Cabrera-Pardo, Jorge Peiró Cadahía, Matthew J. Gaunt
A palladium(II)-catalysed C(sp3)–H carbonylation of free(NH) secondary aliphatic amines to 2-pyrrolidinones is described.
The content of this RSS Feed (c) The Royal Society of Chemistry
- H-bond Stabilized Quinone Electrode Material for Li-Organic Batteries: the
Strength of Weak Bonds
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02995D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Louis Sieuw, Alia Jouhara, Eric Quarez, Chloe Auger, Jean-François Gohy, Philippe Poizot, Alexandru Vlad
Small organic materials are generally plagued by their high solubility in battery electrolytes. Finding approaches to suppress the solubilization while not penalizing the gravimetric capacity remains a persisting challenge. Here...
The content of this RSS Feed (c) The Royal Society of Chemistry
- An enzyme-activatable probe liberating AIEgen: on-site sensing and
long-term tracking of β-galactosidase in ovarian cancer cells
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC04266G, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kaizhi Gu, Wanshan Qiu, Zhiqian Guo, Chenxu Yan, Shiqin Zhu, Defan Yao, Ping Shi, He Tian, Weihong Zhu
Development of fluorescent probes for on-site sensing and long-term tracking of specific biomarkers is particularly desirable for the early detection of diseases. However, available small-molecule probes tend to facilely diffuse...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Direct observation of the intermediate in an ultrafast isomerization.
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03258K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Tyler M. Porter, Jiaxi Wang, Yingmin Li, Bo Xiang, Jennifer Catherine Salsman, Joel S Miller, Wei Xiong, Clifford P. Kubiak
Using a combination of two-dimensional infrared (2D IR) and variable temperature Fourier transform infrared (FTIR) spectroscopies the rapid structural isomerization of a five-coordinate ruthenium complex is investigated. In methylene chloride,...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Wetting the lock and key enthalpically favours polyelectrolytes binding
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02966K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Emeric Jeamet, Jean Septavaux, Alexandre Héloin, Marion Donnier-Maréchal, Melissa Dumartin, Benjamin OURRI, Pradeep Kumar Mandal, Ivan Huc, Emmanuelle Bignon, Elise Dumont, Christophe Morell, Jean-Patrick Francoia, Florent PERRET, Laurent Vial, Julien Leclaire
By using a combination of readily accessible experimental and computational experiments in water, we explored the factors governing the association between a polyanionic dyn[4]arene and a series of α,ω-alkyldiammonium ions...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Hybrid CuCoO-GO Enables Ultrasensitive Detection of Antibiotics with
Enhanced Laser Desorption/Ionization at Nano-interfaces
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03692F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jian Liu, Enhui Wu, Kun Feng, Rui Shi, Rui Lv, Fuzhong Ouyang, Shawn Li, Jun Zhong
The soaring concerns globally on antibiotic overuse have made urgent calls for the development of rapid and sensitive detection methods. Here we report that hybrid CuCoO-GO matrix allows for sensitive...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Fluorescence enhancement of a ligand-activated fluorescent protein induced
by collective noncovalent interactions
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03558J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Euihyun Lee, Sang-Hee Shim, Minhaeng Cho
Fluorescent protein contains an internal chromophore constituted of amino acids or an external chromophore covalently bonded to the protein. To increase their fluorescence intensities, many research groups have attempted to...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Methylation-effect in Prolonging the Pure Organic Room Temperature
Phosphorescence Lifetime
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03019G, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Zhu Mao, Zhan Yang, Zhenguo Fan, Eethamukkala Ubba, Wenlang Li, Yang Li, Juan Zhao, Zhiyong Yang, Matthew Phillip Aldred, Zhenguo Chi
Prolonging the phosphorescence lifetime of pure organic phosphorescent materials by methyl-substitution strategy is described. We present a chemical strategy for improving the phosphorescence lifetime of triplet excitons at ambient conditions...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Highly Efficient Gene Release in Spatiotemporal Precision Approached by
