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Catalysis Science and Technology
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ISSN (Print) 2044-4753 - ISSN (Online) 2044-4761
Published by Royal Society of Chemistry, The

[42 journals] [SJR: 1.353] [H-I: 14]

Sustainable catalytic conversions of renewable substrates
- Authors: Pieter C. A. Bruijnincx; Yuriy Roman-Leshkov
  Pages: 2180 - 2181
  Abstract: Catal. Sci. Technol. , 2014, 4 ,2180-2181
  DOI : 10.1039/C4CY90025A, Editorial Pieter C. A. Bruijnincx, Yuriy Roman-Leshkov Recent advances in catalysis show how a multi-disciplinary approach helps break the barriers encountered during the conversion of lignocellulosic biomass into sustainable, value-added fuels and chemicals. The content of this RSS Feed (c) The Royal Society of Chemistry
  Issue No: Vol. 4 (2014)
An examination of the intrinsic activity and stability of various solid
acids during the catalytic decarboxylation of [gamma]-valerolactone
- Authors: Aimee B. Kellicutt; Roozbeh Salary, Omar Ali Abdelrahman, Jesse Q. Bond
  Pages: 2267 - 2279
  Abstract: Catal. Sci. Technol. , 2014, 4 ,2267-2279
  DOI : 10.1039/C4CY00307A, Paper Aimee B. Kellicutt, Roozbeh Salary, Omar Ali Abdelrahman, Jesse Q. Bond Rates of [gamma]-valerolactone (GVL) decarboxylation were measured in the gas phase under anhydrous conditions from 523-723 K over a series of solid acids including amorphous silica alumina, MFI zeolites, supported phosphotungstic acid, and [gamma]-Al 2 O 3 . The content of this RSS Feed (c) The Royal Society of Chemistry
  Issue No: Vol. 4 (2014)
Regioselective catalytic acetoxylation of limonene
- Authors: Marc von Czapiewski; Michael A. R. Meier
  Pages: 2318 - 2325
  Abstract: Catal. Sci. Technol. , 2014, 4 ,2318-2325
  DOI : 10.1039/C4CY00231H, Paper Marc von Czapiewski, Michael A. R. Meier Two efficient strategies for a direct catalytic and regioselective acetoxylation of terpenes are described. The content of this RSS Feed (c) The Royal Society of Chemistry
  Issue No: Vol. 4 (2014)
Catalytic hydrotreatment of pyrolytic lignins to give alkylphenolics and
aromatics using a supported Ru catalyst
- Authors: Arjan Kloekhorst; Jelle Wildschut, Hero Jan Heeres
  Pages: 2367 - 2377
  Abstract: Catal. Sci. Technol. , 2014, 4 ,2367-2377
  DOI : 10.1039/C4CY00242C, Paper Arjan Kloekhorst, Jelle Wildschut, Hero Jan Heeres The catalytic hydrotreatment of two pyrolytic lignins (pine and forestry residue), obtained from the corresponding fast pyrolysis oils, and organosolv Alcell lignin as a benchmark was explored in a batch set-up using Ru/C as the catalyst (400 [degree]C, 4 h, 100 bar initial H 2 pressure). The content of this RSS Feed (c) The Royal Society of Chemistry
  Issue No: Vol. 4 (2014)
Catalytic hydrogenation of C[double bond, length as m-dash]C and C[double
bond, length as m-dash]O in unsaturated fatty acid methyl esters
- Authors: Chaoquan Hu; Derek Creaser, Samira Siahrostami, Henrik Gronbeck, Houman Ojagh, Magnus Skoglundh
  Pages: 2427 - 2444
  Abstract: Catal. Sci. Technol. , 2014, 4 ,2427-2444
  DOI : 10.1039/C4CY00267A, Minireview Chaoquan Hu, Derek Creaser, Samira Siahrostami, Henrik Gronbeck, Houman Ojagh, Magnus Skoglundh Review summarizing recent developments in hydrogenation of C[double bond, length as m-dash]C and C[double bond, length as m-dash]O in FAMEs focusing on catalysts, reaction mechanisms, and reactor conditions. The content of this RSS Feed (c) The Royal Society of Chemistry
  Issue No: Vol. 4 (2014)
A DFT study on direct benzene hydroxylation catalyzed by framework Fe and
Al sites in zeolites
- Authors: Gang Yang; Lijun Zhou
  Pages: 2490 - 2493
  Abstract: Catal. Sci. Technol. , 2014, 4 ,2490-2493
  DOI : 10.1039/C4CY00369A, Communication Gang Yang, Lijun Zhou Framework Fe rather than Al Lewis acidic sites in zeolites are demonstrated to show superior catalytic activity for benzene hydroxylation. The content of this RSS Feed (c) The Royal Society of Chemistry
  Issue No: Vol. 4 (2014)
The enhanced catalytic performance of Pd/SiC for the hydrogenation of
furan derivatives at ambient temperature under visible light irradiation
- Authors: Zhi-Feng Jiao; Xiao-Ning Guo, Zhao-Yang Zhai, Guo-Qiang Jin, Xiao-Min Wang, Xiang-Yun Guo
  Pages: 2494 - 2498
  Abstract: Catal. Sci. Technol. , 2014, 4 ,2494-2498
  DOI : 10.1039/C4CY00275J, Communication Zhi-Feng Jiao, Xiao-Ning Guo, Zhao-Yang Zhai, Guo-Qiang Jin, Xiao-Min Wang, Xiang-Yun Guo Pd/SiC exhibits a tremendous promotion of catalytic activity for the hydrogenation of furan derivatives at ambient temperature under visible light irradiation. The content of this RSS Feed (c) The Royal Society of Chemistry
  Issue No: Vol. 4 (2014)
Polymer-supported catalysts for clean preparation of n-butanol
- Authors: Haibin Jiang; Shuliang Lu, Xiaohong Zhang, Hui Peng, Wei Dai, Jinliang Qiao
  Pages: 2499 - 2503
  Abstract: Catal. Sci. Technol. , 2014, 4 ,2499-2503
  DOI : 10.1039/C4CY00436A, Communication Haibin Jiang, Shuliang Lu, Xiaohong Zhang, Hui Peng, Wei Dai, Jinliang Qiao Embedding of alloy particles into a polymer surface ensures both firm supporting and easy activation. The content of this RSS Feed (c) The Royal Society of Chemistry
  Issue No: Vol. 4 (2014)
High catalytic performance of mesoporous zirconia supported nickel
catalysts for selective CO methanation
- Authors: Aihua Chen; Toshihiro Miyao, Kazutoshi Higashiyama, Mashiro Watanabe
  Pages: 2508 - 2511
  Abstract: Catal. Sci. Technol. , 2014, 4 ,2508-2511
  DOI : 10.1039/C4CY00461B, Communication Aihua Chen, Toshihiro Miyao, Kazutoshi Higashiyama, Mashiro Watanabe Ni/mesoporous ZrO 2 , without precious metals, exhibits high performance for selective CO methanation at a wide range of working temperatures and superior long-term stability. The content of this RSS Feed (c) The Royal Society of Chemistry
  Issue No: Vol. 4 (2014)
Thermally stable gold/alumina aerogel catalysts prepared by a simultaneous
synthesis process for solvent-free aerobic benzyl alcohol oxidation
- Authors: Z. Li; Y. Ji, C. Cadigan, R. M. Richards
  Pages: 2520 - 2525
  Abstract: Catal. Sci. Technol. , 2014, 4 ,2520-2525
  DOI : 10.1039/C3CY01064C, Paper Z. Li, Y. Ji, C. Cadigan, R. M. Richards Gold nanoparticles physically trapped in the framework of alumina aerogel exhibit excellent thermal stability and catalytic activity at high temperature. The content of this RSS Feed (c) The Royal Society of Chemistry
  Issue No: Vol. 4 (2014)
N,O-ligated Pd(II) complexes for catalytic alcohol oxidation
- Authors: Laura M. Dornan; Grainne M. A. Clendenning, Mateusz B. Pitak, Simon J. Coles, Mark J. Muldoon
  Pages: 2526 - 2534
  Abstract: Catal. Sci. Technol. , 2014, 4 ,2526-2534
  DOI : 10.1039/C4CY00296B, Paper Laura M. Dornan, Grainne M. A. Clendenning, Mateusz B. Pitak, Simon J. Coles, Mark J. Muldoon The (HSA)Pd(OAc) 2 complex (where HSA = 8-hydroxyquinoline-2-sulfonic acid) is a highly active catalyst for the oxidation of a range of secondary alcohols in 4-6 hours at a low loading of 0.5 mol%. The crystal structure has been obtained and the influence of reaction conditions on catalyst degradation was also examined. The content of this RSS Feed (c) The Royal Society of Chemistry
  Issue No: Vol. 4 (2014)
Adsorption and desulfurization reaction mechanism of thiophene and its
hydrogenated derivatives over NbC(001) and NbN(001): an ab initio DFT
study
- Authors: Eugenio Furtado de Souza; Teodorico C. Ramalho, Carlos Alberto Chagas, Ricardo Bicca de Alencastro
  Pages: 2550 - 2563
  Abstract: Catal. Sci. Technol. , 2014, 4 ,2550-2563
  DOI : 10.1039/C4CY00306C, Paper Eugenio Furtado de Souza, Teodorico C. Ramalho, Carlos Alberto Chagas, Ricardo Bicca de Alencastro Herein, we present periodic DFT-based calculations on the thiophene and its H-derivatives adsorption and reaction pathways over niobium carbide and nitride cubic face-centered (001) surfaces. The content of this RSS Feed (c) The Royal Society of Chemistry
  Issue No: Vol. 4 (2014)
