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  Subjects -> CHEMISTRY (Total: 846 journals)
    - ANALYTICAL CHEMISTRY (50 journals)
    - CHEMISTRY (597 journals)
    - CRYSTALLOGRAPHY (22 journals)
    - ELECTROCHEMISTRY (25 journals)
    - INORGANIC CHEMISTRY (41 journals)
    - ORGANIC CHEMISTRY (45 journals)
    - PHYSICAL CHEMISTRY (66 journals)

CHEMISTRY (597 journals)                  1 2 3 | Last

Showing 1 - 200 of 735 Journals sorted alphabetically
2D Materials     Hybrid Journal   (Followers: 7)
Accreditation and Quality Assurance: Journal for Quality, Comparability and Reliability in Chemical Measurement     Hybrid Journal   (Followers: 26)
ACS Catalysis     Full-text available via subscription   (Followers: 31)
ACS Chemical Neuroscience     Full-text available via subscription   (Followers: 17)
ACS Combinatorial Science     Full-text available via subscription   (Followers: 23)
ACS Macro Letters     Full-text available via subscription   (Followers: 22)
ACS Medicinal Chemistry Letters     Full-text available via subscription   (Followers: 39)
ACS Nano     Full-text available via subscription   (Followers: 218)
ACS Photonics     Full-text available via subscription   (Followers: 10)
ACS Synthetic Biology     Full-text available via subscription   (Followers: 20)
Acta Chemica Iasi     Open Access   (Followers: 2)
Acta Chimica Sinica     Full-text available via subscription  
Acta Chimica Slovaca     Open Access   (Followers: 1)
Acta Chromatographica     Full-text available via subscription   (Followers: 9)
Acta Facultatis Medicae Naissensis     Open Access  
Acta Metallurgica Sinica (English Letters)     Hybrid Journal   (Followers: 5)
Acta Scientifica Naturalis     Open Access   (Followers: 2)
adhäsion KLEBEN & DICHTEN     Hybrid Journal   (Followers: 5)
Adhesion Adhesives & Sealants     Hybrid Journal   (Followers: 7)
Adsorption Science & Technology     Full-text available via subscription   (Followers: 5)
Advanced Functional Materials     Hybrid Journal   (Followers: 48)
Advanced Science Focus     Free   (Followers: 3)
Advances in Chemical Engineering and Science     Open Access   (Followers: 53)
Advances in Chemical Science     Open Access   (Followers: 12)
Advances in Chemistry     Open Access   (Followers: 12)
Advances in Colloid and Interface Science     Full-text available via subscription   (Followers: 18)
Advances in Drug Research     Full-text available via subscription   (Followers: 22)
Advances in Enzyme Research     Open Access   (Followers: 10)
Advances in Fluorine Science     Full-text available via subscription   (Followers: 8)
Advances in Fuel Cells     Full-text available via subscription   (Followers: 14)
Advances in Heterocyclic Chemistry     Full-text available via subscription   (Followers: 8)
Advances in Materials Physics and Chemistry     Open Access   (Followers: 18)
Advances in Nanoparticles     Open Access   (Followers: 12)
Advances in Organometallic Chemistry     Full-text available via subscription   (Followers: 15)
Advances in Polymer Science     Hybrid Journal   (Followers: 40)
Advances in Protein Chemistry     Full-text available via subscription   (Followers: 18)
Advances in Protein Chemistry and Structural Biology     Full-text available via subscription   (Followers: 18)
Advances in Quantum Chemistry     Full-text available via subscription   (Followers: 5)
Advances in Science and Technology     Full-text available via subscription   (Followers: 10)
African Journal of Bacteriology Research     Open Access  
African Journal of Chemical Education     Open Access   (Followers: 2)
African Journal of Pure and Applied Chemistry     Open Access   (Followers: 7)
Agrokémia és Talajtan     Full-text available via subscription   (Followers: 2)
Alkaloids: Chemical and Biological Perspectives     Full-text available via subscription   (Followers: 3)
AMB Express     Open Access   (Followers: 1)
Ambix     Hybrid Journal   (Followers: 3)
American Journal of Biochemistry and Biotechnology     Open Access   (Followers: 65)
American Journal of Biochemistry and Molecular Biology     Open Access   (Followers: 14)
American Journal of Chemistry     Open Access   (Followers: 25)
American Journal of Plant Physiology     Open Access   (Followers: 13)
American Mineralogist     Full-text available via subscription   (Followers: 12)
Analyst     Full-text available via subscription   (Followers: 38)
Angewandte Chemie     Hybrid Journal   (Followers: 153)
Angewandte Chemie International Edition     Hybrid Journal   (Followers: 204)
Annales UMCS, Chemia     Open Access   (Followers: 1)
Annals of Clinical Chemistry and Laboratory Medicine     Open Access   (Followers: 1)
Annual Reports in Computational Chemistry     Full-text available via subscription   (Followers: 3)
Annual Reports Section A (Inorganic Chemistry)     Full-text available via subscription   (Followers: 3)
Annual Reports Section B (Organic Chemistry)     Full-text available via subscription   (Followers: 7)
Annual Review of Chemical and Biomolecular Engineering     Full-text available via subscription   (Followers: 12)
Annual Review of Food Science and Technology     Full-text available via subscription   (Followers: 14)
Anti-Infective Agents     Hybrid Journal   (Followers: 3)
Antiviral Chemistry and Chemotherapy     Hybrid Journal  
Applied Organometallic Chemistry     Hybrid Journal   (Followers: 6)
Applied Spectroscopy     Full-text available via subscription   (Followers: 22)
Applied Surface Science     Hybrid Journal   (Followers: 26)
Arabian Journal of Chemistry     Open Access   (Followers: 6)
ARKIVOC     Open Access   (Followers: 2)
Asian Journal of Biochemistry     Open Access   (Followers: 1)
Atomization and Sprays     Full-text available via subscription   (Followers: 3)
Australian Journal of Chemistry     Hybrid Journal   (Followers: 7)
Autophagy     Hybrid Journal   (Followers: 2)
Avances en Quimica     Open Access   (Followers: 1)
Biochemical Pharmacology     Hybrid Journal   (Followers: 9)
Biochemistry     Full-text available via subscription   (Followers: 278)
Biochemistry Insights     Open Access   (Followers: 5)
Biochemistry Research International     Open Access   (Followers: 6)
BioChip Journal     Hybrid Journal  
Bioinorganic Chemistry and Applications     Open Access   (Followers: 9)
Bioinspired Materials     Open Access   (Followers: 3)
Biointerface Research in Applied Chemistry     Open Access   (Followers: 2)
Biointerphases     Open Access   (Followers: 1)
Biology, Medicine, & Natural Product Chemistry     Open Access  
Biomacromolecules     Full-text available via subscription   (Followers: 18)
Biomass Conversion and Biorefinery     Partially Free   (Followers: 10)
Biomedical Chromatography     Hybrid Journal   (Followers: 6)
Biomolecular NMR Assignments     Hybrid Journal   (Followers: 3)
BioNanoScience     Partially Free   (Followers: 4)
Bioorganic & Medicinal Chemistry     Hybrid Journal   (Followers: 109)
Bioorganic & Medicinal Chemistry Letters     Hybrid Journal   (Followers: 99)
Bioorganic Chemistry     Hybrid Journal   (Followers: 10)
Biopolymers     Hybrid Journal   (Followers: 18)
Biosensors     Open Access   (Followers: 2)