Light and pH Dual Responsive Copolymers
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC01494A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hung-Hsun Lu, Cheng-Hung Huang, Ting-Yun Shiue, Fu-Sheng Wang, Ko-Kai Chang, Yunching Chen, Chi-How Peng
Triblock copolymer of poly(ethylene glycol)-b-poly(2-dimethylaminoethyl methacrylate)-b-poly(pyrenylmethyl methacrylate) (PEG-b-PDMAEMA-b-PPy) has been developed for an ideal gene delivery system, which showed both the high stability in physiological condition and the efficient gene...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Photoelectrocatalytic H2 Evolution from Integrated Photocatalysts Adsorbed
on NiO
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02575D, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Nils Poldme, Laura O'Reilly, Ian Fletcher, Jose portoles, Igor V. Sazanovich, Michael Towrie, Conor Long, Han Vos, Mary Pryce, Elizabeth Gibson
A new approach to increasing the Faradaic efficiency of dye-sensitised photocathodes for H2 evolution from water, using integrated photocatalysts, furnished with ester groups on the peripheral ligands, [Ru(decb)2(bpt)PdCl(H2O)](PF6)2 (1) and...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Molecular Design of Near-Infrared Fluorescent Pdots for Tumor Targeting:
Aggregation-Induced Emission versus Anti-Aggregation-Caused Quenching
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03510E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Wei-Kai Tsai, Chun I Wang, Chia-Hsien Liao, Chun-Nien Yao, Tsai-Jhen Kuo, Ming-Ho Liu, Chao-Ping Hsu, Shu-Yi Lin, Chang-Yi Wu, Joseph R. Pyle, Jixin Chen, Yang-Hsiang Chan
Semiconducting polymer dots (Pdots) have recently emerged as a new type of ultrabright fluorescent probes that have been proved to be very useful for biomedical imaging. However, Pdots often suffer...
The content of this RSS Feed (c) The Royal Society of Chemistry
- A Chair-type G-quadruplex Structure Formed by a Human Telomeric Variant
DNA in K+ solution
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03813A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Changdong LIU, Bo Zhou, Yanyan Geng, Dick Yan Tam, Rui Feng, Haitao Miao, Naining Xu, Xiao Shi, Yingying You, Yuning Hong, Ben Zhong Tang, Pik Kwan Lo, Vitaly Kuryavyi, Guang Zhu
Guanine tracts of human telomeric DNA sequences are known to fold into eight different four-stranded structures that vary by the conformation of guanine nucleotides arranged in the stack of G-tetrads...
The content of this RSS Feed (c) The Royal Society of Chemistry
- A functional interplay between intein and extein sequence in protein
splicing compensates for the essential block B histidine
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC01074A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kristina Friedel, Monika Popp, Julian J. C. Matern, Emerich M. Gazdag, Ilka V. Thiel, Gerrit Volkmann, Wulf Blankenfeldt, Henning D. D. Mootz
Inteins remove themselves out of a precursor protein by protein splicing. Due to the concomitant structural changes of the host protein, this self-processing reaction has enabled many applications in protein...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Ir(III)-Catalyzed ortho C-H Alkylations of (Hetero)aromatic Aldehydes
Using Alkyl Boron Reagents
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03606C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xiao-Yang Chen, Erik J Sorensen
Transition-metal-catalyzed C-H alkylation reactions directed by aldehydes or ketones have been largely restricted to electronically activated alkenes. Herein, we report a general protocol for the Ir(III)-catalyzed ortho C-H alkylations of...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Photoactive chlorin e6 is a multifunctional modulator of amyloid-β
aggregation and toxicity via specific interactions with its histidine
residues
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC01992D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Guy Leshem, Michal Richman, Elvira Lisniansky, Merav Antman Passig, Maram Habashi, Astrid Graslund, Sebastian Wärmländer, Shai Rahimipour
The self-assembly of Aβ to β-sheet-rich neurotoxic oligomers is a main pathological event leading to Alzheimer’s disease (AD). Selective targeting of Aβ oligomers without affecting other functional proteins is therefore...