Highly active and green mesostructured titanosilicate catalysts
synthesized for selective synthesis of benzoquinones
- Authors: M. Selvaraj
  Pages: 2674 - 2684
  Abstract: Catal. Sci. Technol. , 2014, 4 ,2674-2684
  DOI : 10.1039/C4CY00313F, Paper M. Selvaraj The green mesoporous TiSBA-15(6) catalyst was used in the liquid-phase oxidation of 2,3,6-trimethylphenol (TMP-OH) and produced 2,3,5-trimethyl-1,4-benzoquinone (TMB[double bond, length as m-dash]O) with 100% selectivity. The content of this RSS Feed (c) The Royal Society of Chemistry
  Issue No: Vol. 4 (2014)
Synthesis factors affecting the catalytic performance and stability of
Ru/C catalysts for supercritical water gasification
- Authors: G. Peng; M. Steib, F. Gramm, C. Ludwig, F. Vogel
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00586D, Paper G. Peng, M. Steib, F. Gramm, C. Ludwig, F. Vogel Improvement of the catalytic performance of Ru/C catalysts by selecting acetone as a solvent during the catalyst preparation. To cite this article before page numbers are assigned, use the
  DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Catalyst deactivation and structure sensitivity
- Authors: Dmitry Yu. Murzin
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00349G, Paper Dmitry Yu. Murzin A mathematical framework for the analysis of cluster size effects on the main catalytic reaction and deactivation for coking and poisoning. To cite this article before page numbers are assigned, use the
  DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Conversion of butyronitrile to butyilamines on noble metals: Effect of
solvent on catalyst activity and selectivity
- Authors: Dario Segobia; Andres Trasarti, Carlos Apesteguia
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00741G, Paper Dario Segobia, Andres Trasarti, Carlos Apesteguia The liquid-phase hydrogenation of butyronitrile to butylamines was studied on Pt(0.27%)/SiO2, Pd(0.33%)/SiO2 and Ru(1.80%)/SiO2 using n-butanol, toluene and cyclohexane as solvents. In n-butanol, Pt and Pd catalysts formed preponderantly dibutylamine... The content of this RSS Feed (c) The Royal Society of Chemistry
Fe@CNT-monoliths for the conversion of carbon dioxide to hydrocarbons:
- Authors: Daniel R. Minett; Justin P. O'Byrne, Sofia I. Pascu, Pawel K. Plucinski, Rhodri E. Owen, Matthew D. Jones, Davide Mattia
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00616J, Paper Daniel R. Minett, Justin P. O'Byrne, Sofia I. Pascu, Pawel K. Plucinski, Rhodri E. Owen, Matthew D. Jones, Davide Mattia High carbon dioxide conversion to hydrocarbons using iron nanoparticle (Fe@CNT) catalysts supported on cordierite monoliths. To cite this article before page numbers are assigned, use the
  DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Developments and perspectives of oxide-based catalysts for the oxygen
evolution reaction
- Authors: Emiliana Fabbri; Anja Habereder, Kay Waltar, Rudiger Kotz, Thomas Schmidt
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00669K, Perspective Emiliana Fabbri, Anja Habereder, Kay Waltar, Rudiger Kotz, Thomas Schmidt The growing need to store large amount of energy produced from renewable sources has recently directed substantial R&D efforts toward water electrolysis technologies. Although the description of the electrochemical reaction... The content of this RSS Feed (c) The Royal Society of Chemistry
Structure-activity relation of spinel-type Co-Fe oxides for
low-temperature CO oxidation
- Authors: P. Mountapmbeme Kouotou; H. Vieker, Z. Y. Tian, P. H. Tchoua Ngamou, A. El Kasmi, A. Beyer, A. Golzhauser, K. Kohse-Hoinghaus
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00463A, Paper P. Mountapmbeme Kouotou, H. Vieker, Z. Y. Tian, P. H. Tchoua Ngamou, A. El Kasmi, A. Beyer, A. Golzhauser, K. Kohse-Hoinghaus Cobalt ferrite thin films were synthesized and systematically characterized in view of the catalytic oxidation of carbon monoxide. The adsorbed oxygen at the surface of the films plays a decisive role in the oxidation processes. To cite this article before page numbers are assigned, use the
  DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Highly stable boron-modified hierarchical nanocrystalline ZSM-5 zeolite
for the methanol to propylene reaction
- Authors: Zhijie Hu; Hongbin Zhang, Lei Wang, Hongxia Zhang, Yahong Zhang, Hualong Xu, Wei Shen, Yi Tang
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00376D, Communication Zhijie Hu, Hongbin Zhang, Lei Wang, Hongxia Zhang, Yahong Zhang, Hualong Xu, Wei Shen, Yi Tang A highly stable MTP catalyst, boron-modified hierarchical nanocrystalline ZSM-5 zeolite, has been synthesized by a facile salt-aided seed-induced route. It exhibits a long lifetime (about 725 h) even at a high WHSV (4.0 h -1 ). To cite this article before page numbers are assigned, use the
  DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Hydroisomerization of Long-Chain Paraffins over Nano-Sized Bimetallic
Pt-Pd/H-Beta Catalysts
- Authors: Frank Bauer; Karsten Ficht, Marko Bertmer, Wolf-Dietrich Einicke, Thomas Kuchling, Roger Glaeser
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00561A, Paper Frank Bauer, Karsten Ficht, Marko Bertmer, Wolf-Dietrich Einicke, Thomas Kuchling, Roger Glaeser The hydroisomerization of long-chain n paraffins was studied in the temperature range 205-230 [degree]C at pH2=50 bar using a pilot scale trickle-bed continuous-flow reactor over bimetallic catalysts consisting of mixtures... The content of this RSS Feed (c) The Royal Society of Chemistry
The role of reversibility in the enantioselective conjugate addition of
[small alpha],[small alpha]-disubstituted aldehydes to nitro-olefins
catalyzed by primary amine thioureas
- Authors: Yining Ji; Donna G. Blackmond
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00648H, Paper Yining Ji, Donna G. Blackmond Identification of intermediates in the asymmetric conjugate addition of aldehdyes to nitro-olefins catalyzed by primary amine thioureas add mechanistic insight. To cite this article before page numbers are assigned, use the
  DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
P450-catalyzed asymmetric cyclopropanation of electron-deficient olefins
under aerobic conditions
- Authors: Hans Renata; Z. Jane Wang, Rebekah Z. Kitto, Frances H. Arnold
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00633J, Communication Hans Renata, Z. Jane Wang, Rebekah Z. Kitto, Frances H. Arnold A histidine-ligated variant of P450-BM3 catalyzes cyclopropanation of a variety of electron-deficient olefins under ambient conditions with great selectivity. To cite this article before page numbers are assigned, use the
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Porous WO3-Carbon nanofiber: High-Performance and Recyclable Visible-Light
Photocatalysis
- Authors: Ahmed Taha; Fengting Li
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00777H, Communication Ahmed Taha, Fengting Li Template-free porous carbon nanofibers embedded with WO3 (WO3-CNF) was prepared by combining electrospinning and carbonization. Ammonium tungstate hydrate was used as a semiconductor precursor and porogen. The generated pores in... The content of this RSS Feed (c) The Royal Society of Chemistry
Hydrophobic microporous and mesoporous oxides as Bronsted and Lewis acid
catalysts for biomass conversion in liquid water
- Authors: Rajamani Gounder
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00712C, Minireview Rajamani Gounder Microporous and mesoporous silicates with internal or external hydrophobic surfaces show differences in catalytic reactivity and stability in liquid water. To cite this article before page numbers are assigned, use the
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Dendritic phosphotungstate hybrids efficiently catalyze selective
oxidation of alcohols with H2O2
- Authors: Donghong Yin; Tan Rong, Yaju Chen, Weiguo Zheng, Zhang Yaoyao, Zhao Guangwu