Biotechnic and Histochemistry     Hybrid Journal   (Followers: 1)
Bitácora Digital     Open Access  
Boletin de la Sociedad Chilena de Quimica     Open Access  
Bulletin of the Chemical Society of Ethiopia     Open Access   (Followers: 2)
Bulletin of the Chemical Society of Japan     Full-text available via subscription   (Followers: 24)
Bulletin of the Korean Chemical Society     Hybrid Journal   (Followers: 1)
C - Journal of Carbon Research     Open Access   (Followers: 2)
Canadian Association of Radiologists Journal     Full-text available via subscription   (Followers: 2)
Canadian Journal of Chemistry     Full-text available via subscription   (Followers: 10)
Canadian Mineralogist     Full-text available via subscription   (Followers: 3)
Carbohydrate Research     Hybrid Journal   (Followers: 26)
Carbon     Hybrid Journal   (Followers: 67)
Catalysis for Sustainable Energy     Open Access   (Followers: 6)
Catalysis Reviews: Science and Engineering     Hybrid Journal   (Followers: 8)
Catalysis Science and Technology     Free   (Followers: 6)
Catalysis Surveys from Asia     Hybrid Journal   (Followers: 3)
Catalysts     Open Access   (Followers: 7)
Cellulose     Hybrid Journal   (Followers: 7)
Cereal Chemistry     Full-text available via subscription   (Followers: 4)
ChemBioEng Reviews     Full-text available via subscription   (Followers: 1)
ChemCatChem     Hybrid Journal   (Followers: 8)
Chemical and Engineering News     Free   (Followers: 12)
Chemical Bulletin of Kazakh National University     Open Access  
Chemical Communications     Full-text available via subscription   (Followers: 69)
Chemical Engineering Research and Design     Hybrid Journal   (Followers: 23)
Chemical Research in Chinese Universities     Hybrid Journal   (Followers: 3)
Chemical Research in Toxicology     Full-text available via subscription   (Followers: 19)
Chemical Reviews     Full-text available via subscription   (Followers: 165)
Chemical Science     Open Access   (Followers: 21)
Chemical Technology     Open Access   (Followers: 15)
Chemical Vapor Deposition     Hybrid Journal   (Followers: 4)
Chemical Week     Full-text available via subscription   (Followers: 7)
Chemie in Unserer Zeit     Hybrid Journal   (Followers: 55)
Chemie-Ingenieur-Technik (Cit)     Hybrid Journal   (Followers: 25)
ChemInform     Hybrid Journal   (Followers: 7)
Chemistry & Biodiversity     Hybrid Journal   (Followers: 6)
Chemistry & Biology     Full-text available via subscription   (Followers: 30)
Chemistry & Industry     Hybrid Journal   (Followers: 5)
Chemistry - A European Journal     Hybrid Journal   (Followers: 137)
Chemistry - An Asian Journal     Hybrid Journal   (Followers: 15)
Chemistry and Materials Research     Open Access   (Followers: 17)
Chemistry Central Journal     Open Access   (Followers: 4)
Chemistry Education Research and Practice     Free   (Followers: 5)
Chemistry in Education     Open Access   (Followers: 9)
Chemistry International     Hybrid Journal   (Followers: 2)
Chemistry Letters     Full-text available via subscription   (Followers: 43)
Chemistry of Materials     Full-text available via subscription   (Followers: 189)
Chemistry of Natural Compounds     Hybrid Journal   (Followers: 9)
Chemistry-Didactics-Ecology-Metrology     Open Access  
ChemistryOpen     Open Access   (Followers: 2)
Chemkon - Chemie Konkret, Forum Fuer Unterricht Und Didaktik     Hybrid Journal  
Chemoecology     Hybrid Journal   (Followers: 2)
Chemometrics and Intelligent Laboratory Systems     Hybrid Journal   (Followers: 15)
Chemosensors     Open Access  
ChemPhysChem     Hybrid Journal   (Followers: 8)
ChemPlusChem     Hybrid Journal   (Followers: 2)
ChemTexts     Hybrid Journal  
CHIMIA International Journal for Chemistry     Full-text available via subscription   (Followers: 2)
Chinese Journal of Chemistry     Hybrid Journal   (Followers: 6)
Chinese Journal of Polymer Science     Hybrid Journal   (Followers: 10)
Chromatographia     Hybrid Journal   (Followers: 23)
Chromatography Research International     Open Access   (Followers: 7)
Clay Minerals     Full-text available via subscription   (Followers: 9)
Cogent Chemistry     Open Access  
Colloid and Interface Science Communications     Open Access  
Colloid and Polymer Science     Hybrid Journal   (Followers: 10)
Colloids and Surfaces B: Biointerfaces     Hybrid Journal   (Followers: 8)
Combinatorial Chemistry & High Throughput Screening     Hybrid Journal   (Followers: 3)
Combustion Science and Technology     Hybrid Journal   (Followers: 18)
Comments on Inorganic Chemistry: A Journal of Critical Discussion of the Current Literature     Hybrid Journal   (Followers: 2)
Composite Interfaces     Hybrid Journal   (Followers: 6)
Comprehensive Chemical Kinetics     Full-text available via subscription   (Followers: 2)
Comptes Rendus Chimie     Full-text available via subscription  
Comptes Rendus Physique     Full-text available via subscription   (Followers: 1)
Computational and Theoretical Chemistry     Hybrid Journal   (Followers: 9)
Computational Biology and Chemistry     Hybrid Journal   (Followers: 12)
Computational Chemistry     Open Access   (Followers: 2)
Computers & Chemical Engineering     Hybrid Journal   (Followers: 9)
Coordination Chemistry Reviews     Full-text available via subscription   (Followers: 2)
Copernican Letters     Open Access  
Critical Reviews in Biochemistry and Molecular Biology     Hybrid Journal   (Followers: 5)
Crystal Structure Theory and Applications     Open Access   (Followers: 3)
CrystEngComm     Full-text available via subscription   (Followers: 10)
Current Catalysis     Hybrid Journal   (Followers: 2)
Current Metabolomics     Hybrid Journal   (Followers: 4)
Current Opinion in Colloid & Interface Science     Hybrid Journal   (Followers: 9)
Current Research in Chemistry     Open Access   (Followers: 8)
Current Science     Open Access   (Followers: 48)
Dalton Transactions     Full-text available via subscription   (Followers: 18)
Detection     Open Access   (Followers: 2)
Developments in Geochemistry     Full-text available via subscription   (Followers: 2)
Diamond and Related Materials     Hybrid Journal   (Followers: 11)
Dislocations in Solids     Full-text available via subscription  
Doklady Chemistry     Hybrid Journal  
Drying Technology: An International Journal     Hybrid Journal   (Followers: 3)
Eclética Química     Open Access   (Followers: 1)
Ecological Chemistry and Engineering S     Open Access   (Followers: 4)
Ecotoxicology and Environmental Contamination     Open Access  
Educación Química     Open Access   (Followers: 1)
Education for Chemical Engineers     Hybrid Journal   (Followers: 5)
EJNMMI Radiopharmacy and Chemistry     Open Access  
Elements     Full-text available via subscription   (Followers: 2)
Environmental Chemistry     Hybrid Journal   (Followers: 8)
Environmental Chemistry Letters     Hybrid Journal   (Followers: 4)
Environmental Science & Technology Letters     Full-text available via subscription   (Followers: 5)
Environmental Science : Nano     Partially Free   (Followers: 1)
Environmental Toxicology & Chemistry     Hybrid Journal   (Followers: 19)