The content of this RSS Feed (c) The Royal Society of Chemistry
- A quantitative connection of experimental and simulated folding landscapes
by vibrational spectroscopy
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03786H, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Caitlin M. Davis, Laura Zanetti-Polzi, Martin Gruebele, A Amadei, Richard Brian Dyer, Isabella Daidone
For small molecule reaction kinetics, computed reaction coordinates often mimic experimentally measured observables quite accurately. Although nowadays simulated and measured biomolecule kinetics can be compared on the same time scale,...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Increasing the activity of copper exchanged mordenite in the direct
isothermal conversion of methane to methanol by Pt and Pd doping
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02795A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Patrick Tomkins, Ali Mansouri, Vitaly L. Sushkevich, Lars I. van der Wal, Selmi Erim Bozbag, Frank Krumeich, Marco Ranocchiari, Jeroen van Bokhoven
PtCu- and PdCu-mordenite allow for isothermal reaction at 200 °C for the stepped methane to methanol conversion with comparably high yields. In contrast to traditional Cu-zeolites, these materials are more...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Aromatic secondary amine-functionalized fluorescent NO probes: improved
detection sensitivity for NO and potential applications in cancer
immunotherapy studies
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03694B, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yingying Huo, Junfeng Miao, Junru Fang, HU SHI, Juanjuan Wang, Wei Guo
Tumor-associated macrophages (TAMs), constituting up to 50% of the solid tumor mass and commonly having a pro-tumoral M2 phenotype, are closely associated with a decreased survival in patients. Based on...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Photon-upconverting chiral liquid crystal: significantly amplified
upconverted circularly polarized luminescence
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03806F, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xuefeng Yang, Jianlei Han, Yafei Wang, Pengfei Duan
In this work, we demonstrate a room-temperature chiral liquid crystal which showing remarkable photon upconverted circularly polarized luminescence (UC-CPL). Circularly polarized luminescent materials with higher dissymmetry factor (glum) underpin the...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Transition-Metal Free C-C Bond Cleavage/Borylation of Cycloketone Oxime
Esters
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03315C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Li-Na Guo, Jin-Jiang Zhang, Xin-Hua Duan, Wu Yong, Jun-Cheng Yang
An efficient transition-metal free C-C bond cleavage/borylation of cycloketone oxime esters has been described. In this reaction, the B2(OH)4 reagent not only served as the boron source but also acted...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Metal-Free, Intermolecular Carbopyridylation of Alkenes via
Visible-Light-Induced Reductive Radical Coupling
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03493A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Dan Chen, Lei Xu, Tianyu Long, Shengqing Zhu, Jun Yang, Lingling Chu
An efficient, metal-free strategy for the intermolecular three-component carbopyridylation of styrenes, enabled by Hantzsch ester and visible light, has been described. This versatile protocol gives access to important β-CF3 pyridines,...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Dissolution and Performing Homogeneous Photocatalysis of Polymeric Carbon
Nitride
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03855D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Chaofeng Huang, Jing Wen, Yanfei Shen, Fei He, Li Mi, Ziyu Gan, Jin Ma, Songqin Liu, Haibo Ma, Yuanjian Zhang
As a metal-free conjugated polymer carbon nitride (CN) has attracted tremendous attention as heterogeneous (photo)catalysts. By following prototype of enzymes, making all catalytic sites of accessible via homogeneous reactions is...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Fast Detection and Structural Identification of Carbocations on Zeolites
by Dynamic Nuclear Polarization Enhanced Solid-State NMR
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03848A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.DONG XIAO, Shutao Xu, Nick J. Brownbill, Subhradip Paul, Lihua Chen, Shane Pawsey, Fabien Aussenac, Bao-Lian Su, Xiuwen Han, Xinhe Bao, Zhongmin Liu, Frédéric Blanc
Acidic zeolites are porous aluminosilicates used in a wide range of industrial processes such as adsorbents and catalysis. The formation of carbocation intermediates plays a key role in reactivity, selectivity...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Cu2+ Selective Chelators Relieve Copper-Induced Oxidative Stress In Vivo
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC04041A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.ANANYA RAKSHIT, Kaustav Khatua, Vinit Shanbhag, Peter Comba, Ankona Datta
Copper ions are essential for biological function yet are severely detrimental when present in excess. At the molecular level, copper ions catalyze the production of hydroxyl radicals that can irreversibly...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Photomechanochromic vs Mechanochromic Fluorescence of a Unichromophoric
Bimodal Molecular Solid: Multicolour Fluorescence Patterning