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00675E, Paper Donghong Yin, Tan Rong, Yaju Chen, Weiguo Zheng, Zhang Yaoyao, Zhao Guangwu Keggin-type phosphotungstic acid (HPW) was incorporated into the polyamidoamine (PAMAM) matrix by partly protonating amino groups of PAMAM dendrimer. Characterization results suggested that the PAMAM dendrimer accommodated trivalent PW anions... The content of this RSS Feed (c) The Royal Society of Chemistry
Cyclopentadienyl Molybdenum Alkylester Complexes as Catalyst Precursors
for Olefin Epoxidation
- Authors: Nidhi Grover; Alexander Pothig, Fritz E. Kuhn
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00738G, Paper Nidhi Grover, Alexander Pothig, Fritz E. Kuhn New molybdenum complexes of the type [CpMo(CO)3X], containing ligands X = -CHR2CO(OR1), where R1 = ethyl (1), menthyl (4), bornyl (5) and R2 = H; R1 = ethyl and R2... The content of this RSS Feed (c) The Royal Society of Chemistry
Facile Synthesis of CuCr2O4 Spinel Nanoparticles: A Recyclable
Heterogeneous Catalyst for One Pot Hydroxylation of Benzene
- Authors: Shankha S Acharyya; Shilpi Ghosh, Shubhadeep Adak, Takehiko Sasaki, Rajaram Bal
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00615A, Paper Shankha S Acharyya, Shilpi Ghosh, Shubhadeep Adak, Takehiko Sasaki, Rajaram Bal : A facile hydrothermal synthesis method is developed to prepare CuCr2O4 spinel nanoparticles catalyst with size between 25-50 nm. Detailed characterization of the material was carried out by XRD, ICP-AES,... The content of this RSS Feed (c) The Royal Society of Chemistry
Fischer-Tropsch synthesis on a ruthenium catalyst in two-phase systems: an
excellent opportunity for the control of reaction rate and selectivity
- Authors: Vitaly V. Ordomsky; Andrei Y. Khodakov, Benoit Legras, Christine Lancelot
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00803K, Communication Vitaly V. Ordomsky, Andrei Y. Khodakov, Benoit Legras, Christine Lancelot Localization of Ru/C in the organic phase in biphasic systems leads to high selectivity to long-chain hydrocarbons similar to that in the organic phase at a higher overall Fischer-Tropsch reaction rate. To cite this article before page numbers are assigned, use the
  DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Stability and resistance of nickel catalysts for hydrodeoxygenation:
carbon deposition and effects of sulfur, potassium, and chlorine in the
feed
- Authors: Peter M. Mortensen; Diego Gardini, Hudson W. P. de Carvalho, Christian D. Damsgaard, Jan-Dierk Grunwaldt, Peter A. Jensen, Jakob B. Wagner, Anker D. Jensen
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00522H, Paper Peter M. Mortensen, Diego Gardini, Hudson W. P. de Carvalho, Christian D. Damsgaard, Jan-Dierk Grunwaldt, Peter A. Jensen, Jakob B. Wagner, Anker D. Jensen Study of resistance of Ni/ZrO 2 to carbon deposition and bio-oil impurities in hydrodeoxygenation of guaiacol in 1-octanol. To cite this article before page numbers are assigned, use the
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Hyperpolarisation through reversible interactions with parahydrogen
- Authors: Lyrelle S Lloyd; Aziz Asghar, Michael J Burns, Adrian Charlton, Steven Coombes, Michael J Cowley, Gordon J Dear, Simon B Duckett, Georgi R. Genov, Gary GR Green, Louise A. R. Highton, Amy J Ruddlesdon, Alexander J. J. Hooper, Majid Khan, Iman G. Khazal, Richard J Lewis, Ryan Edward Mewis, Andrew D Roberts
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00464G, Paper Lyrelle S Lloyd, Aziz Asghar, Michael J Burns, Adrian Charlton, Steven Coombes, Michael J Cowley, Gordon J Dear, Simon B Duckett, Georgi R. Genov, Gary GR Green, Louise A. R. Highton, Amy J Ruddlesdon, Alexander J. J. Hooper, Majid Khan, Iman G. Khazal, Richard J Lewis, Ryan Edward Mewis, Andrew D Roberts We describe here how the complexes Ir(COD)(NHC)Cl [NHC = IMes, SIMes, IPr, SIPr, ICy, IMe and ImMe2NPri2] provide significant insight into the catalytic process that underpins the hyperpolarization method signal... The content of this RSS Feed (c) The Royal Society of Chemistry
Expansion of pulse responses from temporal analysis of products (TAP) for
more accurate data analysis
- Authors: Kevin Morgan; Alexandre Goguet, Christopher Hardacre, Evgenii V. Kondratenko, Colin McManus, Sergiy O. Shekhtman
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00543K, Paper Kevin Morgan, Alexandre Goguet, Christopher Hardacre, Evgenii V. Kondratenko, Colin McManus, Sergiy O. Shekhtman The current work discloses the development of a function which mathematically expands the tail of truncated TAP pulse response, so that accurate TAP data analysis can be conducted. To cite this article before page numbers are assigned, use the
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Hydrocarbon oxidation catalyzed by a cheap nonheme imine-based iron(II)
complex
- Authors: Giorgio Olivo; Giorgio Arancio, Luigi Mandolini, Osvaldo Lanzalunga, Stefano Di Stefano
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00626G, Communication Giorgio Olivo, Giorgio Arancio, Luigi Mandolini, Osvaldo Lanzalunga, Stefano Di Stefano An imine-based iron complex, prepared in situ from iron( II ), pyridine-2-carbaldehyde and 2-aminomethylpyridine, effectively catalyzes hydrocarbon oxidation at low loadings. To cite this article before page numbers are assigned, use the
  DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Catalytic properties of copper manganese oxides prepared by
coprecipitation using tetraammonium hydroxide
- Authors: Hisahiro Einaga; Akihiro Kiya, Satoru Yoshioka, Yasutake Teraoka
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00660G, Paper Hisahiro Einaga, Akihiro Kiya, Satoru Yoshioka, Yasutake Teraoka Copper-manganese (Cu-Mn) mixed oxide catalysts were prepared by coprecipitation technique from metal nitrates in aqueous solution using tetramethylammonium hydroxide (TMAH) as a pH regulator, followed by calcination at 673 K.... The content of this RSS Feed (c) The Royal Society of Chemistry
Deracemisation of benzylisoquinoline alkaloids employing monoamine oxidase
variants
- Authors: Joerg H. Schrittwieser; Bas Groenendaal, Simon C. Willies, Diego Ghislieri, Ian Rowles, Verena Resch, Johann H. Sattler, Eva-Maria Fischereder, Barbara Grischek, Wolf-Dieter Lienhart, Nicholas J. Turner, Wolfgang Kroutil
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00642A, Paper Joerg H. Schrittwieser, Bas Groenendaal, Simon C. Willies, Diego Ghislieri, Ian Rowles, Verena Resch, Johann H. Sattler, Eva-Maria Fischereder, Barbara Grischek, Wolf-Dieter Lienhart, Nicholas J. Turner, Wolfgang Kroutil Deracemisation of benzylisoquinoline alkaloids was performed employing a recently developed variant of monoamine oxidase from Aspergillus niger (MAO-N variant D11). To cite this article before page numbers are assigned, use the
  DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Selective glycerol transformations to high value-added products catalysed
by aluminosilicate-supported iron oxide nanoparticles
- Authors: Camino Gonzalez-Arellano; Sudipta De, Rafael Luque
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00714J, Paper Camino Gonzalez-Arellano, Sudipta De, Rafael Luque Conversion of glycerol to cyclics acetals (with paraformaldehyde, benzaldehyde, furfural and acetone) and to mono-, di- triacetylglicerides (with levulinic acid) was investigated using a supported iron oxide nanoparticle system of... The content of this RSS Feed (c) The Royal Society of Chemistry
Surface stabilities and NO oxidation kinetics on hexagonal-phase LaCoO3
facets: a first-principles study
- Authors: Xiao Liu; Zhengzheng Chen, Yanwei Wen, Rong Chen, Bin Shan
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00538D, Paper Xiao Liu, Zhengzheng Chen, Yanwei Wen, Rong Chen, Bin Shan The surface stability of hexagonal-phase LaCoO 3 has been studied and the LaO 3 -terminated surface is catalytically most active towards NO oxidation. To cite this article before page numbers are assigned, use the
  DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Silica and zirconia supported tungsten, molybdenum and gallium oxide
catalysts for the synthesis of furfural
- Authors: Prasenjit Bhaumik; Tanushree Kane, Paresh Laxmikant Dhepe
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00530A, Communication Prasenjit Bhaumik, Tanushree Kane, Paresh Laxmikant Dhepe In a one-pot conversion of hemicellulose using acidic WO 3 /SiO 2 catalyst, 61% furfural yield was obtained for at least 8 cycles. The role of the metal and support on activity was elucidated. To cite this article before page numbers are assigned, use the
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Morphology-dependent surface chemistry and catalysis of CeO2 nanocrystals
- Authors: Weixin Huang; Yuxian Gao
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00679H, Perspective Weixin Huang, Yuxian Gao Morphology engineering of CeO 2 deepens the fundamental understanding and improves the catalytic performance. To cite this article before page numbers are assigned, use the
  DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Deoxydehydration of glycerol to allyl alcohol catalyzed by rhenium
derivatives
- Authors: Valentino Canale; Lucia Tonucci, Mario Bressan, Nicola d'Alessandro
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00631C, Paper Valentino Canale, Lucia Tonucci, Mario Bressan, Nicola d'Alessandro Both ReO 3 and methyltrioxorhenium combined with alcohol reductants are used for the efficient deoxydehydration of glycerol to allyl alcohol. To cite this article before page numbers are assigned, use the
  DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Kinetics of the catalytic cracking of naphtha over ZSM-5 zeolite: effect
of reduced crystal size on the reaction of naphthenes
- Authors: Hiroki Konno; Ryota Ohnaka, Jun-ichi Nishimura, Teruoki Tago, Yuta Nakasaka, Takao Masuda
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00733F, Paper Hiroki Konno, Ryota Ohnaka, Jun-ichi Nishimura, Teruoki Tago, Yuta Nakasaka, Takao Masuda The catalytic cracking of model naphthenes (cyclohexane and methylcyclohexane) over ZSM-5 zeolites of different crystal sizes (macro and nanoZSM-5) was examined at reaction temperatures ranging from 748 to 923 K... The content of this RSS Feed (c) The Royal Society of Chemistry
Hydrodeoxygenation of fatty acids and triglycerides by Pt-loaded Nb2O5
catalysts
- Authors: Kenichi Kon; Wataru Onodera, Satoru Takakusagi, Ken-ichi Shimizu
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00757C, Paper Kenichi Kon, Wataru Onodera, Satoru Takakusagi, Ken-ichi Shimizu Pt/Nb 2 O 5 shows more than 60 times higher TON than non-SMSI Pt catalysts and previous catalysts for the hydrodeoxygenation of stearic acid to n -octadecane at 180 [degree]C in 8 bar H 2 . Nb 2 O 5 can act as an activation site of carbonyl groups. To cite this article before page numbers are assigned, use the
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Nanoalloy catalysts: structural and catalytic properties
- Authors: Shiyao Shan; Jin Luo, Lefu Yang, Chuan-Jian Zhong
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00469H, Perspective Shiyao Shan, Jin Luo, Lefu Yang, Chuan-Jian Zhong Noble metals alloyed with certain transition metals in the form of a nanoalloy exhibit enhanced catalytic or electrocatalytic activities for various reactions, especially when oxygen activation is involved in the reactions. To cite this article before page numbers are assigned, use the
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Structure sensitivity in the ruthenium nanoparticle catalyzed
aqueous-phase Fischer-Tropsch reaction
- Authors: Xian-Yang Quek; Robert Pestman, Rutger A. van Santen, Emiel J. M. Hensen
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00709C, Paper Xian-Yang Quek, Robert Pestman, Rutger A. van Santen, Emiel J. M. Hensen Low-temperature Fischer-Tropsch reaction data are reported for Ru nanoparticles suspended in the water phase. To cite this article before page numbers are assigned, use the
  DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Coke formation in the oxidative dehydrogenation of ethylbenzene to styrene
by TEOM
- Authors: C. Nederlof; P. Vijfhuizen, V. Zarubina, I. Melian-Cabrera, F. Kapteijn, M. Makkee
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00498A, Paper C. Nederlof, P. Vijfhuizen, V. Zarubina, I. Melian-Cabrera, F. Kapteijn, M. Makkee A packed bed microbalance reactor setup (TEOM-GC) is used to investigate the formation of coke as a function of time-on-stream on [gamma]-Al 2 O 3 and 3P/SiO 2 catalyst samples under different conditions for the ODH reaction of ethylbenzene to styrene. To cite this article before page numbers are assigned, use the
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Mesoporous strong base supported cobalt oxide as the catalyst for the
oxidation of ethylbenzene
- Authors: Song Shi; chen chen, min wang, Jiping Ma, jin gao, Jie Xu
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00796D, Communication Song Shi, chen chen, min wang, Jiping Ma, jin gao, Jie Xu Mesoporous solid strong base was applied to support cobalt oxide to obtain a strong base-type catalyst, which showed good performance in the heterogeneous oxidation of ethylbenzene under solvent free conditions... The content of this RSS Feed (c) The Royal Society of Chemistry
Recent Progress in Copper-Catalyzed Electrophilic Amination
- Authors: Chanjuan Xi; Xiaoyu Yan, Xianghua Yang
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00773E, Perspective Chanjuan Xi, Xiaoyu Yan, Xianghua Yang Copper-catalyzed coupling reactions have been recognized as one of the most useful strategies for the formation of C-N bond. This perspective gives an overview of recent developments in copper-catalyzed electrophilic... The content of this RSS Feed (c) The Royal Society of Chemistry
Kinetics of the conversion of methyl benzoate to benzamide by the alumina
catalysed reaction with liquid ammonia at 120 [degree]C
- Authors: Haifeng Sun; Michael I Page, John H Atherton, Alan Hall
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C3CY00799E, Paper Haifeng Sun, Michael I Page, John H Atherton, Alan Hall Methyl benzoate is quantitatively converted to benzamide using liquid ammonia at 120 [degree]C over an alumina catalyst. To cite this article before page numbers are assigned, use the
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Hydrodeoxygenation of propanoic acid over silica-supported palladium:
effect of metal particle size
- Authors: Yuliana K. Lugo-Jose; John R. Monnier, Andreas Heyden, Christopher T. Williams
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00605D, Paper Yuliana K. Lugo-Jose, John R. Monnier, Andreas Heyden, Christopher T. Williams A detailed discussion on the effect of Pd/SiO 2 nanoparticle size on the gas-phase hydrodeoxygenation (HDO) of propanoic acid (PAc) is presented. To cite this article before page numbers are assigned, use the
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Tailoring the Physicochemical Properties of Zeolite Catalysts
- Authors: Jeffrey D Rimer; Manjesh Kumar, Rui Li, Alexandra I Lupulescu, Matthew D Oleksiak
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00858H, Minireview Jeffrey D Rimer, Manjesh Kumar, Rui Li, Alexandra I Lupulescu, Matthew D Oleksiak The physicochemical properties of zeolite catalysts, such as crystal topology, composition, size, and morphology, can have a marked effect on their performance for a broad range of reactions - notably... The content of this RSS Feed (c) The Royal Society of Chemistry
Hydrothermal synthesis of octahedra-based layered niobium oxide and its
catalytic activity as a solid acid
- Authors: Toru Murayama; Junli Chen, Jun Hirata, Keeko Matsumoto, Wataru Ueda