        1 2 3 | Last

Journal Cover Chemical Science
  [SJR: 4.974]   [H-I: 79]   [21 followers]  Follow
    
  This is an Open Access Journal Open Access journal
   ISSN (Print) 1478-6524 - ISSN (Online) 2041-6520
   Published by RSC Homepage  [42 journals]
  • Targeted antigen delivery by an anti-Class II MHC VHH elicits focused
           [small alpha]MUC1(Tn) immunity

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00446J, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Tao Fang, Catharina H.M.J. Van Elssen, Joao N. Duarte, Jonathan S. Guzman, Jasdave S. Chahal, Jingjing Ling, Hidde Ploegh
      Unusual patterns of glycosylation on the surface of transformed cells contribute to immune modulation and metastasis of malignant tumors. Active immunization against them requires effective antigen presentation, which is complicated...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Optically Transparent Dense Colloidal Gels

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00901A, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Mykolas Zupkauskas, Yang Lan, Darshana Joshi, Zachary Ruff, Erika Eiser
      Traditionally it has been difficult to study the porous structure of dense colloidal gels and (macro) molecular transport through them simply because of the difference in refractive index between the...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Divergent [{ONNN}Mg-Cl] complexes in the highly active and living lactide
           polymerization

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01514C, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Tomer Rosen, I Goldberg, Wanda Navarra, Vincenzo Venditto, Moshe Kol
      Chloro-magnesium complexes of divergent tetradentate-monoanionic {ONNN}-type ligands which formed as either mononuclear or dinuclear complexes are introduced. These complexes catalyze the ring-opening polymerization of lactide with high activity and living...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Rapid Reversible Borane to Boryl Hydride Exchange by Metal Shuttling on
           the Carborane Cluster Surface

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01846K, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Bennett J Eleazer, Mark D. Smith, Alexey A Popov, Dmitry V. Peryshkov
      In this work, we introduce a novel concept of a borane group vicinal to a metal boryl bond acting as a supporting hemilabile ligand in exohedrally metalated three-dimensional carborane clusters....
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • A Flow Cytometry Assay to Quantify Intercellular Exchange of Membrane
           Components

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00260B, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Dimitrios Poulcharidis, Kimberley Belfor, Alexander Kros, Sander van Kasteren
      Membrane-compound exchange is a vital process for cell-to-cell communication, yet quantification of this process is difficult. Here we present a method using flow cytometry in combination with bioorthogonal and fluorescent...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Kinase-templated abiotic reaction

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01416C, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Jacques Saarbach, Eric Lindberg, Sarah Folliet, Sandrine Georgeon, Oliver Hantschel, Nicolas Winssinger
      Protein kinases are quintessential regulators of cellular function. Numerous pathologies are intimately linked to the dysregulated activity of a particular protein kinase. Herein we report a technology based on a...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Ground-State Dioxygen Undergoes Metal-Free [3+2]-Annulations with Allenes
           and Nitrosoarenes Under Ambient Conditions

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01770G, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Rai-Shung Liu, Jinxian Liu, Manisha Skaria, Pankaj Sharma, Yun-Wei Chiang
      The cycloadditions of molecular dioxygen with neutral [small pi]-bond motifs rely heavily on its singlet-state 1O2 whereas its ground state 3O2 is chemically inactive. We here report novel [3+2]-annulations among ground-state...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Cyclohexa-1,4-dienes in transition-metal-free ionic transfer processes

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01657C, Minireview Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Sebastian Keess, Martin Oestreich
      Safe- and convenient-to-handle surrogates of hazardous chemicals are always in demand. Recently introduced cyclohexa-1,4-dienes with adequate substitution fulfill this role as El+/H- equivalents in B(C6F5)3-catalysed transfer reactions of El-H to...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Imaging Drug Uptake by Bioorthogonal Stimulated Raman Scattering
           Microscopy

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01837A, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. William J Tipping, Martin Lee, Alan Serrels, Valerie G Brunton, Alison N Hulme
      Stimulated Raman scattering (SRS) microscopy in tandem with bioorthogonal Raman labelling strategies is set to revolutionise the direct visualisation of intracellular drug uptake. Rational evaluation of a series of Raman-active...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Tailored theranostic apolipoprotein E3 porphyrin-lipid nanoparticles
           target glioblastoma tumours

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00732A, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Maneesha Rajora, Lili Ding, Michael Valic, Wenlei Jiang, Marta Overchuk, Juan Chen, Gang Zheng
      The development of curative glioblastoma treatments and tumour-specific contrast agents that can overcome the blood-brain barrier (BBB) and infiltrative tumour morphology remains a challenge. Apolipoprotein E3 (apoE3) is a high...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Identifying the First Folded Alkylbenzene via Ultraviolet, Infrared, and
           Raman Spectroscopy of Pentylbenzene through Decylbenzene

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC02027A, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Daniel M. Hewett, Sebastian Bocklitz, Daniel P. Tabor, Edwin L. Sibert, Martin Suhm, Timothy Zwier
      The conformational preferences of pentyl- through decylbenzene are studied under jet-cooled conditions in the gas phase. Laser-induced fluorescence excitation spectra, fluorescence-dip infrared spectra in the alkyl CH stretch region, and...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Single Crystal Structures and Theoretical Calculations of Uranium
           Endohedral Metallofullerenes (U@C2n, 2n=74, 82) Show Cage Isomer Dependent
           Oxidation States for U

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01711A, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Wenting Cai, Roser Morales-Martinez, Xingxing Zhang, Daniel Najera, Elkin Romero, Alejandro Jose Metta Magana, Antonio Rodriguez-Fortea, Skye Fortier, Ning Chen, Josep M Poblet, Luis Echegoyen
      Charge transfer is a general phenomenon observed for all endohedral mono-metallofullerenes. Since the detection of the first endohedral metallofullerene (EMF), La@C 82 , in 1991, it has always been observed that the...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Manipulating energy transfer in lanthanide-doped single nanoparticles for
           highly enhanced upconverting luminescence

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC01393K, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Zhu Zhuo, Yongsheng Liu, Dajiu Liu, Ping Huang, Feilong Jiang, Xueyuan Chen, Maochun Hong
      We demonstrate a multilayer-structured design strategy to manipulate the deleterious CR-ETs in lanthanide-doped UCNPs for highly enhanced upconverting luminescence.
      To cite this article before page numbers are assigned, use the
      DOI form of citation above.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • [MIII2MII3]n+ trigonal bipyramidal cages based on diamagnetic and
           paramagnetic metalloligands.

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00487G, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Euan K. Brechin, Sergio Sanz, Helen O'Connor, Vicente Marti-Centelles, Priyanka Comar, Mateusz Pitak, Simon Coles, Giulia Lorusso, Elias Palacios, Marco Evangelisti, Amgalanbaatar Baldansuren, Nicholas F Chilton, Hogni Weihe, Eric J L McInnes, Paul Lusby, Stergios Piligkos
      A family of five [MIII2MII3]n+ trigonal bipyramidal cages (MIII = Fe, Cr and Al; MII = Co, Zn and Pd; n = 0 for 1-3 and n = 6 for...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Near UV-Visible Electronic Absorption Originating from Charged Amino Acids
           in a Monomeric Protein

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00880E, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Saumya Prasad, Imon Mandal, Shubham Singh, Ashim Paul, Bhubaneswar Mandal, Ravindra Venkatramani, Rajaram Swaminathan
      Electronic absorption spectra of proteins are primarily characterized over the ultraviolet region (185-320 nm) of the electromagnetic spectrum. While recent studies on peptide aggregates have revealed absorption beyond 350 nm,...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Structural and Electrostatic Effects at the Surfaces of Size- and
           Charge-Selected Aqueous Nanodrops

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00481H, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Richard J Cooper, Jeremy T. O'Brien, Terrence M Chang, Evan R Williams
      The effects of ion charge, polarity and size on the surface morphology of size-selected aqueous nanodrops containing a single ion and up to 550 water molecules are investigated with infrared...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Visualizing the bidirectional electron transfer in a Schottky junction
           consisting of single CdS nanoparticles and a planar gold film

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC00990A, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Zhimin Li, Yimin Fang, Yongjie Wang, Yingyan Jiang, Tao Liu, Wei Wang
      The surface plasmon polaritons induced the injection of a hot electron into the CdS nanoparticles at a Schottky junction.
      To cite this article before page numbers are assigned, use the
      DOI form of citation above.
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Single copy-sensitive electrochemical assay for circulating methylated DNA
           in clinical samples with ultrahigh specificity based on a sequential
           discrimination-amplification strategy

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01035D, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Xuyao Wang, Feng Chen, Dexin Zhang, Yue Zhao, Jing Wei, Lihua Wang, Shiping Song, Chunhai Fan, Yongxi Zhao
      Tumor-related circulating methylated DNA represents only a small fraction of the total DNA in clinical samples (e.g. plasma), challenging the accurate analysis of specific DNA methylation patterns. Yet conventional assays...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Two-Photon AIE Bio-probe with Large Stokes Shift for Specific Imaging of
           Lipid Droplets