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03740J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Li-Yun Hsu, Subhendu Maity, Yuki Matsunaga, Ying-Feng Hsu, Yi-Hung Liu, Shie-Ming Peng, Teruo Shinmyozu, Jye-Shane Yang
Mechanofluorochromism (MFC) of molecular solids generally results from the variation of intermolecular interactions induced by external mechanical forces. However, the use of internal photomechanical forces to perturb intermolecular interactions for...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Al(OCArF3)3 – A Thermally Stable Lewis Superacid
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02981D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Julius F Kögel, Alexey Y Timoshkin, Artem Schröder, Enno Lork, Jens Beckmann
The adduct free Lewis superacid Al(OCArF3)3 was obtained by the reaction of ArF3COH with AlEt3 and fully characterized (ArF = C6F5). It comprises a high thermal stability up to 180...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Controllably Realizing Elastic/Plastic Bending based on a Room Temperature
Phosphorescent Waveguiding Organic Crystal
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03135E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hongyu Zhang, Hao Liu, Zhengyi Bian, Qinyu Cheng, Linfeng Lan, Yue Wang
The study of flexible (elastically bendable and plastically bendable) organic single crystals becomes a hot research field in the crystal engineering recently. In general, crystal elasticity and plasticity are incompatible...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Hetero-metallic Active Sites Coupled with Strong Reductive Polyoxometalate
for Selectively Photocatalytic CO2-to-CH4 Conversion in Water
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03471K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Zhong-Min Su, Shuai-Lei Xie, Jiang Liu, Long-Zhang Dong, Shun-Li Li, Ya-Qian Lan
Photocatalytic reduction of combustion product CO2 to value-added synthetic natural gas (≥ 95% CH4) for further utilization has been a promising strategy for energy sustainable development, but it is challenging...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Manganese(II) Phosphate Nanosheet Assembly with Native Out-of-Plane Mn
Centres for Electrocatalytic Water Oxidation
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03764G, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hongfei Liu, Xueqing Gao, Xiaolong Yao, Mingxing Chen, Guo-Jun Zhou, Jing Qi, Xueli Zhao, Weichao Wang, Wei Zhang, Rui Cao
Nature selects Mn-clusters as catalysts for water oxidation, which is a significant reaction in photosynthesis. Thus, it is of critical importance to develop Mn-based superstructures and study their catalytic details...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Mechanistic Investigation into the C(sp3)–H Acetoxylation of
Morpholinones
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03434F, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Matthew J Gaunt, Cornelia Buettner, Darren Willcox, Benjamin Chappell
he study of a selective palladium(II)-catalyzed C(sp3)–H acetoxylation reaction on a class of cyclic alkyl amine is reported. Computational modelling and kinetic studies were used to provide support for a...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Multiple Adaptation of Constitutional Dynamic Networks and Information
Storage in Constitutional Distributions of Acylhydrazones
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03858A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.MEN Guangwen, Jean-Marie Lehn
We report a study of the behavior of four dynamic covalent libraries (DCLs) based on acylhydrazones aAbB and of the corresponding square constitutional dynamic networks (CDNs) NA–ND under the effect...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Correction: Engineering microbial physiology with synthetic polymers:
cationic polymers induce biofilm formation in Vibrio cholerae and
downregulate the expression of virulence genes
Abstract: Chem. Sci., 2018, Advance Article
DOI : 10.1039/C8SC90189A, Correction Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Nicolas Perez-Soto, Lauren Moule, Daniel N. Crisan, Ignacio Insua, Leanne M. Taylor-Smith, Kerstin Voelz, Francisco Fernandez-Trillo, Anne Marie Krachler
To cite this article before page numbers are assigned, use the
DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
- Cs3VO(O2)2CO3: An exceptionally thermostable carbonatoperoxovanadate with
the extremley large second-harmonic generation response
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC03672A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Guohong Zou, Zhien Lin, Hongmei Zeng, Hongil Jo, Seong-Ji Lim, Tae-Soo You, Kang Min Ok
A novel nonlinear optical (NLO) carbonatoperoxovanadate, Cs3VO(O2)2CO3 with an exceptionally high thermostability was successfully synthesized by introducing highly polarizable Cs+ cation and inorganic polydentate carbonate anions into asymmetric peroxovanadates. The...
The content of this RSS Feed (c) The Royal Society of Chemistry
- Asking more from metabolic oligosaccharide engineering
Abstract: Chem. Sci., 2018, Accepted Manuscript
DOI : 10.1039/C8SC02241K, Perspective Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Pierre André Gilormini, Anna R Batt, Matthew Robert Pratt, Christophe Biot
Glycans form one of the four classes of biomolecules, are found in every living system and present a huge structural and functionnal diversity. As an illustration of this diversity, it...
The content of this RSS Feed (c) The Royal Society of Chemistry