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00713A, Paper Toru Murayama, Junli Chen, Jun Hirata, Keeko Matsumoto, Wataru Ueda Layered-structure type niobium oxides were synthesized by the hydrothermal method by using ammonium niobium oxalate as a precursor. The synthesized niobium oxide showed characteristic peaks at 2[small theta] = 22.7[degree] and... The content of this RSS Feed (c) The Royal Society of Chemistry
Applications of isotopic tracers in Fischer-Tropsch synthesis
- Authors: Gary Jacobs; Burtron H. Davis
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00600C, Paper Gary Jacobs, Burtron H. Davis This focused review article highlights five applications of isotopic tracers to Co, Fe, and Ru-based Fischer-Tropsch synthesis catalysts over a time period spanning six decades. To cite this article before page numbers are assigned, use the
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Bimetallic Au-Ni/CSs catalysts for acetylene hydrochlorination
- Authors: Yanfeng Pu; Jinli Zhang, Xia Wang, Haiyang Zhang, Li Yu, Yanzhao Dong, Wei Li
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00769G, Paper Yanfeng Pu, Jinli Zhang, Xia Wang, Haiyang Zhang, Li Yu, Yanzhao Dong, Wei Li Gold and gold-based bimetallic catalysts for acetylene hydrochlorination were prepared with HAuCl4[round bullet, filled]4H2O and NiCl2[round bullet, filled]6H2O as precursors and analyzed by the characterization methods of BET, TG, XRD, TEM, TPR, and XPS.... The content of this RSS Feed (c) The Royal Society of Chemistry
Transformations of polyols to organic acids and hydrogen in aqueous
alkaline media
- Authors: T. van Haasterecht; T. W. van Deelen, K. P. de Jong, J. H. Bitter
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00249K, Paper T. van Haasterecht, T. W. van Deelen, K. P. de Jong, J. H. Bitter Carbon nanofiber supported Ni and Cu nano-particles are active for the anaerobic aqueous phase transformation of polyols into organic acids (glycolic acid and lactic acid) and hydrogen at low temperatures (140-180 [degree]C). To cite this article before page numbers are assigned, use the
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Asymmetric hydrolytic kinetic resolution with recyclable polymeric
Co(III)-salen complexes: A practical strategy in the preparation of
(S)-Metoprolol, (S)-Toliprolol and (S)-Alprenolol: Computational rationale
for enantioselectivity
- Authors: Tamal Roy; Sunirmal Barik, Manish Kumar, Rukhsana Ilyas Kureshy, Bishwajit Ganguly, Noor-ul H. Khan, Sayed H. R. Abdi, Hari Chand Bajaj
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00594E, Paper Tamal Roy, Sunirmal Barik, Manish Kumar, Rukhsana Ilyas Kureshy, Bishwajit Ganguly, Noor-ul H. Khan, Sayed H. R. Abdi, Hari Chand Bajaj A series of chiral polymeric Co(III) salen complexes based on a number of achiral and chiral linkers were synthesized and their catalytic performances were assessed in asymmetric hydrolytic kinetic resolution... The content of this RSS Feed (c) The Royal Society of Chemistry
Vapor phase hydrodeoxygenation of furfural to 2-methylfuran on molybdenum
carbide catalysts
- Authors: Wen-Sheng Lee; Zhenshu Wang, Weiqing Zheng, Dionisios G. Vlachos, Aditya Bhan
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00286E, Paper Wen-Sheng Lee, Zhenshu Wang, Weiqing Zheng, Dionisios G. Vlachos, Aditya Bhan Vapor phase hydrodeoxygenation (HDO) of furfural over Mo 2 C catalysts at low temperatures (423 K) and ambient pressure showed high/low selectivity to C[double bond, length as m-dash]O bond/C-C bond cleavage, resulting in selectivity to 2-methylfuran and furan of ~50-60% and <1%, respectively. To cite this article before page numbers are assigned, use the
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Mechanism of Fe additive improving the activity stability of
microzeolite-based Mo/HZSM-5 catalyst in the non-oxidative methane
dehydroaromatization at 1073 K under periodic CH4-H2 switch mode
- Authors: Yuebing Xu; Yang Song, Yoshizo Suzuki, Zhanguo Zhang
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00613E, Paper Yuebing Xu, Yang Song, Yoshizo Suzuki, Zhanguo Zhang The catalytic stabilities of Fe-modified and -unmodified 5%Mo/HZSM-5 catalysts in the non-oxidative methane dehydroaromatization were compared at 1073 K and three reaction/H2-regeneration cycle periods: 5 min CH4-5 min H2, 5... The content of this RSS Feed (c) The Royal Society of Chemistry
Searching for cheaper catalysts with high activity and stability in Ce-M-O
systems (M=Fe, Co, Ni)
- Authors: Ying Zuo; liping li, Xinsong Huang, Guangshe Li
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00526K, Paper Ying Zuo, liping li, Xinsong Huang, Guangshe Li For almost all catalysts, doping with cheaper transition metal ions could reduce the price necessary for applications, while there usually occurs a catalytic activity degradation. This work reports on the... The content of this RSS Feed (c) The Royal Society of Chemistry
Gas-phase epoxidation of propylene over iron-containing catalysts: the
effect of iron incorporation in the support matrix
- Authors: Blazej Horvath; Martin Sustek, Ivo Vavra, Matej Micusik, Miroslav Gal, Milan Hronec
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00273C, Paper Blazej Horvath, Martin Sustek, Ivo Vavra, Matej Micusik, Miroslav Gal, Milan Hronec The gas-phase epoxidation of propylene using iron as a catalytically active metal has been studied. To cite this article before page numbers are assigned, use the
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Ionic liquid modified montmorillonite-supported Ru nanoparticles: highly
efficient heterogeneous catalysts for the hydrodeoxygenation of phenolic
compounds to cycloalkanes
- Authors: Huanjun Xu; Kongchen Wang, Hongye Zhang, Leiduan Hao, Jilei Xu, Zhimin Liu
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00250D, Paper Huanjun Xu, Kongchen Wang, Hongye Zhang, Leiduan Hao, Jilei Xu, Zhimin Liu A bifunctional catalyst, Ru/MMT@IL-SO 3 H, was developed, which displayed high efficiency and excellent stability for hydrodeoxygenation of phenolic compounds to cycloalkanes. To cite this article before page numbers are assigned, use the
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A review of advanced catalyst development for Fischer-Tropsch synthesis of
hydrocarbons from biomass derived syn-gas
- Authors: Hessam Jahangiri; James Bennett, Parvin Mahjoubi, Karen Wilson, Sai Gu
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00327F, Perspective Hessam Jahangiri, James Bennett, Parvin Mahjoubi, Karen Wilson, Sai Gu This review summarizes recent developments in FT-catalyst design with regards to optimizing catalyst activity and selectivity towards synthetic fuels. To cite this article before page numbers are assigned, use the
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Synergy between Lewis acid sites and hydroxyl groups for the isomerization
of glucose to fructose over Sn-containing zeolites: a theoretical
perspective
- Authors: Guanna Li; Evgeny A. Pidko, Emiel J. M. Hensen
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00186A, Paper Guanna Li, Evgeny A. Pidko, Emiel J. M. Hensen The cooperative action of Lewis acidic lattice Sn and hydrogen bond donor sites in zeolites is key for efficient glucose isomerization catalysis. To cite this article before page numbers are assigned, use the
  DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Selective formation of [small alpha],[small omega]-ester amides from the
aminocarbonylation of castor oil derived methyl 10-undecenoate and other
unsaturated substrates
- Authors: Cristina Jimenez-Rodriguez; Angel A. Nunez-Magro, Thomas Seidensticker, Graham R. Eastham, Marc R. L. Furst, David J. Cole-Hamilton
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00158C, Paper Cristina Jimenez-Rodriguez, Angel A. Nunez-Magro, Thomas Seidensticker, Graham R. Eastham, Marc R. L. Furst, David J. Cole-Hamilton Methyl 10-undecenoate from castor oil is aminocarbonylated to [small alpha],[small omega]-amidoesters for possible use in polyamide or polyester amide monomer production. To cite this article before page numbers are assigned, use the