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01400G, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Meijuan Jiang, Xinggui Gu, Jacky Wing Yip Lam, Yilin Zhang, Ryan T. K. Kwok, Kam Sing Wong, Ben Zhong Tang
      Lipid droplets are dynamic organelles involved in various physiological processes and their detection is thus of high importance to biomedical research. Recent reports show that AIE probes for lipid droplet...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Nanoscale metal-organic frameworks coated with poly(vinyl alcohol) for
           ratiometric peroxynitrite sensing through FRET

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01077J, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Zhaoyang Ding, Jingyun Tan, Gang Feng, Zhen Yuan, Changfeng Wu, Xuanjun Zhang
      This work describes a facile yet powerful approach to energy-transfer NMOF(Nanoscale metal-organic framework) for ratiometric peroxynitrite (ONOO-) sensing. Poly(vinyl alcohol)(PVA) is chosen to organize energy donor (NMOF) and acceptor (molecular...
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  • Discrimination of supramolecular chirality using a protein nanopore

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC01940H, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. James A. Cooper, Stefan Borsley, Paul J. Lusby, Scott L. Cockroft
      Transmembrane protein nanopores are shown to be capable of discriminating the supramolecular chirality of cage complexes at the single-molecule level.
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  • Quantified electrostatic preorganization in enzymes using the geometry of
           the electron charge density

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC01301A, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Amanda Morgenstern, Matthew Jaszai, Mark E. Eberhart, Anastassia N. Alexandrova
      The exact positions of critical points in the charge density in enzyme active sites reflects electrostatic preorganization.
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  • Desulfination by 2'-hydroxybiphenyl-2-sulfinate desulfinase proceeds via
           electrophilic aromatic substitution by the Cysteine-27 proton

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00496F, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Inacrist Geronimo, Shawn Nigam, Christina Payne
      Biodesulfurization is an attractive option for enzymatically removing sulfur from the recalcitrant thiophenic derivatives that comprise the majority of organosulfur compounds remaining in hydrotreated petroleum products. Desulfurization in the bacteria...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Chiral phosphine-mediated intramolecular [3+2] annulation: enhanced
           enantioselectivity by achiral Bronsted acid

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00952F, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Weijun Yao, Zhaoyuan Yu, Shan Wen, Huanzhen Ni, Nisar Ullah, Yu Lan, Yixin Lu
      Enantioselective intramolecular [3+2] annulation of chalcones bearing an allene moiety has been successfully developed. The reaction was effectively promoted by amino acid-derived phosphines, in combination with achiral Bronsted acids. Dihydrocoumarin...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Predicting Electronic Structure Properties of Transition Metal Complexes
           with Neural Networks

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01247K, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Jon Paul Janet, Heather Kulik
      High-throughput computational screening has emerged as a critical component of materials discovery. Direct density functional theory (DFT) simulation of inorganic materials and molecular transition metal complexes is often used to...
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  • Comparison of structural dynamics and coherence of d-d and MLCT
           light-induced spin state trapping

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C6SC05624E, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. S. Zerdane, L. Wilbraham, M. Cammarata, O. Iasco, E. Riviere, M.-L. Boillot, I. Ciofini, E. Collet
      Femtosecond optical spectroscopy revealed that the coherent structural dynamics accompanying LIESST was stronger with d-d than MLCT excitation.
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  • Engineering Microbial Physiology with Synthetic Polymers: Cationic
           Polymers Induce Biofilm Formation in Vibrio cholerae and Downregulate the
           Expression of Virulence Genes.

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00615B, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Nicolas Perez-Soto, Lauren Moule, Daniel Crisan, Ignacio Insua, Leanne Taylor-Smith, Kerstin Voelz, Anne Marie Krachler, Francisco Fernandez-Trillo
      Here we report the first application of non-bactericidal synthetic polymers to modulate the physiology of a bacterial pathogen. Poly(N-[3-(dimethylamino)propyl] methacrylamide) (P1) and poly(N-(3-aminopropyl)methacrylamide) (P2), cationic polymers that bind to the...
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  • Criegee Intermediate-Hydrogen Sulfide Chemistry at the Air/Water Interface

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01797A, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Manoj Kumar, Jie Zhong, Joseph S Francisco, Xiao Cheng Zeng
      We carry out Born-Oppenheimer molecular dynamic simulations to show that the reaction between the smallest Criegee intermediate, CH2OO, and hydrogen sulfide (H2S) at the air/water interface can be observed within...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Introducing Unactivated Acyclic Internal Aliphatic Olefins in Cobalt
           Catalyzed Allylic Selective Dehydrogenative Heck Reaction

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01204G, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Debabrata Maiti, Soham Maity, Pravas Dolui, Rajesh Kancherla
      Unactivated acyclic internal aliphatic olefins are often found unreactive in conventional alkenylation reactions. Addressing this problem, a cobalt catalyzed allylic selective dehydrogenative Heck reaction with internal aliphatic olefins has been...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Inhibition of the Ras/Raf Interaction and Repression of Renal Cancer
           Xenografts In Vivo by an Enantiomeric Iridium(III) Metal-Based Compound

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00311K, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Li-Juan Liu, Wanhe Wang, Shi-ying Huang, Yanjun Hong, Guodong Li, Sheng Lin, Jinglin Tian, Zongwei Cai, Hui-Min David Wang, Dik-Lung Ma, Chung-Hang Leung
      Targeting protein-protein interactions (PPIs) offers tantalizing opportunities for therapeutic intervention for the treatment of human diseases. Modulating PPI interfaces with organic small molecules has been found to be exceptionally challenging,...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Determination of the absolute configuration of compounds bearing chiral
           quaternary carbon centers using the crystalline sponge method

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01524K, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Shiho Sairenji, Takashi Kikuchi, Mohamed A Abozeid, Shinobu Takizawa, Hiroaki Sasai, Yuichiro Ando, Kohsuke Ohmatsu, Takashi Ooi, Makoto Fujita
      Determination of the absolute configuration of chiral tetra-substituted carbon centers is one of the most taxing steps in the enantioselective construction of this structural motif in asymmetric synthesis. Here, we...
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  • Enantioselective Palladium-Catalyzed Diboration of 1,1-Disubstituted
           Allenes

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01254C, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Wenjun Tang, Jiawang Liu, Ming Nie, Qing-Hai Zhou, Shen Gao, Wenhao Jiang, Lung Wa Chung, Kuiling Ding
      A practical and enantioselective palladium-catalyzed diboration of 1,1-disubstituted allenes is developed by employing a P-chiral monophosphorus ligand BI-DIME to form a series of diboronic esters containing a chiral tertiary boronic...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • The Lubricating Role of Water in the Shuttling of Rotaxanes

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01593C, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Haohao Fu, Xueguang Shao, Christophe Jean Chipot, Wensheng Cai
      We have investigated at the atomic level amide-based rotaxanes set in motion in four different solvents, namely, ethyl ether, acetonitrile, ethanol and water. In three non-aqueous solvents, shuttling of the...
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  • Remarkable Effect of Alkalis on Chemoselective Hydrogenation of
           Functionalized Nitroarenes over High-Loading Pt/FeOx Catalysts

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00568G, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Haisheng Wei, Yujing Ren, Ai-Qin Wang, Xiaoyan Liu, Xin Liu, Leilei Zhang, Shu Miao, Lin Li, Jingyue Liu, Junhu Wang, Guofu Wang, Dangsheng Su, Tao Zhang
      The chemoselective hydrogenation of substituted nitroarenes to the corresponding functionalized anilines is a type of important reactions in fine chemistry, and the chemoselectivity is critically dependent on the rational design...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Artificial Light-Harvesting n-type Porphyrin for Panchromatic Organic
           Photovoltaic Devices

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01275F, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Wisnu Tantyo Hadmojo, Dajeong Yim, Havid Aqoma, Du Yeol Ryu, Tae Joo Shin, Eojin Hwang, Woo-Dong Jang, In Hwan Jung, Sung-Yeon Jang
      A near-infrared-harvesting n-type porphyrin-based acceptor for organic photovoltaics (OPV) is developed. The n-type acceptor, PDI-PZn-PDI, is designed by connecting a zinc porphyrin (PZn) core to two perylenediimide (PDI) wings through...
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  • Direct Local Solvent Probing by Transient Infrared Spectroscopy Reveals
           the Mechanism of Hydrogen-Bond Induced Nonradiative Deactivation

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00437K, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Bogdan Dereka, Eric Vauthey
      The fluorescence quenching of organic dyes via H-bonding interactions is a well-known phenomenon. However, the mechanism of this Hydrogen-Bond Induced Nonradiative Deactivation (HBIND) is not understood. Insight into this process...
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  • Correction: Simultaneous engineering of an enzyme's entrance tunnel and
           active site: the case of monoamine oxidase MAO-N

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC90029E, Correction Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Guangyue Li, Peiyuan Yao, Rui Gong, Jinlong Li, Pi Liu, Richard Lonsdale, Qiaqing Wu, Jianping Lin, Dunming Zhu, Manfred T. Reetz
      To cite this article before page numbers are assigned, use the
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      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • "On demand" redox buffering by H2S contributes to antibiotic resistance
           revealed by a bacteria-specific H2S donor

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC00873B, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Prashant Shukla, Vinayak S. Khodade, Mallojjala SharathChandra, Preeti Chauhan, Saurabh Mishra, Shivakumara Siddaramappa, Bulagonda Eswarappa Pradeep, Amit Singh, Harinath Chakrapani
      Enhancement of hydrogen sulfide in bacteria reveals a key role for this gas in mediating antibiotic resistance.
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  • Powder diffraction and crystal structure prediction identify four new
           coumarin polymorphs

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC00168A, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Alexander G. Shtukenberg, Qiang Zhu, Damien J. Carter, Leslie Vogt, Johannes Hoja, Elia Schneider, Hongxing Song, Boaz Pokroy, Iryna Polishchuk, Alexandre Tkatchenko, Artem R. Oganov, Andrew L. Rohl, Mark E. Tuckerman, Bart Kahr
      Crystal structures of four new coumarin polymorphs were solved by crystal structure prediction method and their lattice and free energies were calculated by advanced techniques.
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  • The photophysics of naphthalene dimers controlled by sulfur bridge
           oxidation

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC01285C, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Claudia Climent, Mario Barbatti, Michael O. Wolf, Christopher J. Bardeen, David Casanova
      Oxidation state of bridge controls the deactivation mechanism of naphthalene dimers.
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  • Orange, red, yellow: biosynthesis of azaphilone pigments in Monascus fungi

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC00475C, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Wanping Chen, Runfa Chen, Qingpei Liu, Yi He, Kun He, Xiaoli Ding, Lijing Kang, Xiaoxiao Guo, Nana Xie, Youxiang Zhou, Yuanyuan Lu, Russell J. Cox, Istvan Molnar, Mu Li, Yanchun Shao, Fusheng Chen
      Each major step leading to the classical yellow, orange and red constituents of Monascus azaphilone pigments was defined.
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  • Tumor microenvironment-triggered fabrication of gold nanomachines for
           tumor-specific photoacoustic imaging and photothermal therapy

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC00700K, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Zhengze Yu, Meimei Wang, Wei Pan, Hongyu Wang, Na Li, Bo Tang
      An alpha-cyclodextrin ([small alpha]-CD)-based gold/DNA nanomachine was developed as a novel theranostic agent for tumor-selective diagnosis and therapy.
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      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Target-triggered cascade assembly of a catalytic network as an artificial
           enzyme for highly efficient sensing

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC01453H, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Lei Zhang, Fengjiao Ma, Jianping Lei, Jintong Liu, Huangxian Ju
      A hemin-based enzymatic network is constructed with high catalytic activity that is comparable to natural horseradish peroxidase via triple signal amplification.
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  • A universal fluorogenic switch for Fe(II) ion based on N-oxide chemistry
           permits the visualization of intracellular redox equilibrium shift towards
           labile iron in hypoxic tumor cells

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C6SC05457A, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Tasuku Hirayama, Hitomi Tsuboi, Masato Niwa, Ayaji Miki, Satoki Kadota, Yukie Ikeshita, Kensuke Okuda, Hideko Nagasawa
      Oxygen-dependent fluctuation of labile Fe( II ) was visualized by a new N-oxide-based fluorescent probe for Fe( II ) ion.
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      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Palladium-catalyzed difluoromethylation of heteroaryl chlorides, bromides
           and iodides

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC00691H, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Changhui Lu, Yang Gu, Jiang Wu, Yucheng Gu, Qilong Shen
      A palladium-catalyzed difluoromethylation of a series of heteroaryl chlorides, bromides and iodides under mild conditions is described.
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  • Metal-free direct alkylation of unfunctionalized allylic/benzylic sp3 C-H
           bonds via photoredox induced radical cation deprotonation

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC00953D, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Rong Zhou, Haiwang Liu, Hairong Tao, Xingjian Yu, Jie Wu
      An unprecendented direct alkylation of unfunctionalized allylic/benzylic sp 3 C-H bonds via photoredox induced radical cation deprotonation is disclosed.
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  • Single particle tracking-based reaction progress kinetic analysis reveals
           a series of molecular mechanisms of cetuximab-induced EGFR processes in a
           single living cell

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC01159H, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Do-Hyeon Kim, Dong-Kyun Kim, Kai Zhou, Soyeon Park, Yonghoon Kwon, Min Gyu Jeong, Nam Ki Lee, Sung Ho Ryu
      Reaction progress kinetic analysis utilizing single molecule trajectories revealed the comprehensive molecular mechanisms of cetuximab induced EGFR endocytosis.
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      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Expanding the biomass derived chemical space

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC00936D, Perspective Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Nicolas Brun, Peter Hesemann, Davide Esposito
      The derivatization and covalent modification of biomass derived platform chemicals expand the biomass derived chemical spaces allowing for the preparation of new bioactive molecules and materials.
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      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Phosphine-catalyzed enantioselective [3 + 2] cycloadditions of
           [gamma]-substituted allenoates with [small beta]-perfluoroalkyl enones

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC01432E, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Wei Zhou, Huamin Wang, Mengna Tao, Chao-Ze Zhu, Tao-Yan Lin, Junliang Zhang
      Herein we present a phoshine-catalyzed highly regio-, diastereo- and enantioselective [3 + 2] cycloaddition of [gamma]-substituted allenoates with [small beta]-perfluoroalkyl enones, delivering a wide range of densely functionalized perfluoroalkylated cyclopentenes with three contiguous chiral stereocenters.
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  • The structure of a resonance state

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC00452D, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. A. Garcia-Vela
      The existence of a structure in a resonance state regarding the fragment state distributions produced upon resonance decay is investigated.
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  • A well-defined NHC-Ir(III) catalyst for the silylation of aromatic C-H
           bonds: substrate survey and mechanistic insights

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C6SC04899D, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Laura Rubio-Perez, Manuel Iglesias, Julen Munarriz, Victor Polo, Vincenzo Passarelli, Jesus J. Perez-Torrente, Luis A. Oro
      A well-defined NHC-Ir( III ) catalyst provides access to a wide range of aryl- and heteroarylsilanes by intermolecular dehydrogenative C-H bond silylation.
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  • Understanding co-polymerization in amyloid formation by direct observation
           of mixed oligomers

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00620A, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Lydia M Young, Ling H Tu, Dan Raleigh, Alison E Ashcroft, S E Radford
      Although amyloid assembly in vitro is commonly investigated using single protein sequences, fibril formation in vivo can be more heterogeneous, involving co-assembly of proteins of different length, sequence and/or post-translational...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Elucidating the 3D structures of Al(III)-A[small beta] complexes: a
           template free strategy based on the pre-organization hypothesis