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The effects of Pd chemical state on the activity of Pd/Al2O3 catalysts in
CO oxidation
- Authors: Yanhui Zhang; Yafeng Cai, Yun Guo, Haifeng Wang, Li Wang, Yang Lou, Yanglong Guo, Guanzhong LU, Yanqin Wang
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00552J, Paper Yanhui Zhang, Yafeng Cai, Yun Guo, Haifeng Wang, Li Wang, Yang Lou, Yanglong Guo, Guanzhong LU, Yanqin Wang CO adsorption and O2 activation played important role in CO oxidation on supported Pd catalyst, which was depended on the chemical state of Pd. A series supported Pd on Al2O3... The content of this RSS Feed (c) The Royal Society of Chemistry
Heterobimetallic dual-catalyst systems for the hydrolytic kinetic
resolution of terminal epoxides
- Authors: Xiang Hong; Mohamed Mellah, Emmanuelle Schulz
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00235K, Paper Xiang Hong, Mohamed Mellah, Emmanuelle Schulz A combination of cobalt- and manganese-salen complexes as heterobimetallic dual-catalysts has been efficiently used for the HKR of (terminal) epoxides. To cite this article before page numbers are assigned, use the
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Liberation of N-heterocyclic carbenes (NHCs) from thermally labile
progenitors: protected NHCs as versatile tools in organo- and
polymerization catalysis
- Authors: Stefan Naumann; Michael R. Buchmeiser
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00344F, Minireview Stefan Naumann, Michael R. Buchmeiser The thermally triggered release of catalytically active, free NHCs from various heat-sensitive progenitors is discussed. To cite this article before page numbers are assigned, use the
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Study of niobium and tantalum doped titania supported Pt electrocatalysts
for methanol oxidation reaction and oxygen reduction reaction
- Authors: Xiaoteng Liu; Xu Wu, Keith Scott
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00393D, Paper Xiaoteng Liu, Xu Wu, Keith Scott Niobium and Tantalum doped TiO2 nanoparticles were prepared as catalyst substrates by an improved sol-gel method. 20 wt.% Pt supported on these substrates catalysts were synthesised and studied for methanol... The content of this RSS Feed (c) The Royal Society of Chemistry
A reusable CuII based metal-organic framework as a catalyst for the
oxidation of olefins
- Authors: Patricio Cancino; Veronica Paredes-Garcia, Pedro Aguirre, Evgenia Spodine
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00152D, Paper Patricio Cancino, Veronica Paredes-Garcia, Pedro Aguirre, Evgenia Spodine The metal-organic framework [Cu 2 (bipy) 2 (btec)] [infinity] was used as a heterogeneous catalyst in the liquid phase oxidation of styrene and cyclohexene with tert -butylhydroperoxide (TBHP) as the oxidant either in water-dichloroethane or n -decane medium. To cite this article before page numbers are assigned, use the
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Direct Evidence for a Coordination-Insertion Mechanism in Ethylene
Oligomerization Catalysed by Neutral 2,6-Bisiminopyridine Iron Monoalkyl
Complexes
- Authors: M. Angeles Cartes; Antonio Rodriguez-Delgado, Pilar Palma, Luis J. Sanchez, Juan Campora
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00612G, Communication M. Angeles Cartes, Antonio Rodriguez-Delgado, Pilar Palma, Luis J. Sanchez, Juan Campora 1H NMR studies on ethylene oligomerization catalysed by the neutral monoalkyl complex [Fe(Me)(iPrBIP)] allows direct observation of alkyliron intermediates as well as reversible ethylene coordination to the metal center, providing... The content of this RSS Feed (c) The Royal Society of Chemistry
Coupling ZnxCd1-xS nanoparticles with graphene-like MoS2: superior
interfacial contact, low overpotential and enhanced photocatalytic
activity under visible-light irradiation
- Authors: Yongtao Lu; Dandan Wang, Ping Yang, Yukou Du, Cheng Lu
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00331D, Paper Yongtao Lu, Dandan Wang, Ping Yang, Yukou Du, Cheng Lu A novel nanocomposite composed of graphene-like MoS 2 sheets and Zn x Cd 1- x S nanoparticles was used for photocatalytic hydrogen generation under visible light irradiation. To cite this article before page numbers are assigned, use the
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The deactivation mechanism of two typical shape-selective HZSM-5 catalysts
for alkylation of toluene with methanol
- Authors: Junhui Li; Hao Xiang, Min Liu, Qunlong Wang, Zhirong Zhu, Zhonghua Hu
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00095A, Paper Junhui Li, Hao Xiang, Min Liu, Qunlong Wang, Zhirong Zhu, Zhonghua Hu Different coking behaviours of two shape-selective HZSM-5 catalysts (prepared by SiO 2 and La 2 O 3 modifications, respectively) in toluene methylation were revealed. To cite this article before page numbers are assigned, use the
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Verification of the dual cycle mechanism for methanol-to-olefin conversion
in HSAPO-34: a methylbenzene-based cycle from DFT calculations
- Authors: Chuan-Ming Wang; Yang-Dong Wang, Zai-Ku Xie
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00262H, Paper Chuan-Ming Wang, Yang-Dong Wang, Zai-Ku Xie The dual cycle mechanism for the MTO conversion in which ethene is produced through a methylbenzene-based hydrocarbon pool cycle was verified by periodic DFT calculations with vdW correction in HSAPO-34. To cite this article before page numbers are assigned, use the
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Nickel-based solid catalysts for ethylene oligomerization - a review
- Authors: Annie Finiels; Francois Fajula, Vasile Hulea
  Abstract: Catal. Sci. Technol. , 2014, Advance Article
  DOI : 10.1039/C4CY00305E, Perspective Annie Finiels, Francois Fajula, Vasile Hulea The properties of Ni-based inorganic porous materials and their catalytic performance in ethylene oligomerization are reviewed. To cite this article before page numbers are assigned, use the
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Mechanistic Analysis of Water Oxidation Catalyzed by Mononuclear Copper in
Aqueous Bicarbonate Solutions
- Authors: Christopher J. Cramer; Stuart Winikoff
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00500G, Communication Christopher J. Cramer, Stuart Winikoff We characterize a mechanism for a monomeric copper catalyst reported to oxidize water in bicarbonate solution when subject to sufficiently high external potentials at near neutral pH values. Density functional... The content of this RSS Feed (c) The Royal Society of Chemistry
Catalytic CO2 conversion to organic carbonates with alcohols in
combination with dehydration system
- Authors: Masayoshi Honda; Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00557K, Perspective Masayoshi Honda, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige Recent progress on direct organic carbonate synthesis from CO2 and alcohols has been reviewed on the basis of dehydration systems. Versatile dehydration systems have been developed, which drastically improves yields... The content of this RSS Feed (c) The Royal Society of Chemistry
Dramatic promotion of copper-alumina catalysts by sodium for acetone
trimerisation
- Authors: Emanuelle LIGNER; Frederic Meunier, arnaud travert, Sylvie Maury, Nicolas Cadran
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00440J, Communication Emanuelle LIGNER, Frederic Meunier, arnaud travert, Sylvie Maury, Nicolas Cadran Na-promoted Cu-Al materials are efficient multifunctional catalysts for the direct conversion of gas phase acetone to diisobutyl ketone (DIBK) with unprecedented yields (up to 31 %). The Na content is... The content of this RSS Feed (c) The Royal Society of Chemistry
A Survey of Pendant Donor-Functionalised (N,O) Phosphine Ligands for
Cr-Catalysed Ethylene Tri- and Tetramerisation.