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01296A, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Jon Inaki Mujika, Jaime Rodriguez-Guerra, Xabier Lopez, Jesus M Ugalde, Luis Rodriguez-Santiago, Mariona Sodupe, Jean-Didier Marechal
      Senile plaques are extracellular deposits found in patients with Alzheimer's' Disease (AD) and are mainly constituted by insoluble fibrils of [small beta]-amyloids (A[small beta]) peptides. The mechanistic details about how AD develops...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Variation of the Fermi level and the Electrostatic Force of a Metallic
           Nanoparticle upon Colliding with an Electrode

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00848A, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Pekka Peljo, Jose Antonio A Manzanares, Hubert Girault
      When a metallic nanoparticle (NP) comes in close contact with an electrode, its Fermi level equilibrates with that of the electrode if their separation is less than the cut-off distance...
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  • Optical control of a receptor-linked guanylyl cyclase using a
           photoswitchable peptidic hormone

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C6SC05044A, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Tom Podewin, Johannes Broichhagen, Christina Frost, Dieter Groneberg, Julia Ast, Helena Meyer-Berg, Nicholas H. F. Fine, Andreas Friebe, Martin Zacharias, David J. Hodson, Dirk Trauner, Anja Hoffmann-Roder
      The photoswitchable peptidomimetic hormone TOP271 allows the precise optical control of cGMP generation via the receptor-linked enzyme NPR-A in explanted aortic rings and islets of Langerhans.
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  • Functionalized AIE nanoparticles with efficient deep-red emission,
           mitochondrial specificity, cancer cell selectivity and multiphoton
           susceptibility

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC00908A, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Alexander Nicol, Wei Qin, Ryan T. K. Kwok, Jeffrey Mark Burkhartsmeyer, Zhenfeng Zhu, Huifang Su, Wenwen Luo, Jacky W. Y. Lam, Jun Qian, Kam Sing Wong, Ben Zhong Tang
      Mitochondria targeting biotinylated AIE nanoparticles are used as multiphoton imaging probes to identify cancer cells.
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  • Integrative approach for the analysis of the proteome-wide response to
           bismuth drugs in Helicobacter pylori

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC00766C, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Yuchuan Wang, Ligang Hu, Feng Xu, Quan Quan, Yau-Tsz Lai, Wei Xia, Ya Yang, Yuen-Yan Chang, Xinming Yang, Zhifang Chai, Junwen Wang, Ivan K. Chu, Hongyan Li, Hongzhe Sun
      An integrative metalloproteomic approach to unveil the role of antimicrobial metals in general using bismuth as an example.
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  • Riboflavin as a bioorthogonal photocatalyst for the activation of a PtIV
           prodrug

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC01109A, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Silvia Alonso-de Castro, Emmanuel Ruggiero, Ane Ruiz-de-Angulo, Elixabete Rezabal, Juan C. Mareque-Rivas, Xabier Lopez, Fernando Lopez-Gallego, Luca Salassa
      Riboflavin acts as bioorthogonal photocatalyst to activate a Pt IV anticancer prodrug in the biological environment.
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  • Quantum Chemical Calculation of Electron Ionization Mass Spectra for
           General Organic and Inorganic Molecules

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00601B, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Vilhjalmur Asgeirsson, Christoph Alexander Bauer, Stefan Grimme
      We introduce a fully stand-alone version of the Quantum Chemistry Electron Ionization Mass Spectra (QCEIMS) program [S. Grimme, Angew. Chem. Int. Ed. , 2013, 52 , 6306] allowing efficient simulations for molecules...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Pyroglutamate-modified A[small beta](3-42) Affects Aggregation Kinetics of
           A[small beta](1-42) by Accelerating Primary and Secondary Pathways

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C6SC04797A, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Christina Dammers, Melanie Schwarten, Alexander Buell, Dieter Willbold
      The aggregation into amyloid fibrils of amyloid-[small beta] (A[small beta]) peptides is a hallmark of Alzheimer's disease. A variety of A[small beta] peptides have been discovered in vivo, with pyroglutamate-modified A[small beta] (pEA[small beta]) forming...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Design of template-stabilized active and earth-abundant oxygen evolution
           catalysts in acid

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01239J, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Michael X. Huynh, Tuncay Ozel, Chong Liu, Eric C. Lau, Daniel G. Nocera
      Oxygen evolution reaction (OER) catalysts that are earth-abundant and are active and stable in acid are unknown. Active catalysts derived from Co and Ni oxides dissolve at low pH, whereas...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Regulation and Imaging of Gene Expression via a RNA Interference
           Antagonistic Biomimetic Probe

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00909G, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Kai Zhang, Xue-Jiao Yang, Wei Zhao, Ming-Chen Xu, Jing-Juan Xu, Hong-Yuan Chen
      Regulation of gene expression is highly important in the area of cell biology. In this work a novel convenient and versatile strategy is reported which permits both gene regulation and...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Enantioselective Total Synthesis of (-)-Colchicine, (+)-Demecolcinone and
           Metacolchicine: Determination of the Absolute Configurations of the Latter
           Two Alkaloids

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01341H, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Bo Chen, Xin Liu, Ya-Jian Hu, Dongmei Zhang, Lijuan Deng, Jieyu Lu, Long Min, Wen-Cai Ye, Chuang-Chuang Li
      Here, we describe a concise, enantioselective, and scalable synthesis of (-)-colchicine (9.2% overall yield, >99% ee). Moreover, we have also achieved the first syntheses of (+)-demecolcinone and metacolchicine, and determined...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Transfer of photosynthetic NADP+/NADPH recycling activity to a porous
           metal oxide for highly specific, electrochemically-driven organic
           synthesis

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC00850C, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Bhavin Siritanaratkul, Clare F. Megarity, Thomas G. Roberts, Thomas O. M. Samuels, Martin Winkler, Jamie H. Warner, Thomas Happe, Fraser A. Armstrong
      A bio-hybrid material has been discovered, which offers a new direction for fast, specific enzyme-catalyzed organic synthesis.
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  • Controlled inhibition of methyltransferases using photoswitchable
           peptidomimetics: towards an epigenetic regulation of leukemia

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC00137A, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Lea Albert, Jing Xu, Ruiwei Wan, Vasundara Srinivasan, Yali Dou, Olalla Vazquez
      Shine light on epigenetics: we describe how photoswitchable peptidomimetics modulate the activity of the MLLl enzyme affecting epigenetic states.
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  • Dual-targeted peptide-conjugated multifunctional fluorescent probe with
           AIEgen for efficient nucleus-specific imaging and long-term tracing of
           cancer cells

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC00402H, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Yong Cheng, Chunli Sun, Xiaowen Ou, Bifeng Liu, Xiaoding Lou, Fan Xia
      Precisely targeted transportation of a long-term tracing regent to a nucleus with low toxicity is one of the most challenging concerns in revealing cancer cell behaviors.
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  • Importance of double-resonance effects in two-photon absorption properties
           of Au25(SR)18-

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC00968B, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Zhongwei Hu, Lasse Jensen
      We show that double-resonance effects for Au 25 (SR) 18 - are less pronounced and do not lead to significantly enhanced two-photon absorption cross-sections.
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  • Amino-functionalized conjugated polymer electron transport layers enhance
           the UV-photostability of planar heterojunction perovskite solar cells

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC00077D, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Dan Li, Chen Sun, Hao Li, Hui Shi, Xuxia Shai, Qiang Sun, Junbo Han, Yan Shen, Hin-Lap Yip, Fei Huang, Mingkui Wang
      Long-term photostability and high performance were achieved by perovskite solar cells with an amino-functionalized conjugated polymer as a new electron transport layer.
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  • Colloidal thallium halide nanocrystals with reasonable luminescence,
           carrier mobility and diffusion length

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC01219E, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Wasim J. Mir, Avinash Warankar, Ashutosh Acharya, Shyamashis Das, Pankaj Mandal, Angshuman Nag
      Colloidal TlI and TlBr nanocrystals are prepared, which show violet-blue luminescence, high carrier mobility and long diffusion lengths thus suggesting the suppression of deep-trap states.
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  • Synthesis of bioactive and stabilized cyclic peptides by macrocyclization
           using C(sp3)-H activation

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C6SC05530C, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Jian Tang, Yadong He, Hongfei Chen, Wangjian Sheng, Huan Wang
      Synthesis of cyclic peptides with novel C[small beta]-Ar crosslinks has been achieved by C(sp 3 )-H activation, and their biological properties have been evaluated for the first time.
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  • Hybrid photocathode consisting of a CuGaO2 p-type semiconductor and a
           Ru(II)-Re(I) supramolecular photocatalyst: non-biased visible-light-driven
           CO2 reduction with water oxidation

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC00940B, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Hiromu Kumagai, Go Sahara, Kazuhiko Maeda, Masanobu Higashi, Ryu Abe, Osamu Ishitani
      A new Ru( II )-Re( I )/CuGaO 2 hybrid photocathode was developed and combined with a CoO x /TaON photoanode to drive non-biased visible-light-driven CO 2 reduction with water oxidation.
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  • Carbon dioxide binary crystals via the thermal decomposition of RDX at
           high pressure.

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01379E, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Lauren Evelyn Connor, Carole Morrison, Iain D H Oswald, Colin R Pulham, Mark R Warren
      A carbon dioxide and nitrous oxide solid solution has been captured in a diamond anvil cell following the thermal decomposition of 1,3,5-Trinitroperhydro-1,3,5-triazine (RDX) at high temperatures and pressures. This is...
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  • Fluoride-Catalyzed Carbonylation Polymerization: A facile step-growth
           technique to polycarbonates

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C6SC05582F, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Vilhelm Johan Olsson, Daniel Hult, Sandra Garcia Gallego, Michael Malkoch
      Fluoride-Catalyzed Carbonylation Polymerization (FCCP) is herein presented as a novel catalytic polymerization methodology that complements ROP and unlocks a greater synthetic window to advanced polycarbonates. The overall two-step strategy is...
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  • Graphene oxide - carbon nanotube hybrid assemblies: Cooperatively
           strengthened OH[middle dot][middle dot][middle dot]O=C hydrogen bonds and
           removal of chemisorbed water

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00223H, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. J. David Nunez, Ana M Benito, Stephan Rouziere, Pascale Launois, Raul Arenal, Pulickel M. Ajayan, Wolfgang K. Maser
      Owing to their great interest for energy storage and sensing applications, multi-layer papers consisting of graphene oxide - carbon nanotube (GO-CNT) hybrid sheets were prepared by in-situ exfoliation of graphite...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Dialing in single-site reactivity of a supported calixarene-protected
           tetrairidium cluster catalyst

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00686A, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Andrew Palermo, Andrew Solovyov, Daniel Ertler, Alexander Okrut, Bruce C Gates, Alexander Katz
      A sterically closed Ir4 carbonyl cluster, 1, comprising a tetrahedral metal frame and three tert-butyl-calix[4]arene(OPr)3(OCH2PPh2) (Ph = phenyl; Pr = propyl) ligands at the basal plane, was characterized with variable-temperature...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Single Operation Palladium Catalysed C(sp3)-H Functionalisation of
           Tertiary Aldehydes: Investigations into Transient Imine Directing Groups

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01218G, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Sahra St John-Campbell, Andrew J P White, James A Bull
      Simple amine and diamine derivatives can promote the palladium catalysed direct -C-H arylation of aliphatic aldehydes via transient imine formation. Trifluoroacetate was shown to be crucial in promoting the reaction....
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Catechol adsorption on graphene nanoplatelets: isotherm, flat to vertical
           phase transition and desorption kinetics

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01331K, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Lifu Chen, Xiuting Li, Eden Elizabeth Louise Tanner, Richard G Compton
      The adsorption of catechol (1,2-dihydroxybenzene) on graphene nanoplatelets (GNPs) is investigated electrochemically and spectroscopically. The reversible adsorption of catechol on GNPs is Langmuirian with an adsorption constant of (0.2 +/-...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Identification of key structural features of the elusive Cu-A[small beta]
           complex generating ROS in Alzheimer's Disease

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00809K, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Clemence Cheignon, Megan Jones, Elena Atrian-Blasco, Isabelle Kieffer, Peter Faller, Fabrice Collin, Christelle Hureau
      Oxidative stress is linked to the etiology of Alzheimer's disease (AD), the most common cause of dementia in the elderly. Redox active metal ions such as copper catalyze the production...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Carbon Dioxide Hydrogenation Catalysed by Well-defined Mn(I) PNP Pincer
           Hydride Complexes

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00209B, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Federica Bertini, Mathias Glatz, Nikolaus Gorgas, Berthold Stoeger, Maurizio Peruzzini, Luis Filipe F. Veiros, Karl Kirchner, Luca Gonsalvi
      The catalytic reduction of carbon dioxide is of great interest for its potential as hydrogen storage method and to use carbon dioxide as C-1 feedstock. In an effort to replace...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • A complex stereochemical relay approach to the antimalarial alkaloid
           ocimicide A1. Evidence for a structural revision.

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01127J, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Herman Nikolayevskiy, Kyaw Moe Tun, Paul R Rablen, Choukri Ben Mamoun, Seth Herzon
      Ocimicide A 1 ( 1 ) and the semisynthetic derivative ocimicide A 2 ( 2 ) are highly potent antimalarial agents efficacious against chloroquine-sensitive and -resistant Plasmodium falciparum strains with IC 50 values in the nanomolar and...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Anomalous Effect of Non-Alternant Hydrocarbons on Carbocation and
           Carbanion Electronic Configurations

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01047H, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Logan John Fischer, Andrew Dutton, Arthur H. Winter
      Carbocations are widely viewed to be closed-shell singlet electrophiles. Here, computations show that azulenyl-substituted carbocations have triplet ground states. This triplet ground state for azulenyl carbocations stands in striking contrast...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Photoelectrocatalytic H2 Evolution in Water with Molecular Catalysts
           Immobilised on p-Si via a Stabilising Mesoporous TiO2 Interlayer

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01277B, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Jane J. Leung, Julien Warnan, Dong Heon Nam, Jenny Z. Zhang, Janina Willkomm, Erwin Reisner
      The development of photoelectrodes capable of light-driven hydrogen evolution from water is an important approach for the storage of solar energy in the form of a chemical energy carrier. Nevertheless,...
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  • Metal exchange in lithiocuprates: implications for our understanding of
           structure and reactivity

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01423F, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Andrew Wheatley, Andrew Peel, Ryan Ackroyd
      New reagents have been sought for directed ortho cupration in which the use of cyanide reagents is eliminated. CuOCN reacts with excess TMPLi (TMP = 2,2,6,6-tetramethylpiperidide) in the presence of...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Characterization of the Flavoenzyme XiaK as an N-Hydroxylase and
           Implications in Indolosesquiterpene Diversification

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01182B, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Qingbo Zhang, Huixian Li, Yu Sun, Lu Yu, Yiguang Zhu, Hanning Zhu, Liping Zhang, Shuming Li, Yuemao Shen, Changlin Tian, Ang Li, Hung-wen Liu, Changsheng Zhang
      Flavoenzymes are ubiquitous in biological systems and catalyze a diverse range of chemical transformations. The flavoenzyme XiaK from the biosynthetic pathway for the indolosesquiterpene xiamycin A is demonstrated to mediate...
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  • Designing brighter near-infrared fluorescent proteins: insights from
           structural and biochemical studies

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC00855D, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Mikhail Baloban, Daria M. Shcherbakova, Sergei Pletnev, Vladimir Z. Pletnev, J. Clark Lagarias, Vladislav V. Verkhusha
      A new chromophore in near-infrared fluorescent proteins is described, and amino acid residues affecting their spectra and brightness are identified.
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  • An N-nitrosation reactivity-based two-photon fluorescent probe for the
           specific in situ detection of nitric oxide