- Authors: James A Suttil; Peter Wasserscheid, David S McGuinness, Michael Guy Gardiner, Stephen J Evans
  Abstract: Catal. Sci. Technol. , 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00457D, Paper James A Suttil, Peter Wasserscheid, David S McGuinness, Michael Guy Gardiner, Stephen J Evans In this study three classes of ligands are explored for ethylene tri-/tetramerisation in conjunction with chromium and both triethylaluminium (AlEt3) and methylaluminoxane (MAO) co-catalysts. Hydrazine based ligands containing an N-H... The content of this RSS Feed (c) The Royal Society of Chemistry
In situ acidic carbon dioxide/ethylene glycol system for aerobic oxidative
iodination of electron-rich aromatics catalyzed by Fe(NO3)3[round bullet,
filled]9H2O
- Abstract: Catal. Sci. Technol., 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00721B, PaperRan Ma, Cheng-Bin Huang, AN-Hua Liu, Xue-Dong Li, Liang-Nian HeAn environmentally benign reversible acidic CO2/ethylene glycol system was developed for the iron (III)-catalyzed aerobic oxidative iodination of electron-rich aromatics without using any conventional acid additive or organic solvent. Notably,...The content of this RSS Feed (c) The Royal Society of Chemistry
Synthesis and functionalization of SSZ-13 as an NH3-SCR catalyst
- Abstract: Catal. Sci. Technol., 2014, Advance Article
  DOI : 10.1039/C4CY00384E, PaperAlexander Shishkin, Hannes Kannisto, Per-Anders Carlsson, Hanna Harelind, Magnus SkoglundhHydrothermal synthesis of Na-SSZ-13 using a low concentration of the structure-directing agent N,N,N-trimethyl-1-adamantanimonium hydroxide and functionalization of the SSZ-13 framework through the introduction of Cu and Fe via ion exchange have been carried out.To cite this article before page numbers are assigned, use the
  DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry
Correlating lignin structure to aromatic products in the catalytic fast
pyrolysis of lignin model compounds containing [small beta]-O-4 linkages
- Abstract: Catal. Sci. Technol., 2014, Advance Article
  DOI : 10.1039/C4CY00569D, PaperGregory T. Neumann, Brian R. Pimentel, Dallas J. Rensel, Jason C. HicksLignin model compounds containing a [small beta]-O-4 linker were synthesized to investigate the role of lignin structure and zeolite type on the product distribution during catalytic fast pyrolysis.To cite this article before page numbers are assigned, use the
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Nanosheets of graphitic carbon nitride as metal-free environmental
photocatalysts
- Abstract: Catal. Sci. Technol., 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00832D, PaperFengbo Li, Zhijun Huang, Bingfeng Chen, Guoqing YuanNanosheets of graphitic carbon nitride were prepared through direct heat treatment of guanidinium chloride at 450-600 ℃ in air atmosphere. The resulting materials had a surface area of 109.9 m2/g...The content of this RSS Feed (c) The Royal Society of Chemistry
N-Fluorobenzenaminium tetrafluoroborate generated in situ by aniline and
Selectfluor as a reusable catalyst for the ring opening of epoxides with
amines under microwave irradiation
- Abstract: Catal. Sci. Technol., 2014, Advance Article
  DOI : 10.1039/C4CY00609G, PaperManMohan Singh Chauhan, Geeta Devi Yadav, Firasat Hussain, Surendra SinghCatalysis of ring opening of epoxides with amines by N-fluorobenzenaminium tetrafluoroborate generated in situ by reaction of aniline and Selectfluor under solvent free conditions with microwave irradiation.To cite this article before page numbers are assigned, use the
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Emerging strategies for breaking the 3D amorphous network of lignin
- Abstract: Catal. Sci. Technol., 2014, Advance Article
  DOI : 10.1039/C4CY00701H, PerspectiveSaikat Dutta, Kevin C.-W. Wu, Basudeb SahaThis perspective encompasses the emerging trends and developments for breaking lignin by depolymerization and upgrading to aromatic monomers via deoxygenation, enzymatic oxidation strategies and carbonization.To cite this article before page numbers are assigned, use the
  DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry
Effects of Preparation Variables on an Alumina-Supported FeCuK
Fischer-Tropsch Catalyst
- Abstract: Catal. Sci. Technol., 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00510D, PaperKamyar Keyvanloo, Jonathon B. Horton, William C. Hecker, Morris D. ArgyleThis paper investigates the effects of various, carefully-chosen preparation methods on the performance of Fischer-Tropsch (FT) alumina-supported iron/copper/potassium (FeCuK/Al2O3) catalysts. Two tested preparation methods (co-impregnation and non-aqueous slurry impregnation) yielded...The content of this RSS Feed (c) The Royal Society of Chemistry
Coupling reaction between CO2 and cyclohexene oxide: selective control
from cyclic carbonate to polycarbonate by ligand design of salen/salalen
titanium complexes
- Abstract: Catal. Sci. Technol., 2014, Advance Article
  DOI : 10.1039/C4CY00752B, PaperYong Wang, Yusheng Qin, Xianhong Wang, Fosong WangSelective control from cyclic carbonate to polycarbonate by ligand design of salen/salalen titanium complexes.To cite this article before page numbers are assigned, use the
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Transition Metals-rich Mesoporous Silica and their Enhanced Catalytic
Property
- Abstract: Catal. Sci. Technol., 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00688G, PaperBaowang LU, Katsuya KawamotoaA controllable and simple direct hydrothermal synthesis route was designed for synthesizing well-ordered mesoporous silica incorporating transition metals (M) (Ni, Cu, Zn, Co) with a high metal loading. M-incorporated mesoporous...The content of this RSS Feed (c) The Royal Society of Chemistry
An improved catalytic system for the reduction of levulinic acid to
[gamma]-valerolactone
- Abstract: Catal. Sci. Technol., 2014, Advance Article
  DOI : 10.1039/C4CY00719K, CommunicationJozsef M. Tukacs, Marton Novak, Gabor Dibo, Laszlo T. MikaAn improved bidentate phosphine-modified Ru catalytic system was developed for the selective reduction of levulinic acid to [gamma]-valerolactone.To cite this article before page numbers are assigned, use the
  DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry
Efficient and robust superparamagnetic copper ferrite
nanoparticles-catalyzed sequential methylation and C-H activation:
aldehyde-free propargylamine synthesis
- Abstract: Catal. Sci. Technol., 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00753K, PaperThanh Truong, Nam T. S. Phan, Anh Nguyen, Lam Phamwe have described a method for oxidative cross coupling reactions between N-alkyl anilines and terminal alkynes forming N-aryl-N-methylpropargylamines. Superparamagnetic CuFe2O4 nanoparticles were employed as efficient and robust catalyst. The optimal...The content of this RSS Feed (c) The Royal Society of Chemistry