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC00416H, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Zhiqiang Mao, Hong Jiang, Zhen Li, Cheng Zhong, Wei Zhang, Zhihong Liu
      An N -nitrosation reactivity-based two-photon fluorescent probe for the specific detection of NO was rationally designed, prepared, and applied in the in situ detection of nitric oxide in ischemia reperfusion injury mouse model under two-photon microscopy for the first time.
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  • Kinetic resolution of racemic 2-substituted 1,2-dihydroquinolines via
           asymmetric Cu-catalyzed borylation

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC01556A, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Duanyang Kong, Suna Han, Rui Wang, Meina Li, Guofu Zi, Guohua Hou
      A highly efficient kinetic resolution of racemic 2-substituted 1,2-dihydroquinolines via asymmetric Cu-catalyzed borylation has been realized for the first time to afford chiral 3-boryl-1,2,3,4-tetrahydroquinolines and recover 2-substituted 1,2-dihydroquinolines with excellent enantioselectivities and selectivity factors of up to 569.
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  • Gold(III)-arene complexes by insertion of olefins into gold-aryl bonds

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC00145B, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Feriel Rekhroukh, Charlie Blons, Laura Estevez, Sonia Mallet-Ladeira, Karinne Miqueu, Abderrahmane Amgoune, Didier Bourissou
      The synthesis and characterization of the first gold( III )-arene complexes are described.
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  • Versatile telluracycle synthesis via the sequential electrophilic
           telluration of C(sp2)-Zn and C(sp2)-H bonds

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC01162H, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Bin Wu, Melvina, Xiangyang Wu, Edwin Kok Lee Yeow, Naohiko Yoshikai
      Twofold electrophilic C-Te bond formation has opened access to a wide variety of Te-containing heteroaromatic systems.
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  • Exploring the full catalytic cycle of rhodium(I)-BINAP-catalysed
           isomerisation of allylic amines: a graph theory approach for path
           optimisation

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC00401J, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Takayoshi Yoshimura, Satoshi Maeda, Tetsuya Taketsugu, Masaya Sawamura, Keiji Morokuma, Seiji Mori
      The reaction mechanism of the cationic rhodium( I )-BINAP complex catalysed isomerisation of allylic amines was explored using the artificial force induced reaction method with the global reaction route mapping strategy.
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  • Enantioselective [gamma]-Borylation of Unsaturated Amides and
           Stereoretentive Suzuki-Miyaura Cross-Coupling

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01093A, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Gia L. Hoang, James Takacs
      The rhodium-catalyzed, directed catalytic asymmetric hydroboration of [gamma],[small delta]-unsaturated amides affords a direct route to chiral acyclic secondary [gamma]-borylated carbonyl derivatives in high enantiopmeric purity. In contrast to a similar [small beta]-borylated...
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  • Structural Origins of Broadband Emission from Layered Pb-Br Hybrid
           Perovskites

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC01590A, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Matthew D. Smith, Adam Jaffe, Emma R. Dohner, Aaron Lindenberg, Hemamala I Karunadasa
      Through structural and optical studies of a series of two-dimensional hybrid perovskites, we show that broadband emission upon near-ultraviolet excitation is common to (001) lead-bromide perovskites. Importantly, we find that...
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  • Molecular heterogeneous catalysts derived from bipyridine-based
           organosilica nanotubes for C-H bond activation

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00713B, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Shengbo Zhang, Hua Wang, Mei Li, Jin yu Han, Xiao Liu, Jinlong Gong
      Heterogeneous metal complex catalysts for direct C-H activation with high activity and durability have been ever desired for transforming raw materials into feedstock chemicals. This paper describes the design and...
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  • Micrometre and Nanometre Scale Patterning of Binary Polymer Brushes,
           Supported Lipid Bilayers and Proteins

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00289K, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Alexander Johnson, Jeppe Madsen, Paul Chapman, Abdullah Alswieleh, Omed Al Jaf, Peng Bao, Claire Hurley, Michael L. Cartron, Stephen Evans, Jamie Hobbs, Neil Hunter, Steven P Armes, Graham J. Leggett
      Binary polymer brush patterns were fabricated via photodeprotection of an aminosilane with a photo-cleavable nitrophenyl protecting group. UV exposure of the silane film through a mask yields micrometre-scale amine-terminated regions...
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  • Reactivity of hydride bridges in a high-spin [Fe3([small mu ]-H)3]3+
           cluster: reversible H2/CO exchange and Fe-H/B-F bond metathesis

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C6SC05583D, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Kevin J. Anderton, Brian J. Knight, Arnold L. Rheingold, Khalil A. Abboud, Ricardo Garcia-Serres, Leslie J. Murray
      The triiron trihydride complex Fe 3 H 3 L ( 1 ) [where L 3- is a tris([small beta]-diketiminate)cyclophanate] reacts with CO and with BF 3 [middle dot]OEt 2 to afford (Fe I CO) 2 Fe II ([small mu ] 3 -H) L ( 2 ) and Fe 3 F 3 L ( 3 ), respectively.
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  • Reactivity studies on [Cp[prime or minute]Fe([small mu ]-I)]2: nitrido-,
           sulfido- and diselenide iron complexes derived from pseudohalide
           activation

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC00570A, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Matthias Reiners, Miyuki Maekawa, Constantin G. Daniliuc, Matthias Freytag, Peter G. Jones, Peter S. White, Johannes Hohenberger, Jorg Sutter, Karsten Meyer, Laurent Maron, Marc D. Walter
      Facile pseudohalide activation occurs in the reaction of SCN - , SeCN - and N 3 - with the iron half-sandwich [Cp[prime or minute]Fe([small mu ]-I)] 2 .
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      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • A 2-aza-Cope reactivity-based platform for ratiometric fluorescence
           imaging of formaldehyde in living cells

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC00748E, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Thomas F. Brewer, Guillermo Burgos-Barragan, Niek Wit, Ketan J. Patel, Christopher J. Chang
      We present the first ratiometric fluorescent probes for formaldehyde, a major reactive species in biology, operating in the visible region.
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  • Integration of G-quadruplex and DNA-templated Ag NCs for Nonarithmetic
           Information Processing

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00361G, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Ru-Ru Gao, Tianming Yao, Xiao-Yan Lv, Yan-Yan Zhu, Yi-Wei Zhang, Shuo Shi
      To implement sophisticated molecular logic circuits from scratch, you may not believe how common the building blocks can be and how diverse, powerful such circuits can be scaled up. Using...
      The content of this RSS Feed (c) The Royal Society of Chemistry
       
  • Total chemical synthesis of SUMO-2-Lys63-linked diubiquitin hybrid chains
           assisted by removable solubilizing tags

    • Abstract: Chem. Sci. , 2017, Advance Article

      DOI : 10.1039/C7SC00488E, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Somasekhar Bondalapati, Emad Eid, Sachitanand M. Mali, Cynthia Wolberger, Ashraf Brik
      We report the first total chemical synthesis of four different SUMO-2-Lys63-linked di-ubiquitin hybrid chains, in which the di-ubiquitin is linked to different lysines in SUMO.
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  • Both enrichment and fluorogenic labelling of 5-formyluracil in DNA

    • Abstract: Chem. Sci. , 2017, Accepted Manuscript

      DOI : 10.1039/C7SC00637C, Edge Article Open Access Open Access Creative Commons Licence   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Xiang Zhou, Chaoxin Liu, Yafen Wang, Xiong Zhang, Fan Wu, Wei Yang, Guangrong Zhou, Qian Yao, Jiaqi Wang, Yuqi Chen, Shaoru Wang
      Recently, the detection of the natural thymine modification 5-formyluracil has attracted widespread attention. Herein, we put forward a new insight into designing reagents for both selective biotin enrichment and fluorogenic...
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