Olefin Epoxidation by a (salen)Mn(III) Catalyst Covalently Grafted on
Glass Beads
- Abstract: Catal. Sci. Technol., 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00831F, PaperAntonino Gulino, Salvatrice Millesi, Giuseppe Trusso Sfrazzetto, Rosa M Toscano, Francesco p ballistreri, gaetano a tomaselli, Andrea PappalardoThe asymmetric epoxidation of unfunctionalized prochiral olefins, catalyzed by chiral (salen)Mn(III) complexes, is an important viable route to obtain chiral epoxides. Recently we proposed a monolayer of (salen)Mn(III) molecules on...The content of this RSS Feed (c) The Royal Society of Chemistry
New multicomponent catalysts for the selective aerobic oxidative
condensation of benzylamine to N-benzylidenbenzilimine
- Abstract: Catal. Sci. Technol., 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00795F, PaperCristina Madalina Opris, Octavian D Pavel, Alaina Moragues, Jamal El Haskouri, Daniel Beltran, Pedro Amoros del Torro, Maria Dolores Marcos, Laura Elena Stoflea, Vasile ParvulescuAerobic oxidative condensation of benzylamine to N-benzylidenbenzilimine was carried out on new gold-based catalysts using as supports bimodal UVM-7-like mesoporous silica, containing Ni and Ce (or Sn) as oxide nanodomains...The content of this RSS Feed (c) The Royal Society of Chemistry
Cl- making overall water splitting possible on TiO2-based photocatalysts
- Abstract: Catal. Sci. Technol., 2014, Advance Article
  DOI : 10.1039/C4CY00408F, CommunicationLei Huang, Rengui Li, Ruifeng Chong, Gang Liu, Jingfeng Han, Can LiThe introduction of an appropriate amount of Cl- could trigger the evolution of O2 and H2 simultaneously over a TiO2-based photocatalyst.To cite this article before page numbers are assigned, use the
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Selective hydrogenation of phenol and the related derivatives
- Abstract: Catal. Sci. Technol., 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00583J, MinireviewJiawei Zhong, Jinzhu Chen, Limin ChenSelective hydrogenation of phenol and the related derivatives to cyclohexanone and analogues remains a challenging task. In the present minireview, we highlight the research advancement in this field. The front...The content of this RSS Feed (c) The Royal Society of Chemistry
Glycerol acetylation on mesoporous KIL-2 supported sulphated zirconia
catalysts
- Abstract: Catal. Sci. Technol., 2014, Advance Article
  DOI : 10.1039/C4CY00548A, PaperMargarita Popova, Agnes Szegedi, Alenka Ristic, Natasa Novak TusarZirconia nanomaterials were prepared by impregnation of KIL-2 type silica with 4, 8 and 12 wt.% ZrO2, and were modified by sulphate groups in order to vary the type and strength of acidity.To cite this article before page numbers are assigned, use the
  DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry
An ab initio thermodynamics study of cobalt surface phases under ethanol
steam reforming conditions
- Abstract: Catal. Sci. Technol., 2014, Advance Article
  DOI : 10.1039/C4CY00582A, PaperWenjia Luo, Aravind AsthagiriA combination of DFT and ab initio atomistic thermodynamics study illustrated the surface structure evolution of Co0/Co2+ catalysts under ethanol steam reforming conditions.To cite this article before page numbers are assigned, use the
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Mechanistic examination of AuIII-mediated 1,5-enyne cycloisomerization by
AuBr2(N-imidate)(NHC)/AgX precatalysts - is the active catalyst AuIII or
AuI?
- Abstract: Catal. Sci. Technol., 2014, Advance Article
  DOI : 10.1039/C4CY00617H, PaperJonathan P. Reeds, Mark P. Healy, Ian J. S. FairlambThe role of AuI and AuIII species in 1,5-enyne cycloisomerization reactions has been examined in this paper.To cite this article before page numbers are assigned, use the
  DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry
Theoretical investigation of the hydrodeoxygenation of methyl propionate
over Pd (111) model surfaces
- Abstract: Catal. Sci. Technol., 2014, Advance Article
  DOI : 10.1039/C4CY00511B, PaperSina Behtash, Jianmin Lu, Andreas HeydenTheoretical study of the hydrodeoxygenation of methyl propionate over Pd (111) model surfaces.To cite this article before page numbers are assigned, use the
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Decomposition of methyl species on a Ni(211) surface: investigations of
the electric field influence
- Abstract: Catal. Sci. Technol., 2014, Advance Article
  DOI : 10.1039/C4CY00406J, PaperFanglin Che, Alyssa J. Hensley, Su Ha, Jean-Sabin McEwenDensity functional theory calculations are performed to examine how an external electric field can alter the reaction pathways on a stepped Ni(211) surface with regard to the decomposition of methyl species.To cite this article before page numbers are assigned, use the
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Efficient one-pot synthesis of propargylamines catalysed by gold
nanocrystals stabilized on montmorillonite
- Abstract: Catal. Sci. Technol., 2014, Advance Article
  DOI : 10.1039/C4CY00666F, PaperBibek Jyoti Borah, Subrat Jyoti Borah, Kokil Saikia, Dipak Kumar DuttaSize selective Au0-nanoparticles were generated in situ in the nanopores of montmorillonite and applied in the one-pot, three-component coupling of an aldehyde, an amine and an alkyne to synthesize propargylamines.To cite this article before page numbers are assigned, use the
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Novel Approach for a Cerium-Base High-Efficient Catalyst with Excellent
NH3-SCR Performance
- Abstract: Catal. Sci. Technol., 2014, Accepted Manuscript
  DOI : 10.1039/C4CY00926F, CommunicationHaili Huang, Wenpo Shan, Yang Shijian, Jinhua ZhangA high-efficient NH3-SCR catalyst, CeO2/WO3-TiO2, was prepared by a novel stepwise precipitation approach. This catalyst showed excellent catalytic performance, with superior low-temperature activity, high N2 selectivity and broad operation temperature...The content of this RSS Feed (c) The Royal Society of Chemistry
Enhanced catalytic performance of molybdenum-doped mesoporous SBA-15 for
metathesis of 1-butene and ethene to propene
- Abstract: Catal. Sci. Technol., 2014, Advance Article
  DOI : 10.1039/C4CY00652F, PaperChao Lin, Kai Tao, Hongbo Yu, Dayin Hua, Shenghu ZhouThe doped Mo-SBA-15 catalysts illustrated a superior catalytic performance over supported MoO3/SBA-15 and MoO3/SiO2 catalysts.To cite this article before page numbers are assigned, use the
  DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry